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From waste to wealth:Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries

International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 464-475页

作者： Zhonghua Lu Jun Shen xin zhang Lingcong Chao Liang Chen Ding zhang Tao Wei Shoudong Xu College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024China College of Chemistry Taiyuan University of TechnologyTaiyuan 030024China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430205China School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China

Carbon materials are widely recognized as highly promising electrode materials for various energy storage system *** tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable *** this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances *** on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900H),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were ***,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of *** indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”*** work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR.

关键词： coal tar residue carbon materials anode potassium-ion batteries high value-added

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Staged dendrite suppression for high safe and stable lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第1期100卷 674-683页

作者： Jun Jiang Zhenjie Lu Yanwen Ding Shujun Liu Zhijie Qi Tian Tang Yunfan zhang Zhiyuan Ma Jingwen Sun Liang Xue Wenyao zhang Pan Xiong xin Wang Junwu Zhu Yongsheng Fu Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education Nanjing University of Science and Technology Jiangsu Pylon Battery Co.Ltd

The unavoidable dendrite growth and shuttle effect have long been stranglehold challenges limiting the safety and practicality of lithium-sulfur ***,we propose a dual-action strategy to address the lithium dendrite issue in stages by constructing a multifunctional surface-negatively-charged nanodiamond layer with high ductility and robust puncture resistance on polypropylene （PP） *** uniformly loaded compact negative layer can not only significantly enhance electron transmission efficiency and promote uniform lithium deposition,but also reduce the formation of dendrite during early deposition *** importantly,under the strong puncture stress encountered during the deterioration of lithium dendrite growth under limiting current,the high ductility and robust puncture resistance（145.88 MPa） of as-obtained nanodiamond layer can effectively prevent short circuits caused by unavoidable lithium *** Li||Li symmetrical cells assembled with nanodiamond layer modified PP demonstrated a stable cycle of over 1000 h at 2 mA cm-2with a polarization voltage of only 29.3 ***,the negative charged layer serves as a physical barrier blocking lithium polysulfide ions,effectively mitigating capacity *** improved cells achieved a capacity decay of only 0.042%per cycle after 700 cycles at 3 C,demonstrating effective suppression of dendrite growth and capacity attenuation,showing promising prospect.

关键词： Ductility

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Breaking the structural symmetry of active sites in zeolite imidazolate framework for enhanced CO2 photoreduction

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Science China Chemistry 2025年

作者： Yupeng Han Yayu Yan Qiaohong Li xin Wu Fei Wang Jian zhang State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences University of Chinese Academy of Sciences College of Chemistry Fuzhou University

Adjusting the structure and composition of active sites is a highly effective method for activating linear ***, precise control of interfacial chemistry within molecular-scale environments presents a significant challenge in heterogeneous catalysis. In our study, we present symmetry-broken Mo-O-Co triple-atom active sites within the hybrid zeolite imidazole framework HZIF-CoMo. These sites disrupt the electronic balance and create a weak built-in electric field, thus promoting photocatalytic CO2reduction. The CO yield over HZIF-CoMo is improved to 3.1 mmol g-1h-1, which is over four times higher than the parent cobalt-imidazole framework MAF-6-Co. Both experimental and theoretical studies indicate that electronic modulation through the symmetry-breaking Mo-O-Co moiety acts as an organizing knob to accelerate charge separation and result in more carriers participating in the catalytic reaction. This work provides important insights into optimizing site-related electronic structures for targeted photocatalytic reactions.

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Visible-light-responsive homologous heterostructure of oxynitrides constructed to boost charge separation and water splitting

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Science China Chemistry 2025年第01期 186-191页

作者： Hai Zou Yunfeng Bao Xueshang xin Yu Qi Tengfeng Xie Fuxiang zhang State Key Laboratory of Catalysis Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics Chinese Academy of Sciences School of Chemistry and Chemical Engineering Liaoning Normal University College of Chemistry Jilin University

Constructing type II heterostructures represents a widely recognized strategy for enhancing charge separation and photocatalytic efficiency,but it remains challenging to fabricate homologous heterostructures based on visible-light-responsive semiconductors,especially for popularly investigated （oxy）nitrides with low thermal ***,we synthesized a homologous heterostructure （denoted as YTON＿H） based on the oxynitrides of YTaO4-xNyand YTa *** heterostructure exhibits type II band structure alignment and intimate interface achieved through a magnesium （Mg） powder-assisted nitridation *** with widely reported heterologous heterostructures,the as-obtained YTON＿H homologous heterostructure could similarly exhibit enhanced charge separation as well as photocatalytic water splitting performance with respect to its counterparts(YTaO4-xNyand YTaON2).Meanwhile,detailed structural characterizations and spectroscopy analysis have been made to confirm the formation of heterostructure and promotion of spatial charge separation.

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层次型无线传感器网络节点布置方案的研究

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计算机工程与应用 2008年第35期44卷 112-114页

作者：蔡忠欣张华忠山东大学计算机科学与技术学院济南250101

对于大规模层次型的无线传感器网络,越靠近sink的节点,数据转发量越大,能量消耗速度越快,因此节点的密度分布状况对整个网络的生命期有着很大的影响。对层次型无线传感器网络的节点能耗分布状况和密度分布状况进行了分析,提出一种适合... 详细信息

对于大规模层次型的无线传感器网络,越靠近sink的节点,数据转发量越大,能量消耗速度越快,因此节点的密度分布状况对整个网络的生命期有着很大的影响。对层次型无线传感器网络的节点能耗分布状况和密度分布状况进行了分析,提出一种适合于大规模网络的节点布置方案。通过与均匀布置方案相比较,提出的方案能够使网络生命期得到很大的延长。

关键词：无线传感器网络层次型网络密度分布节点布置

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Polybenzimidazolium-reinforced polyimide separators to inhibit dendrites for high-security lithium-ion batteries

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Science China Chemistry 2025年

作者： Guohua Sun Jiaqi Cui Qingsong zhang Yisong Zhou xinluo Li Yingying zhang Zhanao zhang xin zhang Jiantao Fan Pengpeng Li Lianlong Hou Nanjun Chen Hebei Key Laboratory of Flexible Functional Materials School of Materials Science and Engineering Hebei University of Science and Technology State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical Technology Academy for Advanced Interdisciplinary Studies Southern University of Science and Technology State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University

Lithium dendrite formation poses a significant safety hazard in lithium-ion batteries（LIBs）, severely impeding their widespread adoption and further technological advancements. Here, we present a novel quaternized polybenzimidazolium（q-PBI） to armor polyimide（PI） nanofiber separator（q-PBI@PI）, in which the q-PBI containing lithiophilicity and anionphilicity sites serves as the multifunctional nano-layers to suppress the Li dendrite and reinforce the mechanical properties of PI nanofiber ***, the q-PBI@PI separator displays an unprecedented mechanical strength of 82.8 MPa, significantly outperforming previously reported PI nanofiber membranes（typically below 50.0 MPa）. Besides, we demonstrate that the q-PBI@PI separator simultaneously possesses low nucleation overpotential（59 mV） and exceptional average coulombic efficiency due to the suppression of Li dendrite. Importantly, q-PBI@PI-based Li||Li battery enables a stable Li plating-stripping at 1.0 m A cm-2for600 h. Attributing to these exceptional merits, the armored PI separator-based LIBs display remarkable specific capability and capacity retention. The density function theory calculations reveal that q-PBI is conducive to the desolvation of Li+and can immobilize Li+and PF6-ions near affinity sites of PI nanofibers for inhibiting the formation of Li dendrites. Our work paves a new avenue for the design of next-generation high-performing separators in LIBs.

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Multi-receptive field interaction network for shape from polarization

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Science China(Information Sciences) 2025年第1期 394-395页

作者： Yini PENG Rui LIU Zhiyuan zhang Zhongyuan WANG Jiayi MA xin TIAN Electronic Information School Wuhan University Computer Science School Wuhan University Wuhan Institute of Quantum Technology

Shape from polarization (SfP) method can use the polarization information in reflected light to estimate the surface normal of the target,which can further reconstruct the shape of the *** a simple image capture process,it can use low-cost equipment to meet a high precision imaging requirement,which can be used in remote scenes and other applications.

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Effect of Temperature on Expression of Glutamine Synthetase in Rice Plants

Effect of Temperature on Expression of Glutamine Synthetase ...

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中国植物生理学会全国学术年会暨成立40周年庆祝大会

作者： Lu Bin-bin Ou Ji-quan Zhou Zhong-xin Lin Qing-hua zhang Chu-fu (Key Laboratory of MOE for Plant Developmental Biology, Wuhan University, Wuhan 430072)

＜正＞ In higher plants, glutamine synthetase （GS） is a key enzyme for assimilating ammonium into organiccompounds. The expression of GS is regulated by development, nitrogen and light. Temperature is animportant factor that affects the development of plants, but it is rarely reported how temperature affect theexpression of GS in plant species. Lawlor has done some research work in wheat, and found that highertemperature can stimulate the activity of GS and the level of soluble proteins. Rice and wheat grow in differentenvironment, rice is suitable for the higher temperature, so it is very necessary and valuable for us to studythe effect of temperature on GS of rice *** seeds （Shanyou 64） were first surface sterilized and thenplaced in an incubator （30℃） for germination and were finally transplanted to the nylon net floating onnitrogen-containing nutrient solution. The seedlings were grown in an incubator with temperature about 30

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Thermally activated delayed fluorescence enhanced by macrocyclization

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Science China Chemistry 2025年

作者： Shuo Li Chenghao Zhu Lijun Mao xin zhang Zecong Ye Chunju Li Da Ma School of Pharmaceutical and Chemical Engineering & Institute for Advanced Studies Taizhou University School of Chemical Engineering and Light Industry Guangdong University of Technology Tianjin Key Laboratory of Structure and Performance for Functional Molecules Tianjin Normal University

Thermally activated delayed fluorescence (TADF) depends on reverse intersystem crossing (RISC) from the lowest triplet to the singlet excited state. Here, a macrocyclization strategy is developed to achieve TADF emission by promoting RISC. 5-(9Hcarbazol-9-yl) isophthalonitrile, a fluorescent molecule, is coupled with 1,4-dimethoxybenzene by methylene bridges to form a macrocycle with TADF emission. Experimental results and theoretical calculation indicate that the macrocyclization strategy contributes to RISC promotion and suppression of nonradiative decay, resulting in effective TADF emission transformed from prompt fluorescence. Three TADF luminophores are cyclized with the same strategy, and an enhanced TADF emission of up to3.8 folds is observed. The marriage of macrocycle chemistry and luminescent materials will provide new guidelines for designing efficient TADF materials.

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濒危药用植物缙云黄芩扦插繁殖研究

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西南大学学报（自然科学版） 2017年第10期39卷 35-41页

作者：黄琴邓洪平王鑫张华雨西南大学生命科学学院/三峡库区生态环境教育部重点实验室/重庆三峡库区植物生态与资源重点实验室重庆400715 四川省林业科学研究院成都610081

为寻找缙云黄芩扦插繁殖最佳条件,为缙云黄芩快速繁殖提供技术保障,改善其濒危现状,采用正交试验和单因素随机试验,研究枝条年龄、枝条木质化程度、基质、激素种类、激素质量浓度和处理时间对缙云黄芩扦插生根的影响,并在此基础上,对缙... 详细信息

为寻找缙云黄芩扦插繁殖最佳条件,为缙云黄芩快速繁殖提供技术保障,改善其濒危现状,采用正交试验和单因素随机试验,研究枝条年龄、枝条木质化程度、基质、激素种类、激素质量浓度和处理时间对缙云黄芩扦插生根的影响,并在此基础上,对缙云黄芩进行野外回归试验.正交试验结果发现,扦插的最佳组合为200 mg/L IBA处理插穗2h.在基质试验中,生根效果最佳的处理为蒸馏水;其次为蛭石与珍珠岩比例为1∶1处理,其在平均根长、最长根长和生根指数上效果最好,河沙处理在生根率方面最好.2年生枝条生根效果优于当年生枝条.半木质化程度的枝条是扦插的最佳选择,其生根效果最好,硬枝次之,软枝最弱.野外回归试验结果表明,大棚组和野外组插穗均能存活和生长,大棚组缙云黄芩插穗在成活率、平均出芽数和最多出芽数方面均优于野外组.

关键词：缙云黄芩扦插繁殖野外回归

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