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Reversible aqueous zinc-ion battery based on ferric vanadate cathode

Chinese Chemical Letters 2022年第10期33卷 4628-4634页

作者： Wang Yang Wu Yang Yongfeng Huang Chengjun Xu Liubing Dong Xinwen Peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640China Tsinghua Shenzhen International Graduate School Tsinghua UniversityShenzhen 518055China College of Chemistry and Materials Science Jinan UniversityGuangzhou 511443China

Rechargeable aqueous zinc-ion batteries have attracted extensive interest because of low cost and high safety.However,the relationship between structure change of cathode and the zinc ion storage mechanism is still complex and challenging.Herein,open-structured ferric vanadate(Fe_(2)V_(4)O_(13))has been developed as cathode material for aqueous zinc-ion batteries.Intriguingly,two zinc ion storage mechanism can be observed simultaneously for the Fe2V4O13 electrode,i.e.,classical intercalation/deintercalation storage mechanism in the tunnel structure of Fe_(2)V_(4)O_(13),and reversible phase transformation from ferric vanadate to zinc vanadate,which is verified by combined studies using various in-situ and ex-situ techniques.As a result,the Fe_(2)V_(4)O_(13) cathode delivers a high discharge capacity of 380 mAh/g at 0.2 A/g,and stable cyclic performance up to 1000 cycles at 10 A/g in the operating window of 0.2-1.6 V with 2 mol/L Zn(CF_(3)SO_(3))_(2) aqueous solution.Moreover,the assembled Fe_(2)V_(4)O_(13)//Zn flexible quasi-solid-state battery also exhibits a relatively high mechanical strength and good cycling stability.The findings reveal a new perspective of zinc ion storage mechanism for Fe_(2)V_(4)O_(13),which may also be applicable to other vanadate cathodes,providing a new direction for the investigation and design of zinc-ion batteries.

关键词： Aqueous zinc-ion battery Ferric vanadate cathode Reversible phase transformation Zinc ion storage mechanism Biomass-based flexible quasi-solid-state battery

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Porous carbon coupled with an interlaced MoP–MoS2 heterojunction hybrid for efficient hydrogen evolution reaction

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Journal of Energy Chemistry 2020年第6期29卷 45-51,I0003页

作者： Qiusheng Zhou Jianrui Feng Xinwen Peng Linxin Zhong Runcang Sun State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640GuangdongChina College of Chemistry Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)Nankai UniversityTianjin 300071China Center for Lignocellulose Science and Engineering and Liaoning Key Laboratory Pulp and Paper EngineeringDalian Polytechnic UniversityDalian 116034LiaoningChina

The design and development of electrocatalysts composed of non-noble-metal catalysts with both large surface area and high electrical conductivities are crucial for the hydrogen evolution reaction(HER).Here,a xylose-based porous carbon is coupled with a MoS2-Mo P heterojunction(MoS2-Mo P/FPC)hybrid and used as a promising catalyst for HER.The hybrid is prepared by immobilizing petal-like MoS2 nanosheets on porous carbon(MoS2/FPC),followed by controlling the phosphidation in Ar/H2 to form MoS2-Mo P/FPC.Red phosphorus provides the P species that can induce the construction of the heterojunction under the reducing atmosphere,along with the generation of a Mo P phase and the splitting of the MoS2 phase.The as-prepared MoS2-Mo P/FPC catalyst offers a low overpotential of 144 mV at a current density of 10 m A cm^-2 and a small Tafel slope of 41 m V dec^-1 for the HER in acidic media,as well as remarkable stability.Apart from the active nature of the hybrid,its outstanding activity is attributed to the MoS2-Mo P heterojunction,and the good charge/mass-transfer ability of porous carbon.This strategy provides a new method to develop and design low-cost and high-performance catalysts for the HER.

关键词： MoS2 Heterojunction Carbon Electrocatalyst

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Cellulose nanofiber-derived carbon aerogel for advanced room-temperature sodium–sulfur batteries

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Carbon Energy 2023年第1期5卷 1-15页

作者： Wu Yang Wang Yang Ren Zou Yongfa Huang Haihong Lai Zehong Chen Xinwen Peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhouChina

Room-temperature sodium–sulfur(RT/Na–S)batteries are regarded as promising large-scale stationary energy storage systems owing to their high energy density and low cost as well as the earth-abundant reserves of sodium and sulfur.However,the diffusion of polysulfides and sluggish kinetics of conversion reactions are still major challenges for their application.Herein,we developed a powerful and functional separator to inhibit the shuttle effect by coating a lightweight three-dimensional cellulose nanofiber-derived carbon aerogel on a glass fiber separator(denoted NSCA@GF).The hierarchical porous structures,favorable electronic conductivity,and three-dimensional interconnected network of N,S-codoped carbon aerogel endow a multifunctional separator with strong polysulfide anchoring capability and fast reaction kinetics of polysulfide conversion,which can act as the barrier layer and an expanded current collector to increase sulfur utilization.Moreover,the hetero-doped N/S sites are believed to strengthen polysulfide anchoring capability via chemisorption and accelerate the redox kinetics of polysulfide conversion,which is confirmed from experimental and theoretical results.As a result,the assembled Na–S coin cells with the NSCA@GF separator showed a high reversible capacity(788.8 mAh g^(−1) at 0.1 C after 100 cycles)and superior cycling stability(only 0.059%capacity decay per cycle over 1000 cycles at 1 C),thereby demonstrating the significant potential for application in high-performance RT/Na–S batteries.

关键词： carbon aerogel cellulose nanofiber N,S codoping redox kinetics sodium–sulfur batteries

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Biomass-based N doped carbon as metal-free catalyst for selective oxidation of D-xylose into D-xylonic acid

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Green Energy & Environment 2022年第6期7卷 1310-1317页

作者： Zengyong Li Yiming Huang Xiao Chi Di Li Linxin Zhong Xuehui Li Chuanfu Liu Xinwen Peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou510640China School of Chemistry and Chemical Engineering South China University of TechnologyGuangzhou510640China

Rational design and facile preparation of low-cost and efficient catalysts for the selective converting of biomass-derived monosaccharides into high value-added chemicals is highly demanded,yet challenging.Herein,we first demonstrate a N doped defect-rich carbon(NC-800-5)as metal-free catalyst for the selective oxidation of D-xylose into D-xylonic acid in alkaline aqueous solution at 100℃ for 30 min,with 57.4%yield.The doped graphitic N is found to be the active site and hydroxyl ion participating in the oxidation of D-xylose.Hydroxyl ion and D-xylose first adsorb on NC-800-5 surface,and the aldehyde group of D-xylose is catalyzed to form germinal diols ion.Then,C–H bond break to yield carboxylic group.Furthermore,NC-800-5 catalyst shows high stability in recycled test.

关键词： Biomass carbon Metal-free catalysts D-xylose Sugar acid Selective oxidation

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Metal coordination assists fabrication of multifunctional aerogel

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Journal of Materials Science & Technology 2021年第12期71卷 67-74页

作者： Yijie Hu Hao Zhuo Zehong Chen Xinwen Peng Linxin Zhong Runcang Sun State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640China Centre for Lignocellulose Science and Engineering College of Light Industry and Chemical EngineeringDalian Polytechnic UniversityDalian 116034China

Interfacial design is one of the most promising ways in improving mechanical properties of nanocomposites.In this work,a multifunctional aerogel with excellent mechanical performances,sensing sensitivity,and fire retardancy is fabricated by taking advantage of metal coordination between biopolymer and Fe3+.Montmorillonite(MMT)nanosheets are added to induce a‘brick and mortar’structure.The coordination remarkably reduces structural defects,leading to well-formed lamellas that can effectively distribute stress under sever compression without plastic deformation.The structural merits impart the aerogel highly reversible compressibility even at 99%strain and superior durability.Besides,it demonstrates high sensing performance in wearable health monitoring devices,and shows fire resistance property that can maintain elasticity in a flame.The work offers a facile and effective method to create multifunctional aerogels from various polymers.

关键词： Foam Composites Resilient Carbon

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Atomically dispersed Mn-Nx catalysts derived from Mn-hexamine coordination frameworks for oxygen reduction reaction

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Carbon Energy 2024年第5期6卷 114-126页

作者： Guoyu Zhong Liuyong Zou Xiao Chi Zhen Meng Zehong Chen Tingzhen Li Yongfa Huang Xiaobo Fu Wenbo Liao Shaona Zheng Yongjun Xu Feng peng Xinwen Peng Guangdong Provincial Key Laboratory of Distributed Energy Systems School of Chemical Engineering and Energy TechnologyDongguan University of TechnologyDongguanChina State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhouChina Department of Chemistry Centre for Advanced 2D Materials(CA2DM)National University of SingaporeSingaporeSingapore School of Chemistry and Chemical Engineering Guangzhou UniversityGuangzhouChina

Metal-organic frameworks recently have been burgeoning and used as precursors to obtain various metal-nitrogen-carbon catalysts for oxygen reduction reaction(ORR).Although rarely studied,Mn-N-C is a promising catalyst for ORR due to its weak Fenton reaction activity and strong graphitization catalysis.Here,we developed a facile strategy for anchoring the atomically dispersed nitrogen-coordinated single Mn sites on carbon nanosheets(MnNCS)from an Mn-hexamine coordination framework.The atomically dispersed Mn-N4 sites were dispersed on ultrathin carbon nanosheets with a hierarchically porous structure.The optimized MnNCS displayed an excellent ORR performance in half-cells(0.89 V vs.reversible hydrogen electrode(RHE)in base and 0.76 V vs.RHE in acid in half-wave potential)and Zn-air batteries(233 mW cm^(−2)in peak power density),along with significantly enhanced stability.Density functional theory calculations further corroborated that the Mn-N4-C1_(2)site has favorable adsorption of*OH as the rate-determining step.These findings demonstrate that the metal-hexamine coordination framework can be used as a model system for the rational design of highly active atomic metal catalysts for energy applications.

关键词： carbon nanosheets electrocatalyst metal-organic frameworks Mn-N4 oxygen reduction reaction Zn-air batteries

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Base-free selective oxidation of monosaccharide into sugar acid by surface-functionalized carbon nanotube composites

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Chinese Chemical Letters 2023年第11期34卷 116-123页

作者： Zengyong Li Di Li Linxin Zhong Xuehui Li Chuanfu Liu Xinwen Peng State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510641China School of Chemistry and Chemical Engineering South China University of TechnologyGuangzhou 510641China

Selective oxidation of biomass-derived monosaccharide into high value-added chemicals is highly desirable from sustainability perspectives.Herein,we demonstrate a surface-functionalized carbon nanotubesupported gold(Au/CNT-O and Au/CNT-N)catalyst for base-free oxidation of monosaccharide into sugar acid.Au/CNT-O and Au/CNT-N surfaces successfully introduced oxygen-and nitrogen-containing functional groups,respectively.The highest yields of gluconic acid and xylonic acid were 93.3%and 94.3%,respectively,using Au/CNT-N at 90℃ for 240 min,which is higher than that of using Au/CNT-O.The rate constants for monosaccharide decomposition and sugar acid formation in Au/CNT-N system were higher,while the corresponding activation energy was lower than in Au/CNT-O system.DFT calculation revealed that the mechanism of glucose oxidation to gluconic acid involves the adsorption and activation of O_(2),adsorption of glucose,dissociation of the formyl C-H bond and formation of O-H bond,and formation and desorption of gluconic acid.The activation energy barrier for the glucose oxidation over Au/CNT-N is lower than that of Au/CNT-O.The nitrogen-containing functional groups are more beneficial for accelerating monosaccharide oxidation and enhancing sugar acid selectivity than oxygen-containing functional groups.This work presents a useful guidance for designing and developing highly active catalysts for producing high-value-added chemicals from biomass.

关键词： Surface functionalization Base-free oxidation Sugar acid Kinetic study DFT calculation

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Thermoelectric generator based on anisotropic wood aerogel for low-grade heat energy harvesting

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Journal of Materials Science & Technology 2022年第25期120卷 150-158页

作者： Xuan Zhao Zehong Chen Hao Zhuo Yijie Hu Ge Shi Bing Wang Haihong Lai Sherif Araby Wenjia Han Xinwen Peng Linxin Zhong State Key Laboratory of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510641China Department of Mechanical and Aerospace Engineering Nazarbayev University53 Kabanbay Batyr AvenueNur-SultanKazakhstan State Key Laboratory of Bio-based Material and Green Papermaking Qilu University of TechnologyJinan 250353China

Thermoelectric generators(TEGs)have received increasing attention due to their potential to harvest low-grade heat energy(<100℃ )and provide power for the Internet of Things(IoT)and wearable electronic devices.Herein,a wood-based ordered framework is used to fabricate carbon nanotube/poly(3,4-ethylenedioxythiophene)(CNT/PEDOT)wood aerogel for TEG.The prepared CNT/PEDOT wood aerogel with an anisotropic structure exhibits a low thermal conductivity of 0.17 W m^(−1)K^(−1)and is advantageous to develop a sufficient temperature gradient.Meanwhile,CNT/PEDOT composites effectively decouple the relationship between the Seebeck coefficient and electrical conductivity by energy filtering effect to enhance thermoelectric(TE)output properties.The vertical TEG assembled by the CNT/PEDOT wood aerogels reveals an output power of 1.5μW and a mass-specific power of 15.48μW g^(−1)at a temperature difference of 39.4 K.Moreover,the layered structure renders high compressibility and fatigue resistance.The anisotropic structure,high mechanical performance,and rapid thermoelectric response,enabling the TEG based on CNT/PEDOT wood aerogel offer opportunities for continuous power supply to low-power electronic devices.

关键词： Wood Nano cellulose Energy harvesting Wearable devices Thermoelectric generator

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Preface to the Special Issue on Fengyun Meteorological Satellites: Data, Application and Assessment

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Advances in Atmospheric Sciences 2021年第8期38卷 1265-1266页

作者： peng ZHANG Jun YANG Jinsong WANG xinwen YU Fengyun Meteorological Satellite Innovation Center National Satellite Meteorological CenterChina Meteorological AdministrationBeijing 100081China China Meteorological Administration Beijing 100081China

Humans have a more than sixty-year history of observing Earth from space beginning after the launch of the first meteor-ological satellite,Television Infrared Observation Satellite(TIROS),in 1960.Satellite observations have transformed the way scientists observe and study Earth(Ackerman et al.,2019).With the progress of satellite data assimilation in the 1990s,modern Numerical Weather Prediction(NWP)became deeply tied to global satellite observations(Eyre et al.,1993).Scient-ists expect that meteorological satellites will play a more important role in future Earth Science studies.

关键词： Earth Satellite meteorological

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A Free-Standing Lignin Derived Hollow Carbon Nanofiber as Highly Efficient Oxygen Reduction Reaction for Flexible Zn-air battery

A Free-Standing Lignin Derived Hollow Carbon Nanofiber as Hi...

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中国化学会第三届中国能源材料化学研讨会

作者： Lei,Zhang Linxin,Zhong xinwen,peng Runcang Sun State Key Laboratory of Pulp and Paper Engineering South China University of Technology Beijing Key Laboratory of Lignocellulosic Chemistry Beijing Forestry University

The use of lignin as a precursor for the synthesis of materials is nowadays considered very interesting from a sustainability standpoint.A novel biomass-based nitrogen-doped free-standing hollow carbon fibrous was fab...

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