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Metal–Organic Gel Leading to Customized Magnetic‑Coupling Engineering in Carbon Aerogels for Excellent Radar Stealth and Thermal Insulation Performances

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Nano-Micro Letters 2024年第3期16卷 36-52页

作者： Xin Li Ruizhe Hu Zhiqiang Xiong Dan Wang Zhixia Zhang Chongbo Liu xiaojun zeng Dezhi Chen Renchao Che Xuliang Nie Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Nanchang Hangkong UniversityNanchang 330063People’s Republic of China School of Environmental and Chemical Engineering Nanchang Hangkong UniversityNanchang 330063People’s Republic of China Laboratory of Advanced Materials Department of Materials Science and Collaborative Innovation Center of Chemistry for Energy Materials and Collaborative Innovation Center of Chemistry for Energy MaterialsFudan UniversityShanghai 200438People’s Republic of China School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen 333403People’s Republic of China College of Chemistry and Materials Jiangxi Agricultural UniversityNanchang 330045People’s Republic of China

Metal–organic gel(MOG)derived composites are promising multi-functional materials due to their alterable composition,identifiable chemical homogeneity,tunable shape,and porous structure.Herein,stable metal–organic hydrogels are prepared by regulating the complexation effect,solution polarity and curing speed.Meanwhile,collagen peptide is used to facilitate the fabrication of a porous aerogel with excellent physical properties as well as the homogeneous dispersion of magnetic particles during calcination.Subsequently,two kinds of heterometallic magnetic coupling systems are obtained through the application of Kirkendall effect.FeCo/nitrogen-doped carbon(NC)aerogel demonstrates an ultra-strong microwave absorption of−85 dB at an ultra-low loading of 5%.After reducing the time taken by atom shifting,a FeCo/Fe3O4/NC aerogel containing virus-shaped particles is obtained,which achieves an ultra-broad absorption of 7.44 GHz at an ultra-thin thickness of 1.59 mm due to the coupling effect offered by dual-soft-magnetic particles.Furthermore,both aerogels show excellent thermal insulation property,and their outstanding radar stealth performances in J-20 aircraft are confirmed by computer simulation technology.The formation mechanism of MOG is also discussed along with the thermal insulation and electromagnetic wave absorption mechanism of the aerogels,which will enable the development and application of novel and lightweight stealth coatings.

关键词： Metal-organic gels Heterometallic magnetic coupling Radar stealth Thermal insulation Computer simulation technology

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Hierarchical assembly of NiFe-PB-derived bimetallic phosphides on 3D Ti_(3)C_(2) MXene ribbon networks for efficient oxygen evolution

ChemPhysMater

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ChemPhysMater 2024年第1期3卷 118-124页

作者： Chulong Jin Hanlei Peng xiaojun zeng Zhenyuan Liu Deng Ding School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen 333403China School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212100China College of Chemistry and Environmental Engineering Wuhan Polytechnic UniversityWuhan 430023China

The development of MXene-based heterostructures for electrocatalysis has garnered significant attention owing to their potential as high-performance catalysts that play a pivotal role in hydrogen energy.Herein,we present a multistep strategy for the synthesis of a Ti_(3)C_(2) MXene ribbon/NiFePx@graphitic N-doped carbon(NC)heterostructure that enables the formation of three-dimensional(3D)Ti_(3)C_(2) MXene ribbon networks and bimetallic phosphide nanoarrays.With the assistance of HF etching and KOH shearing,the MXene sheets were successfully transformed into 3D MXene networks with interlaced MXene ribbons.Notably,a hydrothermal method,ion exchange route,and phosphorization process were used to anchor NiFeP_(x)@NC nanocubes derived from Ni(OH)_(2)/NiFe-based Prussian blue(NiFe-PB)onto the MXene ribbon network.The resulting MXene ribbon/NiFeP_(x)@NC heterostructure demonstrated enhanced oxygen evolution reaction(OER)activity,characterized by a low overpotential(164 mV at a current density of 10 mA cm^(-2))and a low Tafel slope(45 mV dec^(-1)).At the same time,the MXene ribbons/NiFeP_(x)@NC heterostructure exhibited outstanding long-term stability,with a 12 mV potential decay after 5000 cyclic voltammetry(CV)cycles.This study provides a robust pathway for the design of efficient MXene-based heterostructured electrocatalysts for water splitting.

关键词： Metal phosphides Prussian blue nanocubes Ti_(3)C_(2)MXene ribbons Interfacial matching OER

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Construction of dual heterogeneous interface between zigzag-like Mo–MXene nanofibers and small CoNi@NC nanoparticles for electromagnetic wave absorption

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先进陶瓷(英文) 2023年第8期12卷 1562-1576页

作者： xiaojun zeng Xiao Jiang Ya Ning Feiyue Hu Bingbing Fan School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen 333403China School of Materials Science&Engineering Zhengzhou UniversityZhengzhou 450001China Jiangsu Key Laboratory of Advanced Metallic Materials School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China

Two-dimensional(2D)transition metal carbides(MXene)possess attractive conductivity and abundant surface functional groups,providing immense potential in the field of electromagnetic wave(EMW)absorption.However,high conductivity and spontaneous aggregation of MXene suffer from limited EMW response.Inspired by dielectric–magnetic synergy effect,the strategy of decorating MXene with magnetic elements is expected to solve this challenge.In this work,zigzag-like Mo_(2)TiC_(2)–MXene nanofibers(Mo-based MXene(Mo–MXene)NFs)with cross-linked networks are fabricated by hydrofluoric acid(HF)etching and potassium hydroxide(KOH)shearing processes.Subsequently,Co-metal–organic framework(MOF)and derived CoNi layered double hydroxide(LDH)ultrathin nanosheets are grown inside Mo–MXene NFs,and the N-doped carbon matrix anchored by CoNi alloy nanoparticles formed by pyrolysis is firmly embedded in the Mo–MXene NFs network.Benefiting from synergistic effect of highly dispersed small CoNi alloy nanoparticles,a three-dimensional(3D)conductive network assembled by zigzag-like Mo–MXene NFs,numerous N-doped hollow carbon vesicles,and abundant dual heterogeneous interface,the designed Mo–MXene/CoNi–NC heterostructure provides robust EMW absorption ability with a reflection loss(RL)value of−68.45 dB at the thickness(d)of 4.38 mm.The robust EMW absorption performance can be attributed to excellent dielectric loss,magnetic loss,impedance matching(Z),and multiple scattering and reflection triggered by the unique 3D network structure.This work puts up great potential in developing advanced MXene-based EMW absorption devices.

关键词： zigzag-like Mo-MXene nanofiber(NF)network dual heterogeneous interface CoNi alloy electromagnetic wave(EMW)absorption

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Coupling of ultrasmall and small CoxP nanoparticles confined in porous SiO2 matrix for a robust oxygen evolution reaction

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Nano Materials Science 2022年第4期4卷 393-399页

作者： xiaojun zeng Haiqi Zhang Xiaofeng Zhang Qingqing Zhang Yunxia Chen Ronghai Yu Martin Moskovits School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen333403China Guangdong Academy of Science Guangdong Institute of New MaterialsNational Engineering Laboratory for Modern Materials Surface Engineering TechnologyThe Key Lab of Guangdong for Modern Surface Engineering TechnologyGuangzhou510650China School of Materials Science and Engineering Beihang UniversityBeijing100191China Department of Chemistry and Biochemistry University of California Santa BarbaraSanta BarbaraCA93106United States

Rational design of electrocatalysts is important for a sustainable oxygen evolution reaction(OER).It is still a huge challenge to engineer active sites in multi-sizes and multi-components simultaneously.Here,a series of CoxP nanoparticles(NPs)confined in an SiO2matrix(SiO2/CoxP)is designed and synthesized as OER electrocatalysts.The phosphorization of the hydrolyzed Co-phyllosilicate promotes the formation of ultrasmall and small Co2P and CoP.These are firmly confined in the SiO2matrix.The coupling of multi-size and multi-component CoxP catalysts can regulate reaction kinetics and electron transfer ability,enrich the active sites,and eventually promote the intrinsic OER activity.The SiO2matrix provides abundant porous structure and oxygen vacancies,and these facilitate the exposure of active sites and improve conductivity.Because of the synergy and interplay of multisized/component CoxP NPs and the porous SiO2matrix,the unique SiO2/CoxP heterostructure exhibits low overpotential(293 m V@10 mA cm-2),and robust stability(decay 12 mV after 5000 CV cycles,97.4%of initial current after 100 h chronoamperometric)for the OER process,exceeding many advanced metal phosphide electrocatalysts.This work provides a novel tactic to design low-cost,simple,and highly efficient OER electrocatalysts.

关键词： Multi-size Multi-component Phyllosilicate SiO2/CoxP heterostructure OER

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Honeycomb-like MXene/NiFeP_(x)–NC with“continuous”single-crystal enabling high activity and robust durability in electrocatalytic oxygen evolution reactions

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Journal of Advanced Ceramics 2023年第3期12卷 553-564页

作者： xiaojun zeng Yifei Ye Yongqing Wang Ronghai Yu Martin Moskovits Galen D.Stucky Advanced Ceramic Materials Research Institute School of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen 333403China School of Materials Science and Engineering Beihang UniversityBeijing 100191China Department of Chemistry and Biochemistry University of California Santa BarbaraCA 93106USA

The development of low-cost,stable,and robust non-noble metal catalysts for water oxidation is a pivotal challenge for sustainable hydrogen production through electrocatalytic water splitting.Currently,such catalysts suffer from high overpotential and sluggish kinetics in oxygen evolution reactions(OERs).Herein,we report a“continuous”single-crystal honeycomb-like MXene/NiFeP_(x)–N-doped carbon(NC)heterostructure,in which ultrasmall NiFeP_(x)nanoparticles(NPs)encapsulated in the NC are tightly anchored on a layered MXene.Interestingly,this MXene/NiFeP_(x)–NC delivers outstanding OER catalytic performance,which stems from“continuous”single-crystal characteristics,abundant active sites derived from the ultrasmall NiFeP_(x)NPs,and the stable honeycomb-like heterostructure with an open structure.The experimental results are rationalized theoretically(by density functional theory(DFT)calculations),which suggests that it is the unique MXene/NiFeP_(x)–NC heterostructure that promotes the sluggish OER,thereby enabling superior durability and excellent activity with an ultralow overpotential of 240 mV at a current density of 10 mA×cm^(−2).

关键词： layered MXene ultrasmall NiFePx nanoparticles(NPs) “continuous”single-crystal honeycomb-like heterostructure oxygen evolution reaction(OER)activity

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Remarkably enhanced dielectric stability and energy storage properties in BNT–BST relaxor ceramics by A-site defect engineering for pulsed power applications

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Journal of Advanced Ceramics 2022年第2期11卷 283-294页

作者： Zhipeng LI Dong-Xu LI Zong-Yang SHEN xiaojun zeng Fusheng SONG Wenqin LUO Xingcai WANG Zhumei WANG Yueming LI Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi Province China National Light Industry Key Laboratory of Functional Ceramic MaterialsSchool of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen 333403China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Chengdu Hongke Electronic Technology Co. Ltd.Chengdu 610000China

Lead-free bulk ceramics for advanced pulsed power capacitors show relatively low recoverable energy storage density(Wrec)especially at low electric field condition.To address this challenge,we propose an A-site defect engineering to optimize the electric polarization behavior by disrupting the orderly arrangement of A-site ions,in which Ba_(0.105)Na_(0.325)Sr_(0.245−1.5x)□_(0.5x)Bi_(0.325)+xTiO_(3)(BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T,x=0,0.02,0.04,0.06,and 0.08)lead-free ceramics are selected as the representative.The BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T ceramics are prepared by using pressureless solid-state sintering and achieve large W_(rec)(1.8 J/cm^(3))at a low electric field(@110 kV/cm)when x=0.06.The value of 1.8 J/cm3 is super high as compared to all other W_(rec) in lead-free bulk ceramics under a relatively low electric field(<160 kV/cm).Furthermore,a high dielectric constant of 2930 within 15%fluctuation in a wide temperature range of 40–350℃is also obtained in BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T(x=0.06)ceramics.The excellent performances can be attributed to the A-site defect engineering,which can reduce remnant polarization(P_(r))and improve the thermal evolution of polar nanoregions(PNRs).This work confirms that the BNS_(0.245−1.5x)□_(0.5x)B_(0.325+x)T(x=0.06)ceramics are desirable for advanced pulsed power capacitors,and will push the development of a series of Bi0.5Na0.5TiO3(BNT)-based ceramics with high W_(rec) and high-temperature stability.

关键词： relaxor ferroelectrics energy storage ceramics ceramic capacitor Bi_(0.5)Na_(0.5)TiO_(3)(BNT) defect engine

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BS_(0.5)BNT-based relaxor ferroelectric ceramic/glass-ceramic composites for energy storage

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Journal of Advanced Ceramics 2023年第4期12卷 695-710页

作者： Xuhai Shi Kai Li Zong-Yang Shen Junqi Liu Chaoqun Chen xiaojun zeng Bo Zhang Fusheng Song Wenqin Luo Zhumei Wang Yueming Li China National Light Industry Key Laboratory of Functional Ceramic Materials Energy Storage and Conversion Ceramic Materials Engineering Laboratory of Jiangxi ProvinceAdvanced Ceramic Materials Research InstituteSchool of Materials Science and EngineeringJingdezhen Ceramic UniversityJingdezhen 333403China

Relaxor ferroelectric ceramics have very high dielectric constant(e)but relatively low electrical breakdown strength(Eb),while glass-ceramics exhibit higher E,due to the more uniformly dispersed amorphous phases and submicrocrystals/nanocrystals inside.How to effectively combine the advantages of both relaxor ferroelectric ceramics and glass-ceramics is of great significance for the development of new dielectric materials with high energy storage performance.In this work,we firstly prepared BaO-SrO-Bi_(2)O_(3)-Na_(2)0-TiO_(2)-Al_(2)O_(3)-SiO_(2)(abbreviated as GS)glass powders,and then fabricated(Ba_(0.3)Sr_(0.7))_(0.5)(Bi_(0.5)Na_(0.5))_(0.5)TiO_(3)+x wt%GS ceramic composites(abbreviated as BSo.sBNT-xGS,x=0,2,6,10,14,16,and 18).Submicrocrystals/nanocrystals with a similar composition to BSo.sBNT were crystalized from the glass,ensuring the formation of uniform core-shell structure in BSo.sBNT-xGS relaxor ferroelectric ceramic/glass-ceramic composites.When the addition amount of GS was 14 wt%,the composite possessed both high&r(>3200 at 1 kHz)and high E,(~170 kV/cm)at room temperature,and their recoverable energy storage density and efficiency were Wrec=2.1 J/cm’and n=65.2%,respectively.The BSo.sBNT-14GS composite also had several attractive properties such as good temperature,frequency,cycle stability,and fast charge-discharge speed.This work provides insights into the relaxor ceramic/glass-ceramic composites for pulsed power capacitors and sheds light on the utilization of the hybrid systems.

关键词： relaxor ferroelectrics energy storage ceramics glass-ceramics Bi_(0.5)Na_(0.5)TiO_(3)(BNT) Ba_(0.3)Sr_(0.7)TiO_(3)(BST)

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Synthesis of Acrylonitriles via Mild Base Promoted Tandem Nucleophilic Substitution-Isomerization ofα-Cyanohydrin Methanesulfonates

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Chinese Journal of Chemistry 2021年第4期39卷 913-917页

作者： Shiwen Liu Lingling Meng xiaojun zeng Gerald B.Hammond Bo Xu College of Textiles and Clothing&Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province Yancheng Institute of TechnologyYanchengJiangsu 224003China Key Laboratory of Science and Technology of Eco-Textiles Ministry of EducationCollege of ChemistryChemical Engineering and BiotechnologyDonghuo UniversityShanghai 201620China Department of Chemistry University of LouisvilleLouisvilleKentucky 40292United States

Main observation and conclusion We have developed an efficient synthesis of acrylonitriles via mild base promoted tandem nucleophilic substitution-isomerization ofα-cyanohydrin methanesulfonates with alkenylboronic acids.This transition metal-free protocol works under simple and mild conditions and offers good chemical yields for a wide range of substrates and demonstrates good functional group tolerance.

关键词： Acrylonitriles Nucleophilic substitution Isomerization α-Cyanohydrin methanesulfonates Alkenyl boronic acids

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Preliminary 3D printing of large inclined-shaped alumina ceramic parts by direct ink writing

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Journal of Advanced Ceramics 2020年第3期9卷 312-319页

作者： Liangliang YANG xiaojun zeng Allah DITTA Bo FENG Lizhong SU Yue ZHANG Key Laboratory of Aerospace Materials and Performance(Ministry of Education) School of Materials Science and EngineeringBeihang UniversityBeijing 100191China Department of Chemistry and Biochemistry University of California Santa BarbaraSanta BarbaraCalifornia 93106United States

Three dimensional(3D)printing technology by direct ink writing(DIW)is an innovative complex shaping technology,possessing advantages of flexibility in fabrication,high efficiency,low cost,and environmental-friendliness.Herein,3D printing of complex alumina ceramic parts via DIW using thermally induced solidification with carrageenan swelling was investigated.The rheological properties of the slurry under different thermally-induced modes were systematically studied.The solidification properties of thermally-induced pastes with varying contents of carrageenan were optimized.The experimental results showed that the optimized paste consisting of 0.4 wt%carrageenan could be rapidly solidified at about 55℃,which could print inclined-plane more than 60°in vertical without support,resulting in better homogeneity of the green body.A nearly pore-free structure was obtained after sintering at 1600℃ for 2 h.

关键词： three dimensional(3D)printing alumina paste solidification prcperty thermally-induced carrageenan

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Cu_(x)S_(y)-MoS_(2)异质结构的介电损耗调控及其高效电磁波吸收

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人工晶体学报 2024年第2期53卷 276-285页

作者：蒋肖李博何邦曾小军景德镇陶瓷大学材料科学与工程学院景德镇333403

二硫化钼(MoS_(2))因高的比表面积和独特的电子结构在电磁波(EMW)吸收领域备受关注,但其高导电性导致EMW吸收性能较差。为了解决这个问题,本文引入Cu_(x)S_(y)纳米颗粒,构建一种独特的Cu_(x)S_(y)-MoS_(2)异质结构,以实现适当的阻抗匹... 详细信息

二硫化钼(MoS_(2))因高的比表面积和独特的电子结构在电磁波(EMW)吸收领域备受关注,但其高导电性导致EMW吸收性能较差。为了解决这个问题,本文引入Cu_(x)S_(y)纳米颗粒,构建一种独特的Cu_(x)S_(y)-MoS_(2)异质结构,以实现适当的阻抗匹配和衰减能力。通过调控Cu_(x)S_(y)纳米颗粒,达到调节介电损耗能力,以使Cu_(x)S_(y)-MoS_(2)材料在低、中、高频率下都能表现出优异的EMW吸收性能。Cu_(x)S_(y)-MoS_(2)样品在12.68 GHz的频率下,表现出高达-72.77 dB的反射损耗(RL),而材料的匹配厚度仅为1.99 mm,优于大多数金属硫化物异质结构。此外,它还具有宽的有效吸收带宽(EAB),在1.73 mm处达到5.1 GHz(12.9~18.0 GHz)。这项工作为设计具有强吸收、宽频带和薄厚度的MoS_(2)基吸波材料提供了新的策略。

关键词： Cu_(x)S_(y) MoS_(2) 异质结构介电损耗电磁波吸收

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