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MOF-templated tubular Ni_(1−x)Co_(x)S_(2)-CdS heterojunction with intensified direct Z-scheme charge transmission for highly promoted visible-light photocatalysis

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Nano Research 2024年第7期17卷 6281-6293页

作者： Chuan Jiang Yuanxin Qiu xinxin xin Yanyan Li Huilin Li Hui Wang Jixiang Xu Haifeng Lin Lei Wang Volodymyr Turkevych Key Laboratory of Eco-chemical Engineering International S&T Cooperation Foundation of Eco-chemical Engineering and Green ManufactureCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization Key Laboratory of Rubber-Plastics of Ministry of EducationSchool of Polymer Science and EngineeringQingdao University of Science and TechnologyQingdao 266042China V.Bakul Institute for Superhard Materials National Academy of Sciences of UkraineKyiv 04074Ukraine

Hollow semiconductor nanostructures with direct Z-scheme heterojunction have significant advantages for photocatalytic reactions,and optimizing the interfacial charge transmission of Z-scheme heterojunction is the hinge to achieve excellent solar conversion *** this work,tubular Ni_(1−x)Co_(x)S_(2)-CdS heterostructures with reinforced Z-scheme charge transmission were constructed through an In-metal-organic framework(MOF)templated *** Z-scheme charge transfer mechanism was sufficiently confirmed by combining density functional theory(DFT)calculation,X-ray photoelectron spectroscopy(XPS),surface photovoltage spectroscopy(SPV),and radical testing ***,the use of sodium citrate complexant contributes to the formation of intimate heterointerface,and the Fermi level gap between CdS and NiS_(2)is enlarged through Co doping into NiS_(2),which enhances the built-in electric field and photo-carriers transmission driving force for Ni_(1−x)Co_(x)S_(2)-CdS heterojunction,resulting in an evidently promoted activity toward H2 evolution reaction(HER).Under visible-light(λ>400 nm)irradiation,the Ni_(1−x)Co_(x)S_(2)-CdS composite with 10 mol%Co doping and 80 wt.%CdS(NC_(0.10)S-80%CdS)achieved an outstanding HER rate up to 35.94 mmol·g^(−1)·h^(−1)(corresponding to the apparent quantum efficiency of 34.7%at 420 nm),approximately 76.4 times that of 3 wt.%Pt-loaded CdS and it is much superior to that of most CdS-based photocatalysts ever ***,the good photocatalytic durability of Ni_(1−x)Co_(x)S_(2)-CdS heterostructures was validated by cycling and long-term HER *** work could inspire the development of high-performance Z-scheme heterojunction via optimizing the morphology and interfacial charge transmission.

关键词： tubular heterostructure Z-scheme charge transmission interfacial coupling built-in electric field visible-light photocatalysis

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基于分子模拟的微观结构特征对无烟煤吸附CH_(4)、CO_(2)影响规律对比研究

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煤炭科学技术 2024年第3期52卷 106-114页

作者：辛鑫昕撒占友杨帅王冬梅刘杰卢守青邵兵青岛理工大学机械与汽车工程学院山东青岛266520 中国农业银行股份有限公司日照东港支行山东日照276800

为探究煤的孔径、芳香片层堆砌度、芳香片层延展度、气体温度、气体压力对CH_(4)和CO_(2)竞争吸附的影响,以晋城矿区3号煤为研究对象,对不同温度、压力、孔径、芳香片层堆砌度、芳香片层延展度下煤吸附CH_(4)、CO_(2)二元混合气体的过... 详细信息

为探究煤的孔径、芳香片层堆砌度、芳香片层延展度、气体温度、气体压力对CH_(4)和CO_(2)竞争吸附的影响,以晋城矿区3号煤为研究对象,对不同温度、压力、孔径、芳香片层堆砌度、芳香片层延展度下煤吸附CH_(4)、CO_(2)二元混合气体的过程进行研究。基于工业分析、X射线衍射试验对煤的微观结构进行测试与分析,采用巨正则系综蒙特卡洛(GCMC)方法对煤吸附混合气体的过程进行分子模拟。结果表明:气体压力增加有利于吸附,压力为5 MPa时,CO_(2)的吸附量已接近饱和;温度增加会导致煤对CO_(2)的最大吸附量和吸附热降低;孔径增大会使煤对CH_(4)的吸附量增大,孔径从1 nm增加到2 nm,CH4的吸附量增加最快;随着芳香片层堆砌度的增加,煤吸附的气体分子数变化不明显,但单位质量煤对CO_(2)的吸附量呈迅速下降趋势,对CH4的吸附量略有降低;随着芳香片层延展度的增加,煤吸附的CH_(4)分子数缓慢增加,吸附的CO_(2)分子数快速增加,单位质量的煤对2种气体的吸附量变化不明显;从吸附量和吸附热2个角度来看,CO_(2)在竞争吸附过程中均处于优势地位,因此向煤层注入CO_(2)可有效驱替CH_(4)。研究结果加强了分子层面对CH_(4)、CO_(2)二元混合气体吸附的认识,可为注CO_(2)强化煤层气开采奠定理论基础。

关键词：晋城矿区微观结构 GCMC 分子模拟 CO_(2)−ECBM

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Building mm Wave on the Evolving C-V2X:mm Wave NR-V2X

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China Communications 2024年第1期21卷 88-101页

作者： Shanzhi Chen xinxin He Rui Zhao Jinling Hu xin Zhang China Information and Communication Technology Group Co. Ltd.(CICT)the State Key Laboratory of Wireless Mobile CommunicationsBeijing 100083China Beijing Laboratory of Advanced Information Networks Beijing Key Laboratory of Network System Architecture and ConvergenceBeijing University of Posts and TelecommunicationsBeijing 100876China CICT Connected and Intelligent Technologies Co. LtdChina Academy of Telecommunication TechnologyBeijing 100191China CICT Mobile Communications Technology Co.Ltd.

Since the evolving standardization of cellular V2X(C-V2X)technologies is continuously developed by 3GPP,research on new radio(NR-V2X)has been on schedule by academic and *** millimeter wave(mm Wave)frequency band is supposed to provide large transmission bandwidth,yet the development of mm Wave band in NR-V2X is still in preliminary *** this article,a comprehensive discussion of mm Wave NR-V2X is given covering trends,standardization landscape,and enabling technologies,aiming at tackling the challenge of channel modeling,directional channel access,beamforming and blockage *** vision of mm Wave NR-V2X is to fully support the development of automated driving,holographic control display and improved in-car infotainment for the future.

关键词： C-V2X enabling technologies mmWave NR-V2X

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Synchronous deprotonation–protonation for mechanically robust chitin/aramid nanofibers conductive aerogel with excellent pressure sensing, thermal management, and electromagnetic interference shielding

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Nano Research 2024年第3期17卷 2038-2049页

作者： xinxin Zhang Kunpeng Qian Jianhui Fang Sineenat Thaiboonrod Miao Miao xin Feng Department of Chemistry College of SciencesShanghai UniversityShanghai 200444China Research Center of Nano Science and Technology College of SciencesShanghai UniversityShanghai 200444China School of Materials Sciences and Engineering Shanghai UniversityShanghai 200444China National Nanotechnology Center(NANOTEC) National Science and Technology Development Agency(NSTDA)Thailand Science ParkPathum Thani 12120Thailand

Aerogels with regularly porous structure and uniformly distributed conductive networks have received extensive attention in wearable electronic sensors,electromagnetic shielding,and so ***,the poor mechanical properties of the emerging nanofibers-based aerogels are limited in practical *** this work,we developed a synchronous deprotonation–protonation method in the KOH/dimethyl sulfoxide(DMSO)system at room temperature for achieving chitin cross-linked aramid nanofibers(CANFs)rather than chitin nanofibers(ChNFs)and aramid nanofibers(ANFs)separately by using chitin and aramid pulp as raw *** freeze-drying process,the cross-linked chitin/aramid nanofibers(CA)aerogel exhibited the synergetic properties of ChNF and ANF by the dual-nanofiber compensation *** mechanical stress of CA aerogel was 170 kPa at 80%compressive strain,increased by 750%compared with pure ChNF ***,the compressibility of CA aerogel was somewhat improved compared to ANF *** enhancement verified that the crosslinking reaction between ANF and ChNF during the synchronous deprotonation process was ***,the conductive aerogels with uniform porous structure(CA-M)were successfully obtained by vacuum impregnating CA aerogels in Ti_(3)C_(2)T_(x) MXene solution,displaying low thermal conductivity(0.01 W/(m·K)),high electromagnetic interference(EMI)shielding effectiveness(SE)(75 dB),flame retardant,and heat ***,the as-obtained CA-M aerogels were also applied as a pressure sensor with excellent compression cycle stability and superior human motion monitoring *** a result,the dual-nanofiber based conductive aerogels have great potentials in flexible/wearable electronics,EMI shielding,flame retardant,and heat insulation.

关键词： synchronous deprotonation–protonation electromagnetic interference(EMI)shielding flame retardant heat insulation pressure sensing

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EuSHT Acts as a Hub Gene Involved in the Biosynthesis of 6-Hydroxyluteolin and Quercetin Induced by Salt Stress in Eucommia ulmoides

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Phyton-International Journal of Experimental Botany 2024年第8期93卷 2095-2113页

作者： Fuxin Li Enyan Chen xinxin Chen Jingyu Jia Hemin Wang Jie Zhang Jianrui Sun xin Li College of Food and Bioengineering Henan University of Science and TechnologyLuoyang471023China Henan Engineering Research Center of Food Microbiology Luoyang471023China National Demonstration Center for Experimental Food Processing and Safety Education Luoyang471000China

Salt stress inhibits plant growth and affects the biosynthesis of its secondary *** are natural compounds that possess many important biological activities,playing a significant role in the medicinal activity of Eucommia ulmoides(***).To investigate the mechanism by which salt stress affects the biosynthesis of flavonoids in ***,a comprehensive analysis of metabolomics and transcriptomics was *** results indicated that salt stress led to the wilting and darkening of *** leaves,accompanied by a decrease in chlorophyll levels,and significantly induced malondialdehyde(MDA)and relative electrical *** salt stress,most metabolites in the flavonoid biosynthesis pathway of *** were upregulated,indicating that flavonoid biosynthesis is likely the main induced pathway under salt *** them,secondary metabolites such as 6-Hydroxyluteolin and Quercetin are likely key metabolites induced by salt *** correlation analysis of transcriptomics and metabolomics revealed that EuSHT is a hub gene induced by salt stress,promoting the production of flavonoids such as *** co-expression network showed a strong positive correlation between EuSHT and the biosynthesis of 6-Hydroxyluteolin and Quercetin,while it exhibited a negative correlation with Catechin *** branches leading to Luteolin and Dihydroquercetin are likely the main pathways for flavonoid compound biosynthesis in the plant stress response during salt *** results of this study provided a preliminary mechanism of secondary metabolites such as flavonoids in the medicinal plant *** induced by salt stress and provided new theoretical support for discussing the mechanism of plant stress *** also provided useful information for subsequent exploration of resistance genes in ***.

关键词： Eucommia ulmoides ﬂavonoid salt stress transcriptomics widely targeted metabolomics

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Landscape of human organoids:Ideal model in clinics and research

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The Innovation 2024年第3期5卷 146-164页

作者： xinxin Han Chunhui Cai Wei Deng Yanghua Shi Lanyang Li Chen Wang Jian Zhang Mingjie Rong Jiping Liu Bangjiang Fang Hua He Xiling Liu Chuxia Deng Xiao He xin Cao Organ Regeneration X Lab Lisheng East China Institute of BiotechnologyPeking UniversityJiangsu 226200China Shanghai Lisheng Biotech Shanghai 200092China LongHua Hospital Shanghai University of Traditional Chinese Medicine725 Wanping South RoadXuhui DistrictShanghai 200032China Department of Oncology Shanghai Ninth People’s HospitalShanghai Jiao Tong University School of MedicineShanghai 200125China Department of Neurosurgery Third Affiliated HospitalNaval Medical UniversityShanghai 200438China Shanghai Key Laboratory of Forensic Medicine Shanghai Forensic Service PlatformAcademy of Forensic ScienceMinistry of JusticeShanghai 200063China Cancer Center Faculty of Health SciencesUniversity of MacaoTaipaMacao SARChina Ministry of Education Frontiers Science Center for Precision Oncology University of MacaoTaipaMacao SAR 999078China CAS Key Lab for Biomedical Effects of Nanomaterials and Nanosafety Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China Zhongshan Hospital Institute of Clinical Science Fudan University Shanghai Medical CollegeShanghai 200032China

In the last decade,organoid research has entered a golden era,signifying a pivotal shift in the biomedical *** year 2023 marked a milestone with the publication of thousands of papers in this arena,reflecting exponential ***,amid this burgeoning expansion,a comprehensive and accurate overview of the field has been conspicuously *** review is intended to bridge this gap,providing a panoramic view of the rapidly evolving organoid *** meticulously analyze the organoid field from eight distinctive vantage points,harnessing our rich experience in academic research,industrial application,and clinical *** present a deep exploration of the advances in organoid technology,underpinned by our long-standing involvement in this *** narrative traverses the historical genesis of organoids and their transformative impact across various biomedical sectors,including oncology,toxicology,and drug *** delve into the synergy between organoids and avant-garde technologies such as synthetic biology and single-cell omics and discuss their pivotal role in tailoring personalized medicine,enhancing high-throughput drug screening,and constructing physiologically pertinent disease *** comprehensive analysis and reflective discourse provide a deep dive into the existing landscape and emerging trends in organoid *** spotlight technological innovations,methodological evolution,and the broadening spectrum of applications,emphasizing the revolutionary influence of organoids in personalized medicine,oncology,drug discovery,and other *** ahead,we cautiously anticipate future developments in the field of organoid research,especially its potential implications for personalized patient care,new avenues of drug discovery,and clinical *** trust that our comprehensive review will be an asset for researchers,clinicians,and patients with keen interest in personalized medical *** offer a broad view of the

关键词： landscape intended advances

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OsPRMT6a-mediated arginine methylation of OsJAZ1 regulates jasmonate signaling and spikelet development in rice

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Molecular Plant 2024年第6期17卷 900-919页

作者： Kun Dong Fuqing Wu Siqi Cheng Shuai Li Feng Zhang xinxin xing xin Jin Sheng Luo Miao Feng Rong Miao Yanqi Chang Shuang Zhang Xiaoman You Peiran Wang xin Zhang Cailin Lei Yulong Ren Shanshan Zhu Xiuping Guo Chuanyin Wu Dong-Lei Yang Qibing Lin Zhijun Cheng Jianmin Wan State Key Laboratory of Crop Gene Resources and Breeding National Key Facility for Crop Gene Resources and Genetic ImprovementInstitute of Crop SciencesChinese Academy of Agricultural SciencesBeijing 100081China State Key Laboratory for Crop Genetics and Germplasm Enhancement Nanjing Agricultural UniversityNanjing 210095China

Although both protein arginine methylation(PRMT)and jasmonate(JA)signaling are crucial for regulating plant development,the relationship between these processes in the control of spikelet development remains *** this study,we used the CRISPR/Cas9 technology to generate two OsPRMT6a loss-of-function mutants that exhibit various abnormal spikelet ***,we found that OsPRMT6a can methylate arginine residues in JA signal repressors OsJAZ1 and *** showed that arginine methylation of OsJAZ1 enhances the binding affinity of OsJAZ1 with the JA receptors OsCOI1a and OsCOI1b in the presence of JAs,thereby promoting the ubiquitination of OsJAZ1 by the SCF^(OsCOI1a/OsCOI1b) complex and degradation via the 26S *** process ultimately releases OsMYC2,a core transcriptional regulator in the JA signaling pathway,to activate or repress JA-responsive genes,thereby maintaining normal plant(spikelet)***,in the osprmt6a-1 mutant,reduced arginine methylation of OsJAZ1 impaires the interaction between OsJAZ1 and OsCOI1a/OsCOI1b in the presence of *** a result,OsJAZ1 proteins become more stable,repressing JA responses,thus causing the formation of abnormal spikelet ***,we discovered that JA signaling reduces the OsPRMT6a mRNA level in an OsMYC2-dependent manner,thereby establishing a negative feedback loop to balance JA *** further found that OsPRMT6a-mediated arginine methylation of OsJAZ1 likely serves as a switch to tune JA signaling to maintain normal spikelet development under harsh environmental conditions such as high ***,our study establishes a direct molecular link between arginine methylation and JA signaling in rice.

关键词： protein arginine methylation jasmonate signaling negative feedback loop spikelet development adaptation to heat stress rice

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红萝卜侧面悬置排种勺式精量排种器设计与试验

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农业机械学报 2024年第5期55卷 77-86,97页

作者：顿国强郭娜纪欣鑫李鑫王雷哈尔滨剑桥学院智能农机装备工程实验室哈尔滨150069 东北林业大学机电工程学院哈尔滨150040

为解决传统机械式蔬菜排种器无法实现精量播种及存在伤种的问题,设计了一种红萝卜侧面悬置排种勺式精量排种器。采用排种盘侧面悬置的排种勺完成种子的充种、清种、投种,实现了非接触式作业过程,理论分析了种子进入及脱离种勺的运动过程... 详细信息

为解决传统机械式蔬菜排种器无法实现精量播种及存在伤种的问题,设计了一种红萝卜侧面悬置排种勺式精量排种器。采用排种盘侧面悬置的排种勺完成种子的充种、清种、投种,实现了非接触式作业过程,理论分析了种子进入及脱离种勺的运动过程,并阐明其不伤种的基本原理,确定了排种盘、排种勺以及排种管的基本结构参数,采用EDEM离散元仿真软件模拟了不同排种勺结构尺寸下的工作过程,以排种勺型孔直径、深度及放样曲面圆角比为试验因素,以单粒率、多粒率、空粒率为试验指标,采用三因素五水平二次通用旋转组合设计进行仿真试验,确定排种勺最优结构参数为:型孔直径5 mm,深度4.3 mm,放样曲面圆角比0.12,基于此参数进行离散元仿真试验,通过自制排种器试验台进行台架试验以及将排种器安装到播种机上进行田间试验,仿真试验结果为单粒率93%、多粒率4%、空粒率3%,台架试验结果为合格指数平均值92.2%、重播指数平均值4.6%、漏播指数平均值3.2%,相对误差分别为0.86%、15%、6.67%,田间试验结果为:合格指数90.5%、重播指数6.9%、漏播指数2.6%,证明此排种器精量播种性能良好。同时与毛刷窝眼轮式排种器进行损伤率对比试验,损伤率分别为0.43%、1.27%,相对误差为66.14%,表明种子损伤明显降低。

关键词：红萝卜排种器侧面悬置排种勺离散元仿真精量排种

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经口内镜下肌切开术治疗贲门失弛缓症的现状和进展

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胃肠病学 2017年第1期22卷 55-58页

作者：李粉婷高欣欣王新谢华红第四军医大学西京消化病院 710032

贲门失弛缓症是由食管-胃交界处神经肌肉功能障碍所致的一种食管动力障碍的功能性疾病,主要特征为食管缺乏蠕动、食管下括约肌松弛受限。目前治疗方法包括肉毒素治疗、支架植入、腹腔镜Heller肌切开术和内镜下球囊扩张术,但这些治疗手... 详细信息

贲门失弛缓症是由食管-胃交界处神经肌肉功能障碍所致的一种食管动力障碍的功能性疾病,主要特征为食管缺乏蠕动、食管下括约肌松弛受限。目前治疗方法包括肉毒素治疗、支架植入、腹腔镜Heller肌切开术和内镜下球囊扩张术,但这些治疗手段存在短期内易复发、损伤较大等不足。随着内镜技术的不断发展,新型微创术式经口内镜下肌切开术(POEM)在临床上得到广泛应用,亦可用于一些特殊患者,如Ⅲ型贲门失弛缓症、高龄、小儿、乙状结肠型贲门失弛缓症等。本文就POEM治疗贲门失弛缓症的现状和进展作一综述。

关键词：贲门失弛缓经口内镜下肌切开术治疗手术后并发症

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随机需求下生鲜电商供应链物流合作与运营决策

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中国管理科学 2024年第2期32卷 87-98页

作者：崔鑫李春发周驰米新新沈瑶天津理工大学管理学院天津300384

物流服务合作对生鲜电商供应链订货定价决策与产品保鲜水平具有重要影响。基于物流服务商独立运营、与供应商合作、与电商平台合作三种物流合作模式分析,分别构建考虑市场随机需求与保鲜努力的生鲜电商供应链运营决策模型,对比探讨不同... 详细信息

物流服务合作对生鲜电商供应链订货定价决策与产品保鲜水平具有重要影响。基于物流服务商独立运营、与供应商合作、与电商平台合作三种物流合作模式分析,分别构建考虑市场随机需求与保鲜努力的生鲜电商供应链运营决策模型,对比探讨不同模式下的产品定价、产品保鲜努力与市场需求,并结合数值算例分析生鲜电商市场需求预测与供应链成员合作模式偏好。研究结果表明:物流合作能有效分担物流保鲜成本与市场预测风险,降低产品零售价格,提高物流保鲜努力水平;独立运营模式下生鲜电商应采取较保守的产品订货策略,而合作运营模式下可适当提高产品订货量;两种合作经营模式可提高合作企业利润与供应链整体利润,利润合理分配是成员企业合作经营的关键。

关键词：生鲜电商随机需求保鲜努力物流合作 Stackelberg博弈

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