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Orbitronics for energy-efficient magnetization switching

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Science China(Information Sciences) 2025年第1期68卷 398-399页

作者： Yuxuan YAO Daoqian zhu Qingtao XIA Jianing LIANG Yuhao JIANG Zhiyang PENG Jiaxu LI Chen XIAO Renyou XU Wenwen WANG Xiantao SHANG Shiyang LU Dapeng zhu Hong-Xi LIU Kaihua CAO Weisheng ZHAO Fert Beijing Institute School of Integrated Circuit Science and Engineering Beihang University National Key Lab of Spintronics Institute of International Innovation Beihang University Qingdao Research Institute Beihang University Truth Memory Corporation

Spin-orbit torque （SOT）,as a promising writing method for magnetic random-access memory （MRAM）,has garnered widespread interest for over a decade [1].Heavy metals,such as β-W,have been broadly adopted as spin current sources,but suffer from phase change at a limited thickness,resulting in a dramatic reduction of the charge-tospin conversion efficiency θSH[2].The thickness limitation leads to stringent etching conditions and large distribution among devices,posing challenges for simultaneously satisfying SOT efficiency,etching-stop margins,and back-end-ofline （BEOL） compatibility.

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Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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Journal of Energy Chemistry 2025年第1期100卷 458-468页

作者： Peng zhu Cun Liu Yiren Yu Guoshu Gao Yumeng Zhao Xiongfu Zhang Guodong Liu Guohui Yang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. Here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high-quality MFI zeolite nanosheets through a Silicalite-1(Sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the Si source. Our approach was effective for synthesizing both Sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achieved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where Sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： Aspect ratio

Combination of fruquintinib with venetoclax for the treatment of colorectal cancer

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Oncology Research 2025年第1期33卷 225-234页

作者： WEI ZHANG WEICHENG WANG RUI WANG XIAO HAN LIJUN zhu WENJIE GUO YANHONG GU Department of Oncology The First Affiliated Hospital of Nanjing Medical UniversityNanjing210029China State Key Laboratory of Pharmaceutical Biotechnology School of Life SciencesNanjing UniversityNanjing210023China Department of Oncology The Affiliated Taizhou People’s Hospital of Nanjing Medical UniversityTaizhou225300China

Background:As a novel blocker of vascular endothelial growth factor receptor(VEGFR),fruquintinib has been approved for treating colorectal cancer(CRC).However,its dosage and therapeutic efficacy are limited by its widespread adverse ***,recognized as the initial inhibitor of B-cell lymphoma protein 2(BCL2),has shown potential in boosting the effectiveness of immunotherapy against *** study investigated the efficacy and mechanisms of fruquintinib combined with venetoclax in treating *** and Materials:We developed a colon cancer mouse model with the CT26 colon cell line to demonstrate fruquintinib and venetoclax’s efficacy against *** we employed various techniques to evaluate different aspects of the experimental *** was used to detect cell proliferation and angiogenesis in tumor *** blot analysis was utilized to examine the occurrence of cell apoptosis,and flow cytometry to quantitate immune cells within the tumor ***,immunofluorescence was employed to measure cytokine ***:The strongest inhibition on tumor growth was achieved by the combination of fruquintinib with venetoclax,as opposed to individual drug *** was found to amplify the impact of fruquintinib,leading to decreased cancer cell proliferation,increased cancer cell apoptosis,lowered angiogenesis,better vascular structure normalization,and improved immune cell ***:Our findings indicate that the addition of venetoclax enhances the impact of fruquintinib on vascular normalization and modulation of the tumor immune *** study presents the justification for utilizing the fruquintinib and venetoclax combination in treating *** holds promise in being assimilated into anticancer medications for CRC.

关键词： Colorectal cancer(CRC) B-cell lymphoma protein 2(BCL2) Venetoclax Vascular endothelial growth factor receptor(VEGFR) Fruquintinib Anti-angiogenesis Immunotherapy

Trinuclear gold-catalyzed site-selective alkylation of peptides

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Science China Chemistry 2025年第1期68卷 249-256页

作者： Qing-Yun Fang Chengyihan Gu Yinghan Chen Wencheng Yan Yong Liang Weipeng Li Chengjian zhu Jie Han Jin Xie State Key Laboratory of Coordination Chemistry Jiangsu Key Laboratory of Advanced Organic Materials Chemistry and Biomedicine Innovation Center (Chem BIC) School of Chemistry and Chemical Engineering Nanjing University Green Catalysis Center College of Chemistry Zhengzhou University State Key Laboratory of Natural Medicines China Pharmaceutical University

Selective modification of peptides has always been a challenging issue. The selective alkylation of peptides can alter the biological activity and physical properties of molecules, and it has gained significant research interest. We herein disclose an intriguing gold-catalyzed alkylation of peptides using bench-stable unactivated alkyl bromides under photoredox catalysis. A wide range of structurally diverse primary, secondary and tertiary alkyl bromides serve as effective coupling partners to precisely connect with the α-C(sp3)–H in glycine residue of peptides. This protocol demonstrates an exceptionally broad scope for alkyl halides and excellent tolerance for a wide range of useful functional groups. A series of relay transformations to construct cyclic peptides, to proceed click reaction and to realize peptide fluorescence labeling further enhance its synthetic practicality. In addition, mechanistic studies and density functional theory(DFT) calculations reveal an inner-sphere and subsequent outersphere single electron transfer(SET) mechanism.

关键词： gold catalysis peptide alkylation C-C coupling radical

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Hengqin:Gateway for Going Global

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China Today 2025年第1期74卷 50-53页

作者： zhu JIE zhuhai Dahengqin Company Limited

The synergy and complementary strengths between Macao and Hengqin can create an important channel for Chinese companies to *** enterprises have placed much emphasis on going global in recent years,from traditional manufacturing giants to emerging tech unicorns,and from traditional sectors to emerging industries like electric vehicles,lithium batteries,and photovoltaic *** enthusiasm to internationalize reached unprecedented levels in 2024.

关键词： companies Gateway lithium

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农业科技培训存在的问题及对策

现代农业科技 2020年第22期 238-239,242页

作者：王小娥王旭周佳民宋荣朱校奇湖南省农业科学院生产管理处湖南长沙410125 湖南省农业环境生态研究所湖南长沙410125 湖南省农业科学院药用植物研究中心湖南长沙410125

当前,我国农业生产方式发生了巨大变化。为提高农民生产技术水平,本文基于我国农业科技培训体系不健全、资金短缺、培训效果不理想等问题进行了分析,提出了构建长效培训体系、政府加大资金投入、拓宽培训渠道等建议,以促进我国农村产业... 详细信息

当前,我国农业生产方式发生了巨大变化。为提高农民生产技术水平,本文基于我国农业科技培训体系不健全、资金短缺、培训效果不理想等问题进行了分析,提出了构建长效培训体系、政府加大资金投入、拓宽培训渠道等建议,以促进我国农村产业可持续发展。

关键词：农业科技培训问题对策

An Approximation Method for Singular Trudinger-Moser Inequality

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应用数学 2025年第1期38卷 64-70页

作者： zhu Maochun XU Wenyan JIANG Rou School of Mathematical Sciences Jiangsu UniversityZhenjiang 212013China

In this paper,we construct a power type functional which is the approximation functional of the Singular Trudinger-Moser ***,we obtain the concentration level of the functional and show it converges to the concentrati... 详细信息

关键词： Singular Trudinger-Moser inequality Approximation functional Concentration level

Introduction and Cultivation of Salvia hispanica L.(Chia)and Its Value of Health Care

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Agricultural Science & Technology 2017年第12期18卷 2263-2267,2285页

作者：宋荣严蓓周佳民朱校奇徐军易自力湖南农业大学生物科学技术学院湖南长沙410128 湖南省农业环境生态研究所湖南长沙410128 湖南农业大学植物保护学院湖南长沙410128

Botanical traits, genetic resources and cultivation of Salvia hispanica L. were reviewed in the article, which introduced the reasons why S. hispanica had late blooming period and low yield during the planting process in China, and envis- aged how to solve the late blooming period and low yield appeared during the planting process. Emphasis was laid on the introduction of the research progress of efficacy constituents and health care value of Chia seeds with the aim to take full advantage of S. hispanica.

关键词： Salvia hispanica L. Chia seeds Genetic resources Cultivation Polyunsaturated fatty acids

Molecular Structure of Kerogen in the Longmaxi Shale: Insights from Solid State NMR, FT-IR, XRD and HRTEM

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Acta Geologica Sinica(English Edition) 2019年第4期93卷 1015-1024页

作者： WANG xiaoqi zhu Yanming LIU Yu LI Wu Key Laboratory of Coalbed Methane Resources and Reservoir Formation on Process Ministry of EducationChina University of Mining and TechnologyXuzhou 221008JiangsuChina School of Resources and Geosciences China University of Mining and TechnologyXuzhou 221116JiangsuChina

Kerogen plays an important role in shale gas adsorption,desorption and ***,it is necessary to characterize the molecular structure of *** this study,four kerogen samples were isolated from the organic-rich shale of the Longmaxi *** spectroscopy was used to determine the maturity of these kerogen *** transmission electron microscopy(HRTEM),13 C nuclear magnetic resonance(13 C NMR),X-ray diffraction(XRD)and Fourier transform infrared(FT-IR)spectroscopy were conducted to characterize the molecular structure of the shale *** results demonstrate that VReqv of these kerogen samples vary from 2.3%to 2.8%,suggesting that all the kerogen samples are in the dry gas *** macromolecular carbon skeleton of the Longmaxi Formation kerogen is mainly aromatic(fa’=0.56).In addition,the aromatic structural units are mainly composed of naphthalene(23%),anthracene(23%)and phenanthrene(29%).However,the aliphatic structure of the kerogen macromolecules is relatively low(fal*+falH=0.08),which is presumed to be distributed in the form of methyl and short aliphatic chains at the edge of the aromatic *** oxygen-containing functional groups in the macromolecules are mainly present in the form of carbonyl groups(fac=0.23)and hydroxyl groups or ether groups(falO=0.13).The crystallite structural parameters of kerogen,including the stacking height(Lc=22.84?),average lateral size(La=29.29?)and interlayer spacing(d002=3.43?),are close to the aromatic structural parameters of anthracite or overmature ***-resolution transmission electron microscopy reveals that the aromatic structure is well oriented,and more than 65%of the diffractive aromatic layers are concentrated in the main *** to the continuous deep burial,the longer aliphatic chains and oxygen-containing functional groups in the kerogen are substantially ***,the ductility and stacking degree of the aromatic structure increases during therm

关键词： organic-rich shale molecular structure kerogen HRTEM Sichuan Basin