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Tandem asymmetric dearomatized functionalization reaction of phenols with Evans-ynamides enabled by divergent electrophiles

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Science China Chemistry 2025年第2期68卷 649-660页

作者： Ying-Qi Zhang Gan-Lu qian Yun liu Jia-Hui Li xin Hong zhou Xu Bo zhou Long-Wu Ye State Key Laboratory of Physical Chemistry of Solid Surfaces Key Laboratory of Chemical Biology of Fujian Provinceand College of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China Center of Chemistry for Frontier Technologies Department of ChemistryState Key Laboratory of Clean Energy UtilizationZhejiang UniversityHangzhou 310027China Jiangsu Key Laboratory of New Drug Research and Clinical Pharmacy School of PharmacyXuzhou Medical UniversityXuzhou 221004China State Key Laboratory of Elemento-Organic Chemistry Nankai UniversityTianjin 300071China State Key Laboratory of Organometallic Chemistry Chinese Academy of SciencesShanghai 200032China

Herein,we disclose a highly regio-/chemoselective tandem asymmetric dearomatized halofunctionalization reaction of phenoltethered ynamides with diverse electrophilic halogenation sources in a catalyst-free manner for the practical and rapid assembly of a series of halogenated spirocyclic ***,the related dearomatized selenation and protonation are also achieved,affording the corresponding selenated and protonated spirocycles in high ***,the enantioselectivities of these products can be perfectly induced by Evans auxiliaries(99%ees).Significantly,this protocol not only represents the first tandem asymmetric halofunctionalization reaction of phenol derivatives,but also constitutes the first asymmetric halogenation/selenation of *** calculations indicate a remote induction model of Evans chiral auxiliary-attached keteniminium.

关键词： alkynes cyclization dearomatization Evans chiral auxiliary spirocycles

Rational modulation of fluorophosphate cathode by anionic groups to reduce the polarization behavior for fast-charging sodium-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 509-521页

作者： xinyuan Wang Fan Zhang xingyu zhou qian Wang Changyu liu Yangyang liu Hui Wang Xiaojie liu Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry&Materials ScienceNorthwest UniversityXi’an 710127ShaanxiChina

Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific *** functional theory (DFT) and finite element simulations show that incorporating SO_(4)^(2-)into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge ***,the average Na+diffusion coefficient of Na_(3)V_(2)(PO_(4))_(1.95)(SO_(4))_(0.05)O_(2)F(VPS-1) is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g^(-1)) and cycling stability (111.0 mAh g^(-1)capacity after 1000 cycles at 10 C current density) for ***-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 *** assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.

关键词： Anionic group modulation Polarization behavior Fast-charging Sodium-ion battery Fluorophosphate Cathode

Physical Layer Security Scheme With AoI-Awareness for Industrial IoT Based on Covert Communications

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IEEE/CAA Journal of Automatica Sinica 2025年第1期12卷 276-278页

作者： Yaping Li Zhi-xin liu Jia-Wei Su Ya-zhou Yuan the Key Laboratory of Industrial Computer Control Engineering of Hebei Province Yanshan University

Dear Editor,Industrial Internet of things(IIoT) is a typical application of cyberphysical system(CPS). In the IIoT, wireless communication is an inevitable trend to replace the deployment-limited wired transmission for cases with large-scale and mobile devices. However, wireless communication gives rise to critical issues related to physical security, such as malicious detections and attacks [1].

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Dual-role regulator of a novel miR-3040 in photoperiod-mediated wing dimorphism and wing development in green peach aphid

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Insect Science 2025年第1期32卷 80-94页

作者： Yun-Hui Zhang xin qian xin Zong Shi-Heng An Shuo Yan Jie Shen College of Plant Protection Henan Agricultural UniversityZhengzhouChina Department of Plant Biosecurity College of Plant ProtectionChina Agricultural UniversityBeijingChina

Wing dimorphism is regarded as an important phenotypic plasticity involved in the migration and reproduction of ***,the signal transduction and regulatory mechanism of wing dimorphism in aphids are still ***,the optimal environmental conditions were first explored for inducing winged offspring of green peach aphid,and the short photoperiod was the most important environmental cue to regulate wing *** to 16 L:8 D photoperiod,the proportion of winged offspring increased to 90%under 8 L:16 D ***,5 differentially expressed microRNAs(miRNAs)in aphids treated with long and short photoperiods were identified using small RNA sequencing,and a novel miR-3040 was identified as a vital miRNA involved in photoperiod-mediated wing *** specifically,the inhibition of miR-3040 expression could reduce the proportion of winged offspring induced by short photoperiod,whereas its activation increased the proportion of winged offspring under long ***,the expression level of miR-3040 in winged aphids was about 2.5 times that of wingless aphids,and the activation or inhibition of miR-3040 expression could cause wing deformity,revealing the dual-role regulator of miR-3040 in wing dimorphism and wing *** summary,the current study identified the key environmental cue for wing dimorphism in green peach aphid,and the first to demonstrate the dual-role regulator of miR-3040 in photoperiod-mediated wing dimorphism and wing development.

关键词： miR-3040 Myzus persicae photoperiod wing development wing dimorphism

Enteromorpha prolifera polysaccharide-Fe(Ⅲ) complex promotes intestinal development as a new iron supplement

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Science China(Life Sciences) 2025年第1期68卷 219-231页

作者： Yingying Feng Yuying Wu Jialu Wang Zhenglin Dong qian Yu Shuangshuang Xia Chunxue liu Haihua Wang xin Wu Tianjin Institute of Industrial Biotechnology Chinese Academy of SciencesTianjin 300308China CAS Key Laboratory of Agro-ecological Processes in Subtropical Region Institute of Subtropical AgricultureChinese Academy of SciencesChangsha 410125China ANYOU Biotechnology Group Co.Ltd Taicang 215412China Qingdao Seawin Biotech Group Co. LTDQingdao 266071China

Iron is a crucial micronutrient, and its deficiency can have detrimental effects on the health of infants. Dietary polysaccharide-iron(Ⅲ) complexes(PICs) are promising for addressing iron deficiency due to their minimal adverse reactions and high iron absorption rate. This study aimed to investigate the effects of dietary Enteromorpha prolifera polysaccharide-Fe(Ⅲ) complex(EP-Fe) on newborns, using 3-day weaned piglets as the iron-deficiency model. Results showed that EP-Fe improved iron levels and promoted intestinal development in piglets. Transcriptome sequencing revealed that EP-Fe increased the survival of intestinal epithelial cells under hypoxia by upregulating the expression of genes that promote the development of the vascular system. Additionally, EP-Fe enhanced the mucosal barrier functions by inhibiting myosin light chain kinase(MLCK)/phosphorylated myosin light chain(p-MLC) signaling pathway to increase the expression of intestinal tight junction proteins. Furthermore, the 16S r RNA gene sequencing of gut microbiota showed that EP-Fe promoted the enrichment of Bacteroides_fragilis and other gut microbes that can metabolize carbohydrates. In conclusion, EP-Fe is an effective iron supplement for newborns, and it can be developed as a comprehensive nutritional supplement.

关键词： Enteromorpha prolifera polysaccharide-Fe(III)complex iron deficiency intestinal development gut microbiota weaned piglet

Post-tunable salt gel electrolytes toward flexible supercapacitor switches

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Journal of Energy Chemistry 2025年第1期100卷 114-124页

作者： Hui Wang Shuang Chen Xuming liu Qin Zhang xin liu Polymeric and Soft Materials Laboratory School of Chemistry and Life Science and Advanced Institute of Materials ScienceChangchun University of TechnologyChangchun 130012JilinChina Polymeric and Soft Materials Laboratory School of Chemical Engineering and Advanced Institute of Materials ScienceChangchun University of TechnologyChangchun 130012JilinChina

Convertible hydrogel supercapacitors have emerged as promising energy storage devices in switches,diodes,and ***,inherent weaknesses in ionic conductivity,mechanical properties,and water retention of hydrogel electrolytes seriously hinder their *** by the hardness conversion of sea cucumber skin,a conductivity and mechanics dual-tunable salt gel electrolyte is successfully *** salt gel presents a reversible switching of conductors-insulators and a mechanical regulation between softness and hardness via the dissolution-crystallization transition of sodium acetate trihydrate(SAT).Meanwhile,the salt gels spontaneously grow a layer of“armor”through saturated phase-change salt crystals effectively reducing water evaporation of hydrogel ***,this phase-change soft-rigid conversion strategy will expand the capabilities of gel-based flexible supercapacitors(area capacitance:258.6 mF cm^(-2)),and the capacitance retention rate could still reach 86.9%after 3000 cycles at high ***,the salt gel supercapacitor is potentially used in over-heat alarm *** is anticipated that the strategy of conductivity and mechanics of dual-tunable salt gel would provide a new perspective on the development of energy storage devices,wearable electronics,and flexible robots.

关键词： Supercapacitors Salt gels Reversible phase transition Post-tuning Conductivity switching

Versatile chiroptical induction/manipulation through specific solvation of ion pairs by alcohols

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Science China Chemistry 2025年第2期68卷 610-621页

作者： Chunhong liu xin Chen Yanling Shen Ting Zhao Dayang zhou Kun Li Jiecheng Ji Wanhua Wu Xuemei Pu Cheng Yang Key Laboratory of Green Chemistry&Technology of Ministry of Education Sichuan UniversityChengdu 610064China Comprehensive Analysis Center ISIROsaka UniversityOsaka 565-0871Japan

While extensive research has explored manipulating supramolecular chirality through internal and external factors,the specific solvation effect remains uncharted *** study synthesized ortho-functionalized pillar[5]arene(P[5])derivatives Mn and Dn via thiol-Michael addition,characterizing them through spectroscopic and X-ray single-crystal *** and Dn interacted with chiral amines,yielding significant circular dichroism(CD)***,the chiral induction exhibited pronounced specific solvation effects,where achiral alcohols either enhanced,attenuated,or reversed CD *** over 40 alcohols revealed correlations between the specific solvation effects and alcohol polarity and *** dynamics simulations unveiled that the alcohol interacted distinctly through hydrogen bonding,with one ion pair bonding up to four alcohol *** Rp-and Sp-preference of the P[5]core could be altered by the number of bonded *** work uncovers the critical role of alcohol-specific solvation in ion pair-involved chiral assembly,pertinent for asymmetric ion-pairing catalysis and the use of alcohol additives in organic solvents.

关键词： chiroptical induction specific solvation ion pair pillararene H-bond

Artificial self-powered and self-healable neuromorphic vision skin utilizing silver nanoparticle-doped ionogel photosynaptic heterostructure

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Journal of Semiconductors 2025年第1期46卷 205-213页

作者： xinkai qian Fa Zhang Xiujuan Li Junyue Li Hongchao Sun Qiye Wang Chaoran Huang Zhenyu Zhang Zhe zhou Juqing liu Key Laboratory of Flexible Electronics(KLoFE)&Institute of Advanced Materials(IAM) Nanjing Tech University(NanjingTech)Nanjing 211816China

Artificial skin should embody a softly functional film that is capable of self-powering,healing and sensing with neuromorphic ***,the pursuit of a bionic skin that combines high flexibility,self-healability,and zero-powered photosynaptic functionality remains *** this study,we report a self-powered and self-healable neuromorphic vision skin,featuring silver nanoparticle-doped ionogel heterostructure as *** localized surface plasmon resonance induced by light in the nanoparticles triggers temperature fluctuations within the heterojunction,facilitating ion migration for visual sensing with synaptic *** abundant reversible hydrogen bonds in the ionogel endow the skin with remarkable mechanical flexibility and self-healing *** assembled a neuromorphic visual skin equipped with a 5×5 photosynapse array,capable of sensing and memorizing diverse light patterns.

关键词： neuromorphic vision skin ionogel heterojuction lspr photosynapse

Differential-geometry-based multi-dimensional joint position-velocity estimation using Crab pulsar profile distortion

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Chinese Journal of Aeronautics 2025年第1期38卷 551-567页

作者： Jin liu Huanzi ZHANG Xiaolin NING xin MA School of Electronic Information Wuhan University of Science and TechnologyWuhan 430081China School of Instrumentation and Optoelectronic Engineering Beihang UniversityBeijing 100191China Hefei National Laboratory Hefei 230088China

The traditional orbit determination method based on pulsar profile distortion can determine the six elements of the ***,the estimation accuracies of these methods are limited and the computational load of a six-dimensional search is *** solve this problem,the differential-geometry-based Multi-dimensional Joint Position-Velocity Estimation(MJPVE)using Crab pulsar profile distortion is proposed in this ***,through theoretical analysis,it is found that the pulsar profile distortion caused by the initial state error in some joint positionvelocity directions is very *** other words,the accuracies of estimation in these directions are very ***,the search dimension can be reduced,which in turn greatly reduces the computational ***,we construct the chi-squared function of the pulsar profile with respect to the estimation error in joint position-velocity direction and use differential geometry to find the joint position-velocity directions corresponding to different degrees of ***,we utilize the grid search based on directory folding in these joint position-velocity directions corresponding to large degrees of distortion to obtain the joint position-velocity *** experimental results show that compared with the grouping bi-chi-squared inversion method,MJPVE has high precision and extensive navigation information.

关键词： Joint Position-Velocity Estimation Pulsars Profile Distortion Orbit Determination Differential Geometry