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Crystalline-amorphous M@MN_x(M=Co,Fe,Ni)encapsulated in nitrogen-doped carbon for enhanced efficient and durable hydrogen evolution reaction

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Rare Metals 2024年第4期43卷 1547-1556页

作者： yang yang xiao-Chuan Duan Shao-hui Guo Xian-Ming Zhang College of Materials Science and Engineering College of ChemistryKey Laboratory of Interface Science and Engineering in Advanced MaterialsTaiyuan University of TechnologyYuci030600China

Developing earth-abundant electrocatalysts for hydrogen evolution reaction(HER)is important for the sustainable energy ***,efficient and stable heterocatalysts consisting of crystalline-amorphous M@MN_(x)(M=Co,Fe,Ni)encapsulated in N-doped carbon layers supported with N-doped graphene sheets(denoted as M@MN_(x)@NC-NG)are synthesized by facile hydrothermal reaction and nitridation *** the nitriding process,metal ions in M(tzbc)_2(H_(2)O)_4(tzbc=4-(1H-1,2,4-triazol-1-yl)benzoic acid)complexes are reduced to crystalline M cores,accompanied by the formation of amorphous MN_(x)shells;the tzbc ligands are insitu carbonized to form outermost N-doped carbon(NC)layers that connect with inner MN_(x)via M-N-C motifs inherited from the complex precursors and inhibit the transition of MN_(x)from amorphous to crystalline *** Co@CoN_(x)@NC-NG catalyst exhibits excellent HER activity with small overpotentials of 45 and 64 mV at a cathode current density of 10 mA·cm^(-2)and low Tafel slopes of 40 and 85 mV·dec^(-1)in 0.5 mol·L^(-1)H_(2)SO_4 and1.0 mol·L^(-1)KOH electrolytes,*** Co@CoN_(x)@NC-NG retains 97%of the initial overpotential after 100,000 s in both acidic and alkaline *** outstanding HER performance originates from the crystalline-amorphous Co@CoN_(x)that redistributes electrons around the heterointerfaces,facilitating the conversion process of H^(+)/H_(2)O to hydrogen and thereby promoting HER *** outermost NC layers serve as the armor of Co@CoN_(x),and graphene nanosheets act as carriers of egg-like Co@CoN_(x)@NC and conduction paths for electron shuttles,ensuring stable and continuous electrocatalytic hydrogen production.

关键词： Hydrogen evolution reaction Electrocatalysts Iron group metals Heterojunction Crystalline-amorphous structure

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Crude oil wax:A review on formation,experimentation,prediction,and remediation techniques

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Petroleum Science 2022年第5期19卷 2343-2357页

作者： Wyclif Kiyingi Ji-Xiang Guo Rui-Ying Xiong Li Su xiao-hui yang Shi-Ling Zhang Unconventional Petroleum Research Institute China University of PetroleumBeijing102249China Sinopec Northwest Oil Field Branch UrumqiXinjiang830011China CNPC Engineering Technology R&D Company Limited BeijingChina

Wax deposition during crude oil production,transportation,and processing has been a headache since the early days of oil *** may lead to low mobility ratios,blockage of production tubing/pipelines as well as fouling of surface and processing facilities,among *** snags cause massive financial constraints increasing projects’*** of meticulous research have been dedicated to this problem that is worth a ***,this paper reviews the mechanisms,experimentation,thermodynamic and kinetic modeling,prediction,and remediation techniques of wax *** overall assessment suggests that available models are more accurate for single than multi-phase flows while the kind of remediation and deployment depend on the environment and severity *** severe cases,both chemical and mechanical are synergistically ***,future prospective research areas that require attention are ***,this review could be a valuable tool for novice researchers as well as a foundation for further research on this topic.

关键词： Oil wax Phase modeling Inhibitors Dispersants Multi-phase flow

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Label-free quantification of peptides in solution by disposable patterned hydrophilic chip based MALDI imaging

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Chinese Chemical Letters 2016年第6期27卷 901-904页

作者： Ting Wu xiao-hui yang Chuan-Jing Zhang Zhen-Ping Wang Yi-Ping Du Shanghai Key Laboratory of Functional Materials Chemistry Research Centre of Analysis and Test East China University of Science and Technology

Quantification of a mixture of peptides in solution was achieved by disposable patterned hydrophilic chip based matrix-assisted laser desorption/ionization mass spectrometric imaging（MALDI MSI）.Compared with other quantitative methods for peptides in solution, this method is label-free and does not require separation of the multiple components of the solution before analysis. Uniform hydrophilic spots and high mass accuracy measurements provided confident identification and quantitative analysis of imaged compounds. The linear correlation between concentration and grayscale of image in the range of 5 fmol/μ L to 1 pmol/μ L was obtained for all four peptides. Good sensitivity and excellent reproducibility were also achieved. The method expands the application of MALDI MSI from tissues to solutions.

关键词： MALDI imaging Quantitative analysis Label-free Microarray Patterned hydrophilic chip

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Particle segregation mechanism of S-D system in a rotating drum

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PARTICUOLOGY 2024年第10期93卷 300-308页

作者： xiao, Erliang Zhang, Wei Chi, Zhipeng Li, Ran yang, hui Univ Shanghai Sci & Technol Sch Opt Elect & Comp Engn Shanghai 200093 Peoples R China Shanghai Univ Med & Hlth Sci Coll Med Instrumentat Shanghai 201318 Peoples R China

Complex segregation occurs in a binary particle system with differing particle sizes and densities, particularly when the larger particles are heavier (S-D system, i.e., size minus density system). Predicting the segregation pattern driven by multiple mechanisms simultaneously is often challenging. This study explores the segregation mechanisms in a quasi-2D circular drum containing a S-D system, realizing a transition between the S-core and Core-and-band patterns by adjusting the drum rotation speed. During the transition of the segregation pattern, only the S-core pattern chiefly driven by the percolation mechanism is initially observed. As the rotation speed increases, the buoyancy mechanism and particle diffusion gradually strengthen, jointly driving the formation of the Core-and-band pattern. A dimensionless strength ratio, l 1/4 H=h, where H and h respectively represent the diffusion and buoyancy strengths at length scales, is introduced to elucidate this transition. The Core-and-band pattern emerges when l reached 1.4. (c) 2024 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights are reserved, including those for text and data mining, AI training, and similar technologies.

关键词： Particle segregation S -D system Segregation mechanisms competition Segregation pattern Rotating drum GRANULAR MIXTURES DRIVEN SEGREGATION SIZE SEGREGATION DENSITY RATIO PERCOLATION BEHAVIOR SPEED

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Metabolomic Analysis in Saliva and Different Brain Regions of Older Mice with Postoperative Delirium Behaviors

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Biomedical and Environmental Sciences 2024年第2期37卷 133-145页

作者： LIU xiao CAO Ying LIN xiao Wan GAO Dan yang MIAO hui hui LI Tian Zuo Department of Anesthesiology Beijing Shijitan HospitalCapital Medical UniversityBeijing 100038China

Objective Postoperative delirium(POD)has become a critical challenge with severe consequences and increased incidences as the global population ***,the underlying mechanism is yet *** study aimed to explore the changes in metabolites in three specific brain regions and saliva of older mice with postoperative delirium behavior and to identify potential non-invasive *** Eighteen-month-old male C57/BL6 mice were randomly assigned to the anesthesia/surgery or control *** tests were conducted 24 h before surgery and 6,9,and 24 h after *** C3(C3)and S100 calcium-binding protein B protein(S100beta)levels were measured in the hippocampus,and a metabolomics analysis was performed on saliva,hippocampus,cortex,and amygdala *** In total,43,33,38,and 14 differential metabolites were detected in the saliva,hippocampus,cortex,and amygdala,respectively.“Pyruvate”“alpha-linolenic acid”and“2-oleoyl-1-palmitoy-snglycero-3-phosphocholine”are enriched in one common pathway and may be potential non-invasive biomarkers for *** changes were observed in the three brain regions,with the upregulation of 1-methylhistidine and downregulation of *** Dysfunctions in energy metabolism,oxidative stress,and neurotransmitter dysregulation are implicated in the development of *** identification of changes in the level of salivary metabolite biomarkers could aid in the development of noninvasive diagnostic methods for POD.

关键词： Metabolomic Postoperative delirium(POD) Mechanism Biological marker

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A New Nortriterpenoid Glycoside from Sinofranchetia chinensis

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Chinese Chemical Letters 2001年第1期12卷 55-58页

作者： xiao hui yang Rui Jun MA Run Hua LU xiao Ning WEI Yun Pu WANG Han Qing WANG Jie KONG Department of Biology Northwest Normal UniversityLanzhou 730070 United Laboratory ofTibetanMedicines andNaturalMedicines Lanzhou Institute of Chemical Physics Chinese Academy of SciencesChee Zheng Tibetan Medicines GroupLanzhou 730000 Department of Chemistry NorthwestNormal UniversityLanzhou 730070

A new 30-nortriterpenoid glycopside, 3-O-a-L-arabinopyranosyl-30-norhederagenin 28-O-a-L-rhamnopyranosyl(1-->4)-beta -D-glucopyranosyl (1-->6)-beta -D-glucopyranoside 1, named sinofoside A was isolated from Sinofranchetia chinensis. Its structure was elucidadated by spectra FAB-MS, 2D-NMR including H-1-H-1 COSY, H-1-C-13 COSY, TOSCY, HMBC and NOESY techniques.

关键词： Sinofranchetia chinensis nortriterpenoid glycopside sinofoside A 2D-NMR

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Stromal thrombospondin 1 suppresses angiogenesis in oral submucous fibrosis

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International Journal of Oral Science 2024年第1期16卷 163-172页

作者： xiao yang hui Zhao Rui Li yang Chen Zhi Xu Zhengjun Shang State Key Laboratory of Oral&Maxillofacial Reconstruction and Regeneration Key Laboratory of Oral Biomedicine Ministry of EducationHubei Key Laboratory of StomatologySchool&Hospital of StomatologyWuhan UniversityWuhanChina Department of Oral and Maxillofacial-Head and Neck Oncology School of Stomatology–Hospital of StomatologyWuhan UniversityWuhanChina Department of Stomatology Union HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhanChina

A decline in mucosal vascularity is a histological hallmark of oral submucous fibrosis (OSF), a premalignant disease that is largely induced by betel quid chewing. However, the lack of available models has challenged studies of angiogenesis in OSF. Here, we found that the expression of thrombospondin 1 (THBS1), an endogenous angiostatic protein, was elevated in the stroma of tissues with OSF. Using a fibroblast-attached organoid (FAO) model, the overexpression of THBS1 in OSF was stably recapitulated in vitro. In the FAO model,treatment with arecoline, a major pathogenic component in areca nuts, enhanced the secretion of transforming growth factor (TGF)-β1 by epithelial cells, which then promoted the expression of THBS1 in fibroblasts. Furthermore, human umbilical vein endothelial cells (HUVECs)were incorporated into the FAO to mimic the vascularized component. Overexpression of THBS1 in fibroblasts drastically suppressed the sprouting ability of endothelial cells in vascularized FAOs (v FAOs). Consistently, treatment with arecoline reduced the expression of CD31in v FAOs, and this effect was attenuated when the endothelial cells were preincubated with neutralizing antibody of CD36, a receptor of THBS1. Finally, in an arecoline-induced rat OSF model, THBS1 inhibition alleviated collagen deposition and the decline in vascularity in vivo. Overall, we exploited an assembled organoid model to study OSF pathogenesis and provide a rationale for targeting THBS1.

关键词： angiogenesis elevated endogenous

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Layer-Wise Pre-Training Low-Rank NMF Model for Mammogram-Based Breast Tumor Classification

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Journal of the Operations Research Society of China 2019年第4期7卷 515-537页

作者： Wen-Ming Wu xiao-hui yang Yun-Mei Chen Juan Zhang Dan Long Li-Jun yang Chen-Xi Tian Data Analysis Technology Lab Institute of Applied MathematicsSchool of Mathematics and StatisticsHenan UniversityKaifeng 475004HenanChina Department of Mathematics University of FloridaGainesvilleFL 32611USA Zhejiang Cancer Hospital Hangzhou 310022China

Image-based breast tumor classification is an active and challenging *** this paper,a robust breast tumor classification framework is presented based on deep feature representation learning and exploiting available information in existing *** representation learning of mammograms is fulfilled by a modified nonnegative matrix factorization model called LPML-LRNMF,which is motivated by hierarchical learning and layer-wise pre-training(LP)strategy in deep ***-rank(LR)constraint is integrated into the feature representation learning model by considering the intrinsic characteristics of ***,the proposed LPML-LRNMF model is optimized via alternating direction method of multipliers and the corresponding convergence is *** completing classification,an inverse projection sparse representation model is introduced to exploit information embedded in existing samples,especially in test *** on the public dataset and actual clinical dataset show that the classification accuracy,specificity and sensitivity achieve the clinical acceptance level.

关键词： Breast tumor classification Mammogram LPML-LRNMF Inverse space sparse representation ADMM

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MIXED EXCITATION IN ELECTROLUMINESENCE

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Chinese Journal of Polymer Science 2001年第6期19卷 579-583页

作者： Xu-rong Xu Xiu-lai Xu xiao-feng Wang xiao-hui yang Zheng Xu Yan-bing Hou Institute of Optoelectronics Technology Northern Jiaotong University Beijing 100044 China 北方交通大学北京

Among the present three types of electric field-induced luminescence we noticed similarities between the inorganic and organic materials in electric field intensity. In this high electric field range SiO2 has three functions: acceleration, excitation and multiplication of electrons. Based on the acceleration effect, cathodoluminescence-like emission of organic molecules and polymers was found. By using the three functions of SiO2 or II-VI compounds and the heterojunction of inorganic and organic material we realized different variants of mixed excitation in electroluminescence.

关键词： cathodoluminescence-like emission mixed excitation inorganic-organic heterogeneous junction

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Effect of Mn addition on microstructure and mechanical properties of GX40CrNiSi25-12 austenitic heat resistant steel

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China Foundry 2024年第3期21卷 205-212页

作者： Guan-yu Jiang Meng-wu Wu xiao-guang yang hui Wang Yu-yuan Zhu Hubei Key Laboratory of Advanced Technology for Automotive Components Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Xiangyang 441000HubeiChina Wescast Industries(China)Co. Ltd.Wuhan 430100China

Three types of steels were designed on the basis of GX40CrNiSi25-12 austenitic heat resistant steel by adding different Mn contents(2wt.%,6wt.%,and 12wt.%).Thermodynamic calculation,microstructure characterization and mechanical property tests were conducted to investigate the effect of Mn addition on the microstructure and mechanical properties of the austenitic heat resistant *** show that the matrix structure in all the three types of steels at room temperature is completely *** NbC and M_(23)C_(6)precipitate at grain boundaries of austenite *** the increase of Mn content,the number of carbides increases and their distribution becomes more *** the Mn content increases from 1.99%to 12.06%,the ultimate tensile strength,yield strength and elongation increase by 14.6%,8.0%and 46.3%,*** improvement of the mechanical properties of austenitic steels can be explained by utilizing classic theories of alloy strengthening,including solid solution strengthening,precipitation strengthening,and grain *** increase in alloy strength can be attributed to solid solution strengthening and precipitation strengthening caused by the addition of *** improvement of the plasticity of austenitic steels can be explained from two aspects:grain refinement and homogenization of precipitated phases.

关键词： austenitic heat resistant steel manganese microstructure mechanical properties

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