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Frontiers of Chemical Science and Engineering 2022年第7期16卷 1090-1100页

作者： Yong-Hui Wen Long Cheng Tian-Ming Xu xing-hai liu Ning-Jie Wu College of Chemical Engineering Zhejiang University of TechnologyHangzhou 310014China Zhejiang Base of National Southern Pesticide Research Centre Zhejiang Research Institute of Chemical IndustryHangzhou 310023China

Twenty six novel pyrimidin-4-amine derivatives containing the 1,2,4-oxadiazole motif were synthesized. Their chemical structures were confirmed by ^(1)H nuclear magnetic resonance (NMR), ^(13)C NMR, and high-resolution mass spectrography. The insecticidal activity results indicated that some of them possessed excellent insecticidal activity (100%) against Mythimna separate, especially for compounds 6d, 6f, 6o, 6w, 6y and 6z. These compounds exhibited no activity against the insects Aphis medicagini and Tetranychus cinnabarinus. The structure- insecticidal activity relationships are discussed. Density functional theory analysis can potentially be used to design more active compounds. These results provide useful insecticide design information for further optimization.

关键词： synthesis pyrimidin-4-amine derivatives 1,2,4-oxadiazole insecticidal activity structure-activity relationship

Needs and challenges of optical atmospheric monitoring on the background of carbon neutrality in China

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Frontiers of Environmental Science & Engineering 2024年第6期18卷 49-62页

作者： Wenqing liu Chengzhi xing Anhui Institute of Optics and Fine Mechanics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 23001China

The achievement of the targets of coordinated control of PM2.5 and O3 and the carbon peaking and carbon neutrality depend on the development of pollution and greenhouse gas monitoring *** monitoring technology,based on its technical characteristics of high scalability,high sensitivity and wide-targets detection,has obvious advantages in pollution/greenhouse gases monitoring and has become an important direction in the development of environmental monitoring *** present,a system of environmental optical monitoring technology with differential optical absorption spectroscopy(DOAS),cavity ring-down spectroscopy(CRDS),light detection and ranging(LIDAR),laser heterodyne spectroscopy(LHS),tunable diode laser absorption spectroscopy(TDLAS),fourier transform infrared spectroscopy(FTIR)and fluorescence assay by gas expansion(FAGE)as the main body has been ***,with the promotion of“reduction of pollution and carbon emissions”strategy,there have been significant changes in the sources of pollution/greenhouse gases,emission components and emission concentrations,which have put forward new and higher requirements for the development of monitoring *** the future,we should pay more attention to the development of new optical monitoring techniques and the construction of stereoscopic monitoring system,the interdisciplinarity(among mathematics,physics,chemistry and biology,etc.),and the monitoring of greenhouse gases and research on atmospheric chemistry.

关键词： Pollution Greenhouse gas Optical atmospheric monitoring Needs and challenges

An improved analysis method for assessing the nuclear-heating impact on the stability of toroidal field magnets in fusion reactors

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Nuclear Science and Techniques 2024年第6期35卷 163-176页

作者： Yu-Dong Lu Jin-xing Zheng Xu-Feng liu Huan Wu Jian Ge Kun Xu Ming Li hai-Yang liu Lei Zhu Fei liu Institute of Plasma Physics Hefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China

The superconducting magnet system of a fusion reactor plays a vital role in plasma confinement,a process that can be dis-rupted by various operational factors.A critical parameter for evaluating the temperature margin of superconducting magnets during normal operation is the nuclear heating caused by D-T *** study investigates the impact of nuclear heat-ing on a superconducting magnet system by employing an improved analysis method that combines neutronics and thermal *** the magnet system,toroidal field(TF)magnets are positioned closest to the plasma and bear the highest nuclear-heat load,making them prime candidates for evaluating the influence of nuclear heating on *** enhance the modeling accuracy and facilitate design modifications,a parametric TF model that incorporates heterogeneity is established to expedite the optimization design process and enhance the accuracy of the computations.A comparative analysis with a homogeneous TF model reveals that the heterogeneous model improves accuracy by over 12%.Considering factors such as heat load,magnetic-field strength,and cooling conditions,the cooling circuit facing the most severe conditions is selected to calculate the temperature of the *** selection streamlines the workload associated with thermal-hydraulic *** approach enables a more efficient and precise evaluation of the temperature margin of TF ***,it offers insights that can guide the optimization of both the structure and cooling strategy of superconducting magnet systems.

关键词： Superconducting magnet Nuclear heating Neutronics Thermal hydraulics

Tumor microenvironment-responsive arsenic-loaded layered double hydroxides film with synergistic anticancer and bactericidal activity

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Rare Metals 2024年第3期43卷 1207-1221页

作者： Shun xing Dong-Hui Wang hai-Feng Zhang Li-Dan liu Cheng-Ce Li Chao Wei Jun-Yu liu Nai-Jian Ge Xuan-Yong liu State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of CeramicsChinese Academy of SciencesShanghai200050China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing100049China Intervention Center Eastern Hepatobiliary Surgery HospitalThe Third Affiliated Hospital of Naval Medical UniversityShanghai200438China School of Health Sciences and Biomedical Engineering Hebei University of TechnologyTianjin300130China

Malignant obstruction makes gallbladder cancer have a high mortality ***-titanium alloy(nitinol)stents are commonly used as a local intervention to maximize patient survival time,but the stents lack antitumor and antibacterial capacity and are vulnerable to secondary ***-based drugs show good therapeutic promise against gallbladder *** meet clinical *** layered double hydroxides(LDHs)film is constructed on the nitinol,whose arsenite loading amounts rose by 60%after simple heat treatment compared with the conventional anion-exchange *** addition,calcination promotes the dissolution of nickel ions from the LDHs lattice,resulting in a powerful synergistic killing effect on tumor cells together with the released *** importantly,the calcined arsenic-loaded LDHs are sensitive to the acidic microenvironment of tumor tissues,which presents a much lower arsenic and nickel release amount in the normal tissues,guaranteeing its ***,the vertically sharp LDHs nanosheets can synergize with arsenic to achieve effective physical cleavage and chemical killing of adherent and planktonic *** short,we attempt to use arsenic drugs for local interventions and reasonably avoid their toxic side effects,which provides a new design idea for nitinol stents applied in the treatment of gallbladder cancer.

关键词： Nitinol Layered double hydroxides Arsenic Gallbladder cancer

Binding property of Al/Mg/Al thin plates fabricated by one-pass hot rolling with different reduction ratios,temperatures and annealing treatments

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Rare Metals 2018年第2期37卷 136-142页

作者： Ai-Li Wei xing-hai liu Li Dong Wei Liang School of Materials Science and Engineering Taiyuan University of Technology

In this study, Al-Mg-Al trilaminated thin plates were fabricated by one-pass hot rolling to improve the processing capacity and bonding strength of magne- sium alloy plates. The effects of processing parameters were investigated. The results show that the optimal bonding strength is up to 20 MPa with a reduction ratio of 40 % and rolling temperature of 400 ℃, superior than that in other one-pass rolling studies with regard to thin lami- nated plates. In addition, a favorable property is achieved with the annealing temperature of 250-300 ℃ or annealing time of 1.5 h. When the annealing temperature exceeds 300 ℃ or annealing time exceeds 1.5 h, respectively, the bonding strength of Al/Mg/Al plate decreases. The scan- ning electron microscopy （SEM） and energy-dispersive spectroscopy （EDS） analyses suggest that the appearance of thin diffusion layers between Al and Mg interfaces is helpful to improve the bonding strength, while the presence of thick diffusion layer would reduce the bonding strength greatly.

关键词： Al-Mg-Al thin plates One-pass rolling Bonding strength Mesophase Microstructure

Design and synthesis of thiol-terminated imidothioether oligomer as thermally latent hardener and modifier for high-performance epoxy/thiol thermosets

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Science China Chemistry 2024年第2期67卷 632-641页

作者： xing liu Jianjun Zhou Shumei liu Jianqing Zhao School of Materials Science and Engineering South China University of TechnologyGuangzhou510640China Key Lab Guangdong High Property&Functional Polymer Materials Key Laboratory of Polymer Processing EngineeringMinistry of EducationGuangzhou510640China

Conventional base-catalyzed epoxy/aliphatic thiol systems have a poor storage stability,and are impossible to be one-pot systems.A widely accepted solution is to use the latent catalysts,which are usually insoluble anionic initiators sensitive to impurities and moisture,and have many limitations in practical *** this work,a soluble thiol-terminated imidothioether oligomer(TPI) was synthesized and used as a latent hardener and modifier to prepare one-pot epoxy/thiol systems without the latent *** latent behavior and curing mechanism of epoxy systems(EP/TPI series),consisted of bisphenol A diglycidyl ether(DGEBA),pentaerythritol tetrakis(mercaptoacetate)(PETMP) and TPI,were *** thiol exchange reaction between TPI and PETMP preceded the curing reaction of DGEBA,and produced aromatic thiols,which were unreactive at ambient conditions and reacted with DGEBA to form the thermosets at temperatures above 130 ℃.At the loading of 24.4 wt%TPI,the epoxy system(EP/TPI-3) had a shelf life of 13 days and was completely cured within 20 min at 180 ℃.Meanwhile,the catalyst-free curing process of EP/TPI-3 system was insensitive to impurities and ***,the thermal and mechanical properties of EP/TPI-3 thermoset were simultaneously improved,thereinto,the glass transition temperature,Young's modulus and ultimate tensile strength were increased by 16.7 ℃,12.9%,and 13.6%,respectively,compared with those of the commercial DGEBA/PETMP *** work shows that TPI has the potential to be a powerful alternative to commercial latent catalysts,and EP/TPI thermosets with high performance have broad application prospects.

关键词： thiol-terminated imidothioether oligomer epoxy systems thiol exchange reaction thermal latency high performance

Ancient mitochondrial genome depicts sheep maternal dispersal and migration in Eastern Asia

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Journal of Genetics and Genomics 2024年第1期51卷 87-95页

作者： liu Yang xing Zhang Yaning Hu Piao Zhu Hua Li Zhenyu Peng hai Xiang Xinying Zhou xingbo Zhao National Engineering Laboratory for Animal Breeding Key Laboratory of AnimalGeneticsBreeding and ReproductionMinistry of Agriculture and Rural AffairsCollege of Animal Science and TechnologyChina Agricultural UniversityBeijing 100193China Guangdong Provincial Key Laboratory of Animal Molecular Design and Precise Breeding School of Life Science and EngineeringFoshan UniversityFoshanGuangdong 528225China State Key Laboratory of Agricultural Genomics BGI-ShenzhenShenzhenGuangdong 518083China Key Laboratory of Vertebrate Evolution and Human Origins Institute of Vertebrate Paleontology and PaleoanthropologyChinese Academy of SciencesBeijing 100044China

Sheep have been one of the most important groups of animals since ancient ***,the knowledge of their migration routes and genetic relationships is still poorly *** investigate sheep maternal migration histories alongside Eurasian communications routes,in this study,we obtain mitochondrial genomes(mitogenomes)from 17 sheep remains in 6 Chinese sites and 1 Uzbekistan site dated 4429–3100 years before present(BP).By obtaining the mitogenomes from the sheep(4429–3556 BP)found in the Tongtian Cave site in Xinjiang,Altai region of northwest China,our results support the emergence of haplogroup C sheep in Xinjiang as early as 4429–3556 *** combined phylogenetic analyses with extant ancient and modern sheep mitogenomes suggest that the Uzbekistan-Altai region may have been a migration hub for early sheep in eastern *** least two migration events have taken place for sheep crossing Eurasia to China,one passing by Uzbekistan and Northwest China to the middle and lower reaches of the Yellow River at approximately 4000 BP and another following the Altai region to middle Inner Mongolia from 4429 BP to 2500 ***,this study provides further evidence for early sheep utilization and migration patterns in Eastern Asia.

关键词： Sheep Ancient DNA Eastern Asia Mitochondrial genome Migration Altai

Damping capacity of Fe_(83)Ga_(17) magnetostrictive alloy under magnetic field

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Rare Metals 2024年第1期43卷 402-409页

作者： Shao-Wen Yan xing Mu Bing-Jie liu Li-Hong Xu Shi-hai Guo Yan Qi Hong-Ping Zhang Department of Functional Material Research Central Iron and Steel Research InstituteBeijing 100081China

The damping performance of Fe_(83)Ga_(17) alloys has been investigated in the static magnetic field (H). The results demonstrate that the damping peak value can be adjusted between 0.020 and 0.085 under the magnetic f... 详细信息

关键词： alloy magnetic alloys

High Permeability in Broadband of Co-sputtered [Fe-Fe_(20)Ni_(80)/Cr]_(n) Multilayer Films

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Journal of Wuhan University of Technology(Materials Science) 2024年第2期39卷 410-416页

作者：罗创钰 liu xing 王峰李维 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China College of Materials and Chemical Engineering Hezhou UniversityHezhou 542899China

To achieve high microwave permeability in wide-band for the micron-thick magnetic films,[Fe-Fe_(20)Ni_(80)/Cr]_(n) multilayer structure was proposed by co-sputtering Fe and FeNi to form the magnetic layers and Cr to form the *** multilayer structure contributes to the high permeability by reducing the coercivity and diminishing out-of-plane *** maximum imaginary permeability of[Fe-Fe_(20)Ni_(80)/Cr]_(n) multilayer film reaches a large value of 800 at 0.52 GHz even though its overall thickness exceeds 1μ***,the magnetic resonance frequency of the multilayer film can be modulated from 0.52 to 1.35 GHz by adjusting the sputtering power of Fe from 0 to 86 W,and its bandwidth for μ’’>200(Δf) is as large as 2.0 *** desirable broad Δf of magnetic permeability,which can be well fitted by the Landau-Lifshitz-Gilbert equations,is due to dual magnetic resonances originated from double magnetic phases of Fe and FeNi that are of different saturation *** micron-thick multilayer films with high permeability in extended waveband are promising candidate for electromagnetic noise suppression application.

关键词： magnetron sputtering multiple magnetic resonance high permeability electromagnetic noise suppression

Advancements in Remote Sensing Image Dehazing: Introducing URA-Net with Multi-Scale Dense Feature Fusion Clusters and Gated Jump Connection

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Computer Modeling in Engineering & Sciences 2024年第9期140卷 2397-2424页

作者： Hongchi liu xing Deng haijian Shao School of Computer Jiangsu University of Science and TechnologyZhenjiang212003China Department of Electrical and Computer Engineering University of NevadaLas Vegas89119USA

The degradation of optical remote sensing images due to atmospheric haze poses a significant obstacle,profoundly impeding their effective utilization across various *** methodologies have emerged as pivotal components of image preprocessing,fostering an improvement in the quality of remote sensing *** enhancement renders remote sensing data more indispensable,thereby enhancing the accuracy of target *** defogging techniques based on simplistic atmospheric degradation models have proven inadequate for mitigating non-uniform haze within remotely sensed *** response to this challenge,a novel UNet Residual Attention Network(URA-Net)is *** paradigmatic approach materializes as an end-to-end convolutional neural network distinguished by its utilization of multi-scale dense feature fusion clusters and gated jump *** essence of our methodology lies in local feature fusion within dense residual clusters,enabling the extraction of pertinent features from both preceding and current local data,depending on contextual *** intelligently orchestrated gated structures facilitate the propagation of these features to the decoder,resulting in superior outcomes in haze *** validation through a plethora of experiments substantiates the efficacy of URA-Net,demonstrating its superior performance compared to existing methods when applied to established datasets for remote sensing image *** the RICE-1 dataset,URA-Net achieves a Peak Signal-to-Noise Ratio(PSNR)of 29.07 dB,surpassing the Dark Channel Prior(DCP)by 11.17 dB,the All-in-One Network for Dehazing(AOD)by 7.82 dB,the Optimal Transmission Map and Adaptive Atmospheric Light For Dehazing(OTM-AAL)by 5.37 dB,the Unsupervised Single Image Dehazing(USID)by 8.0 dB,and the Superpixel-based Remote Sensing Image Dehazing(SRD)by 8.5 *** noteworthy,on the SateHaze1k dataset,URA-Net attains preeminence in overall performance,yieldi

关键词： Remote sensing image image dehazing deep learning feature fusion