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Endoscopic surgery for intraventricular hemorrhage:A comparative study and single center surgical experience

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World Journal of Clinical Cases 2022年第16期10卷 5208-5216页

作者： Feng-Bo Wang xiao-Wa Yuan jin-xiao li Ming Zhang Zhao-Hui Xiang Department of Neurosurgery Xinyi People's HospitalXinyi 221400Jiangsu ProvinceChina

BACKGROUND Intraventricular hemorrhage is a neurosurgical emergency,and a dangerous condition associated with high morbidity and ***,hematoma evacuation is generally executed by external intracranial drainage(EVD)or surgical ***,endoscopic evacuation is emerging as a good alternative because it brings relatively less invasion and ***,successful endoscopic evacuation requires skilled manipulation of endoscopic devices and the evidence supporting its efficacy differs in different *** To improve the technique usage and provide more evidence of endoscopic evacuation efficacy,we summarize our surgical experience and compared the outcomes of the endoscopic evacuation with EVD using real-world *** We retrospectively studied 96 consecutive patients with intraventricular hemorrhage who underwent either endoscopic surgery(n=43)or non-endoscopic surgery(n=53)for hemorrhage evacuation between November 2013 and September 2019 in our ***’conditions prior to and after the operation were evaluated and analyzed to assess the efficacy of the *** consciousness status improvement and perioperative in-hospital parameters in the two types of operation groups were assessed and *** Patients in the endoscopic and non-endoscopic groups presented with a similar state of consciousness,with a comparable Glasgow Coma Scale(GCS)*** average operation time of the endoscopic group was longer than that of the nonendoscopic group(median 2.42 h vs 1.08 h,Pline Graeb score that indicated more severe hemorrhage than the non-endoscopic group(Graeb median:Endoscopic group=9 vs non-endoscopic group=8,P=0.023),the clearance rate of hematoma was as high as 60.5%.Both the endoscopic and non-endoscopic groups showed an improved GCS index after ***,this improvement was more marked in patients in the endoscopic group(median improvement of G

关键词： Ventriculoscope Intraventricular hemorrhage Minimal invasion Ventricular irrigation fluid Endoscopic evacuation Efficacy

基于多层混合级联RBFNN的自适应烟丝恒流量调控系统

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制造业自动化 2024年第6期46卷 204-208页

作者：金立杰张江涛肖金利刘柯尔张永生河北白沙烟草有限责任公司保定卷烟厂河北保定071003 湖南中烟工业有限责任公司吴忠卷烟厂宁夏吴忠751199 郑州世峰节能科技有限公司河南郑州450040

为解决烟草制丝过程中恒流量控制系统瞬时流量波动大的问题,提出了一种烟丝输送恒流量控制系统的软、硬件优化方法。硬件方面采用智能光栅检测高度,通过将物料高度转换为4~20 mA电流信号,实现了物料高度任意位置的精确检测,为系统控制... 详细信息

为解决烟草制丝过程中恒流量控制系统瞬时流量波动大的问题,提出了一种烟丝输送恒流量控制系统的软、硬件优化方法。硬件方面采用智能光栅检测高度,通过将物料高度转换为4~20 mA电流信号,实现了物料高度任意位置的精确检测,为系统控制提供硬件支持;软件方面提出了一种基于多层混合级联RBFNN的自适应烟丝恒流量调控算法,该算法通过混合级联多层RBFNN前馈神经网络来解决单层RBFNN拟合能力较差的问题,并通过不同的物料状态、流量等数据,实现了快速稳定的自适应计量管物料高度调控。测试结果表明:改进后的烟丝恒流量控制系统的波动由0.4%降低到0.18%。可为实现恒流量控制的最优状态及提高智能制造水平提供重要参考。

关键词：恒流量系统流量波动多层混合级联RBFNN 机器学习

Nickel-catalyzed reductive coupling reaction of monofluoroalkyl triflates with alkyl carboxylic acids toward the synthesis of α-alkyl-α-fluoro-alkylketones

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中国化学快报:英文版 2023年第10期34卷 163-167页

作者： Rui Wang Jie Xu jin-xiao li Bing-Bing Wu Ruo-Xing jin Yu-Xiang Bi Xi-Sheng Wang Key Laboratory of Precision and Intelligent Chemistry University of Science and Technology of ChinaHefei 230026China

The synthesis methods ofα-fluoro-arylketones were well-established through electrophilic/nucleophilic fluorination and transition metal catalyzed ***,due to the site selectivity and substrate restriction,only a few cases have been developed to affordα-alkyl-α-***,we report a general and efficient method of preparing diverseα-alkyl-α-fluoro-alkylketones via nickelcatalyzed reductive coupling reaction of monofluoroalkyl triflates with low-cost industrial raw material alkyl carboxylic *** transformations demonstrate high efficiency,mild conditions,and excellent functional group *** strategy provides a general and efficient method for the synthesis ofα-alkyl-α-fluoro-alkylketones。

关键词： Ni-catalyzed Reductive coupling α-Fluoroketones α-Alkyl-α-fluoro-alkylketones Monofluoroalkyl triflates

Influence of crystal-transforming agent on the performance and mechanism ofα-high-strength gypsum prepared from FGD gypsum

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Particuology 2024年第4期87卷 37-45页

作者： Zhuoyue Xu xiao Wang Biao jin Dawang Zhang Hui li College of Materials Science and Engineering Xi'an University of Architecture and TechnologyXi'an710055China Schoolof Materials and Chemical Engineering Henan University of Urban ConstructionPingdingshan46736China

This paper investigates the impact of flue gas desulfurization(FGD)gypsum's crystal modifier on the characteristics and microcosmic mechanism ofα-high strength *** results demonstrate that all three crystal modifiers can convert FGD gypsum toα-high-strength *** acid(CA)has the most significant influence onα-high-strength gypsum,and the preparedα-high-strength gypsum is short columnar,with an aspect ratio in the range of 1-3,and has a faster setting time,a larger specific surface area,and a smaller standard consistency,higher compressive strength,greater surface hardness,and smaller crystal particle *** initial setting time of theα-high-strength gypsum manufactured with CA crystal modifier was decreased by 36%compared to the blank sample,the final setting time was lowered by 37.5%,and the water consumption of the standard consistency was reduced by 8%.The maximum strength is 32 MPa after 2 h,the absolute dry compressive strength is up to 38 MPa,and the surface hardness is improved by 24.43%.

关键词： Flue gas desulfurization gypsum Crystal modifier Microscopic mechanism α-high-strength gypsum

Reduced Macrophage Uptake of Nanoparticles through Surface Modification of Polypeptides with Valine Residues

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Chinese Journal of Chemistry 2024年第11期42卷 1209-1216页

作者： Ning li Shanshan xiao xiaoxiong jin Ziyuan Song Institute of Functional Nano&Soft Materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials and DevicesSoochow UniversitySuzhouJiangsu215123 China

The structural and surface properties of nanomedicines play an important role in determining their biological fate. Surface chemistry of nanomedicines is one of the key parameters, where researchers used various strategies such as PEGylation to avoid the undesired clearance of nanoparticles (NPs) for enhanced targeting effect. Nevertheless, the fine-tuning of surface chemistry through polymer functionalization remains largely unexplored. In this concise report, we find that the incorporation of only 10 mol% valine residues into the surface-anchored poly(L-glutamic acid) significantly lowered the macrophage uptake of NPs. The introduction of other hydrophobic amino acid residues, however, increased the NPs internalization instead. The chirality and the side-chain structure of valine played an important role in the unexpected uptake behavior. We believe this work highlights the impact of slight changes of the surface-anchored polymer structure on the behavior of NPs, drawing people's attention to the careful design of surface chemistry to optimize the nanomedicine design.

关键词： Nanoparticles Copolymers Structure-activity relationships Surface chemistry Polypeptide Macrophage uptake

Experimental Study on Engineering Behavior of Solidified Soil for Scour Repair and Protection

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China Ocean Engineering 2024年第4期38卷 625-635页

作者： WU xiao-ni li Ru-yu SHU Jian TANG Chao CHEN jin-jian WANG Hui-li JIANG Hai-li WANG xiao State Key Laboratory of Ocean Engineering Department of Civil EngineeringShanghai Jiao Tong UniversityShanghai 200240China Shanghai Road and Bridge Group Co. Ltd.Shanghai 200433China Shanghai Engineering Research Center of Urban Infrastructure Renewal Shanghai 200032China Jiangsu Kunze Technology Co. Ltd.Nanjing 210000China

A new scour countermeasure using solidified slurry for offshore foundation has been proposed *** solidified slurry is pumped to seabed area around foundation for scour protection or pumped into the developed scour holes for scour repair as the fluidized material solidifies *** the pumping operation and solidification,the engineering behaviors of solidified slurry require to be considered synthetically for the reliable application in scour repair and protection of ocean engineering such as the pumpability related flow value,flow diffusion behavior related rheological property,anti-scour performance related retention rate in solidification and bearing capacity related strength property after *** this study,a series of laboratory tests are conducted to investigate the effects of mix proportion(initial water content and binder content)on the flow value,rheological properties,density,retention rate of solidified slurry and unconfined compressive strength(UCS).The results reveal that the flow value increases with the water content and decreases with the binder *** the solidified slurry exhibits Bingham plastic behavior when the shear rate is larger than 5 s^(-1).The Bingham model has been employed to fit the rheology test results,and empirical formulas for obtaining the density,yield stress and viscosity are established,providing scientific support for the numerical assessment of flow and diffusion of solidified *** rate of solidified slurry decreases with the water flow velocity and flow value,which means the pumpability of solidified slurry is contrary to anti-scour *** unconfined compressive strength after solidification reduces as the water content increases and binder content decreases.A design and application procedure of solidified soil for scour repair and protection is also proposed for engineering reference.

关键词： scour repair and protection solidified soil pumpability strength flow properties anti-scour performance

A micro-crosslinked amphoteric hydrophobic association copolymer as high temperature-and salt-resistance fluid loss reducer for water-based drilling fluids

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Petroleum Science 2024年第3期21卷 1980-1991页

作者： Jian li Yu-Xi Ji xiao-xiao Ni Kai-He Lv Xian-Bin Huang jin-Sheng Sun School of Petroleum Engineering China University of Petroleum(East China)Qingdao266580ShandongChina Key Laboratory of Unconventional Oil&Gas Development China University of Petroleum(East China)Qingdao26650ShandongChina Inspection and Testing Center of Huabei Oil Field Company PetroChinaRenqiu062552HebeiChina Drilling Fluid Research Institute CNPC Engineering Technology R&D Company LimitedBeijing102206China

During ultradeep oil and gas drilling,fluid loss reducers are highly important for water-based drilling fluids,while preparing high temperature-and salt-resistance fluid loss reducers with excellent rheology and filtration performance remains a ***,a micro-crosslinked amphoteric hydrophobic association copolymer(i.e.,DADC)was synthesized using N,N-dimethyl acrylamide,diallyl dimethyl ammonium chloride,2-acrylamido-2-methylpropane sulfonic acid,hydrophobic monomer,and pentaerythritol triallyl ether *** to the synergistic effects of hydrogen bonds,electrostatic interaction,hydrophobic association,and micro-crosslinking,the DADC copolymer exhibited outstanding temperature-and *** rheological experiments have shown that the DADC copolymer had excellent shear dilution performance and a certain degree of salt-responsive viscosity-increasing *** DADC copolymer could effectively adsorb on the surface of bentonite particles through electrostatic interaction and hydrogen bonds,which bring more negative charge to the bentonite,thus improving the hydration and dispersion of bentonite particles as well as the colloidal stability of the drilling ***,the drilling fluids constructed based on the DADC copolymer exhibited satisfactory rheological and filtration properties(FLHTHP=12 m L)after aging at high temperatures(up to200℃)and high salinity(saturated salt)***,this work provided new insights into designing and fabricating high-performance drilling fluid treatment agents,demonstrating good potential applications in deep and ultradeep drilling engineering.

关键词： Fluid loss reducer Temperature-and salt-resistance Hydrophobic association Amphoteric Micro-crosslinking

Study on the atmospheric heat engine efficiency and heat source characteristics of the Qinghai-Tibet Plateau in summer

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Science China Earth Sciences 2024年第1期67卷 117-133页

作者： Yujie li xiaoqing GAO Yaoming MA Zeyong HU Zhenchao li liwei YANG xiao jin Xiyin ZHOU Key Laboratory of Land Surface Process and Climate Change in Cold and Arid Regions of Chinese Academy of Sciences Northwest Institute of Eco-Environment and ResourcesChinese Academy of SciencesLanzhou 730000China Tianjin Key Laboratory for Oceanic Meteorology Tianjin Institute of Meteorological ScienceTianjin 300074China Institute of Tibetan Plateau Research Chinese Academy of SciencesBeijing 100049China University of Chinese Academy of Sciences Beijing 100049China

There are many types of atmospheric heat engines in land-air *** accurate definition,calculation and interpretation of the efficiency of atmospheric heat engines are key to understanding energy transfer and transformation of landair *** atmosphere over the Qinghai-Tibet Plateau(QTP)in summer can be regarded as a positive heat *** study of the heat engine efficiency is helpful to better understand land-air interaction and thermal-dynamic processes on the *** also provides a new perspective to explain the impact of the QTP on the climate of China,East Asia and even the *** this paper,we used MOD08 and ERA5 reanalysis data to calculate the atmospheric heat engine efficiency,surface heat source and atmospheric heat source on the QTP in summer(May to September)from 2000 to *** average atmospheric heat engine efficiency on the QTP in summer from 2000 to 2020 varies between 1.2%and 1.5%,which is less than 1.6%;the heat engine efficiency in summer is higher than that in June,July and August;the Qaidam Basin is the region with the highest atmospheric heat engine efficiency,followed by the western *** mean surface heat source on the QTP in summer from 2000 to 2020 is 96.0 W m^(−2),the atmospheric heat source is 90.7 W m^(−2),and the release of precipitation condensation latent heat is the most important component of the atmospheric heat source on the QTP in *** is a strong and significant positive correlation between the atmospheric heat engine efficiency and the surface heat source on the QTP in *** precipitation condensation latent heat is the most important component of the atmospheric heat source in summer and can reflect the precipitation *** is a strong and significant negative correlation between the atmospheric heat engine efficiency and the atmospheric heat source on the QTP in summer.

关键词： Qinghai-Tibet Plateau Climate change Land-air system Atmospheric heat engine Heat source on the Qinghai-Tibet Plateau

Construction of biomimetic proton transport channels in metal-organic framework

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Chinese Chemical Letters 2024年第3期35卷 513-517页

作者： xiao-Min li Junchao Jia Danting Yang Jiali jin Junkuo Gao School of Materials Science and Engineering Institute of Functional Porous MaterialsZhejiang Sci-Tech UniversityHangzhou 310018China Zhejiang Key Laboratory of Pathophysiology School of Public HealthSchool of MedicineNingbo UniversityNingbo 315211China

Construction of proton transport channels in metal-organic frameworks(MOFs)with simple synthesis processes,high proton conductivities and good performance stabilities has been of great interest for proton exchange membrane fuel cell(PEMFC).Herein,we mimic the proton transport behavior of amino acid residues in bacteriorhodopsin,select UiO-66-COOH as the host,glycine and aspartic acid as the functional guest molecules,and then functionalize the MOF framework with amino acids to obtain biomimetic proton transport *** strategy endows UiO-66-COOH-Asp a high proton conductivity of 1.19×10^(-2)S/cm at 70℃and 98%RH,excellent cycle stability of performances and performance durability,which can be comparable to the reported MOFs-based proton ***,the proton conduction mechanism in UiO-66-COOH-Asp is elaborated in detail due to its visual structure,which is also one of the advantages of adopting MOFs as research platform,making it possible to optimize the structure-activity relationship of advanced ***,this strategy has clear objectives and simple synthesis,which has made certain contributions to both theoretical research and future industrial production of proton conductors.

关键词： MOF Amino acids Biomimetic proton transport channels Synergistic effect Proton conduction mechanism