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High-temperature oxidation behavior of DZ125 Ni-based superalloy under tensile stress

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Rare Metals 2022年第12期41卷 4188-4193页

作者： Hong-Yu Qi xiao-bo liang Shao-Lin Li xiao-Guang Yang School of Energy and Power Engineering Beihang UniversityBeijing 100191China Collaborative Innovation Center of Advanced Aero-Engine Beijing 100191China

The key in antioxidant capacity of aero-engine hot components is the protective oxide *** factors can affect the performance of oxide *** effect of tensile stress on high-temperature oxidation behavior of directionally solidified DZ125 Ni-based superalloy was investigated by thermogravimetric analysis(TGA).Tensile samples were subjected to stress of 100 MPa,and the oxidation behavior was studied at 980℃in *** surface and cross-sectional morphologies of the oxidized coating were analyzed by scanning electron microscope(SEM).The influence of tensile stress on the oxidation behavior of directionally solidified DZ125 Ni-based superalloy at high temperature was *** show that an applied tensile stress generally leads to larger Cr/Ni mass ratio in the oxide scales,greater overall chromium depletion values directly under the oxide scales,lower specific weight gain values and thinner oxide *** factors are attributed to the formation of fast diffusion paths for Cr atoms to diffuse to the surface under tensile stress,thus causing a reduction in the duration of the less protective transient oxidation period and promoting a faster formation of the protective Cr_(2)O_(3)layer.

关键词： DZ125 Ni-based superalloy High-temperature oxidation Tensile stress Diffusion

Treatment of advanced rectal cancer after renal transplantation

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World Journal of Gastroenterology 2011年第15期17卷 2058-2060页

作者： Hai-Yi Liu xiao-bo liang Yao-Ping Li Yi Feng Dong-bo Liu Wen-Da Wang Department of Anal and Colorectal Surgery Shanxi Cancer Hospital Affiliated Cancer Hospital of Shanxi Medical University Taiyuan 030013 Shanxi Province China

Renal transplantation is a standard procedure for endstage renal disease today. Due to immunosuppressive drugs and increasing survival time after renal transplantation, patients with transplanted kidneys carry an increased risk of developing malignant tumors. In this case report, 3 patients with advanced rectal cancer after renal transplantation for renal failure were treated with anterior resection or abdominoperineal resection plus total mesorectal excision, followed by adjuvant chemotherapy. One patient eventually died of metastasized cancer 31 mo after therapy, although his organ grafts functioned well until his death. The other 2 patients were well during the 8 and 21 mo followup periods after rectal resection. We therefore strongly argue that patients with advanced rectal cancer should receive standard oncology treatment, including operation and adjuvant treatment after renal transplantation. Colorectal cancer screening in such patients appears justified.

关键词： Rectal cancer Renal transplantation Endstage renal disease Treatment Screening

超细晶Cu-Cr-Zr合金的高温拉伸性能及断裂机制

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金属学报 2016年第11期52卷 1477-1483页

作者：王庆娟周晓梁博周滢西安建筑科技大学冶金工程学院西安710055

研究了2种变形处理方式下的超细晶Cu-Cr-Zr合金从室温到600℃的拉伸性能、断口微观组织特征及其断裂机制.结果表明:经4道次等径弯曲通道挤压(ECAP)+时效+4道次ECAP变形处理的合金(No.1试样)的抗拉强度随拉伸温度的升高而降低,室温时,合... 详细信息

研究了2种变形处理方式下的超细晶Cu-Cr-Zr合金从室温到600℃的拉伸性能、断口微观组织特征及其断裂机制.结果表明:经4道次等径弯曲通道挤压(ECAP)+时效+4道次ECAP变形处理的合金(No.1试样)的抗拉强度随拉伸温度的升高而降低,室温时,合金抗拉强度为577.17 MPa,延伸率为14.6%;在300℃开始发生动态再结晶软化,抗拉强度迅速减小,到600℃时抗拉强度仅为59.12 MPa.经过8道次ECAP+时效变形处理的合金(No.2试样),室温抗拉强度为636.71 MPa,延伸率为12.1%;从400℃开始析出相对晶界的钉扎作用开始逐渐减弱,抗拉强度大幅降低,600℃时的抗拉强度为65.20 ***.2试样比No.1试样具有更好的室温性能和热稳定性.2种方式处理下合金延伸率随拉伸温度的升高而升高,在高温下都表现出超塑性.高温拉伸断口微观形貌为大量密集、深入的韧窝,其高温断裂机制为微孔聚集的韧性断裂.

关键词： Cu-Cr-Zr合金超细晶高温拉伸断裂机制

Sky location of massive black hole binaries in the foreground of Galactic white dwarf binaries

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Science China(Physics,Mechanics & Astronomy) 2025年第1期Mechanics & Astronomy) .卷 97-108页

作者： Pan Guo Hong-bo Jin Cong-Feng Qiao Yue-liang Wu The International Centre for Theoretical Physics Asia-Pacific University of Chinese Academy of Sciences The School of Physical Sciences University of Chinese Academy of Sciences Institute for Frontiers in Astronomy and Astrophysics Beijing Normal University National Astronomical Observatories Chinese Academy of Sciences Institute of Theoretical Physics Chinese Academy of Sciences

For space-based gravitational wave （GW） detection,the main noise source for massive black hole binaries （MBHBs） is attributed to approximately 10～7double white dwarf binaries in the *** a GW source,the amplitude of the detector response,recorded by a space-based gravitational wave detector,exhibits a modulation effect with a year period when observing the source from various orbital *** the adverse conditions mentioned above,where there is a strong foreground noise and annual modulation in the signals,we employed the wavelet transform and the strong-amplitude relevant orbital position search methods,which allows the weak MBHB sources to achieve higher locating *** detail,for two MBHB sources of lower intensity,the precision of luminosity distance,represented by the ratio ?DL/DLat the 95%confidence level,is enhanced by factors of ～*** angular resolutions,denoted by??s,are enhanced by a factor of ～*** improvements increase the number of detectable GW sources,facilitate multi-messenger follow-up observations and provide constraints on the cosmological constant.

关键词： space-based gravitational wave detection gravitational waves massive black hole binaries

High-dense nanocrystalline W-based alloy prepared by hot isostatic pressing with uniform microstructure, ultrahigh hardness and good thermal stability

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Tungsten 2025年第1期7卷 120-136页

作者： Zao-Ming Wu Lin He Lin-Sen Ye xiao-Feng Yang Jia-Jia Zhang Hong-bo Lei Institute of Materials China Academy of Engineering Physics

High-density uniform microstructure nanocrystalline W-10wt.% Cr-5wt.% Y（W-10Cr-5Y） alloy with an average grain size of 85 nm and a relative density of 99.8% was successfully prepared.W-Cr-Y alloys with different amounts of second-phase particles were prepared by high-energy ball milling and hot isostatic pressing *** effects of composition design,ball milling parameters,and sintering parameters on the microstructure of W-Cr-Y alloys were studied.A feasible technology for controlling the synthesis of high-density nanocrystalline W-based alloys has been *** microstructure analysis of nanocrystalline W-10Cr-5Y alloy shows that there are two types of doping in the second phase:intergranular doping and intragranular *** "uniform distribution YOx-rich particles" effectively suppresses the grain growth of W and leads to the formation of nanocrystalline W-10Cr-5Y alloy.W-10Cr-5Y has an ultra-high hardness,with a Vickers hardness of 1312±12 kgf·***-temperature annealing treatment shows that W-10Cr-5Y has good thermal stability at 1000 and1100℃,as demonstrated by the comparison of Vickers hardness and grain size between annealed and unannealed alloys.

关键词： Hot isostatic pressing Microstructure Nanocrystalline tungsten Thermal stability Vickers hardness

Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to boost Oxygen Evolution Activities for Rechargeable Zn‑Air Batteries

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Nano-Micro Letters 2025年第1期17卷 176-190页

作者： xiaohong Zou Qian Lu Mingcong Tang Jie Wu Kouer Zhang Wenzhi Li Yunxia Hu xiaomin Xu xiao Zhang Zongping Shao liang An Department of Mechanical Engineering The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and TechnologyNanjing University of Information Science and TechnologyNanjing 210044People’s Republic of China Department of Chemistry The Chinese University of Hong KongMa Lin BuildingShatinHong Kong SAR 999077People’s Republic of China WA School of Mines:Minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia Research Institute for Advanced Manufacturing The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China Research Institute for Smart Energy The Hong Kong Polytechnic UniversityHung HomKowloonHong Kong SARPeople’s Republic of China

Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe *** is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe *** the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts.

关键词： Catalyst-support interaction Supported catalysts Heterointerface Oxygen evolution reaction Zn-air batteries

A promising approach for quantifying focal stroke modeling and assessing stroke progression:optical resolution photoacoustic microscopy photothrombosis

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Neural Regeneration Research 2025年第7期20卷 2029-2037页

作者： xiao liang Xingping Quan xiaorui Geng Yujing Huang Yonghua Zhao Lei Xi Zhen Yuan Ping Wang Bin Liu Faculty of Health Sciences University of MacaoMacao Special Administrative RegionChina Center for Cognitive and Brain Sciences University of MacaoMacao Special Administrative RegionChina Department of Biomedical Engineering Southern University of Science and TechnologyShenzhenGuangdong ProvinceChina State Key Laboratory of Quality Research in Chinese Medicine Institute of Chinese Medical SciencesUniversity of MacaoTaipaMacao Special Administrative RegionChina Department of Emergency Zhujiang HospitalSouthern Medical UniversityGuangzhouGuangdong ProvinceChina

To investigate the mechanisms underlying the onset and progression of ischemic stroke,some methods have been proposed that can simultaneously monitor and create embolisms in the animal cerebral ***,these methods often require complex systems and the effect of age on cerebral embolism has not been adequately studied,although ischemic stroke is strongly *** this study,we propose an optical-resolution photoacoustic microscopy-based visualized photothrombosis methodology to create and monitor ischemic stroke in mice simultaneously using a 532 nm pulsed *** observed the molding process in mice of different ages and presented age-dependent vascular embolism ***,we integrated optical coherence tomography angiography to investigate age-associated trends in cerebrovascular variability following a *** imaging data and quantitative analyses underscore the differential cerebrovascular responses to stroke in mice of different ages,thereby highlighting the technique's potential for evaluating cerebrovascular health and unraveling age-related mechanisms involved in ischemic strokes.

关键词： age-dependent cerebral cortex ischemic stroke mouse model optical coherence tomography angiography photoacoustic microscopy photothrombosis vascular imaging

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一种雷达主瓣欺骗干扰抑制算法

现代防御技术 2017年第2期45卷 209-216页

作者：董玮李小波单凉王瑜电子工程学院安徽合肥230037

针对单通道雷达受到主瓣干扰,提出了一种基于多周期采样的抗主瓣干扰方法。首先针对距离密集假目标欺骗干扰,建立了基于多脉冲重复间隔(paulse repeat interval)采样的抗主瓣欺骗干扰模型并对其可行性进行证明,然后对信号源个数进行估计... 详细信息

针对单通道雷达受到主瓣干扰,提出了一种基于多周期采样的抗主瓣干扰方法。首先针对距离密集假目标欺骗干扰,建立了基于多脉冲重复间隔(paulse repeat interval)采样的抗主瓣欺骗干扰模型并对其可行性进行证明,然后对信号源个数进行估计,最后借助提出的盲源分离方法将干扰信号与目标回波信号分离,达到抗干扰效果。理论分析和仿真表明,该方法具有较好的分离效果及干扰抑制能力。

关键词：多PRI采样抗主瓣干扰距离密集假目标盲源分离脉压检测单通道

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Synthesis of chiral phosphine derivatives through a copper（I）-catalyzed desymmetric SNAr reaction

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Science China Chemistry 2025年

作者： Shuai Zhang Pei-Zhi Liu Yan-bo Li Qi Zhang Jun-Zhao xiao Yi-Fan Wang Tian-Yu Wei Jia-Wei Jiang Ye Wang Qian Peng liang Yin Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences State Key Laboratory of Elemento-Organic Chemistry and Tianjin Key Laboratory of Biosensing and Molecular Recognition College of Chemistry Frontiers Science Center for New Organic Matter Nankai University Haihe Laboratory of Sustainable Chemical Transformations

Axially chiral phosphines are a class of extremely important ligands in asymmetric catalysis. Herein, an unprecedented copper（I）-catalyzed asymmetric SNAr reaction with HP（S）R2is uncovered, which delivers a series of axially chiral phosphine derivatives in high yields with excellent enantioselectivity. Furthermore, the diastereoselective reaction with the kinetic resolution of racemic HP（S）ArR proceeds smoothly, providing the products with moderate diastereoselectivity and excellent enantioselectivity. Control experiments indicate that HP（S）Ph2is much more active than HPPh2and HP（O）Ph2as the pronucleophile in the present reaction. It is found that the SNAr reaction （the first SNAr） proceeds in a desymmetric manner, providing the desired chiral products while a continued SNAr reaction （the second SNAr） slightly occurs in a kinetic resolution manner in the present catalytic system, which enhances the ee of the desired chiral products. DFTcalculations support a concerted reaction pathway rather than a step-wise mechanism. Finally, axially chiral olefin-phosphines produced by the present method work as suitable ligands in Pdcatalyzed asymmetric allylic substitution with C-, N-, and O-nucleophiles and Rh-catalyzed asymmetric addition of arylboronic acid to benzil.

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