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Green Energy & Environment 2024年第3期9卷 565-572页

作者： Huarong Fan Yubing Si Yiming Zhang Fulong Zhu xin wang Yongzhu Fu College of Chemistry and Center of Green Catalysis Zhengzhou UniversityZhengzhou450001China School of materials and Energy University of Electronic Science and Technology of ChinaChengdu611731China

Lithium-sulfur batteries(LSBs)with high energy densities have been demonstrated the potential for energy-intensive demand ***,their commercial applicability is hampered by hysteretic electrode reaction kinetics and the shuttle effect of lithium polysulfides(LiPSs).In this work,an interlayer consisting of high-entropy metal oxide(Cu_(0.7)Fe_(0.6)mn_(0.4)Ni_(0.6)Sn_(0.5))O_(4) grown on carbon nanofibers(HEO/CNFs)is designed for *** CNFs with highly porous networks provide transport pathways for Li^(+) and e^(-),as well as a physical sieve effect to limit LiPSs *** particular,the grapevine-like HEO nanoparticles generate metal-sulfur bonds with LiPSs,efficiently anchoring active *** unique structure and function of the interlayer enable the LSBs with superior electrochemical performance,i.e.,the high specific capacity of 1381 mAh g^(-1) at 0.1 C and 561 mAh g^(-1) at 6 *** work presents a facile strategy for exploiting high-performance LSBs.

关键词： Electrospun carbon nanofibers Grapevine-like morphology Hierarchical physical sieve effect High-entropy induced chemisorption Lithium-sulfur battery

Hole mobility enhancement in monolayer WSe2 p-type transistors through molecular doping

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Science China(Information Sciences) 2024年第6期67卷 207-213页

作者： Shiyuan LIU Xiong XIONG xin wang xinhang SHI Ru HUANG Yanqing WU School of Integrated Circuits and Beijing Advanced Innovation Center for Integrated Circuits Peking University Wuhan National High magnetic Field Center and School of Integrated Circuits Huazhong University of Science and Technology

Two-dimensional （2D） transition metal dichalcogenide （TmDC） semiconductor materials exhibit extraordinary electrical properties,holding promise for the realization of next-generation complementary metal-oxide-semiconductor （CmOS） devices at ultimate ***,constrained by effective device doping strategies,the hole mobility and device performance of tungsten diselenide （WSe2） p-type transistors,especially monolayer chemical vapor deposition （CVD）-grown WSe2,have not met *** this paper,an effective performance enhancement of monolayer WSe2p-type transistor was achieved through a molecular doping *** monolayer WSe2directly on SiO2back-gated substrates and leveraging energy band alignment design,4-nitrobenzenediazonium tetrafluoroborate （4-NBD） molecular dopant with a concentration of 10 m m was utilized to modulate the Fermi level position of monolayer WSe2for hole *** devices demonstrated a more than 98%increase in hole mobility,reaching up to 97 cm2·V-1·s-1while maintaining the current on/off ratio of *** p-type WSe2transistors with 1μm channel length exhibit a high drive current surpassing 176μA·μm-1,exceeding previous CVD-WSe2devices with similar channel *** straightforward and effective approach to improving the electrical performance of WSe2transistors paves the way for advanced logic technologies based on transition metal dichalcogenide semiconductors.

关键词： CVD-grown WSe$_2$ molecular doping 4-NBD p-type transistors hole mobility

Advancements in S-scheme heterojunction materials for photocatalytic environmental remediation

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Journal of materials Science & Technology 2024年第2期169卷 182-198页

作者： Changliang Nie Xiaohan wang Ping Lu Yukun Zhu xin Li Hua Tang School of Environmental Science and Engineering State Key Laboratory of Bio-fibers and Eco-textilesQingdao UniversityQingdao266071China Institute of Biomass Engineering Key Laboratory of Energy Plants Resource and UtilizationMinistry of Agriculture and Rural AffairsSouth China Agricultural UniversityGuangzhou510642China School of Environmental Science and Engineering Shandong UniversityQingdao266237China

Recently,S-scheme heterojunctions have gained considerable attention in the field of photocatalytic environmental remediation as their potential to achieve efficient spatial charge separation coupled with strong redox ***,this review provides an overview of the current state-of-the-art in the development of S-scheme-based photocatalysts for the purification of environmental *** review first covers the fundamentals of heterogeneous photocatalysis for environmental ***,an introduction to the background,mechanism,design principles,and characterization techniques of S-scheme heterojunctions is ***,the review presents a comparison and summary of using various S-scheme photocatalysts for the removal of several target pollutants,such as bacteria,heavy metals,nitrogen oxides,antibiotics,and ***,the modification strategies of S-scheme heterojunction photocatalysts are also ***,a brief discussion of the challenges and prospects associated with S-scheme photocatalytic systems is demonstrated.

关键词： S-scheme heterojunctions Photocatalyst Pollutant Environmental remediation

Regulating the oxidation state of Pd to enhance the selective hydrogenation for 5-hydroxymethylfurfural

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Chinese Journal of Chemical Engineering 2024年第8期72卷 60-68页

作者： xin Li Yue ma Xuning wang Jianguo Wu Dong Cao Daojian Cheng State Key Laboratory of Organic-Inorganic Composites and College of Chemical Engineering Beijing University of Chemical TechnologyBeijing 100029China

The highly selective hydrogenation of 5-hydroxymethylfurfural to 2,5-dihydroxymethylfuran is an important reaction in the field of biomass hydrogenation,because it is a bridge between biomass resources and chemical ***,we precisely constructed carbon nitride supported Pd-based catalysts by a simple impregnation-reduction *** changing the reduction temperature,catalysts with different oxidation state could be precisely ***,the important correlation between the ratio of Pd^(0)/Pd^(2+)and catalytic activity is revealed during the selective hydrogenation of *** Pd/g—C_(3)N_(4)—300 catalyst with a Pd^(0)/Pd^(2+)ratio of 3/2 showed the highest catalytic activity,which could get 96.9%5-hydroxymethylfurfural conversion and 90.3%2,5-dihydroxymethylfuran *** density functional theory calculation revealed that the synergistic effect between Pd0and Pd2+in Pd/g—C_(3)N_(4)—300 system could boost the adsorption of the substrate and the dissociation of *** this work,we highlight the important correlation between metal oxidation state and catalytic activity,which provides valuable insights for the rational design of precious metal catalysts for hydrogenation reactions.

关键词： Pd/g-C_(3)N_(4) Selective hydrogenation 5-hydroxymethylfurfural 2,5-dihydroxymethylfuran Oxidation state

mussel-inspired PTW@PDA composites for developing high-energy gun propellants with reduced erosion and enhanced mechanical strength

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Defence Technology（防务技术） 2024年第2期32卷 675-690页

作者： Xijin wang Zhitao Liu Pengfei Sun Feiyun Chen Bin Xu xin Liao School of Chemistry and Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094JiangsuChina China North Industries Group Corporation Limited Beijing 100045China

The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun *** address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K_(2)Ti_(6)O_(13)),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing *** interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW *** to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-Kbased protective coating being detected on the eroded *** 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of *** the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic *** strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.

关键词： High energy gun propellant Potassium titanate whiskers Polydopamine modification Erosion inhibitors mechanical reinforcing fillers

Development of functional dye with redshifted absorption based on Knoevenagel condensation at 1-site in phenyl[b]-fused BODIPY

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Chinese Chemical Letters 2024年第6期35卷 349-352页

作者： Tianze wang Junyi Ren Dongxiang Zhang Huan wang Jianjun Du xin-Dong Jiang Guiling wang Liaoning&Shenyang Key Laboratory of Functional Dye and Pigment Shenyang University of Chemical TechnologyShenyang 110142China Department of Cell Biology China Medical UniversityShenyang 110122China State Key Laboratory of Fine Chemicals Dalian University of TechnologyDalian 116024China

Integrating ring-fused modification withπ-conjugated extension is an effective approach for designing,synthesizing,and application for novel borondipyrromethene(BODIPY)*** this work,based on phenyl[b]-fused BODIPY,we made reasonable modification of the methyl group at 1-site to generate dye *** possessed near-infrared region(NIR)absorption and emission properties,and the intramolecular charge transfer(ICT)resulted in low ***,heat energy is evidently released in the presence of light,which can be exploited for intracellular photothermal therapy via the cell apoptosis process,reducing the inflammatory side-effects induced by *** research provides a crucial foundation for the novel molecule via BODIPY multi-directional alteration and its potential application in anti-tumor phototherapy.

关键词： NIR dyes [b]-Fused BODIPY Knoevenagel condensation Photothermal therapy Cell apoptosis

mechanical properties and interfacial characteristics of 6061 Al alloy plates fabricated by hot-roll bonding

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International Journal of minerals,metallurgy and materials 2024年第8期31卷 1890-1899页

作者： Zongan Luo xin Zhang Zhaosong Liu Hongyu Zhou mingkun wang Guangming Xie State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819China

This work aims to investigate the mechanical properties and interfacial characteristics of 6061 Al alloy plates fabricated by hotroll bonding(HRB)based on friction stir *** results showed that ultimate tensile strength and total elongation of the hot-rolled and aged joints increased with the packaging vacuum,and the tensile specimens fractured at the matrix after exceeding 1 ***-equilibrium grain boundaries were formed at the hot-rolled interface,and a large amount of mg_(2)Si particles were linearly precipitated along the interfacial grain boundaries(IGBs).During subsequent heat treatment,mg_(2)Si particles dissolved back into the matrix,and Al_(2)O_(3) film remaining at the interface eventually evolved into *** addition,the local IGBs underwent staged elimination during HRB,which facilitated the interface healing due to the fusion of grains at the *** process was achieved by the dissociation,emission,and annihilation of dislocations on the IGBs.

关键词： 6061 Al alloy hot-roll bonding vacuum mechanical properties interfacial grain boundaries

Realizing the purification and grain refinement of mg-Gd-Y alloy by one-step flux refining

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Journal of materials Science & Technology 2024年第6期173卷 202-217页

作者： xin Tong Guohua Wu ming Sun Qiman wang Liang Zhang Wencai Liu National Engineering Research Center of Light Alloy Net Forming and State Key Laboratory of metal matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240China School of materials and Chemistry University of Shanghai for Science and TechnologyShanghai 200093China

In the conventional melt preparation of magnesium rare-earth(mg-RE)alloys,the repeated heating/cooling process involved in grain refinement and flux refining usually prolongs the preparation period and aggravates melt *** this work,the purification and grain refinement of mg-9Gd-3Y(GW93)alloy was simultaneously realized by one-step refining at 740℃ by using a self-developed compound *** results show that,only after holding for 10 min,the inclusion content of the alloy is reduced by 81%to 0.29%,while the grain size is reduced by 84%to 119μm.A physical model depicting the interactions between compound flux and alloy melt was proposed based on thermodynamic calculation and microstructure *** grain refinement mechanism has been analyzed by considering the presence of Zr particle(Zr_(p))and Zr solute(Zr_(s)).In addition,the generated RECl_(3) was found to be readily absorbed by the flux,decreasing the surface tension and promoting the purification efficacy of the flux,which plays an important role in the promoted elongation of the as-cast mg-9Gd-3Y-0.5Zr(GW93K)*** work presents a unique prospect in simplifying the melt preparation of mg-RE alloy with a promoted quality.

关键词： mg-Gd-Y-Zr alloy Purification Grain refinement Compound flux Settling behavior

Effect of End Shape on Flow and Heat Transfer Characteristics of Two Parallel Plates

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Journal of Thermal Science 2024年第3期33卷 815-832页

作者： ZHANG Guang HONG Tianxiao wang Dongrui xin Jialin TAO Junyu LIN Zhe Key Laboratory of Fluid Transmission Technology of Zhejiang Province Zhejiang Sci-Tech UniversityHangzhou310018China

Flow around a pair of flat plates is a basic hydrodynamics *** this paper,the flow and heat transfer characteristics of two parallel plates with different edge shapes are numerically *** different inclined angles,the influence of chamfered and rounded structures with different sizes at the end-edge on unsteady flow and heat transfer characteristics of two parallel plates are *** is found that the instability and unsteadiness of flow decrease with the increase of end-edge size,and the non-uniformity of wake velocity of both rounded and chamfered plates decreases *** non-uniformity of wake temperature increases firstly and then decreases at a small inclined angle,and the amplitude becomes the largest when S_(rou)(S_(cha))=3,while it basically keeps monotonically increasing at a large inclined ***,the global heat transfer performance of the flat plate is obviously affected by the end-edge modification,especially the chamfered *** the increase of chamfered size,the global Nusselt number basically shows the decreasing *** study provides a theoretical basis for the application of plate-shape structure in engineering fields.

关键词： two parallel plates end shape flow characteristic heat transfer numerical simulation

A Comparative Study on the Post-Buckling Behavior of Reinforced Thermoplastic Pipes(RTPs)Under External Pressure Considering Progressive Failure

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China Ocean Engineering 2024年第2期38卷 233-246页

作者： DING xin-dong wang Shu-qing LIU Wen-cheng YE Xiao-han College of Engineering Ocean University of ChinaQingdao 266100China Shandong Provincial Key Laboratory of Ocean Engineering Ocean University of ChinaQingdao 266100China Department of marine Technology Norwegian University of Science and Technology(NTNU)Trondheim NO-7491Norway

The collapse pressure is a key parameter when RTPs are applied in harsh deep-water *** investigate the collapse of RTPs,numerical simulations and hydrostatic pressure tests are *** the numerical simulations,the eigenvalue analysis and Riks analysis are combined,in which the Hashin failure criterion and fracture energy stiffness degradation model are used to simulate the progressive failure of composites,and the“infinite”boundary conditions are applied to eliminate the boundary *** for the hydrostatic pressure tests,RTP specimens were placed in a hydrostatic chamber after filled with *** has been observed that the cross-section of the middle part collapses when it reaches the maximum *** collapse pressure obtained from the numerical simulations agrees well with that in the ***,the applicability of NASA SP-8007 formula on the collapse pressure prediction was also *** has a relatively greater difference because of the ignorance of the progressive failure of *** the parametric study,it is found that RTPs have much higher first-ply-failure pressure when the winding angles are between 50°and 70°.Besides,the effect of debonding and initial ovality,and the contribution of the liner and coating are also discussed.

关键词： reinforced thermoplastic pipes post-buckling behavior progressive failure of composites debonding initial ovality