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Unconventional Fluorescent and Multi-responsive Polyethyleneimine with LCST and UCST Behavior:Synthesis,Characterization and Biological Applications

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Chinese Journal of Polymer Science 2024年第6期42卷 826-837页

作者： Feng-Ming Yin Li-Li Wu Shu-Sheng Li xiao-na pan xiao-Li Zhu Xu-Bao Jiang Xiang Zheng Kong College of Chemistry and Chemical Engineering University of JinanJinan250022China Shandong Institute for Product Quality Inspection Jinan250102China College of Chemical Engineering Tianjin UniversityTianjin300072China

Non-aromatic fluorescent and multi-responsive materials,exhibiting inherent fluorescence emission and controlled phase change,have garnered significant attention in recent ***,the underlying interaction between their fluorescent properties and phase transition remains *** this study,we synthesized a series of catalyst-free aza-Michael addition-based polyethyleneimine(RFPEI)materials by reacting polyethyleneimine(PEI)with N-isopropyl acrylamide(NIPAM).The resulting RFPEI was comprehensively characterized,and demonstrated dual-phase transition behavior(LCST and UCST)in water,which could be finely tuned by adjusting its composition or external factors such as ***,upon UV irradiation(365 nm),RFPEI exhibited strong fluorescence *** further investigated the effects of NIPAM grafting percentage to PEI,polymer concentration,and pH on the LCST/UCST and fluorescent properties of RFPEI aqueous ***,we showcased the great potential of RFPEI as a versatile tool for physiological cell imaging,trace detection,and controlled release of *** study presents a novel class of stimuli-responsive fluorescent materials with promising applications in the field of biomedicine.

关键词： Polyethyleneimine Multi-responsiveness Intrinsic fluorescence emission Cell imaging Controlled drug release

固定床反应器甲醇制烯烃反应过程的CFD模拟

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高校化学工程学报 2016年第5期30卷 1095-1103页

作者：俞路刘响宋小沫潘娜娜潘艳秋大连理工大学化工学院辽宁大连116024

基于工业甲醇制烯烃反应过程,建立固定床反应器一维拟均相模型,采用集总动力学模型及FLUENT中的多孔介质传递模型、S-A单方程湍流模型进行反应过程的稳态模拟,在验证模型可靠性的基础上,考察操作参数（进料温度、操作压力、进料水醇比... 详细信息

基于工业甲醇制烯烃反应过程,建立固定床反应器一维拟均相模型,采用集总动力学模型及FLUENT中的多孔介质传递模型、S-A单方程湍流模型进行反应过程的稳态模拟,在验证模型可靠性的基础上,考察操作参数（进料温度、操作压力、进料水醇比）对甲醇转化率、产物选择性和烯烃摩尔比的影响,得到温度、组成、选择性等参数沿反应管轴向分布的规律。结果表明：操作条件影响甲醇转化率和产物选择性,较合适的操作条件是进料温度723-773 K、操作压力0.3-0.4 MPa、水醇比低于0.5。该研究结果对于甲醇固定床反应过程的研究及工业操作有良好的指导意义。

关键词：甲醇制烯烃固定床反应器模拟优化集总动力学模型 FLUENT

我国大宗农产品贸易格局及对外依存度研究——基于虚拟耕地资源的分析和评价

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自然资源学报 2017年第6期32卷 915-926页

作者：刘爱民薛莉成升魁强文丽杨晓贾盼娜中国科学院地理科学与资源研究所北京100101 中国科学院大学北京100049 兰州大学资源环境学院兰州730000

我国已成为农产品进口大国,而所有农产品中都隐含有一定的耕地资源,论文基于农产品虚拟耕地资源的分析和评价,系统研究了我国大宗农产品贸易格局及对外依存度。论文所涉及的大宗农产品及其制品主要是土地资源密集型产品,包括粮食、油料... 详细信息

我国已成为农产品进口大国,而所有农产品中都隐含有一定的耕地资源,论文基于农产品虚拟耕地资源的分析和评价,系统研究了我国大宗农产品贸易格局及对外依存度。论文所涉及的大宗农产品及其制品主要是土地资源密集型产品,包括粮食、油料、木薯、植物油、棉花、糖、饲料粕类等7大类,24个具体品种,以2000—2016年分国别的贸易数据为基础,从消费者的角度对大宗农产品虚拟耕地资源贸易量进行了分析和评价。研究结果显示,我国大宗农产品虚拟耕地资源净进口量由2000年的675×10~4 hm^2增加到2016年的5 928×10~4 hm^2,其中美国和巴西是中国农产品虚拟耕地进口量最大的国家,进口量分别由2000年的342×10~4 和146×10~4 hm^2,增加到2016年的2 101×10~4 和2 192×10~4 hm^2,占我国虚拟耕地进口总量比例超过70%;2016年农业耕地资源对外依存度达到30.5%,对巴西和美国的依存度分别为11.3%和10.8%。土地密集型农产品的大量进口,在一定程度上缓解了我国耕地资源紧张的压力,保证了粮食安全。

关键词：大宗农产品贸易虚拟耕地资源对外依存度

Engineering atomic Rb-N configurations to tune radical pathways for highly selective photocatalytic H2O2 synthesis coupled with biomass valorization

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Journal of Energy Chemistry 2025年第1期100卷 215-225页

作者： Jiaye Li Shuang pan Yihuang Chen Qiong Liu College of Chemistry and Materials Engineering Wenzhou University Guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test Technology (China) Institute of Analysis Guangdong Academy of Sciences (China National Analytical CenterGuangzhou)

Photocatalytic oxygen reduction for hydrogen peroxide （H2O2） synthesis presents a green and costeffective production ***,achieving highly selective H2O2synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative ***,we report for the visible light-driven simultaneous co-photocatalytic reduction of O2to H2O2and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride（CNRb）.The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h-1for H2O2generation and photooxidation rate of 3.75 mM h-1for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion （SCC） efficiency of up to 2.27%.Experimental characterizations and DFT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical *** is because the Rb–N serves as the new alternative site to perceive a stronger connection position for O2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product *** study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of H2O2coupled with biomass valorization.

关键词： Atomic economy Radical pathway regulation Rubidium atom coordination Biomass valorization

Observational Constraints on Quark Matter in Neutron Stars

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Chinese Journal of Astronomy and Astrophysics 2007年第5期7卷 675-684页

作者： na-na pan xiao-Ping Zheng Institute of Astrophysics Huazhong Normal University Wuhan 430079

We study the observational constraints of mass and redshift on the properties of the equation of state （EOS） for quark matter in compact stars based on the quasi-particle description. We discuss two scenarios; strange stars and hybrid stars. We construct the equations of state utilizing an extended MIT bag model taking the medium effect into account for quark matter and the relativistic mean field theory for hadron matter. We show that quark matter may exist in strange stars and in the interior of neutron stars. The bag constant is a key parameter that affects strongly the mass of strange stars. The medium effect can lead to the stiffer hybrid-star EOS approaching the pure hadronic EOS, due to the reduction of quark matter, and hence the existence of heavy hybrid stars. We find that a middle range coupling constant may be the best choice for the hybrid stars being compatible with the observational constraints.

关键词： dense matter -- gravitation -- stars neutron -- stars rotation -- stars oscillations

The role of axon guidance molecules in the pathogenesis of epilepsy

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Neural Regeneration Research 2025年第5期20卷 1244-1257页

作者： Zheng Liu Chunhua pan Hao Huang Department of Neurology Affiliated Hospital of Zunyi Medical UniversityZunyiGuizhou ProvinceChina

Current treatments for epilepsy can only manage the symptoms of the condition but cannot alter the initial onset or halt the progression of the disease. Consequently, it is crucial to identify drugs that can target novel cellular and molecular mechanisms and mechanisms of action. Increasing evidence suggests that axon guidance molecules play a role in the structural and functional modifications of neural networks and that the dysregulation of these molecules is associated with epilepsy susceptibility. In this review, we discuss the essential role of axon guidance molecules in neuronal activity in patients with epilepsy as well as the impact of these molecules on synaptic plasticity and brain tissue remodeling. Furthermore, we examine the relationship between axon guidance molecules and neuroinflammation, as well as the structural changes in specific brain regions that contribute to the development of epilepsy. Ample evidence indicates that axon guidance molecules, including semaphorins and ephrins, play a fundamental role in guiding axon growth and the establishment of synaptic connections. Deviations in their expression or function can disrupt neuronal connections, ultimately leading to epileptic seizures. The remodeling of neural networks is a significant characteristic of epilepsy, with axon guidance molecules playing a role in the dynamic reorganization of neural circuits. This, in turn, affects synapse formation and elimination. Dysregulation of these molecules can upset the delicate balance between excitation and inhibition within a neural network, thereby increasing the risk of overexcitation and the development of epilepsy. Inflammatory signals can regulate the expression and function of axon guidance molecules, thus influencing axonal growth, axon orientation, and synaptic plasticity. The dysregulation of neuroinflammation can intensify neuronal dysfunction and contribute to the occurrence of epilepsy. This review delves into the mechanisms associated with

关键词： axon guidance drug-resistant epilepsy epilepsy nerve regeneration nervous system diseases neural pathways neuroinflammatory diseases neuronal plasticity neurons synaptic remodeling

Cooling of hybrid stars with spin down compression

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Research in Astronomy and Astrophysics 2009年第12期9卷 1351-1358页

作者： Miao Kang xiao-Dong Wang na-na pan College of Physics and Electronics Henan University Kaifeng 475004 China College of Mathematics and Physics Chongqing University of Posts and TelecommunicationsChongqing 400065 China

We study the cooling of hybrid stars coupled with spin-down. Due to the spindown of hybrid stars, the interior density continuously increases and different neutrino reactions may be triggered （from the modified Urca process to the quark and nucleon direct Urca process） at different stages of evolution. We calculate the rate of neutrino emissivity of different reactions and simulate the cooling curves of the rotational hybrid stars. The results show that the cooling curves of hybrid stars clearly depend on a magnetic field if the direct Urca reactions occur during the spin-down. Comparing the results of the rotational star model with the transitional static model, we find the cooling behavior of the rotational model is more complicated; the temperature of the star is higher, especially when direct Urca reactions appear in the process of rotation. Then, we find that the predicted temperatures of some rotating hybrid stars are compatible with the pulsar＇s data which are in contradiction with the results of the transitional method.

关键词： dense matter -- stars: rotation -- equation of state

Co-production of hydrogen, oxygen, and electricity via an integrated solar-driven system with decoupled water electrolyzer and na-Zn ion battery

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Journal of Energy Chemistry 2025年第1期100卷 621-627页

作者： Fei Lv Longjie Liu Jiazhe Wu Pengfei Wang Lixia pan Dengwei Jing Yubin Chen International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University

Combining water electrolysis and rechargeable battery technologies into a single system holds great promise for the co-production of hydrogen （H2） and ***,the design and development of such systems is still in its ***,an integrated hydrogen-oxygen （O2）-electricity co-production system featuring a bipolar membrane-assisted decoupled electrolyzer and a na-Zn ion battery was established with sodium nickelhexacyanoferrate （naNiHCF） and Zn2+/Zn as dual redox *** decoupled electrolyzer enables to produce H2and O2in different time and space with almost 100%Faradaic efficiency at 100 mA ***,the charged naNiHCF and Zn electrodes after the electrolysis processes formed a na-Zn ion battery,which can generate electricity with an average cell voltage of 1.75 V at 10 m A *** connecting Si photovoltaics with the modular electrochemical device,a well-matched solar driven system was built to convert the intermittent solar energy into hydrogen and electric energy with a solar to hydrogen-electricity efficiency of 16.7%,demonstrating the flexible storage and conversion of renewables.

关键词： Hydrogen Electricity Decoupled water electrolyzer na-Zn ion battery Solar energy

Burden of mental disorders and risk factors in the Western Pacific region from 1990 to 2021

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World Journal of Psychiatry 2025年第1期15卷 93-105页

作者： Ya-Xin Xu xiao-Xuan Niu Wen-Chang Jia Jing Wen Xue-Lin Cheng Yan Han Ming-Hui Peng Jing Zhou Yao Liu Sun-Fang Jiang xiao-pan Li Department of Health Management Centre Zhongshan HospitalFudan UniversityShanghai 200030China Department of General Practice Zhongshan HospitalFudan UniversityShanghai 200030China Department of Nutrition Zhongshan HospitalFudan UniversityShanghai 200032China School of Public Health Fudan UniversityShanghai 200032China

BACKGROUND The burden of mental disorders(MD)in the Western Pacific Region(WPR)re-mains a critical public health concern,with substantial variations across demogra-phics and *** To analyze the burden of MD in the WPR from 1990 to 2021,along with associated risk factors,to reveal changing trends and emerging *** We used data from the Global Burden of Disease 2021,analyzing prevalence,incidence,and disability-adjusted life years(DALYs)of MD from 1990 to *** methods included age-standardisation and uncertainty analysis to address variations in population structure and data *** Between 1990 and 2021,the prevalence of MD rose from 174.40 million cases[95%uncertainty interval(UI):160.17-189.84]to 234.90 million cases(95%UI:219.04-252.50),with corresponding DALYs increasing from 22.8 million(95%UI:17.22-28.79)to 32.07 million(95%UI:24.50-40.68).During this period,the burden of MD shifted towards older age *** and anxiety disorders were predominant,with females showing higher DALYs for depressive and anxiety disorders,and males more affected by conduct disorders,attention-deficit hyperactivity disorder,and autism spectrum ***,New Zealand,and Malaysia reported the highest burdens,whereas Vietnam,China,and Brunei Darussalam reported the ***,childhood sexual abuse and bullying,and intimate partner violence emerged as significant risk *** This study highlights the significant burden of MD in the WPR,with variations by age,gender,and *** coronavirus disease 2019 pandemic has exacerbated the situation,emphasizing the need for a coordinated response.

关键词： Mental disorders Western pacific region Global Burden of Disease Risk factors Disability-adjusted life years