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Theoretical Exploration of Alloying Effects on Stabilities and Mechanical Properties ofγʹPhase in Novel Co–Al–Nb-Base Superalloys

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1238-1248页

作者： Guan-Cheng Gu Zhao-Jing Han Ze-Yu Chen Zhao-Xuan Li Sheng-Bao Xia Zheng-Ning Li Hua Jin Wei-Wei Xu xing-jun liu Shenzhen Research Institute of Xiamen University School of Aerospace EngineeringXiamen UniversityXiamen361005China Institute of Materials Genome and Big Data Harbin Institute of TechnologyShenzhen518055China

The new developedγ/γʹCo–Al–Nb-base alloys show great potentials as high-temperature ***,finding appropriate compositions to improve performance of alloys still poses a great challenge to the development of Co–Al–Nb-base *** by the lack of alloying effects on fundamental properties of criticalγʹphase,we systematically performed a theoretical investigation on the effect of alloying elements TM(TM:Ti,V,Cr,Zr,Mo,Ta,W,Re,and Ru)on phase stabilities and mechanical properties of L1_(2)-typeγʹ(Co,Ni)_(3)(Al,Nb).By analyzing the stability ofγʹphase with respect to its competitive B2 and D0_(19) phases,the results shown that Ti,V,and Cr enhance the L1_(2) stability and widen the L1_(2)–D0_(19) energy barrier,in which V yields the maximum *** analysis of electronic structure indicated that the alternation of valence electrons at fermi level would be the atomic origin for doping TM inγʹ*** calculated results of mechanical properties shown that V and Cr are expected to be optimal dopant for enhancing the strength and the ductility ofγʹ*** addition of Ta is also beneficial for enhancing the strength at the slight expense of ductility ofγʹ*** drawing the mechanical maps,the preferred composition range for the phases with desired properties is roughly demarcated in theory for the multi-addition of V/Cr and V/Ta inγʹ*** findings would be useful for optimizing the performance of novelγ/γʹCo–Al–Nb-base superalloys.

关键词： Co-Al-Nb-base superalloys γ/γʹdual-phase Phase stability Mechanical properties First-principle methods

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Lepton-Flavor Violating Processes li → ljγ in Topcolor-Assisted Technicolor Models

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Communications in Theoretical Physics 2002年第10期38卷 461-464页

作者： YUE Chong-xing XU Qing-jun liu Guo-Li CCAST World Laboratory P.O. Box 8730 Beijing 100080 China College of Physics and Information Engineering Henan Normal University Xinxiang 453002 China College of Physics and Information Engineering Henan Normal University Xinxiang 453002 China College of Physics and Information Engineering Henan Normal University Xinxiang 453002 China

We consider the lepton-flavor violating (LFV) processes li → ljγ in the framework of topcolor-assistedtechnicolor (TC2) models. We find that the new gauge boson Z' predicted by TC2 models can give significantlycontributions to these processes via the flavor-changing couplings Z'lilj. The present experimental bound on the LFVprocess μ→ eγ gives severe constraints on the TC2 models. Using other experimental constraints on the Z' mass Mz,we obtain constraints on the lepton mixing factors KTμ and KTe. The future LFV experiments will probe into TC2models.

关键词： lepton flavor, topcolor-assisted technicolor (TC2)

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Microstructure and properties of gradient nitrided layer on Ti6Al4V alloys

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Rare Metals 2023年第2期42卷 651-663页

作者： Feng Yang Kun-Mao Li xing-jun liu Hong Sun Cui-Ping Wang College of Materials and Fujian Key Laboratory of Materials Genome and Xiamen Key Laboratory of High Performance Metals and Materials Xiamen UniversityXiamen361005China School of Materials and Architectural Engineering Guizhou Normal UniversityGuiyang550001China Bio-Applications and Systems Engineering Tokyo University of Agriculture and TechnologyTokyo184-8588Japan

The vacuum electromagnetic induction nitriding technology was applied to prepare a gradient nitrided layer on the surface of a Ti6Al4V alloy,which possesses TiN andα-Ti(N)***,transmission electron microscopy was conducted to confirm the presence of numerous high-density stacking faults caused by TiN and Ti_(2)N phases distributed on the surface of the alloy,along with a large number of basal stacking faults inside.A highdensity stacking fault led to serious distortion of lattice *** and numerous edge dislocations caused by defects were observed in the subsurface *** the surface layer,the Vickers hardness reached HV_(0.25)1211.30and the residual compressive stress increased,while the nano-hardness increased to 14.07 from 5.31 GPa in the *** micrometre scratch test results indicated that the plasticity and hardness of the nitrided layer changed in a *** 50-μm effective hardened layer depth and surface compressive stress of the Ti6Al4V alloy were enhanced by the stacking faults.

关键词： Ti6Al4V Induction nitriding Gradient layer High-density dislocation Strengthening mechanism

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一种能温和产氢且具有高活性保持能力的Al-Bi-Zn基复合粉体

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Transactions of Nonferrous Metals Society of China 2024年第5期34卷 1427-1440页

作者：王翠萍余方拯黄岩王明帅邓睿郭毅慧张锦彬杨水源刘兴军厦门大学材料学院福建省表界面工程与高性能材料重点实验室厦门361005 厦门大学厦门市高性能金属材料重点实验室厦门361005 哈尔滨工业大学材料基因与大数据研究院深圳518055 深圳铝基水解制氢材料研发工程研究中心深圳518055

通过相图计算和气体雾化的方法,设计并制备Al-10Bi-7Zn和Al-10Bi-7Zn-1.5X (X:Cu, Fe, Ni)(质量分数,%)复合粉体。研究Cu、Fe和Ni对Al-Bi-Zn基复合粉体水解制氢性能的影响。通过X射线衍射(XRD)和扫描电子显微镜(SEM)以及能量色散谱(EDS... 详细信息

通过相图计算和气体雾化的方法,设计并制备Al-10Bi-7Zn和Al-10Bi-7Zn-1.5X (X:Cu, Fe, Ni)(质量分数,%)复合粉体。研究Cu、Fe和Ni对Al-Bi-Zn基复合粉体水解制氢性能的影响。通过X射线衍射(XRD)和扫描电子显微镜(SEM)以及能量色散谱(EDS)分析对粉体的组成和形貌进行表征。水解制氢性能测试结果表明,添加Cu、Fe或Ni可以改变Al-10Bi-7Zn三元合金复合粉体的制氢速率,并且提高其抗氧化性能。在四元复合粉体体系中,Al-10Bi-7Zn-1.5Ni表现出最佳的制氢性能,在60℃下与蒸馏水反应时,500 min内的产氢率为75.3%(954.1 m L/g),在储存7 d后(30℃,相对湿度60%),1500 min内保持57.9%(733.7 m L/g)的产氢率。此外,机理研究表明,在Al-Bi-Zn基复合粉体中添加Cu、Fe或Ni可以稳定Al基体,抑制复合粉体在空气中的开裂,保持粉体的高活性。

关键词：铝合金气雾化水解反应制氢抗氧化

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Primary Study on Effects of New Rare Earth Agro-Materials on Potato

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Journal of Rare Earths 2004年第Z1期22卷 265-268页

作者： Yang Qifeng Mao Wanhu Wang Jiachen xing Guo Yang jun liu Xiangsheng Gansu Provincial Agro-Technique Extension Centre Lanzhou 730020 China Gansu Provincial Agro-Technique Extension Centre Lanzhou 730020 China National Rare Earth Centre for Agriculture Beijing 100088 China DingXi County Agro-Technology Extension Centre Gansu 730008China National Rare Earth Centre for Agriculture Beijing 100088 China National Rare Earth Centre for Agriculture Beijing 100088 China

Using common phosphate as a check, we studied the growth and yield of potato by new rare earth agro-materials including rare earth phosphate (base fertilizer), rare earth whole plant nutrient fertilizer, and amino acid chelated rare earth ( top dressing), which were used in a single or mixed way in Dingxi city, Gansu *** results are as follows that ( 1 ) After using new rare earth materials, the plant height increases by 0.4 ～ 5.6 cm and the ripen period is delayed by 4 ～ 9 d.(2) They can improve the potato economic characteristics, enhance productivity, decrease black leg and late *** disease index is decreased by 1.6% ～ 10.6%, single plant potato number increases by 0.3 ～ 0.5, and single plant yield increases by 80 g ～ 130 g.(3) The effect of increased yield is significant, and mixed use is better than single *** the single material treatments, rare earth phosphate is the best, rare earth whole plant nutrient fertilizer and amino acid chelated rare earth are the second, and the increased rate are 14.5%, 8.4%, 9.2% so the material mixture-rare earth phosphate mixed of rare earth whole plant nutrient fertilizer or with amino acid chelated rare earth is economically useable, and increase rate are 25.2% and 24.4% compared with common phosphate.

关键词： potato economic characteristics diseases yield economic useable

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Enhanced thermoelectric performance of n-type TiCoSb halfHeusler by Ta doping and Hf alloying

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Rare Metals 2021年第1期40卷 40-47页

作者： Rui-Fang Wang Shan Li Wen-Hua Xue Chen Chen Yu-Mei Wang xing-jun liu Qian Zhang School of Materials Science and Engineering Institute of Materials Genome and Big DataHarbin Institute of TechnologyShenzhen 518055China Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of ScienceBeijing 100190China

The p-type TiCoSb-based half-Heuslers are widely studied due to the good electrical transport properties after hole doping,while the pristine TiCoSb is intrinsically *** is thus desired to obtain a comparable n-type counterpart through optimization of electron *** this work,n-type Ti_(0.9-x)HfxTa_(0.1)CoSb half-Heuslers were fabricated by arc melting,ball milling,and spark plasma *** optimized carrier concentration,together with a decreased lattice thermal conductivity,was obtained by Ta doping at the Ti site,leading to a peak figure of merit(ZT)of 0.7 at 973 K in Ti_(0.9)Ta_(0.1)-*** further alloying Hf at the Ti site,the lattice thermal conductivity was significantly reduced without deteriorating the power *** a result,a peak ZT of 0.9 at 973 K and an average ZT of 0.54 in the temperature range of 300-973 K were achieved in Ti_(0.6)Hf_(0.3)Ti_(0.1)*** work demonstrates that n-type TiCoSb-based halfHeuslers are promising thermoelectric materials.

关键词： Thermoelectric Half-Heusler N-type TiCoSb

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Phase equilibria in Co-Ti-Re ternary system

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稀有金属:英文版 2023年第8期42卷 2736-2746页

作者： Ling-Ling Li Cui-Ping Wang Shui-Yuan Yang Jia-Jia Han Yong Lu Jin-Bin Zhang xing-jun liu College of Materials and Fujian Provincial Key Laboratory of Materials Genome Xiamen UniversityXiamen 361005China College of Materials Science and Engineering Guangdong Ocean UniversityYangjiang 529500China Xiamen Key Laboratory of High-Performance Metals and Materials Xiamen UniversityXiamen 361005China School of Materials Science and Engineering Institute of Materials Genome and Big DataHarbin Institute of TechnologyShenzhen 518055China

The phase equilibria in the Co-Ti-Re ternary system at 800,1000,1100 and 12000C were studied combined with electron probe microanalyzer(EPMA),X-ray diffraction(XRD),scanning electron microscope(SEM)and transmission electron microscope(TEM).The new phaseτwith a large solubility was discovered at all four isothermal sections,and its structure still needs a further study.A large solubility of Re in the CoTi phase was *** solubility of Re in the Co_(3)Ti phase is6.1%at 800℃,8.7%at 1000℃and 7.7%at 1100℃.The present work could be significant for alloy design of Co-based alloys and thermodynamic analysis of the Co-TiRe ternary system.

关键词： Isothermal section Phase equilibria Co-Ti-Re Co-based supperalloys

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Tuning heterogeneous microstructures to enhance mechanical properties of nano-TiN particle reinforced Haynes 230 composites by laser powder bed fusion

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Rare Metals 2024年第9期43卷 4548-4565页

作者： Wen-Jie liu Hui Li Qian-xing Yin He-jun Du School of Power and Mechanical Engineering Wuhan UniversityWuhan 430072China The Institute of Technological Sciences Wuhan UniversityWuhan 430072China School of Mechanical&Aerospace Engineering Nanyang Technological UniversitySingapore 639798Singapore

Laser powder bed fusion(LPBF)is considered to be one of the most promising additive manufacturing technologies for producing components with geometries and high geometrical precision that are unattainable by traditional *** superalloy exhibits exceptional mechanical and high-temperature performances,rendering it a prime candidate for advanced aero-engine *** the high demand for LPBF-manufactured superalloys,the superalloy is one of the materials manufactured difficultly by LPBF due to their large laser absorptivity fluctuation,poor molten pool stability and sharp temperature ***,superalloys are characterized by severe pores,undesirable coarse columnar grains and poor mechanical *** this work,the effect of nano-TiN particles on defects,molten pool characteristics and microstructure and performance of the composites were *** 4.5 wt%TiN/Haynes230 samples exhibited exceptional nanohardness and elastic modulus with maximum values reaching 5.53 GPa and 240.03 GPa,*** superior mechanical properties were attributed to the combined effects of spatter and gas pore inhibition,grain refinement and duplex nanophases ***,the stability of molten pool was enhanced,and spatter was effectively suppressed by adding nano-TiN particles,while grain refinement and columnar to equiaxed transitions were ***,the matrix exhibited a high dislocation density due to a significant hindrance of dislocation movement caused by massive nano-phases(e.g.,TiN and M_(23)C_(6)),resulting in the formation of extensive dislocation tangles and *** work offers novel insights into the role of nanoparticles reinforced superalloy composites by LPBF.

关键词： Composites Laser powder bed fusion Molten pool characteristics Microstructure Mechanical properties

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A hybrid WUDT-NAFnet for simultaneous source data deblending

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Petroleum Science 2024年第3期21卷 1649-1659页

作者： Chao-Fan Ke Shao-Huan Zu jun-xing Cao Xu-Dong Jiang Chao Li xing-Ye liu Key Laboratory of Earth Exploration and Information Technology of Ministry of Education Chengdu University of Technology State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Chengdu University of Technology College of Geophysics Chengdu University of Technology

Simultaneous source technology,which reduces seismic survey time and improves the quality of seismic data by firing more than one source with a narrow time interval,is compromised by the massive blended ***,deblending algorithms have been developed to separate this ***,deep learning(DL)has been proved its great potential in suppressing the *** most popular DL method employs neural network as a filter to attenuate the blended noise in an iterative estimation and subtraction framework(IESF).However,there are still amplitude distortion and blended noise residual problems,especially when dealing with weak signal submerged in strong *** address these problems,we propose a hybrid WUDT-NAFnet,which contains two *** first network is a wavelet based U-shape deblending transformer network(WUDTnet),incorporated into IESF as a robust regularization term to iteratively separate the blended *** second network is a nonlinear activate free network(NAFnet)designed to recover the event amplitude and further suppress the weak noise residual in *** the hybrid network,the blended noise can be separated purposefully and *** using synthetic and field seismic data demonstrate that the WUDTNAFnet outperforms traditional curvelet transform(CT)based method and the deblending transformer(DT)model in terms of ***,for field applications,the data augmentation method of bicubic interpolation is applied to mitigate the feature difference between synthetic and field ***,the trained network exhibits strong signal preservation ability in numerical field example without requiring additional training.

关键词： Simultaneous-source Deblending Deep learning Transformer

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Superatomic Ag_(58) nanoclusters incorporating a [MS_(4)@Ag_(12)]^(2+)(M = Mo or W) kernel show aggregation-induced emission

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Chinese Chemical Letters 2024年第10期35卷 452-456页

作者： jun-Jie Fang Zheng liu Yun-Peng Xie xing Lu State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China

In core-shell silver nanoclusters,the control of core structure presents a more formidable challenge compared to that of the shell ***,we report the successful synthesis and characterization of four distinct silver thiolate nanoclusters[MS_(4)@Ag_(12)@Ag_(46)S_(24)(dppb)_(12)](M=Mo or W),each incorporating a cup-like[MS_(4)@Ag_(12)]^(2+)*** nanoclusters were meticulously prepared using(NH_(4))2Mo S4or(NH_(4))_(2)WS_(4)as both a template and a controlled source of ***,we have observed a unique configuration within these eight-electron superatomic Ag_(58) nanoclusters,where the zerovalent Ag atoms reside exclusively within the inner[MS_(4)@Ag_(12)]^(2+)*** stands in contrast to other superatomic clusters possessing an Ag(0)***,the introduction of phenyl-containing compounds during the synthesis process induced a transformation in the space group symmetry from C_(2)/c to I 4ˉ.This transformative effect was found to originate from the interplay between adjacent 1,4-bis(diphenylphosphino)butane(dppb)ligands,which facilitated enhanced emission through aggregationinduced intermolecular interactions,specifically C-H···π***,our findings contribute substantively to the understanding of the intricate relationship between nanocluster structures and their corresponding properties,shedding light on the crucial roles played by templates and diphosphine ligands in this context.

关键词： Superatom Silver nanocluster Template synthesis Photoluminescence Aggregation-induced emission

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