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Science China Chemistry 2024年第3期67卷 751-752页

作者： xiong liu Chaojiang Niu School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China

Lithium(Li) metal has been considered one of the most promising anodes due to its high theoretical capacity, lightweight and low electrochemical potential. The cell-level energy density of rechargeable lithium metal batteries(LMBs) is expected to surpass 500 Wh kg^(-1) after replacing the graphite anode in lithium-ion batteries [1].

关键词： lithium electrolyte layer

Ti_(3)C_(2)T_(x) MXene in-situ transformed Li_(2)TiO_(3) interface layer enabling 4.5 V-LiCoO_(2)/sulfide all-solid-state lithium batteries with superior rate capability and cyclability

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Chinese Chemical Letters 2024年第6期35卷 195-200页

作者： Yaping Wang Pengcheng Yuan Zeyuan Xu xiong-xiong liu Shengfa Feng Mufan Cao Chen Cao Xiaoqiang Wang Long Pan Zheng-Ming Sun Key Laboratory of Advanced Metallic Materials of Jiangsu Province School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China CALB Technology Co. Ltd.Changzhou 213200China

All-solid-state lithium batteries(ASSLBs)based on sulfide electrolytes promise next-generation energy storage with high energy density and ***,the sulfide electrolytes suffer from phase instability and sluggish interfacial charge transport when pairing with layered oxide cathodes at high ***,a simple and efficient strategy is proposed using two-dimensional Ti_(3)C_(2)T_(x)MXene as starting material to in-situ construct a 15 nm Li_(2)TiO_(3) layer on a typical oxide cathode,LiCoO_(2).The in-situ transformation of Ti_(3)C_(2)T_(x)into Li_(2)TiO_(3) layer occurs at a low temperature of 500℃,avoiding the phase deterioration of LiCoO_(2).The thin Li_(2)TiO_(3) layer is Li^(+)conducting and electrochemically stable,thereby preventing the interfacial decomposition of sulfide electrolytes induced by LiCoO_(2) at high voltages and facilitating Li+transport at the ***,Li_(2)TiO_(3) can stabilize the layer structure of LiCoO_(2) at high ***,the sulfide-based ASSLB using LiCoO_(2)@Li_(2)TiO_(3) cathode can operate stably at a high voltage of up to 4.5 V(***+/Li),delivering an outstanding initial specific discharge capacity of 138.8 m Ah/g with a high capacity retention of 86.2% after 100 cycles at 0.2 *** in-situ transformation strategy may also apply to other MXenes,offering a general approach for constructing other advanced lithiated coatings for oxide cathodes.

关键词： Solid sulfide electrolyte Oxide cathode MXene In-situ transformation Li_(2)TiO_(3) interfacial layer

Phase field modeling of grain stability of nanocrystalline alloys by explicitly incorporating mismatch strain

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Rare Metals 2024年第7期43卷 3370-3382页

作者： Min Zhou Hong-Hui Wu Yuan Wu Hui Wang xiong-Jun liu Sui-He Jiang Xiao-Bin Zhang Zhao-Ping Lu Beijing Advanced Innovation Center for Materials Genome Engineering State Key Laboratory for Advanced Metals and MaterialsUniversity of Science and Technology BeijingBeijing 100083Cnina Institute for Carbon Neutrality University of Science and TechnologyBeijing 100083China Institute of Materials Intelligent Technology Liaoning Academy of MaterialsShenyang 110004China

Ab st ra ct Nanocrystalline materials exhibit unique properties due to their extremely high grain boundary(GB) ***,this high-density characteristic induces grain coarsening at elevated temperatures,thereby limiting the widespread application of nanocrystalline *** experimental observations revealed that GB segregation and second-phase pinning effectively hinder GB migration,thereby improving the stability of nanocry stalline *** this study,a mouified phase-field model that integrates mismatch strain,solute segregation and precipitation was developed to evaluate the influence of lattice misfit on the thermal stability of nanocrystalline *** simulation results indicated that introducing a suitable mismatch strain can effectively enhance the microstructural stability of nanocrystalline *** synergizing precipitation with an appropriate lattice misfit,the formation of second-phase particles in the bulk grains can be suppressed,thereby facilitating solute segregation/precipitation at the *** concentrated solute segregation and precipitation at the GBs effectively hinders grain migration,thereby preventing grain *** findings provide a new perspective on the design and regulation of nanocrystalline alloys with enhanced thermal stability.

关键词： Phase field model Mismatch strain Second-phase precipitation Grain boundary segregation Nanocrystalline alloys

A review of reservoir damage during hydraulic fracturing of deep and ultra-deep reservoirs

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Petroleum Science 2024年第1期21卷 384-409页

作者： Kun Zhang xiong-Fei liu Dao-Bing Wang Bo Zheng Tun-Hao Chen Qing Wang Hao Bai Er-Dong Yao Fu-Jian Zhou National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum-BeijingBeijing102249China School of Mechanical Engineering Beijing Institute of Petrochemical TechnologyBeijing102617China Tuha Downhole Operation Company CNPC Xibu Drilling Engineering Company LimitedShanshan838200XinjiangChina

Deep and ultra-deep reservoirs have gradually become the primary focus of hydrocarbon exploration as a result of a series of significant discoveries in deep hydrocarbon exploration *** reservoirs present unique challenges due to their deep burial depth(4500-8882 m),low matrix permeability,complex crustal stress conditions,high temperature and pressure(HTHP,150-200℃,105-155 MPa),coupled with high salinity of formation ***,the costs associated with their exploitation and development are exceptionally *** deep and ultra-deep reservoirs,hydraulic fracturing is commonly used to achieve high and stable *** hydraulic fracturing,a substantial volume of fluid is injected into the ***,statistical analysis reveals that the flowback rate is typically less than 30%,leaving the majority of the fluid trapped within the ***,hydraulic fracturing in deep reservoirs not only enhances the reservoir permeability by creating artificial fractures but also damages reservoirs due to the fracturing fluids *** challenging“three-high”environment of a deep reservoir,characterized by high temperature,high pressure,and high salinity,exacerbates conventional forms of damage,including water sensitivity,retention of fracturing fluids,rock creep,and proppant *** addition,specific damage mechanisms come into play,such as fracturing fluid decomposition at elevated temperatures and proppant diagenetic reactions at HTHP ***,the foremost concern in deep oil and gas development lies in effectively assessing the damage inflicted on these reservoirs by hydraulic fracturing,comprehending the underlying mechanisms,and selecting appropriate ***'s noteworthy that the majority of existing studies on reservoir damage primarily focus on conventional reservoirs,with limited attention given to deep reservoirs and a lack of systematic *** light of this,our approach entails initially summarizin

关键词： Artificial fracture Deep and ultra-deep reservoir Fracture conductivity Fracturing fluid Hydraulic fracturing Reservoir damage

Chiral liquid crystals based on pillararene and supramolecular self-assembly-induced chirality amplification

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Science China Chemistry 2024年第10期67卷 3373-3381页

作者： Bicong Liang Yujie Cheng xiong liu Lan Jia Xuehong Wei Qiang Zheng Pi Wang Danyu Xia Xuzhou Yan College of Materials Science and Engineering Taiyuan University of Technology Scientific Instrument Center Shanxi University School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative MoleculesShanghai Jiao Tong University

Macrocyclic liquid crystals combine the unique property of liquid crystals and excellent supramolecular assembly ability of macrocyclic compounds. It is a significant challenge to make rational use of the advantages of macrocyclic compounds to prepare new macrocyclic mesogens. Pillararenes, a type of macrocycles with rigid pillar-shaped frameworks and easy-tofunctionalize property, are excellent building blocks to fabricate liquid crystal materials. However, the site-selective modification property of pillararene has been rarely exploited to tailor liquid crystal behaviors. Previously reported pillararene-based liquid crystal systems are almost prepared by per-functionalized pillararenes. Herein, we report the regulation of chiral liquid crystal behaviors by different derivatization of pillararene. Lyotropic and thermotropic liquid crystals with different chirality were obtained by self-assembly of pillararene with different numbers of cholesterol groups. The bridge between thermotropic liquid crystal and lyotropic liquid crystal based on pillararene is built. In addition, the chirality of the mesogens can be amplified through supramolecular self-assembly driven by noncovalent interactions. Based on the different liquid crystal behaviors, the optical signal of the pillararene-based chiral liquid crystals was used to fabricate an information encryption system. This work provides a simple strategy to regulate liquid crystal behaviors via pillararene-based mesogens and realizes information encryption through the combination of different types of liquid crystals.

关键词： chiral liquid crystal pillararene self-assembly cholesterol information encryption

Leaf Morphology Genes SRL1 and RENL1 Co-Regulate Cellulose Synthesis and Affect Rice Drought Tolerance

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Rice science 2024年第1期31卷 103-117,I0020-I0022页

作者： liu Dan ZHAO Huibo WANG Zi’an XU Jing liu Yiting WANG Jiajia CHEN Minmin liu xiong ZHANG Zhihai CEN Jiangsu ZHU Li HU Jiang REN Deyong GAO Zhenyu DONG Guojun ZHANG Qiang SHEN Lan LI Qing QIAN Qian HU Songping ZHANG Guangheng State Key Laboratory of Rice Biology and Breeding China National Rice Research InstituteHangzhou 310006China Research Center of Plant Functional Genes and Tissue Culture Technology College of Bioscience and BioengineeringJiangxi Agricultural UniversityNanchang 330045China Qian Qian Academician Workstation National Nanfan Research Institute(Sanya)Chinese Academy of Agricultural SciencesSanya 572024China

The morphological development of rice(Oryza sativa L.)leaves is closely related to plant architecture,physiological activities,and ***,it is unclear whether there is a co-regulatory relationship between the morphological development of leaves and adaptation to drought *** this study,a drought-sensitive,roll-enhanced,and narrow-leaf mutant(renl1)was induced from a semi-rolled leaf mutant(srl1)by ethyl methane sulfonate(EMS),which was obtained from Nipponbare(NPB)through ***-based cloning and functional validation showed that RENL1 encodes a cellulose synthase,allelic to NRL1/*** RENL1 mutation resulted in reduced vascular bundles,vesicular cells,cellulose,and hemicellulose contents in cell walls,diminishing the water-holding capacity of *** addition,the root system of the renl1 mutant was poorly developed and its ability to scavenge reactive oxygen species(ROS)was decreased,leading to an increase in ROS after drought ***,genetic results showed that RENL1 and SRL1 synergistically regulated cell wall *** results revealed a theoretical basis for further elucidating the molecular regulation mechanism of cellulose on rice drought tolerance,and provided a new genetic resource for enhancing the synergistic regulation network of plant type and stress resistance,thereby realizing simultaneous improvement of multiple traits in rice.

关键词： cellulose cell wall drought tolerance leaf morphology rice

Chiral Phenol-2NO Ligand Cooperation with Achiral Organic Base in the Zn(II)-Catalyzed Asymmetric Alkylation Reaction of Indoles

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Chinese Journal of Chemistry 2024年第13期42卷 1474-1480页

作者： Ke-Lan Xu Yu-Heng Wang Xi-Rui Wang Pan Hu Bo-Wen Pan Wen-Jing Zhang Zi-Yue Chen Ying Zhou xiong-Li liu National&Local Joint Engineering Research Center for the Exploitation of Homology Resources of Southwest Medicine and Food Guizhou UniversityGuiyangGuizhou 550025China College of Pharmaceutical Sciences Guizhou University of Traditional Chinese MedicineGuiyangGuizhou 550025China Green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhouHenan 450001China

The privileged C_(2)-symmetric rigid phenol-type ligand is more attractive but challenging in asymmetric ***,we designed and synthesized a class of rigid-featured chiral tridentate Phenol-2NO ligands,that incorporate the advantages of both the phenol skeleton and pyrroloimidazolone-based N-oxide moiety,from readily available L-prolinamides in operationally simple two steps and up to 44%overall *** importantly,using an achiral quinoline derivative as an additive,the newly developed Phenol-2NO ligand could serve as the anioic ligand upon deprotonative activation to coordinate to Zn(II)to form a highly enantioselective catalyst for the asymmetric Michael-type Friedel-Crafts alkylation reaction of indoles with 2,*** yields(up to 90%)and high enantioselectivities(up to 99%ee)are obtained for a wide range of substrates under mild *** and DFT calculations revealed the reaction mechanism and the origins of the *** also represented the first activation of phenol-type ligand/metal complex by an achiral organic base as the additive in asymmetric catalysis.

关键词： Phenol-2NO C_(2)-Symmetric Rigid-featured Tridentate ligand Asymmetric catalysis Alkylation Synthesis design Heterocycles

Prohibitin 1 inhibits cell proliferation and induces apoptosis via the p53-mediated mitochondrial pathway in vitro

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World Journal of Gastrointestinal Oncology 2024年第2期16卷 398-413页

作者： Juan-Juan Shi Yi-Kai Wang Mu-Qi Wang Jiang Deng Ning Gao Mei Li Ya-Ping Li Xin Zhang Xiao-Li Jia xiong-Tao liu Shuang-Suo Dang Wen-Jun Wang Department of Infectious Diseases The Second Affiliated Hospital of Xi’an Jiaotong UniversityXi'an 710004Shaanxi ProvinceChina Department of Operating Room The Second Affiliated Hospital of Xi’an Jiaotong UniversityXi'an 710004Shaanxi ProvinceChina

BACKGROUND Prohibitin 1(PHB1)has been identified as an antiproliferative protein that is highly conserved and ubiquitously expressed,and it participates in a variety of essential cellular functions,including apoptosis,cell cycle regulation,prolifera-tion,and *** evidence indicates that PHB1 may play an important role in the progression of hepatocellular carcinoma(HCC).However,the role of PHB1 in HCC is *** To investigate the effects of PHB1 on the proliferation and apoptosis of human HCC cells and the relevant mechanisms in *** HCC patients and healthy individuals were enrolled in this study according to the inclusion and exclusion criteria;then,PHB1 levels in the sera and liver tissues of these participates were determined using ELISA,RT-PCR,and *** HepG2 and SMMC-7721 cells were transfected with the pEGFP-PHB1 plasmid and PHB1-specific shRNA(shRNA-PHB1)for 24-72 *** prolif-eration was analysed with an MTT *** cycle progression and apoptosis were analysed using flow cytometry(FACS).The mRNA and protein expression levels of the cell cycle-related molecules p21,Cyclin A2,Cyclin E1,and CDK2 and the cell apoptosis-related molecules cytochrome C(Cyt C),p53,Bcl-2,Bax,caspase 3,and caspase 9 were measured by real-time PCR and Western blot,*** Decreased levels of PHB1 were found in the sera and liver tissues of HCC patients compared to those of healthy individuals,and decreased PHB1 was positively correlated with low differentiation,TNM stage III-IV,and alpha-fetoprotein≥400μg/*** of PHB1 significantly inhibited human HCC cell proliferation in a time-dependent *** revealed that the overexpression of PHB1 arrested HCC cells in the G0/G1 phase of the cell cycle and induced *** proportion of cells in the G0/G1 phase was significantly increased and the proportion of cells in the S phase was decreased in HepG2 cells that were transfected with pEGFP-PHB1 compar

关键词： Prohibitin 1 Hepatocellular carcinoma cells Apoptosis Cell cycle Mitochondrial pathway

MSA-Lab:模型驱动的微服务集成设计平台

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软件学报 2024年第3期35卷 1280-1306页

作者：熊靖浏任秋蓉 Shmuel TYSZBEROWICZ 刘志明刘波西南大学计算机与信息科学学院软件研究与创新中心重庆400715 Software Engineering Department Afeka Academic College of EngineeringTel-Aviv 6998812Israel 西北工业大学软件学院陕西西安710129

从单体系统迁移到微服务系统是当前业界对遗留系统实施再工程化的主流选项之一,基于单体遗留系统的微服务体系架构重构则是实现该迁移的关键步骤.目前学界多集中在微服务识别方法的研究上;业界虽有许多面向微服务架构的遗留系统重构的实... 详细信息

从单体系统迁移到微服务系统是当前业界对遗留系统实施再工程化的主流选项之一,基于单体遗留系统的微服务体系架构重构则是实现该迁移的关键步骤.目前学界多集中在微服务识别方法的研究上;业界虽有许多面向微服务架构的遗留系统重构的实践,但缺乏系统性的方法及高效鲁棒的工具.鉴于此,在微服务识别与模型驱动开发方法前期研究的基础上,研发一种模型驱动的、可用于单体遗留系统微服务化重构的集成设计平台MSA-Lab.它通过分析单体遗留系统运行日志中的方法调用序列,对其中的类和数据表进行类型识别和聚类以构造抽象微服务,同时生成包括微服务图和微服务序列图在内的系统架构设计模型.它包括用于微服务自动识别与设计模型自动生成的核心部件MSA-Generator,以及用于微服务静态结构模型与动态行为模型可视化展现、交互式建模、模型语法约束检验的核心部件MSA-Modeller.在MSA-Lab平台上,通过对4个开源项目实施有效性、鲁棒性、功能转换完备性等实验以及对3个同类型工具实施性能对比实验,结果表明:所提平台拥有很好的有效性、鲁棒性及实现面向日志的功能转换完备性,且性能更加优越.

关键词：微服务架构服务识别设计模型生成交互式建模工具软件设计评估

浅海环境中用于目标深度属性判别的线谱起伏特征量分析

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物理学报 2024年第13期73卷 175-189页

作者：邓玉鑫刘雄厚杨益新西北工业大学航海学院西安710072 陕西省水下信息技术重点实验室西安710072

浅海环境中目标辐射线谱的起伏特征可用于水面、水下目标深度属性判别.已有研究未给出表征水面、水下线谱起伏差异的物理量性质,导致利用不同物理量进行目标深度属性判别时性能不佳.针对这一问题,本文从声源深度起伏所导致的线谱起伏出... 详细信息

浅海环境中目标辐射线谱的起伏特征可用于水面、水下目标深度属性判别.已有研究未给出表征水面、水下线谱起伏差异的物理量性质,导致利用不同物理量进行目标深度属性判别时性能不佳.针对这一问题,本文从声源深度起伏所导致的线谱起伏出发,采用微分方法与统计方法对线谱起伏规律进行分析,研究了线谱起伏产生的物理机理,得到了适合用于水面、水下目标深度属性判别的物理量.首先,分别推导了复声压实部、声功率与声压幅值关于声源深度的导数关系式,得到了以上三种物理量在声源深度起伏时的起伏大小;其次,利用仿真实验数据从接收深度、声源水平距离、线谱频率等层面对理论推导进行验证,并对线谱的归一化起伏特征进行了分析.最后,利用海试数据验证了相关结论.结果表明,当声源的深度起伏时,水面、水下线谱的起伏差异源自各阶模态的相互作用.声源频率、声源水平距离、接收深度三种因素决定了模态间相互作用的性质.声压幅值适用于构建目标深度属性判别特征量,可用于表征低频线谱的强度起伏差异.数值仿真和海试数据处理结果表明,相较于声压实部和声功率,利用声压幅值构建的归一化水面、水下目标深度属性判别特征量具有更优性能.

关键词：线谱起伏深度属性判别浅海环境简正波