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Effect of phosphor addition on eutectic solidification and microstructure of an Al-13%Si alloy

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China Foundry 2011年第4期8卷 418-423页

作者： Liao Hengcheng zhao Lei xi xiao Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University Nanjing 211189 China

As the refiner or modifier, the master alloys containing high concentration phosphor are widely used in preparing eutectic or hypereutectic Al-Si alloys. To study the effect of phosphor addition on the eutectic solidification and microstructure of the Al-13%Si alloy, an investigation has been undertaken by means of thermal analysis and micro/macro-structure observation. Results indicate that addition of phosphor in near eutectic Al-Si alloy promotes the nucleation of eutectic but has little refinement impact on primary Si particles as expected. Conversely, both primary Si particles and eutectic Si flakes become slightly coarser in P-rich alloys. The coarsening of eutectic Si flakes ties closely to the increased eutectic growth temperature with phosphor addition. The eutectic solidification of the alloy proceeds from the near mold zone towards the center, and it is also found that a few independent nucleation regions emerge in liquid at the solidification front due to the addition of phosphor.

关键词： Al-Si alloy eutectic solidification microstructure thermal analysis phosphor

Lipomatous ependymoma with ZFTA:RELA fusion-positive:A case report

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World Journal of Clinical Cases 2025年第1期13卷 48-55页

作者： xiao-Yu zhao Juan-Han Yu Yi-Hua Wang Yi-xin Liu Lu Xu Lin Fu Ning Yi China Medical University The First Hospital of China Medical UniversityShenyang 110001Liaoning ProvinceChina Department of Pathology The First Hospital of China Medical UniversityShenyang 110001Liaoning ProvinceChina Anshan Cancer Hospital Anshan 114000Liaoning ProvinceChina

BACKGROUND Ependymoma with lipomatous differentiation is a rare type of *** ZFTA fusion-positive supratentorial ependymoma is a novel tumor type in the 2021 World Health Organization classification of central nervous system *** fusion-positive lipomatous ependymoma has not been reported to *** SUMMARY We reported a case of a 15-year-old Chinese male who had a sudden convulsion lasting approximately six *** resonance imaging showed a round cystic shadow of approximately 1.9 cm×1.5 cm×1.9 cm under the right parieto-occipital *** examination showed characteristic perivascular pseudorosettes and adipose differentiation in the ***-chemical staining showed that the tumor cells were negative for cytokeratin,NeuN,Syn and p53,but positive for GFAP,vimentin and S-100 ***-ficant punctate intracytoplasmic EMA immunoreactivity was *** level of Ki-67 was about 5%.Genetic analysis revealed ZFTA:RELA fusion.A cranio-tomy with total excision of the tumor was *** follow-up time was 36 months,no evidence of disease recurrence was found in magnetic resonance *** Based on these findings,the patient was diagnosed as a ependymoma with ZFTA fusion and lipomatous *** case report provides information on the microscopic morphological features of ependymoma with ZFTA fusion and lipomatous differentiation,which can help pathologists to make a definitive diagnosis of this tumor.

关键词： Ependymoma Lipomatous Molecular classification Supratentorial ZFTA:RELA fusion Case report

Ko⁃LLaMA:基于LLaMA的朝鲜语大语言模型

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外语学刊 2025年第1期 1-8页

作者：庞杰闫晓东赵小兵中央民族大学北京100081 国家语言资源监测与研究民族语言中心北京100081 民族语言智能与安全治理教育部重点实验室北京100081

在本文中,我们通过扩展LLaMA现有的词表,增加额外的20,000个朝鲜语Token,从而提高其对朝鲜语的编码和语义理解的能力;并且进一步使用朝鲜语数据进行继续预训练,使用朝鲜语指令微调数据集对模型进行SFT(Supervised Fine⁃Tuning),并分析... 详细信息

在本文中,我们通过扩展LLaMA现有的词表,增加额外的20,000个朝鲜语Token,从而提高其对朝鲜语的编码和语义理解的能力;并且进一步使用朝鲜语数据进行继续预训练,使用朝鲜语指令微调数据集对模型进行SFT(Supervised Fine⁃Tuning),并分析不同数据量对指令精调效果的影响,经过继续预训练和指令微调后的模型显著提高了理解和遵循朝鲜语指令的能力。实验结果表明,新提出的模型Ko⁃LLaMA显著提高了原版LLaMA在理解和生成朝鲜语内容方面的能力。此外,在朝鲜语文本分类数据集YNAT上对Ko⁃LLaMA与擅长少数民族语言的CINO模型及CINO的多种模型组合以及原版LLaMA和GPT⁃3.5进行了效果对比。结果表明,Ko⁃LLaMA的朝鲜语文本分类能力远超CINO和CINO的组合模型以及LLaMA和GPT⁃3.5等未经过朝鲜语语料进行词表扩充和继续预训练的大语言模型。

关键词：朝鲜语大语言模型词表扩充继续预训练指令微调

Double [5]carbohelicene: facile synthesis, chiroptical properties,isomerization study, and lasing application

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Science China Chemistry 2025年第1期 233-240页

作者： Peipei Liu Yantong Li Meng-xiang Wu Hao Kang xiao-Li zhao Lin Xu Linlin Liu xiaodong Li Junfeng Fang Zhiwei Fang Ya Cheng Hai-Bo Yang Huakang Yu Xueliang Shi State Key Laboratory of Petroleum Molecular & Process Engineering Shanghai Key Laboratory of Green Chemistry and Chemical ProcessesSchool of Chemistry and Molecular Engineering East China Normal University School of Physics and Optoelectronics South China University of Technology Institute of Polymer Optoelectronic Materials & Devices State Key Laboratory of Luminescent Materials & Devices South China University of Technology School of Physics and Electronic Science Engineering Research Center of Nanophotonics & Advanced Instrument Ministry of EducationEast China Normal University State Key Laboratory of Precision Spectroscopy School of Physics and Electronic Science East China Normal University

Double carbohelicenes have attracted considerable attention due to their aesthetic structures, distinct π-conjugation extension, inherent chirality, and intriguing optical and electronic properties. Herein, the concise de novo synthesis of a new double[5]carbohelicene 1 together with its chiroptical properties, isomerization process and lasing application is presented. 1 was synthesized by a simple protocol involving the formation of a 6,6′-bipentacene as the key intermediate. It is worth noting that1 existed as two diastereomers 1-PP/MM and 1-PM, which were successfully isolated and unambiguously confirmed by Xray crystallography. The optical resolution of the racemic 1-PP/MM was successfully achieved by chiral-phase highperformance liquid chromatography（HPLC）, and 1-PP and 1-MM were characterized by circular dichroism. Interestingly, it was found that 1-PP/MM could be completely isomerized to 1-PM upon heating, and the detailed thermodynamics and kinetics of the isomerization process were systematically investigated. 1-PM exhibited deep-red luminescence with emission maximum at 723 nm and fluorescence quantum yield as high as 32.95%. Consequently, we can showcase the lasing application of 1-PM by doping with epoxy resin to assemble a bottle microlaser spontaneously, which the lasing wavelength is 796.6 nm at a threshold of 0.8 m J cm-2. We believe that our studies, including the facile synthesis methodology, detailed isomerization studies, and lasing application, will shed some light on the design and synthesis of novel carbohelical systems with more functions.

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Enhanced Biodegradation of High-Salinity and Low- Temperature Crude-Oil Wastewater by Immobilized Crude-Oil Biodegrading Microbiota

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Journal of Ocean University of China 2022年第1期21卷 141-151页

作者： HUANG xiao ZHOU Ting CHEN xi BAI Jie zhao Yangguo Collaborative Innovation Center of Atmospheric Environment and Equipment Technology Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlSchool of Environmental Science and EngineeringNanjing University of Information Science and TechnologyNanjing 210044China The Key Laboratory of Marine Environmental Science and Ecology Ministry of EducationOcean University of ChinaQingdao 266100China Harbin Institute of Technology(Shenzhen) Shenzhen Key Laboratory of Water Resource Utilization and Environmental Pollution ControlShenzhen 518055China

High salt and low temperature are the bottlenecks for the remove of oil contaminants by enriched crude-oil degrading microbiota in Liaohe Estuarine Wetland(LEW),*** improve the performance of crude-oil removal,microbiota was further immobilized by two methods,i.e.,sodium alginate(SA),and polyvinyl alcohol and sodium alginate(PVA+SA).Results showed that the crude oil was effectively removed by the enrichment with an average degrading ratio of 19.42-31.45 mg(L d)^(−1).The optimal inoculum size for the n-alkanes removal was 10%and 99.89%.Some members of genera Acinetobacter,Actinophytocola,Aquabac-terium,Dysgonomonas,Frigidibacter,Sphingobium,Serpens,and Pseudomonas dominated in crude-oil degrading *** the removal efficiency was lower than free bacteria when the temperature was 15℃,SA and PVA+SA immobilization im-proved the resistance to *** composite crude-oil degrading microbiota in this study demonstrated a perspective potential for crude oil removal from surface water under high salinity and low temperature conditions.

关键词： crude-oil degrading microbiota microbial community immobilization high salinity low temperature

Six million Q factor micro fused silica shell resonator with teeth-like tines released by femtosecond laser-assisted chemical etching

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Science China(Technological Sciences) 2024年第6期67卷 1923-1932页

作者： zhao Tao SHI Yan LU Kun xi xiang WU XueZhong xiao DingBang College of Intelligence Science and Engineering National University of Defense TechnologyChangsha410073China

The quality factor(Q factor)is a crucial performance parameter for *** this paper,a novel release method for highquality micro fused silica shell resonators with teeth-like tines with good surface morphology is *** method is based on femtosecond laser-assisted chemical ***,the optimal energy range of femtosecond laser modification is obtained through mechanism ***,the optimal parameters for a straight line and arc pattern are determined by optimizing the average output power,processing speed,and processing *** results demonstrate why edge breakage in rounded corners is easy under different ***,according to these conclusions,the processing is performed on a micro fused silica shell resonator with a Q factor exceeding 6 *** addition,subsurface damage is rare throughout the fabrication process,and the surface roughness of the released cross section reaches the nanometer *** improved Q factor helps suppress mechanical thermal noise and reduce zero bias and zero bias drift,constituting the primary method for enhancing the performance of the resonant gyroscope.

关键词： micro hemispherical resonator fused silica laser-assisted chemical etching quality factor

Berbamine inhibits proliferation and induces apoptosis of KU812 cells by increasing Smad3 activity

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2011年第7期12卷 568-574页

作者： Yun LIANG xi QIU Rong-zhen XU xiao-ying zhao Department of Hematology the Second Affiliated Hospital School of Medicine Zhejiang University Hangzhou 3 10009 China Cancer Institute School of Medicine Zhejiang University Hangzhou 310009 China

Objective: The cytotoxic effect of berbamine on chronic myeloid leukemia (CML) cell line KU812 was evaluated,and the mechanisms of its action were ***: The effect of berbamine on the KU812 cell growth was determined by methyl thiazolyl tetrazolium (MTT) *** cytometry was used to profile cell cycle alteration upon berbamine *** transcription polymerase chain reaction (RT-PCR) was carried out to determine the transcripts of transforming growth factor-β (TGF-β) receptors (TβRs),Smad3,c-Myc,cyclin D1,p21Cip1(p21),and p27Kip1(p27).Changes in the protein levels of total Smad3,phosphorylated Smad3,the downstream targets of Smad3,and specific apoptosis-related factors were evaluated by Western ***: Berbamine inhibited KU812 cell proliferation in a doseand time-dependent manner,and the half maximal inhibitory concentration (IC50) values for treatments of 24,48,and 72 h were 5.83,3.43,and 0.75 μg/ml,*** induced G1 arrest as well as apoptosis in KU812 *** of Smad3 and p21 were up-regulated,while those of TβRI,TβRII,c-Myc,cyclin D1 and p27 were not changed *** protein levels of both total Smad3 and phosphorylated Smad3 were both up-regulated after berbamine treatment,together with decreased c-Myc and cyclin D1 and increased ***,the levels of the anti-apoptotic proteins,such as Bcl-2 and Bcl-xL,were decreased,whereas pro-apoptotic Bax was ***: Berbamine suppresses KU812 cell proliferation through induction of cell cycle arrest in G1 and *** activates Smad3 without additional stimulation of TGF-β,and alters the levels of the Smad3 downstream targets,including c-Myc,cyclin D1 and *** findings suggest that berbamine is a promising drug in the treatment of advanced stage patients with CML.

关键词： Berbamine Apoptosis Smad3 KU812 cells

Gravitational Corrections to Energy-Levels of a Hydrogen Atom

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Communications in Theoretical Physics 2007年第4期47卷 658-662页

作者： zhao Zhen-Hua LIU Yu-xiao LI xi-Guo Institute of Modern Physics the Chinese Academy of Sciences Lanzhou 730000 China Institute of Theoretical Physics Lanzhou University Lanzhou 730000 China

The first-order perturbations of the energy levels of a hydrogen atom in central internal gravitational field are investigated. The internal gravitational field is produced by the mass of the atomic nucleus. The energy shifts are calculated for the relativistic 1S, 2S, 2P, 3S, 3P, 3D, 4S, and 4P levels with Schwarzschild metric. The calculated results show that the gravitational corrections are sensitive to the total angular momentum quantum number.

关键词： hydrogen atom gravitational perturbation generally covariant Dirac equation

Validation of a CIP-based tank for numerical simulation of free surface flows

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Acta Mechanica Sinica 2011年第6期27卷 877-890页

作者： xi-Zeng zhao Colloge of Engineering Ocean University of China266100 Qingdao China RIAM Kyushu University 816-0951 Fukuoka Japan

A constrained interpolation profile CIP-based numerical tank is developed to simulate violent free surface *** numerical simulation is performed by the CIP-based Cartesian grid method,which is described in the present *** tangent of hyperbola for interface capturing（THINC） scheme is applied for capturing complex free *** new model is capable of simulating a flow with violently varied free surface.A series of computations are conducted to assess the developed algorithm and its *** tests include the collapse of water column with and without an obstacle,sloshing in a fixed tank,the generation of regular waves in a tank,the generation of extreme waves in a *** agreements are obtained when numerical results are compared with available analytical,experimental,and other numerical results.

关键词： CIP method. THINC scheme Free surface flow Wave breaking Wave tank