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Chinese Journal of Chemistry 2022年第7期40卷 794-800页

作者： Wan-Wan Yao Yin Qian Xuan-Rong Chen xiao-ming ren State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry&Molecular Engineering Nanjing Tech UniversityNanjingJiangsu 211816China School of Chemistry&Environmental Engineering and Instrumental Analysis Center Yancheng Teachers University YanchengJiangsu 224007China

The family of[M(dmit)_(2)]-salts(dmit2-=2-thioxo-1,3-dithiole-4,5-dithiolate;M=Ni,Pd and Pt)generally show novel magnetic,elec-tric,magnetoelectric and photoelectric ***,a blockwall-type layered[Me3S][Ni(dmit)_(2)]radical salt(1;Me3S+=trime-thylsulfonium)was prepared and characterized by microanalysis,IR spectroscopy,thermal analysis,powder and single crystal X-ray diffraction *** 1 crystalizes in triclinic space group P-1,with two pairs of[Ni(dmit)_(2)]-and Me3S+ions in an asymmetric *** anions form blockwall-type monolayer,being parallel to crystallographic(011)plane,and the cations are accommodated in the spaces of anion *** 1 features a two-dimensional S=1/2 antiferromagnetic(AFM)spin system withθ=-97.8(1)K and a semiconductor withσ≈10-4 S·cm^(-1) and activation energy Ea=0.24(1)eV in 308-368 K.1 shows two-step dielectric relaxa-tions ranged from 173-373 K and 1-107 Hz for the dipole motions of two different polar *** importantly,the dielectric constant of 1 reaches to~17,with high-κ*** study suggests the possibility of achieving high-K materials by introducing po-lar and low rotation barrier components into van der Waals crystal and high-K[Ni(d m it)_(2)]--based electrode materials for applications in supercapacitors.

关键词： Metal-dithiolene complex Radical ionshigh-κ Semiconductors Magnetic properties

Synthesis,structure and photoluminescent property of a novel potassic compound

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Chinese Chemical Letters 2007年第12期18卷 1539-1542页

作者： Guang Xiang Liu Liang Fang Huang Heng Xu xiao ming ren College of Chemistry and Chemical Engineering Anqing Normal University Anqing Anhui 246003 PR China

A novel 3D coordination compound of K（H2TDA）（H20）（1）（H3TDA = 1H-1,2,3-triazole-4,5-dicarboxylic acid） has been prepared and characterized by IR spectroscopy, elemental analysis, ICP and single-crystal X-ray ... 详细信息

关键词： Coordination compound Potassic compound Photoluminescent property

Herpes Simplex Virus Type 1 ICP27 Protein:Its Expression, Purification and Specific Antiserum Production

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Virologica Sinica 2010年第3期25卷 199-205页

作者： Lei ZHAO xiao-ming ren Alan C. ZHENG .State Key Laboratory Wuhan Institute of Virology Chinese Academy of Sciences Wuhan 430071 China The Depautment of Animal Science Beijing University of Agriculture Beijing 102206 China

Herpes simplex virus type 1 (HSV-1) is the causative agent of cold sores and other more serious diseases. HSV-1 infected-cell protein 27 (ICP27) is an immediate-early regulatory phosphoprotein homologous to gene products identified in all classes of herpesviruses so far. To raise the antiserum to ICP27 for further characterization of its biological function, the ICP27 gene was cloned into the pET-28a (+) vector, then ICP27 protein was expressed in E. coli and purified by nickel-nitrilotriacetic acid (Ni 2+ -NTA) affinity resin column, finally the purified protein was used to raise antiserum. Western blot analysis demonstrated that the antiserum recognized the recombinant protein, and the antiserum was able to probe the ICP27 in HSV-1 infected cells with high specificity by immunofluorescence assay (IFA). Therefore, the specific antiserum will provide a valuable tool for further studies investigating ICP27's biological function during HSV-1 infection.

关键词： Herpes simplex virus type 1 (HSV-1) Infected-cell protein 27 (ICP27) Recombinant protein Antiserum Immunofluorescence assay.

The Nucleolus and Viral Infection

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Virologica Sinica 2010年第3期25卷 151-157页

作者： Lei WANG xiao-ming ren Jun-ji XING Alan C. ZHENG State Key Laboratory of Virology Wuhan Institute of Virology Chinese Academy of Sciences Wuhan 430071 China The Department of Animal Science Beijing University of Agriculture Beijing 102206 China

The nucleolus is a subnuclear structure of eukaryocytes. It was thought that nucleolus only participates in the biogenesis and processing of rRNA. However, more and more evidence shows that it has many other functions, such as tRNA precursor processing, stress sensing and it is also involved in gene silencing, senescence and cell cycle regulation. Here, we summarize the recent understandings about the nucleolar functions, the regulation of nucleolar localization of proteins and the role that the nucleolus plays in virus infection, in which some related studies of Herpes simplex virus type 1 (HSV-1) US11, UL24 and bovine herpesvirus-1 infected cell protein 27 (BICP27) carried out in our lab will also be included.

关键词： Nucleolus Stress Cell cycle regulation Virus infection.

Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation

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Chinese Journal of Chemical Engineering 2022年第8期35卷 36-43页

作者： Min Lu Mengxuan Liu Chunli Xu Yu Yin Lei Shi Hong Wu Aihua Yuan xiao-ming ren Shaobin Wang Hongqi Sun School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China School of Engineering Edith Cowan UniversityJoondalupWA 6027Australia State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemistry and Molecular EngineeringNanjing Tech UniversityNanjing 211816China School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA 5005Australia

Refractory antibiotics in domestic wastewater are hard to be completely eliminated by conventional methods,and then lead to severe environmental contamination and adverse effects on public *** present work,advanced oxidation processes(AOPs)are adopted to remove the antibiotic of sul-fachloropyridazine(SCP).Nanosized Mn_(2)O_(3) was fabricated on the SBA-15 material to catalytically acti-vate potassium peroxydisulfate(PDS)to generate reactive oxygen radicals *** and SO_(4).for SCP *** effects of location and size of Mn_(2)O_(3) were explored through choosing either the as-made or template free SBA-15 as the precursor of *** influences from the site and size of Mn_(2)O_(3) on the oxidation activity were *** was found that Mn_(2)O_(3) with a large size at the exterior of SBA-15(Mn-tfSBA)was slightly easier to degrade SCP at a low manganese loading of 1.0-2.0 mmol.g;however,complete SCP removal could only be achieved on the catalyst of Mn_(2)O_(3) with a refined size at the interior of SBA-15(Mn-asSBA).Moreover,the SO_(4).species were revealed to be the decisive radicals in the SCP degradation *** the as-made mesoporous silica as a support provides a new idea for the further development of environmentally friendly catalysts.

关键词： Advanced oxidation processes(AOPs) Sulfate radical Antibiotic degradation Manganese Mesoporous silica

Research on design and firing performance of Si-based detonator

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Defence Technology（防务技术） 2014年第1期10卷 34-39页

作者： Rui-zhen XIE xiao-ming ren Lan LIU Yan XUE Dong-xiao FU Rui ZHANG Science and Technology on Applied Physical Chemistry Laboratory Shaanxi Applied Physics-Chemistry Research Institute

For the chip integration of MEMS(micro-electromechanical system) safety and arming device, a miniature detonator needs to be developed to reduce the weight and volume of explosive train. A Si-based micro-detonator is designed and fabricated, which meets the requirement of MEMS safety and arming device. The firing sensitivity of micro-detonator is tested according to GJB/z377A-94 sensitivity test methods:Langlie. The function time of micro-detonator is measured using wire probe and photoelectric transducer. The result shows the average firing voltage is 6.4 V when the discharge capacitance of firing electro-circuit is 33 mF. And the average function time is 5.48 ms. The firing energy actually utilized by Si-based micro-detonator is explored.

关键词： Si基雷管设计解除保险装置微机电系统性能烧制测试方法

Coordination polymers with simultaneous emission of ligand-based fluorescence and phosphorescence under ambient condition

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Coordination polymers with simultaneous emission of ligand-b...

中国化学会第八届全国配位化学会议

作者： Lu Zhai xiao-ming ren State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry &Molecular Engineering Nanjing Tech University

As an important type of luminescent system, phosphorescent materials, especially room temperature phosphorescence(RTP) materials have attracted extensive attention recently due to involvement of triplet excited states and comparatively slower decay rates compare to the fluorescence systems.1 The luminescent CP/MOF materials feature easily tunable structures units and photoemission properties regarding the traditional inorganic phosphors,and one major advantage of luminescent CPs/MOFs is their ability to trigger long-lived phosphorescence at ambient temperature owing to fairly efficient restriction of vibrational decay with respect to purely organic *** present herein some CPs showing simultaneous emission of ligand-based fluorescence and phosphorescence under ambient condition, which opens a new way to develop new RTP materials.

关键词： Coordination polymer p-block metal ion Room–temperature phosphorescence

Proton Conducting Natures of Zr-MOFs and Their Mixed Matrix Membranes

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Proton Conducting Natures of Zr-MOFs and Their Mixed Matrix ...

中国化学会第十届全国无机化学学术会议

作者： Qiu ren Hong-Bin Luo Jin Zhang xiao-ming ren State Key Laboratory of Materials-Oriented Chemical Engineering Nanjing Tech University College of Chemistry and Molecular Engineering Nanjing Tech University

Metal-organic frameworks, as newly emerging materials, show compelling intrinsic structural features, e.g., the highly crystalline nature, designable and tunable porosity, and tailorable functionality, rendering them suitable for proton conducting materials. In this context, the Zirconium（IV）-based MOFs（abbr. Zr-MOFs） have attracted great attention of researchers owing to their unique advantages, such as extra highly thermal stability and excellently chemical stability in the acidic environment, as well as fast proton conducting feature. Recently, we have being investigated the proton conductance of a series of Zr-MOFs and the mixed matrix membranes of Zr-MOFs with organic polymers, and our results demonstrate that the nanocrystals of Zr-MOFs are easily prepared by tuning the pH value of the react system, the superior proton conducting nature is achievable via the strategy of postsynthesis of ligands or guests exchange and the mixed matrix membranes of Zr-MOFs with organic polymers are new types of proton exchange membranes（ref. Figure 1）, which show promising applications in a ranges of electrochemical devices, viz. electrochemical reactors, fuel cells, electrochromic displays and electrochemical sensors.

关键词： MOFs Proton conductor Mixed matrix membrane

Open-framework crystalline proton conducting materials

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Open-framework crystalline proton conducting materials

中国化学会第八届全国配位化学会议

作者： Hong-Bin Luo Yang Zou xiao-ming ren State Key Laboratory of Materials-Oriented Chemical Engineering Nanjing Tech University College of Chemistry and Molecular Engineering Nanjing Tech University

Proton conducting materials show importantly technological applications as key components in the energy conversion, electrochemical sensing and electrochromic devices. The exploration of novel proton conducting materials is significant to develop efficiently electrochemical devices. The open-framework phosphates and chalcogenides, as well as some MOFs featured with excellent thermal and superior water stability, and often exhibit much high proton conductivity,1-5 such natures make these open-frameworks being promising candidates for proton-conducting materials and having great potential for use in electrochemical devices.

关键词： Open-framework Proton conducting materials Superior water stability High proton conductivity

Inorganic-organic hybrid solid for proton conductor

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Inorganic-organic hybrid solid for proton conductor

中国晶体学会第六届学术年会暨会员代表大会（功能分子晶体分会）

作者： Hong-Bin Luo Hai-Rong Zhao xiao-ming ren State Key Laboratory of Materials-Oriented Chemical Engineering Nanjing Tech University College of Chemistry and Molecular Engineering Nanjing Tech University

Proton conducting materials show importantly technological applications as key components in the energy conversion,electrochemical sensing and electrochromic devices,and the exploration for new types of proton-conduct...

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