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Study on metal recovery process and kinetics of oxidative leaching from spent LiFePO_(4)Li-batteries

Chinese Journal of Chemical Engineering 2024年第4期68卷 94-102页

作者： xiaoming Zhang wen Xie Xiaolei Zhou wenjie Zhang Jiawei wen Xin Wang Guoyong Huang Shengming Xu College of New Energy and Materials China University of PetroleumBeijing 102249China State Key Laboratory of Heavy Oil Processing College of Chemical EngineeringChina University of PetroleumBeijing 102249China Beijing Spacecrafts Beijing 100094China Ganfeng Lithium Group Co. Ltd.Xinyu 338000China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Beijing Key Laboratory of Fine Ceramics Tsinghua UniversityBeijing 100084China

A green environmental protection and enhanced leaching process was proposed to recover all elements from spent lithium iron phosphate(LiFePO_(4))lithium batteries.In order to reduce the influence of Al impurity in the recovery process,NaOH was used to remove impurity.After impurity removal,the spent LiFePO_(4)cathode material was used as raw material under the H2SO4 system,and the pressure oxidation leaching process was adopted to achieve the preferential leaching of lithium.The E-pH diagram of the Fe ePeAleH_(2)O system can determine the stable region of each element in the recovery process of spent LiFePO_(4)Li-batteries.Under the optimal conditions(500 r·min^(-1),15 h,363.15 K,0.4 MPa,the liquidesolid ratio was 4:1 ml·g^(-1)and the acidematerial ratio was 0.29),the leaching rate of Li was 99.24%,Fe,Al,and Ti were 0.10%,2.07%,and 0.03%,respectively.The Fe and P were precipitated and recovered as FePO_(4)·2H_(2)O.The kinetic analysis shows that the process of high-pressure acid leaching of spent LiFePO_(4)materials depends on the surface chemical reaction.Through the life cycle assessment(LCA)of the spent LiFePO_(4)whole recovery process,eight midpoint impact categories were selected to assess the impact of recovery process.The results can provide basic environmental information on production process for recycling industry.

关键词： Spent LiFePO_(4)Li-batteries Oxidative leaching Kinetic study Life cycle assessment

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Current Status and Perspectives of Dual-Atom Catalysts Towards Sustainable Energy Utilization

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Nano-Micro Letters 2024年第7期16卷 402-440页

作者： Yizhe Li Yajie Li Hao Sun Liyao Gao Xiangrong Jin Yaping Li Zhi LV Lijun Xu wen Liu xiaoming Sun State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Science EngineeringCollege of ChemistryBeijing University of Chemical TechnologyBeijing 100029People’s Republic of China Xinjiang Coal Mine Mechanical and Electrical Engineering Technology Research Center Xinjiang Institute of EngineeringUrumqi 830023Xinjiang Uygur Autonomous RegionPeople’s Republic of China

The exploration of sustainable energy utilization requires the imple-mentation of advanced electrochemical devices for efficient energy conversion and storage,which are enabled by the usage of cost-effective,high-performance electro-catalysts.Currently,heterogeneous atomically dispersed catalysts are considered as potential candidates for a wide range of applications.Compared to conventional cata-lysts,atomically dispersed metal atoms in carbon-based catalysts have more unsatu-rated coordination sites,quantum size effect,and strong metal-support interactions,resulting in exceptional catalytic activity.Of these,dual-atomic catalysts(DACs)have attracted extensive attention due to the additional synergistic effect between two adja-cent metal atoms.DACs have the advantages of full active site exposure,high selectiv-ity,theoretical 100%atom utilization,and the ability to break the scaling relationship of adsorption free energy on active sites.In this review,we summarize recent research advancement of DACs,which includes(1)the comprehensive understanding of the synergy between atomic pairs;(2)the synthesis of DACs;(3)characterization meth-ods,especially aberration-corrected scanning transmission electron microscopy and synchrotron spectroscopy;and(4)electrochemical energy-related applications.The last part focuses on great potential for the electrochemical catalysis of energy-related small molecules,such as oxygen reduction reaction,CO_(2) reduction reaction,hydrogen evolution reaction,and N_(2) reduction reaction.The future research challenges and opportunities are also raised in prospective section.

关键词： Dual-atom catalysts Synergetic effect Electrocatalysis Oxygen reduction reaction CO_(2)reduction reaction Hydrogen evolution reaction N2 reduction reaction

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Centimeter-sized Cs_(3)Cu_(2)I_(5)single crystals grown by oleic acid assisted inverse temperature crystallization strategy and their films for high-quality X-ray imaging

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Journal of Energy Chemistry 2023年第4期79卷 382-389页

作者： Tao Chen Xin Li Yong Wang Feng Lin Ruliang Liu wenhua Zhang Jie Yang Rongfei Wang xiaoming wen Bin Meng Xuhui Xu Chong Wang National Center for International Research on Photoelectric and Energy Materials School of Materials and EnergyYunnan UniversityKunming 650091YunnanChina College of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan ProvinceKunming University of Science and TechnologyKunming 650093YunnanChina Centre for Translational Atomaterials Swinburne University of TechnologyHawthorn 3122Australia

Low-dimensional halide perovskites have become the most promising candidates for X-ray imaging,yet the issues of the poor chemical stability of hybrid halide perovskite,the high poisonousness of lead halides and the relatively low detectivity of the lead-free halide perovskites which seriously restrain its commercialization.Here,we developed a solution inverse temperature crystal growth(ITCG)method to bring-up high quality Cs_(3)Cu_(2)I_(5)crystals with large size of centimeter order,in which the oleic acid(OA)is introduced as an antioxidative ligand to inhibit the oxidation of cuprous ions effieiently,as well as to decelerate the crystallization rate remarkalby.Based on these fine crystals,the vapor deposition technique is empolyed to prepare high quality Cs_(3)Cu_(2)I_(5)films for efficient X-ray imaging.Smooth surface morphology,high light yields and short decay time endow the Cs_(3)Cu_(2)I_(5)films with strong radioluminescence,high resolution(12 lp/mm),low detection limits(53 nGyair/s)and desirable stability.Subsequently,the Cs_(3)Cu_(2)I_(5)films have been applied to the practical radiography which exhibit superior X-ray imaging performance.Our work provides a paradigm to fabricate nonpoisonous and chemically stable inorganic halide perovskite for X-ray imaging.

关键词： Inverse temperature crystal growth Cs_(3)Cu_(2)I_(5)single crystal Vapor deposition Cs_(3)Cu_(2)I_(5)films X-ray imaging

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外源水杨酸对浙江楠幼苗抗寒生理的影响

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森林与环境学报 2024年第1期44卷 79-84页

作者：顾雯高捍东薛晓明南京林业大学南方现代林业协同创新中心江苏南京210037 南京林业大学林学院江苏南京210037 南京警察学院刑事科学技术学院江苏南京210023

为探究低温条件下外源水杨酸(salicylic acid,SA)对浙江楠(Phoebe chekiangensis)幼苗抗寒生理的影响,以期为浙江楠的保护、引种、栽培和开发利用提供科学依据。设置5个SA浓度(0、0.1、0.5、1.0、2.0 mmol·L^(-1))对浙江楠1年生容器苗... 详细信息

为探究低温条件下外源水杨酸(salicylic acid,SA)对浙江楠(Phoebe chekiangensis)幼苗抗寒生理的影响,以期为浙江楠的保护、引种、栽培和开发利用提供科学依据。设置5个SA浓度(0、0.1、0.5、1.0、2.0 mmol·L^(-1))对浙江楠1年生容器苗进行连续3 d的叶面喷施处理,随后利用人工气候室模拟0℃低温,再进行连续7 d的低温胁迫处理,以20℃常温为对照(CK),测定相对电导率(REC)、叶绿素(Chl)含量、丙二醛(MDA)含量、过氧化物酶(POD)活性、超氧化物歧化酶(SOD)活性、可溶性蛋白(SP)含量、可溶性糖(SS)含量、脯氨酸(Pro)含量等生理指标,对浙江楠相关抗寒生理指标进行了相关性和主成分分析。结果表明,适宜浓度的外源SA可以有效缓解REC、MDA含量的上升及Chl含量的下降,促进抗氧化酶活性增加及渗透调节物质积累,减轻低温造成的胁迫伤害。主成分分析结果表明,外源SA预处理在0℃胁迫下能有效提高浙江楠幼苗的抗寒能力,其中1 mmol·L^(-1)的SA处理具有最大缓解效应。

关键词：浙江楠水杨酸低温胁迫生理特性耐寒性

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非厄米力学系统基本原理与研究进展

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力学进展 2024年第1期54卷 1-60页

作者：耿琳琳袁锦波程文胡更开周萧明飞行器动力学与控制教育部重点实验室北京理工大学宇航学院

非厄米理论是研究开放系统动力学行为的一种理论框架,其概念起源于量子力学,借助该理论可以揭示出奇异点、手性模态转换、拓扑趋肤效应等新奇现象,为反常波动与振动调控提供了新思路.本文着重以力学的语言对非厄米系统的基础概念进行介... 详细信息

非厄米理论是研究开放系统动力学行为的一种理论框架,其概念起源于量子力学,借助该理论可以揭示出奇异点、手性模态转换、拓扑趋肤效应等新奇现象,为反常波动与振动调控提供了新思路.本文着重以力学的语言对非厄米系统的基础概念进行介绍,阐明经典系统与非厄米系统的关联和扩展关系,并介绍相关前沿研究进展.首先介绍非厄米力学系统中的奇异点、宇称-时间反演对称性等基本概念,并介绍奇异点微扰理论及其在高灵敏度传感等领域的应用机理,之后介绍奇异点附近特征值曲面的拓扑结构,以及环绕奇异点的模态演化规律,最后介绍非厄米力学系统中的拓扑波动行为.

关键词：非厄米系统非保守系统奇异点宇称-时间反演对称非厄米拓扑

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Tunable Multicolor Fluorescence of Perovskite-Based Composites for Optical Steganography and Light-Emitting Devices

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Research 2023年第1期2022卷 185-195页

作者： Kewei Ma Qingfeng Gui Cihui Liu Yunyi Yang Fangjian Xing Yunsong Di xiaoming wen Baohua Jia Zhixing Gan Center for Future Optoelectronic Functional Materials School of Computer and Electronic Information/School of Artificial IntelligenceNanjing Normal UniversityNanjing 210023China College of Naval Architecture and Ocean Engineering Jiangsu Maritime InstituteNanjing 211170China Centrefor Translational Atomaterials Schoolof ScienceSwinburne University of TechnologyJohn Street Hawthon VIC3122Australia School of Science RMIT UniversityMelbourne3000 VICAustralia College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China

Multicolor fluorescence of mixed halide perovskites enormously enables their applications in photonics and optoelectronics.However,it remains an arduous task to obtain multicolor emissions from perovskites containing single halogen to avoid phase segregation.Herein,a fluorescent composite containing Eu-based metal-organic frameworks(MOFs),OD Cs PbBre,and 3D CsPbBrs is synthesized.Under excitations at 365 nm and 254nm,the pristine composite emits blue(B)and red(R)fluorescence,which are ascribed to radiative defects within CsPbBr and 5Do→7F,transitions of Eu^(3+),respectively.Interestingly,after light soaking in the ambient environment,the blue fluorescence gradually converts into green(G)emission due to the defect repairing and 0D-3D phase conversion.This permanent and unique photochromic effect enables anticounterfeiting and microsteganography with increased security through a micropatterning technique.Moreover,the RGB luminescence is highly stable after encapsulation by a transparent polymer layer.Thus,trichromatic light-emitting modules are fabricated by using the fluorescent composites as color-converting layers,which almost fully cover the standard color gamut.Therefore,this work innovates a strategy for construction of tunable multicolor luminescence by manipulating the radiative defects and structural dimensionality.

关键词： composite composites perovskite

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Stable ultraviolet ultrafast laser based on all-polarizationmaintaining fiber femtosecond laser

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Chinese Optics Letters 2024年第3期22卷 76-82页

作者：田昊朱喆林巍李子豪温俊鹏修昊范怡衡韦池一韦小明杨中民 School of Physics and Optoelectronics/State Key Laboratory of Luminescent Materials and Devices Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and DevicesGuangdong Provincial Key Laboratory of Fiber Laser Materials and Applied TechniquesSouth China University of TechnologyGuangzhou 510640China Research Institute of Future Technology South China Normal UniversityGuangzhou 510006China

We report a high-stability ultrafast ultraviolet(UV)laser source at 352 nm by exploring an all-fiber,all-polarizationmaintaining(all-PM),Yb-doped femtosecond fiber laser at 1060 nm.The output power,pulse width,and optical spectrum width of the fiber laser are 6 W,244 fs,and 17.5 nm,respectively.The UV ultrashort pulses at a repetition rate of 28.9 MHz are generated by leveraging single-pass second-harmonic generation in a 1.3-mm-long BiB_(3)O_(6)(BIBO)and sum frequency generation in a 5.1-mm-long BIBO.The maximum UV output power is 596 mW.The root mean square error of the output power of UV pulses is 0.54%.This laser,with promising stability,is expected to be a nice source for frontier applications in the UV wavelength window.

关键词： all-polarization-maintaining fiber ultrafast fiber laser UV laser

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非连续光对无土栽培番茄苗期无机元素吸收的影响

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农业机械学报 2024年第4期55卷 327-336,345页

作者：陈晓丽刘艺涵徐凡魏晓明郑文刚北京市农林科学院智能装备技术研究中心北京100097 天津农学院园艺园林学院天津300384

本研究在人工光型植物工厂中采用岩棉种植番茄植株,分析了在总光量一致的基础上红光背景下蓝光补充介入和蓝光取代介入两种非连续供光模式对番茄植株营养液无机元素吸收及叶片色素光谱参量的影响。结果表明,与连续红光相比,蓝光以不同... 详细信息

本研究在人工光型植物工厂中采用岩棉种植番茄植株,分析了在总光量一致的基础上红光背景下蓝光补充介入和蓝光取代介入两种非连续供光模式对番茄植株营养液无机元素吸收及叶片色素光谱参量的影响。结果表明,与连续红光相比,蓝光以不同方式介入均降低了番茄叶片中K元素含量而提高了茎中K元素含量,蓝光介入一定程度上抑制了番茄K元素由茎向叶片的运输;蓝光以不同方式介入均提高了番茄地上部中Mg含量(增幅8.93%~13.63%),而降低了地上部Fe含量(降幅28%~48%)及Mn含量(降幅3.93%~21.24%)。其中蓝光补充介入模式下番茄叶片中Mg元素含量随着蓝光补充强度的升高而增加,叶片Mg含量在蓝光取代介入模式下高于蓝光补充介入模式而地上部Fe含量趋势则相反,蓝光取代介入的非连续光模式较蓝光补充介入模式而言更有利于刺激叶片中Mg的积累而抑制地上部Fe的积累。与连续红光相比,蓝光以不同方式介入后番茄叶片色素光谱参量Hue值(色相角)和MCARI值(修正叶绿素吸收比指数)均有所提高,相反,Red/Green值(红绿区域光谱反射比)均有所降低,蓝光补充介入模式下叶片Hue值和MCARI值随蓝光补充强度的升高而增大,R/RB_(80)处理下Hue、MCARI值最高,较对照分别提高4%、124%;蓝光取代模式下Hue值和MCARI值随蓝光间歇时间的延长先增大后减小,R/RB_((1h))处理下Hue、MCARI值最高,较对照分别提高6%、215%。番茄叶片在绿光波段的反射率与各处理下Hue、MCARI值变化趋势接近,而番茄叶片中Mg元素含量与叶绿素光谱参量呈正相关性。蓝光取代介入的非连续光模式较蓝光补充介入模式而言更有利于刺激叶片类胡萝卜素分解和叶绿素积累,非连续供光模式通过调控番茄植株无机元素的吸收进而作用于叶片色素的形成。本研究为无土栽培番茄光环境调控提供了理论依据。

关键词：植物工厂 LED供光模式番茄苗期非连续光无机元素

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Oxygen-deficient bismuth tungstate and bismuth oxide composite photoanode with improved photostability

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Science Bulletin 2018年第15期63卷 990-996页

作者： Hoi Ying Chung Weijian Chen xiaoming wen Judy N. Hart Hao Wu Yuekun Lai Rose Amal Yun Hau Ng Particles and Catalysis Research Croup School of Chemical Engineering The University of New South Wales (UNSW) Sydney NSW 2052 Australia School of Photovoltaic and Renewable Energy Engineering The University of New South Wales (UNSW) Sydney NSW 2052 Australia Centre for Micro-Photonics Faculty of Science Engineering and Technology Swinburne University of Technology Melbourne VIC 2122 Australia School of Materials Science and Engineering The University of New South Wales (UNSW) Sydney NSW 2052 Australia National Engineering Laboratory for Modern Silk College of Textile and Clothing Engineering Soochow University Suzhou 215123 China

A homogeneous layer of Bi_2O_3-Bi_(14)WO_(24) composite(BWO/Bi_2O_3) thin film was fabricated using a combination of electrodeposition and thermal treatment. The evenly distributed Bi14 WO24 component within the Bi_2O_3 layer was found to be important in stabilising the photoelectrochemical performances of Bi_2O_3 photoanode by promoting the photoelectron transport. The unmodified Bi_2O_3 suffered from severe photocorrosion as proven by X-ray diffraction(XRD) and inductively coupled plasma(ICP) analyses while the composite thin film was active without noticeable activity decay for at least 3 h of illumination. This strategy might be applicable to other photocatalysts with stability issues.

关键词：氧化物合成钨酸盐 Bi2O3 光催化剂铋热处理分布式

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稀土上转换发光材料的设计及在光动力治疗中的应用研究进展

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材料导报 2024年第8期38卷 95-106页

作者：甘晓明苏玉仙应文伟王建峰刘力周晓峰温世鹏北京化工大学北京市先进弹性体工程技术研究中心北京100029 中日友好医院泌尿外科北京100029

作为一种新兴的无创治疗方法,光动力治疗在癌症治疗方面具有副作用小、累积毒性小、有效杀伤肿瘤以及精准的靶向治疗而不损伤邻近组织等优势,是理想的癌症治疗方法之一。本文首先简要概括了光动力治疗的机理、基本要素以及细胞作用机制... 详细信息

作为一种新兴的无创治疗方法,光动力治疗在癌症治疗方面具有副作用小、累积毒性小、有效杀伤肿瘤以及精准的靶向治疗而不损伤邻近组织等优势,是理想的癌症治疗方法之一。本文首先简要概括了光动力治疗的机理、基本要素以及细胞作用机制,讨论了稀土上转化发光材料的设计特点以及光动力治疗对上转化发光材料的要求,进一步详述了上转换发光纳米材料、光敏剂以及靶向体的材料结合方式和应用效果,最后综述了光动力治疗和放疗、化疗及光热治疗相结合的协同治疗的进展。

关键词：光动力治疗稀土上转换发光材料光敏剂癌症治疗

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