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Pyrolyzed bacterial cellulose/graphene oxide sandwich interlayer for lithium–sulfur batteries

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Rare Metals 2017年第5期36卷 418-424页

作者： yu-Di Shen Zhi-Chang xiao Li-xiao Miao De-Bin Kong xiao-yu zheng Yan-Hong Chang Lin-Jie Zhi Chinese Academy of Sciences Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and Technology Beijing 100190China Department of Environmental Engineering University of Science and Technology of BeijingBeijing 100083China Beijing Key Laboratory of Resource-Oriented Treatment of Industrial Pollutants University of Science and Technology of BeijingBeijing 100083China Institute of Forensic Science Ministry of Public SecurityBeijing 100038China

Herein, a facile strategy for the synthesis of sandwich pyrolyzed bacterial cellulose（PBC）/graphene oxide（GO） composite was reported simply by utilizing the large-scale regenerated biomass bacterial cellulose as precursor. The unique and delicate structure where three-dimensional interconnected bacterial cellulose（BC） network embedded in two-dimensional GO skeleton could not only work as an effective barrier to retard polysulfide diffusion during the charge/discharge process to enhance the cyclic stability of the Li–S battery, but also offer a continuous electron transport pathway for the improved rate *** a result, by utilizing pure sulfur as cathodes, the Li–S batteries assembled with PBC/GO interlayer can still exhibit a capacity of nearly 600 mAh·g^-1 at 3C and only 0.055% capacity decay per cycle can be observed over 200 cycles. Additionally, the cost-efficient and environmentfriendly raw materials may enable the PBC/GO sandwich interlayer to be an advanced configuration for Li–S batteries.

关键词： Biomass materials Graphene oxide Separator Lithium–sulfur batteries

PAA-capped GdF3 nanoplates as dual-mode MRI and CT contrast agents

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Science Bulletin 2015年第12期60卷 1092-1100,I0002页

作者： xiao-yu zheng Ling-Dong Sun Tao zheng Hao Dong Yang Li Ye-FuWang Chun-Hua Yan Beijing National Laboratory for Molecular Sciences State Key Laboratory of Rare Earth Materials Chemistry and ApplicationsPKU-HKU Joint Laboratory in Rare Earth Materials andBioinorganic Chemistry College of Chemistry and Molecular Engineering Peking University Beijing 100871 China

Aiming at improving the sensitivity and accu- racy 9f diagnosis, the combination of magnetic resonance imaging （MRI） and X-ray computed tomography （CT） in a single probe is in urgent need. Here, we report the devel- opment of polyacrylic acid （PAA）-capped GdF3 nanoplates （NPs） as novel MRI and CT dual-mode contrast agents （CAs） with high longitudinal relaxivity （rl） and large X-ray attenuation coefficient. Uniform GdF3 rhombic NPs were fabricated by controlling reaction conditions and intro- ducing dopants. The average size of GdF3 NPs is （10.6 ：k 1.1） nm in long diagonal, （7.0 -t- 0.8） nm in short diagonal, and （4.2 -4- 1.2） nm in thickness. Ligand-exchange treat- ment was performed to render the NPs water-dispersible. The rl of PAA-capped GdF3 NPs （15.8 L/（mmol s）） is four times higher than that of clinically used Gd-DTPA. We suppose that the high r~ value originates from the con- struction of two-dimensional （2D） nanostructures, which endows nanocrystals with larger surface areas and longer rotational correlation time than those of sphere nanostruc- tures with the same volume. The CT contrast enhancement ability of PAA-capped GdF3 NPs was evaluated in com- parison with clinically used Iohexol. The above results suggest that the PAA-capped GdF3 NPs could serve as CAs for MRI and CT dual-mode imaging.

关键词： Nanoplates GdF3 Contrast agent MRI CT

Numerical and experimental study on the falling film flow characteristics with the effect of co-current gas flow in hydrogen liquefaction process

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Petroleum Science 2024年第2期21卷 1369-1384页

作者： Chong-zheng Sun yu-Xing Li Hui Han xiao-Yi Geng xiao Lu College of Energy Storage Technology Shandong University of Science and TechnologyQingdao 266590ShandongChina College of Pipeline and Civil Engineering/Shandong Provincial Key Laboratory of Oil&Gas Storage and Transportation Safety China University of PetroleumQingdao 266580ShandongChina

Liquid hydrogen storage and transportation is an effective method for large-scale transportation and utilization of hydrogen energy. Revealing the flow mechanism of cryogenic working fluid is the key to optimize heat exchanger structure and hydrogen liquefaction process(LH2). The methods of cryogenic visualization experiment, theoretical analysis and numerical simulation are conducted to study the falling film flow characteristics with the effect of co-current gas flow in LH2spiral wound heat *** results show that the flow rate of mixed refrigerant has a great influence on liquid film spreading process, falling film flow pattern and heat transfer performance. The liquid film of LH2mixed refrigerant with column flow pattern can not uniformly and completely cover the tube wall surface. As liquid flow rate increases, the falling film flow pattern evolves into sheet-column flow and sheet flow, and liquid film completely covers the surface of tube wall. With the increase of shear effect of gas-phase mixed refrigerant in the same direction, the liquid film gradually becomes unstable, and the flow pattern eventually evolves into a mist flow.

关键词： Hydrogen liquefaction Spiral wound heat exchanger Flow pattern transition Falling film flow

Investigating the elliptic anisotropy of identified particles in p-Pb collisions with a multi-phase transport model

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Nuclear Science and Techniques 2024年第2期35卷 160-169页

作者： Si-yu Tang Liang zheng xiao-Ming Zhang Ren-Zhuo Wan School of Mathematical and Physical Sciences Wuhan Textile UniversityWuhan 430200China School of Mathematics and Physics China University of Geosciences(Wuhan)Wuhan 430074China Key Laboratory of Quark and Lepton Physics(MOE)and Institute of Particle Physics Central China Normal UniversityWuhan 430079China Hubei Key Laboratory of Digital Textile Equipment Wuhan Textile UniversityWuhan 430200China School of Electronic and Electrical Engineering Wuhan Textile UniversityWuhan 430200China

The elliptic azimuthal anisotropy coefficient(v_(2))of the identified particles at midrapidity(|η|<0.8)was investigated in p-Pb collisions at√s_(NN)=5.02 TeV using a multi-phase transport model(AMPT).The calculations of differential v_(2)based on the advanced flow extraction method of light flavor hadrons(pions,kaons,protons,andΛ)in small collision systems were extended to a wider transverse momentum(p_(T))range of up to 8 GeV/c for the first *** string-melting version of the AMPT model provides a good description of the measured p_(T)-differential v_(2)of the mesons but exhibits a slight deviation from the baryon v_(2).In addition,we observed the features of mass ordering at low p_(T)and the approximate number-of-constituentquark(NCQ)scaling at intermediate p_(T).Moreover,we demonstrate that hadronic rescattering does not have a significant impact on v_(2)in p-Pb collisions for different centrality selections,whereas partonic scattering dominates in generating the elliptic anisotropy of the final *** study provides further insight into the origin of collective-like behavior in small collision systems and has referential value for future measurements of azimuthal anisotropy.

关键词： Azimuthal anisotropy Small collision systems Transport model

Epidemiologic study of soft tissue rheumatism in Shantou and Taiyuan, China

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Chinese Medical Journal 2010年第15期123卷 2058-2062页

作者： ZENG Qing-yu ZANG Chang-hai LIN Ling CHEN Su-biao LI xiao-feng xiao zheng-yu DONG Hai-yuan ZHANG Ai-lian CHEN Ren Department of Rheumatology the First Affiliated Hospital of Shantou University Medical College Shantou Guangdong 515041 China Department of Rheumatology the Second Affiliated Hospital of Shanxi Medical University Taiyuan Shanxi 030013 China Department of Statistics School of Public Health Shanxi Medical University Taiyuan Shanxi 030013 China Chenghai Municipal Hospital Shantou Guangdong 515800 China

Background Soft tissue rheumatism is a group of common rheumatic disorders reported in many *** investigating the prevalence rate of soft tissue rheumatism in different population in China, we carried out a population study in Shantou rural and Taiyuan urban *** Samples of 3915 adults in an urban area of Taiyuan, Shanxi Province, and 2350 in a rural area of Shantou,Guangdong Province were *** International League of Association for Rheumatology （ILAR）-Asia Pacific League of Association for Rheumatology （APLAR） Community Oriented Program for Control of Rheumatic Diseases （COPCORD） core questionnaire was implemented as screening *** positive responders were then all examined by *** Prevalence rate of soft tissue rheumatism was 2.0% in Taiyuan, and 5.3% in *** cuff （shoulder）tendinitis, adhesive capsulitis （frozen shoulder）, lateral epicondylitis （tennis elbow）, and digital flexor tenosynovitis （trigger finger） were the commonly seen soft tissue rheumatism in both ***, plantar fasciitis, and De Quervain＇s tenosynovitis were more commonly seen in Shantou than that in *** 1 case of fibromyalgia was found in Taiyuan and 2 cases in *** prevalence of soft tissue rheumatism varied with age, sex and *** Soft tissue rheumatism is common in Taiyuan and Shantou, *** prevalence of soft tissue rheumatism was quite different with different geographic, environmental, and socioeconomic conditions; and varying with age, sex, and *** prevalence of fibromyalgia is low in the present survey.

关键词： soft tissue rheumatism fibromyalgia epidemiology

Heme oxygenase-1 regulates the major route involved in formation of immune hepatic fibrosis in rats

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Chinese Medical Journal 2010年第22期123卷 3304-3308页

作者： DUAN Zhi-jun YANG Dong WANG Fei SUN Ying-jie SUN xiao-yu zheng Miao-lei Department of Gastroenterology First Affiliated Hospital of Dalian Medical University Dalian Liaoning 116011 China

Background Heme oxygenase （HO） plays roles in some liver diseases, but what it does in immune liver fibrosis is rarely reported. We investigated the regulation mechanisms of HO-1 in rat immune liver fibrosis to find routes for intervention. Methods Male Sprague-Dawley rats were randomly divided into control group （N, n=-12）, fibrosis group （F, n=20）, cobalt protoporphyrin （CoPP） inducing group （Co, n=20） and zinc protoporphyrin （ZnPP） inhibiting group （Zn, n=20）. In groups F, Co and Zn, immune liver fibrosis was established with human serum albumin. At the attacked stage, CoPP （5 mg/kg） and ZnPP （5 mg/kg） were intraperitoneally injected in groups Co and Zn, respectively. After establishment of rat models, the numbers of rats reduced to 11, 15, 17 and 12 in groups N, F, Co and Zn respectively, because of death during the process. HO-1 in liver was detected by Western blotting and immunohistochemistry. The indexes of fibrosis were assessed by radioimmunoassay. Concentrations of serum transforming growth factor-β1 （TGF-β1）, and tissue inhibitor of metalloproteinses （TIMP-1） were detected using enzyme-linked immunosorbent assay. Hepatic stellate cell （HSC） and proliferation degree of fibrosis were assessed by pathological examination. Data analysis was performed by SPSS 10.0 software. Results The expression of HO-1 in group F was significantly higher than that in group N, but lower than that in group Co （P 〈0.05）; while that in group Zn was lower than in group F （P 〈0.05）, but still higher than that in group N （P 〈0.01）. Compared with group N, liver functional and liver fibrosis indicators were increased in group F （P 〈0.01）, while comparing to group F, they were decreased in group Co （P 〈0.05） and increased in group Zn （P 〈0.05）. CoPP reduced the extent of hepatocellular injury and hepatic fibrosis in comparison with group F （P 〈0.01）, being the opposite effect of ZnPP （P 〈0.01）. HSC was observed using indirect method and the result showed that the number of HSC in gro

关键词： heme oxygenase-1 immune fibrosis rats

L‑Tyrosine Metabolic Pathway in Microorganisms and Its Application in the Biosynthesis of Plant‑Derived Natural Products

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World Journal of Traditional Chinese Medicine 2022年第3期8卷 386-394页

作者： Yi‑Wen Zhang Feng Nie xiao‑yu zheng Shu‑Juan Zhao The SATCM Key Laboratory for New Resources and Quality Evaluation of Chinese Medicine The MOE Key Laboratory for Standardization of Chinese Medicines and Shanghai Key Laboratory of Compound Chinese MedicinesInstitute of Chinese Materia MedicaShanghai University of Traditional Chinese MedicineShanghaiChina Experiment Center for Teaching and Learning Shanghai University of Traditional Chinese MedicineShanghaiChina

L-tyrosine,an aromatic amino acid,is an important upstream precursor for the synthesis of a series of valuable natural products such as flavonoids and phenolic *** recent years,regulation of the L‑tyrosine metabolic pathway has been devoted to enhancing the production of L-tyrosine and the derived bioactive compounds in microorganisms,usually by increasing the supply of precursors,blocking competitive routes,and modulating the transport ***,we reviewed the strategies to promote L-tyrosine production in microbial hosts and the common strategies to produce bioactive compounds in engineered Escherichia coli and Saccharomyces cerevisiae to better understand and utilize the L-tyrosine metabolic pathway for microbial overproduction of diverse valuable aromatic compounds in the future.

关键词： Biosynthesis Escherichia coli L-tyrosine Saccharomyces cerevisiae

Wireless electrical stimulation generated by piezoelectric nanomaterial promotes the dental pulp regeneration via regulating mitochondrial Ca^(2+)/PKA signaling pathway

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Journal of Materials Science & Technology 2024年第1期168卷 24-34页

作者： Jianmao zheng Jiyuan Zuo Cairong xiao Qining Guo xiaobin Fu Chengyun Ning Peng yu Guangdong Provincial Key Laboratory of Stomatology Hospital of StomatologySun Yat-Sen UniversityGuangzhou 510080China School of Materials Science and Engineering National Engineering Research Center for Tissue Restoration and ReconstructionSouth China University of TechnologyGuangzhou 510641China

The induction of dental pulp stem cells(DPSCs)into odontogenic differentiation is a cutting-edge method of dental pulp regeneration ***,it remains a challenge to develop biomaterials and ther-apies that can induce odontogenic ***,we propose a wireless electrical stimulation strat-egy to induce DPSCs odontogenic differentiation via K_(0.5)Na_(0.5)NbO_(3)piezoelectric nanoparticles(KNN)and polarized KNN(PKNN),which can be endocytosed by *** vitro,several odontogenic differentiation indexes were also increased in DPSCs treated with KNN and PKNN,and the increase was more obvious in the PKNN *** wireless electrical field promoted mitochondrial calcium concentration via mitochondrial calcium unidirectional transporter(MCU),increased the production of adenosine triphos-phate(ATP),and induced odontogenic differentiation through the activation of the cAMP-PKA signaling *** vivo,dental pulp-like tissue was induced by electrical stimulation wirelessly with KNN and PKNN,which was more clinically friendly compared with the wired device,and the induction was more obvious in the PKNN group consistent with in vitro *** conclusion,this work demonstrates the potential of PKNN as an effective stimulus that can induce odontogenic differentiation of DPSCs and be applied to dental pulp regeneration treatment.

关键词： Piezoelectric nanoparticles Dental pulp stem cells Odontogenic differentiation

Research Progress on the Pharmacological Mechanisms of Chinese Medicines that Tonify Qi and Activate Blood Against Cerebral Ischemia/Reperfusion Injury

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World Journal of Traditional Chinese Medicine 2022年第2期8卷 225-235页

作者： xiao-yu zheng Ye-Hao Zhang Wen-Ting Song Dennis Chang Jian-Xun Liu Beijing University of Chinese Medicine Graduate SchoolBeijing 100029 Institute of Basic Medical Sciences of Xiyuan Hospital China Academy of Chinese Medical SciencesBeijing Key Laboratory of Pharmacology of Chinese MateriaBeijing 100091China NICM Health Research Institute Western Sydney UniversityWestmeadNSW 2751Australia

Cerebral ischemia-reperfusion injury(CIRI) refers to a pathological phenomenon that aggravates the injury after the restoration of blood perfusion and oxygen supply to the cerebral ischemia-induced tissues and organs, with a relatively high incidence. The traditional Chinese medicine(TCM) believes that Qi deficiency and blood stasis are the cause of CIRI. Therefore, Chinese medicine for tonifying Qi and activating blood is regarded as an important choice for the treatment of CIRI. In recent years, it has been found that many Chinese herbal medical ingredients and compound Chinese medicine(CCM) have significant anti-CIRI effects, and their mechanisms of action mainly include improving brain blood supply, neuroprotection, regulating signal pathways such as TLR4/HO-1/Bcl-2, protecting mitochondrial function, regulating related protein levels, and regulating oxidative molecule levels. This article summarizes and introduces the pharmacological mechanisms of Tonifying-Qi and activating-blood Chinese medicine and CCM which have the function of anti-CIRI. Our goal is to provide effective reference for further researches on the cerebral protection of related TCMs or compounds and their clinical application.

关键词： Cerebral ischemia-reperfusion injury compound Chinese medicine ingredients of traditional Chinese medicine Qi deficiency and blood stasis Tonifying Qi and activating blood