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Microstructure and wear resistance of AlCrFeNiMo_(0.5)Si_(x) high-entropy alloy coatings prepared by laser cladding

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China Foundry 2022年第6期19卷 473-480页

作者： xiao-cong li Hui liang Yan-zhou Zhao li Gao li Jiang Zhi-qiang Cao Key Laboratory of Solidification Control and Digital Preparation Technology(liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116024LiaoningChina School of Physics and Electronic Technology Liaoning Normal UniversityDalian 116029LiaoningChina

In recent years,the coating prepared by laser cladding has attracted much attention in the field of wear *** this work,AlCrFeNiMo_(0.5)Si_(x)(x=0,0.5,1.0,1.5,2.0)high-entropy alloy coatings were designed and prepared on Q235 steel by laser *** effect of Si content on microstructure,microhardness and wear resistance of the coatings was studied in *** results indicate that the AlCrFeNiMo_(0.5)Si_(x) highentropy alloy coatings show an excellent bonding between substrate and the cladding *** AlCrFeNiMo_(0.5)Si_(x) coatings are composed of nano-precipitated phase with BCC structure and matrix with ordered B2 *** the addition of Si,the white phase(Cr,Mo)_(3)Si with cubic structure appears in the interdendritic,and the morphology of the coating(x=2.0)transforms into lamellar eutectic-like *** addition of Si enhances the microhardness and significantly improves the wear resistance of the *** x increases from 0 to 2.0,the average hardness of the cladding zone increases from 632 HV to 835 HV,and the wear rate decreases from 1.64×10^(-5) mm^(3)·(N·m)^(-1) to 5.13×10^(-6) mm^(3)·(N·m)^(-1).When x≥1.5,the decreasing trend of the wear rate gradually slows *** wear rates of Si1.5 and Si2.0 coatings are 5.85×10^(-6) mm^(3)·(N·m)^(-1) and 5.13×10^(-6) mm^(3)·(N·m)^(-1),respectively,which is an order of magnitude lower than that of Q235 steel.

关键词： high-entropy alloy coatings laser cladding microstructure wear resistance

Pluggable multitask diffractive neural networks based on cascaded metasurfaces

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Opto-Electronic Advances 2024年第2期7卷 23-31页

作者： cong He Dan Zhao Fei Fan Hongqiang Zhou Xin li Yao li Junjie li Fei Dong Yin-xiao Miao Yongtian Wang lingling Huang Beijing Engineering Research Center of Mixed Reality and Advanced Display Key Laboratory of Photoelectronic Imaging Technology and System of Ministry of Education of ChinaSchool of Optics and PhotonicsBeijing Institute of TechnologyBeijing 100081China Institute of Modern Optics Tianjin Key Laboratory of Optoelectronic Sensor and Sensing Network TechnologyNankai UniversityTianjin 300350China Department of Physics and Optoelectronics Faculty of ScienceBeijing University of TechnologyBeijing 100124China Beijing National Laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100191China Beijing Aerospace Institute for Metrology and Measurement Technology Beijing 100076China

Optical neural networks have significant advantages in terms of power consumption,parallelism,and high computing speed,which has intrigued extensive attention in both academic and engineering *** has been considered as one of the powerful tools in promoting the fields of imaging processing and object ***,the existing optical system architecture cannot be reconstructed to the realization of multi-functional artificial intelligence systems *** push the development of this issue,we propose the pluggable diffractive neural networks(P-DNN),a general paradigm resorting to the cascaded metasurfaces,which can be applied to recognize various tasks by switching internal *** the proof-of-principle,the recognition functions of six types of handwritten digits and six types of fashions are numerical simulated and experimental demonstrated at near-infrared ***,the proposed paradigm not only improves the flexibility of the optical neural networks but paves the new route for achieving high-speed,low-power and versatile artificial intelligence systems.

关键词： optical neural networks diffractive deep neural networks cascaded metasurfaces

Challenges in li-ion battery high-voltage technology and recent advances in high-voltage electrolytes

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Journal of Energy Chemistry 2024年第4期91卷 73-98页

作者： Jianguo liu Baohui li Jinghang Cao xiao Xing Gan Cui Shandong Key Laboratory of Oil&Gas Storage and Transportation Safety College of Pipeline and Civil EngineeringChina University of Petroleum(East China)Qingdao 266580ShandongChina

The electrolyte directly contacts the essential parts of a lithium-ion battery,and as a result,the electrochemical properties of the electrolyte have a significant impact on the voltage platform,charge discharge capacity,energy density,service life,and rate discharge *** raising the voltage at the charge/discharge plateau,the energy density of the battery is ***,this causes transition metal dissolution,irreversible phase changes of the cathode active material,and parasitic electrolyte oxidation *** article presents an overview of these concerns to provide a clear explanation of the issues involved in the development of electrolytes for high-voltage lithium-ion ***,solidstate electrolytes enable various applications and will likely have an impact on the development of batteries with high energy *** is necessary to improve the high-voltage performance of electrolytes by creating solvents with high thermal stabilities and high voltage resistance and additives with superior film forming performance,multifunctional capabilities,and stable lithium *** offer suggestions for the future development of high-energy lithium-ion batteries,we conclude by offering our own opinions and insights on the current development of lithium-ion batteries.

关键词： lithium-ion battery High voltage Electrolyte additive Solid electrolyte

A Study of the Effect of the Miller Cycle on the Combustion of a Supercharged Marine Diesel Engine

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Energy Engineering 2024年第5期121卷 1363-1380页

作者： lingjie Zhao cong li Mechanical and Automotive Engineering School Shanghai University of Engineering ScienceShanghai201600China

The Miller cycle is a program that effectively reduces NOx emissions from marine diesel engines by lowering the maximum combustion temperature in the cylinder,thereby reducing NOx *** effectively investigate the impact of Miller cycle optimum combustion performance and emission capability under high load conditions,this study will perform a one-dimensional simulation of the performance of a marine diesel engine,as well as a threedimensional simulation of the combustion in the cylinder.A 6-cylinder four-stroke single-stage supercharged diesel engine is taken as the research *** chassis dynamometer and other related equipment are used to build the test system,carry out the diesel engine bench test,and collect experimental *** simulation results are compared with the test results,and the error is less than 5%.In this study,the authors will use simulation software to simulate several Miller cycle scenarios designed for early inlet valve closure and analyze the impact of the Miller cycle on combustion and emissions at 100%load *** comparing the flow field distribution of the engine at 1500 r/min condition,it was found that proper EIVC can prolong the ignition latency period and homogeneous fuel-air mixture combustion acceleration,but it can reduce pressure and temperature within the piston chamber and NOx ***,the Miller cycle reduces end-of-compression temperatures,which increases combustion duration and exhaust temperatures,making it difficult to improve fuel economy at the optimum fuel consumption point,and closing the intake valves prematurely leads to excessive fuel ***,temperature and heat release rate within the piston chamber,NOx,and SOOT generation were significantly enhanced.

关键词： Miller cycle EIVC combustion NOx emissions marine diesel

Construction of electron rich Fe active sites by FeCu alloy anchoring on carbon nitride for photocatalytic nitrogen reduction

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Rare Metals 2024年第4期43卷 1570-1579页

作者： Gang Dong cong Huang Fei-Yang Chen Xue-Qin liu Zhen li xiao-li Su Tao Zeng Yun-Xia Chen Yi-Huang Chen Yang Wang School of Materials Science and Engineering Jingdezhen Ceramic UniversityJingdezhen333403China Faculty of Materials Science and Chemistry China University of GeosciencesWuhan430074China College of Chemistry and Materials Engineering Wenzhou UniversityWenzhou325035China

Given the clean and inexhaustible solar energy from solar light,photocatalytic ammonia synthesis is extremely ***,high electron-hole recombination rates and insufficient active sites severely limited N2 photoreaction ***,we designed and fabricated FeCu alloy nanoparticles anchored on carbon nitride nanosheets with excellent photocatalyt ic ammonia synthesis *** a coupler between Fe and carbon nitride,Cu promotes the separation of photogenerated charge carriers in carbon nitride under solar light irradiation,and renters the semiconductor a forceful electron donor for the Fe active *** accumulated electrons at Fe sites furtherly facilitated the adsorption and activation of the molecular ***,the uniform dispersed FeCu alloy nanoparticles were on carbon nitride nanosheets enhanced the stability of photocataly tic nitrogen reduction reaction,making the artificial photocataly tic ammonia synthesis more sustainable for *** work highlights that a direct electron transfer channel can be used to regulate the photochemical nitrogen fixation network.

关键词： Photocatalytic N_2 fixation Carbon nitride FeCu alloy Active sites Hydrogenation pathway

congener-derived template to construct lithiophilic organic-inorganic layer/interphase for high volumetric capacity dendrite-free li metal batteries

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Chinese Chemical Letters 2024年第3期35卷 453-460页

作者： Kang Yang Long li Yuanbin xiao Qiaoli Zhang Chenpeng Xi Borong li Yan Yu Chengkai Yang Key Laboratory of Advanced Materials Technologies International(HongKong Macao and Taiwan)Joint Laboratory on Advanced Materials TechnologiesCollege of Materials Science and EngineeringFuzhou UniversityFuzhou 350108China

The development of lithium-metal batteries(LMBs)is seriously restricted by the out-of-control dendrites growth and infinite volume ***,a pervasive organic-inorganic layer construction strategy is reported for the composite lithium metal anode with congener-derived organic-inorganic solid electrolyte interphase(SEI).In this strategy,the organic-inorganic Ag@polydopamine(Ag@PDA)layer is coated on the arbitrary substrates by a simple two-step *** thin and stable congener-derived SEI is insitu formed with fewer inorganic components and more organic components during charging/*** polydopamine with sufficient adhesion groups and lithiophilic Ag layer realize near-zero nucleation overpotential during lithium *** low interface resistance and stable lithium deposition are ***,the practical areal and volumetric capacities of the composite anode with three-dimensional copper(3DCu)as the substrate are 10 mAh/cm^(2)and 1538 mAh/cm^3(*** mass of anode).The symmetrical cell shows very low polarization voltage(10 mV)and more than 2500 h cycles life at 1 mA/cm^(2)(1 mAh/cm^(2)).The liNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)-based full cells show improved capacity retention(82%)after 100 cycles at 0.5 *** modified lithiophilic anode with congener-derived interphase provides a promising strategy to realize the next-generation dendrite-free LMBs.

关键词： lithium metal anode congener-derived lithiophilicity Volumetric capacity Organic-inorganic interphase

Micro-mechanism Study on the Different Antioxidants Protective Effect of Vegetable Oil by ReaxFF Molecular Dynamics

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CSEE Journal of Power and Energy Systems 2024年第3期10卷 1269-1279页

作者： Haoxi cong Xuefeng Hu Hao Pan Qingmin li State Key Laboratory of Alternate Electrical Power System With Renewable Energy Sources North China Electric Power UniversityBeijing 102206China

The aging problem of vegetable oil has severely restricted the popularization and application of vegetable oil *** antioxidants is the most recommended *** present,there is insufficient research on the micromechanism application of the protective effect of antioxidants on vegetable *** this paper,multiple vegetable oil models with different types and concentrations of antioxidants are *** the molecular dynamics simulation based on ReaxFF is carried out at different temperatures and oxygen *** show that the protective mechanism of antioxidants is to release H and combine this with free radicals generated by the decomposition of unsaturated fatty acids(UFA)in the *** addition,the protective effects of four antioxidants show different *** stronger ones are tert-butyl hydroquinone(TBHQ)and butylated hydroxytoluene(BHT),while the weaker ones are butylated hydroxyanisole(BHA)and propyl gallate(PG).TBHQ has a better protective effect at lower concentrations,but the decomposition of UFA is promoted at higher *** the temperature rises,the decomposition of UFA is *** the addition of oxygen,smaller molecular compounds are easily oxidized,and the decomposition of UFA is *** above research could reveal the microscopic mechanism of antioxidant protection on vegetable oil,providing theoretical references for further exploration of effective vegetable oil aging protection technology.

关键词： Antioxidant molecular dynamics transformer vegetable oil

Optical and electrical anisotropy regulation engineering of low-dimensional materials toward polarized detection and imaging applications

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Rare Metals 2024年第7期43卷 2968-2993页

作者： Jian-Bin Zhang Nan Zhou li-Hui Zhang cong-Hui Shang Jia-Xuan li Yi Zhao Guo-Hui Jia Ru-Sen Yang Hua Xu xiao-Bo li Shaanxi Joint Key Laboratory of Graphene Shaanxi Key Laboratory of High-Orbits-Electron Materials and Protection Technology for AerospaceShaanxi Joint Key Laboratory of GrapheneSchool of Advanced Materials and NanotechnologyXidian University Guangzhou Institute of Technology Xidian University Xi'an Thermal Power Research Institute Co. Ltd Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal University

Polarized-sensitive image sensors are a kind of photodetector with great development potential due to their enhanced ability to detect and identify the target objects from the aspect of spatial,spectral and polarized ***,low-dimensional anisotropic materials with inherent anisotropic properties,ultrathin thickness,tunable bandgap and feasible integration with complementary metal oxide semiconductor(CMOS) fabrication processes have attracted great interest for their facilitation of polarized photodetector devices *** the polarized detection performance of low-dimensional materials to satisfy realistic needs stimulates the exploration of modulation of anisotropic *** this review,we comprehensively introduce the latest research progress in modulating the optical and optoelectronic anisotropy characteristics of low-dimensional *** strategy of anisotropy regulation through crystal structure engineering and coupling system is discussed ***,the latest progress in image recognition applications using anisotropic low-dimensional materials is reviewed in ***,we summarize the challenge and propose future opportunities in the practical application of polarized-sensitive imaging photodetectors based on low-dimensional anisotropic materials.

关键词： Anisotropy Polarized detection Image recognition Low-dimensional materials

Coordinated Capacitor Voltage Balancing Method for Cascaded H-bridge Inverter with Supercapacitor and DC-DC Stage

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CES Transactions on Electrical Machines and Systems 2024年第2期8卷 191-201页

作者： Ye Zhang Zixin li Fanqiang Gao cong Zhao Yaohua li IEEE Key Laboratory of High Density Electromagnetic Power and Systems(Chinese Academy of Sciences) Institute of Electrical EngineeringChinese Academy of SciencesHaidian District University of Chinese Academy of Sciences Shijingshan District

Cascaded H-bridge inverter(CHBI) with supercapacitors(SCs) and dc-dc stage shows significant promise for medium to high voltage energy storage applications. This paper investigates the voltage balance of capacitors within the CHBI, including both the dc-link capacitors and SCs. Balance control over the dc-link capacitor voltages is realized by the dcdc stage in each submodule(SM), while a hybrid modulation strategy(HMS) is implemented in the H-bridge to balance the SC voltages among the SMs. Meanwhile, the dc-link voltage fluctuations are analyzed under the HMS. A virtual voltage variable is introduced to coordinate the balancing of dc-link capacitor voltages and SC voltages. Compared to the balancing method that solely considers the SC voltages, the presented method reduces the dc-link voltage fluctuations without affecting the voltage balance of SCs. Finally, both simulation and experimental results verify the effectiveness of the presented method.

关键词： Cascaded H-bridge inverter(CHBI) Hybrid modulation strategy(HMS) Capacitor voltage balancing DClink voltage fluctuation Supercapacitor(SC)