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Science China Chemistry 2024年第9期67卷 2941-2948页

作者： Yang-Ping Zhang Shao-Min Pei Wen-Fa Chen Bin-Wen Liu xiao-ming jiang Guo-Cong Guo State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China School of Physical Science and Technology Shanghai Tech UniversityShanghai 201210China

Non-centrosymmetric(NCS)structure is an indispensable prerequisite for second-order nonlinear optical(NLO)***,the mainstream approach for designing new NCS structures still relies on chemical substitution,necessitating an urgent infusion of fresh *** this work,two isomorphic sulfides AeMn_(6)Ga_(6)S_(16)(Ae=Ca,1;Sr,2)are afforded by modifying the skeleton of centrosymmetric(CS)Mn_(2)Ga_(2)S_(5) via introducing strong electropositive alkaline-earth ***,the incorporation of Ca^(2+)/Sr^(2+)cations allows the elementary[MnGaS_(9)]_(∞)chains to reconfigure into bumpy[MnS_(6)]-[GaS_(4)]layers in a new engagement manner,thus enabling the conversion from CS to NCS *** modifications cause not only strong second-harmonic generation(SHG)responses(~1.5×benchmark AgGaS_(2)@1,700 nm),but also significantly feasible bandgaps(2.60-2.64 e V)compared to the sulfide Mn_(2)Ga_(2)S_(5)(1.36 e V),which ultimately facilitate ultrahigh laser-induced damage thresholds(4.4-6.6×AgGaS_(2)@1,064 nm for compounds 1 and 2).The present study offers an ingenious approach for the transformation of CS to NCS structure.

关键词： second-harmonic generation non-centrosymmetrical structure NLO functional motif solid-state method

通过聚阳离子取代策略实现压缩黄铜矿型硒化物[Rb3BaCl][In_(8)Se_(14)]以获得优异的非线性光学性能

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Science China Materials 2024年第6期67卷 2000-2007页

作者：吴帆陈文发吴子璇姜小明刘彬文郭国聪 State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350007China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China University of Chinese Academy of Sciences Beijing 100049China Fujian College University of Chinese Academy of SciencesFuzhou 350002China

单价Ag+或Li+引入到类金刚石结构的MQ22-(M=Ga,In;Q=S,Se)阴离子基团中能合成出良好的二阶非线性光学(NLO)晶体材料.然而,这些晶体分别面临着较低的抗激光损伤阈值(LIDT)或二氧化硅易被腐蚀等缺点,严重限制了其在高功率激光应用中的实用... 详细信息

单价Ag+或Li+引入到类金刚石结构的MQ22-(M=Ga,In;Q=S,Se)阴离子基团中能合成出良好的二阶非线性光学(NLO)晶体材料.然而,这些晶体分别面临着较低的抗激光损伤阈值(LIDT)或二氧化硅易被腐蚀等缺点,严重限制了其在高功率激光应用中的实用性.在本研究中,基于类金刚石结构的ZnSe,我们采用[Se_(4)Zn_(13)]Se_(2)4→[ClRb_(3)Ba]Se_(24)非常规的聚阳离子取代策略,设计并合成了一种新型的盐包硫属化合物[Rb_(3)BaCl][In_(8)Se_(14)](1).化合物1属于压缩黄铜矿型硒化物并保持了与AgInSe_(2)相同的晶体对称性(I-42d空间群).值得注意的是,由于InSe_(4)四面体结构单元的平行排列,化合物1具有相位匹配的强二次谐波(SHG)响应(2.0倍于AgGaS_(2)@2.90μm).此外,聚阳离子[Rb_(3)BaCl]^(4+)的引入促进了光学带隙(2.02 eV)的增强,有效地避免了对2.09μm激光的双光子吸收;同时结合较低的热膨胀系数,使得化合物1表现出高的LIDT(3.2倍于AgGaS2@2.09μm).本研究验证了在类金刚石结构中进行聚阳离子取代的可行性,并成功获得了性能优异的中远红外NLO材料.

关键词： chalcogenide nonlinear optical material substitution strategy diamond-like structure structure-property relationship

Effects of Sequence Distribution and Physical Aging on Physical Properties of PES/PEES Random, Block, and Alternative Copolymers

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Chemical Research in Chinese Universities 2006年第6期22卷 787-791页

作者： ZHOU xiao-ming jiang Zhen-hua Alan G. MacDiarmid Lab College of Chemistry Jilin University Changchun 130012 P. R. China

The random, block, and alternative copolymers of poly ether sulfone（PES） and poly ether ether sulfone（PEES） were synthesized v/a three kinds of methods. The chemical structures of the three kinds of copolymers were characterized by ^13C NMR. Three kinds of PES/PEES copolymers（ Tg =215 ℃ ）, which were almost identical in composition but different in sequence distribution, were used. Their physical aging process was studied by differential scanning calorimetry（DSC） at three aging temperatures ranging between Tg -15 ℃ and Tg -25℃. The experimental results reveal that the alternative copolymer shows a lower enthalpy relaxation time 〈T〉 and apparent activation energy when compared with the random and block copolymers. The result of the electron-microscopy investigation of the three copolymers that were treated at 200 ℃ for 96 h indicates that the molecular aggregation of the copolymers changed from a randomly coiled amorphous phase to an ordered phase, and the ordered structure of the alternative copolymer was more distinct than that of the random phase. The experimental results of this study suggest that the motion of the sagments is affected by the different molecular-chain sequence distribution.

关键词： Physical aging Apparent activation energy Sequence distribution

Methylation in esophageal carcinogenesis

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World Journal of Gastroenterology 2006年第43期12卷 6933-6940页

作者： Da-Long Wu Feng-Ying Sui xiao-ming jiang xiao-Hong jiang Department of Pharmacology School of Medicine Collegeof Jiaxing Jiaxing 314001 Zhejiang Province China

Genetic abnormalities of proto-oncogenes and tumor suppressor genes have been demonstrated to be changes that are frequently involved in esophageal cancer pathogenesis. However, hypermethylation of CpG islands, an epigenetic event, is coming more and more into focus in carcinogenesis of the esophagus. Recent studies have proved that promoter hypermethylation of tumor suppressor genes is frequently observed in esophageal carcinomas and seems to play an important role in the pathogenesis of this tumor type. In this review, we will discuss current research on genes that are hypermethylated in human esophageal cancer and precancerous lesions of the esophagus. We will also discuss the potential use of hypermethylated genes as targets for detection, prognosis and treatment of esophageal cancer.

关键词： Methylation Esophageal cancer Tumorsuppressor gene Carcinogenesis

Material research from the viewpoint of functional motifs

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National Science Review 2022年第7期9卷 181-197页

作者： xiao-ming jiang Shuiquan Deng Myung-Hwan Whangbo Guo-Cong Guo State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Department of Chemistry North Carolina State University

As early as 2001,the need for the ’functional motif theory’ was pointed out,to assist the rational design of functional *** properties of materials are determined by their functional motifs and how they are arranged in the *** functional motifs and their arrangements is crucial in understanding the properties of materials and rationally designing new materials of desired *** functional motifs of materials are the critical microstructural units(*** components and building blocks)that play a decisive role in generating certain material functions,and can not be replaced with other structural units without the loss,or significant suppression,of relevant *** role of functional motifs and their arrangement in materials,with representative examples,is *** microscopic structures of these examples can be classified into six types on a length scale smaller than ～10 nm with maximum subatomic resolution,***,magnetic,aperio dic,defect,local and electronic *** motif analysis can be employed in the function-oriented design of materials,as elucidated by taking infrared non-linear optical materials as an *** learning is more efficient in predicting material properties and screening materials with high efficiency than high-throughput experimentation and high-throughput *** order to extract functional motifs and find their quantitative relationships,the development of sufficiently reliable databases for material structures and properties is imperative.

关键词： functional motif functional motif arrangements microscopic structures structure-property relationship

Expression of ATP7B in human gastric cardiac carcinomas in comparison with distal gastric carcinomas

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World Journal of Gastroenterology 2006年第47期12卷 7695-7698页

作者： Da-Long Wu Hui-Xing Yi Feng-Ying Sui xiao-Hong jiang xiao-ming jiang Ying-Ying Zhao Department of Pharmacology School of Medicine College of Jiaxing Jiaxing 314001 Zhejiang Province China Department of cliagnostics School of Medicine College of Jiaxing Jiaxing 314001 Zhejiang Province China Department of Gastroenterology The 2nd Affiliated Hospital of Zhengzhou University Zhengzhou 450003 Henan Province China

AIM： To analyze expression of ATP7B in gastric cardiac adenocarcinomas, its clinicopathologic significance, in comparison with distal gastric adenocarcinomas. METHODS： Immunohistochemical avidin-biotin peroxidase complex method was applied to detect the expression of ATP7B in 49 cases of cardiac carcinomas, the corresponding adjacent non-neoplastic epithelium and 55 cases of distal gastric carcinomas. RESULTS： The proportion of ATP7B positive samples in gastric cardiac carcinomas （51.0%, 25 of 49） was significantly higher than that in the corresponding adjacent non-neoplastic epithelium （22.4%, 11 of 49）（P = 0.003）. ATP7B expression in poorly differentiated gastric cardiac carcinomas was significantly higher than that in well/moderately differentiated gastric cardiac carcinomas （P = 0.030）. ATP7B expression in gastric cardiac carcinomas was independent of age, tumor size, nodal stage and metastasis status. ATP7B protein was detected in 30.9% （17/55 cases） of distal gastric carcinomas, markedly lower than that in gastric cardiac carcinomas （P = 0.037）. CONCLUSION： ATP7B protein is frequently overexpressecl in gastric cardiac carcinomas, and correlated with the differentiation of cardiac carcinoma. ATP7B expression in gastric cardiac carcinomas is significantly higher than that in distal gastric carcinomas, which might partially explain the difference of chemotherapy response and prognosis between these two gastric carcinomas.

关键词： ATP7B Platinum Distal gastric carcinoma Gastric cardiac carcinoma Resistance

Double Slag Operation Dephosphorization in BOF for Producing Low Phosphorus Steel

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Journal of Iron and Steel Research International 2009年第3期16卷 6-14页

作者： TIAN Zhi-hong LI Ben-hai ZHANG xiao-ming jiang Zhong-hang Shougang Research Institute of Technology Shougang Group Beijing 100041 China

A study on the production of low phosphorus steel by double slag operation in 210 t converter was carried out. A phosphorus content of less than 0.005% （mass percent） was obtained before tapping. About 80% phosphorus could be removed by the first slag after 5 min. High Fe^3＋ content and high basicity in the first slag were in favor of dephosphorization. On the other hand,Fe3＋ content had less effect on dephosphorization during second slag treatment. In the second slag period,the fraction of dephosphorization increased with the increase of basicity up to a basicity of 6. Further increase of basicity of the second slag had very little effect on dephosphorization. The tapping temperature had great impact on dephosphorization. It was impossible to get phosphorus less that 0.005% when the tapping temperature was higher than 1 943 K. The optimum operation conditions were suggested. On the basis of these conditions,the amount of the second slag and the effect of the remaining first slag were estimated.

关键词： dephosphorization double slag low phosphorus steel converter

Laboratory-scale study of the suppression of PCDD/F emission during coal and MSW co-incineration

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Journal of Environmental Sciences 2007年第6期19卷 762-767页

作者： LU Sheng-yong YAN Jian-hua LI xiao-dong NI ming-jiang CEN Ke-fa State Key Laboratory of Clean Energy Utilization Institute for Thermal Power Engineering Zhejiang University Hangzhou 310027 China

The experimental test of co-incinerating Chinese raw municipal solid waste （MSW） and coal in a laboratory-scale tubular reactor was first reported in present study, and the emission of normal gas components and the effects of the S/Cl molar ratio or coal mixing percentages on polychlorinated dibenzo-p-dioxins and dibenzofurans （PCDDs/Fs） emission were investigated and discussed. The results indicated that OCDD was the only PCDD homologues since others like TCDD-HpCDD was hardly detected, while as the categories of PCDF homologues were comparatively much more general. The amount of PCDD was much larger than that of PCDF in all operating conditions. Since ZPCDF/∑PCDD〈〈1, the dominant role of the precursor formation was proven in our experimental conductions. With increasing the coal addition to MSW （from 0 to 16%）, PCDD and PCDF were reduced considerably. Coal and MSW may suppress the PCDD/F emissions efficiently （over 95%） during the MSW incineration process. The PCDD/F suppression results of the present study could be helpful guidance to the industrial application of Chinese MSW and auxiliary coal co-incineration processes. The PCDD/F stack emission data of two industrial incinerators using co-incineration technology in China seem to have a great positive reduction of PCDDs/Fs.

关键词： co-incineration PCDDs/Fs suppression S/Cl molar ratio

Non-coding RNAs and gastric cancer

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World Journal of Gastroenterology 2014年第18期20卷 5411-5419页

作者： Pei-Fei Li Sheng-Can Chen Tian Xia xiao-ming jiang Yong-Fu Shao Bing-Xiu xiao Jun-ming Guo Department of Biochemistry and Molecular Biology Zhejiang Provincial Key Laboratory of PathophysiologyNingbo University School of Medicine

Non-coding RNAs(ncRNAs)play key roles in development,proliferation,differentiation and *** ncRNA expression is associated with gastric cancer occurrence,invasion,and ***,aberrant expression of microRNAs(miRNAs)is significantly related to gastric cancer tumor stage,size,differentiation and *** interrupt cellular signaling pathways,inhibit the activity of tumor suppressor genes,and affect the cell cycle in gastric cancer *** miRNAs,including miR-21,miR-106a and miR-421,could be potential markers for the diagnosis of gastric *** non-coding RNAs (lncRNAs),a new research hotspot among cancerassociated ncRNAs,play important roles in epigenetic,transcriptional and post-transcriptional *** gastric cancer-associated lncRNAs,such as CCAT1,GACAT1,H19,and SUMO1P3,have been *** addition,Piwi-interacting RNAs,another type of small ncRNA that is recognized by gastroenterologists,are involved in gastric carcinogenesis,and piR-651/823represents an efficient diagnostic biomarker of gastric cancer that can be detected in the blood and gastric *** interfering RNAs also function in posttranscriptional regulation in gastric cancer and might be useful in gastric cancer treatment.

关键词： Non-coding RNA MicroRNA Piwi-interacting RNA Long non-coding RNA Small interfering RNA Gastric cancer

Assessment of Wet Season Precipitation in the Central United States by the Regional Climate Simulation of the WRFG Member in NARCCAP and Its Relationship with Large-Scale Circulation Biases

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Advances in Atmospheric Sciences 2024年第4期41卷 619-638页

作者： Yating ZHAO ming XUE Jing jiang xiao-ming HU Anning HUANG School of Atmospheric Sciences Nanjing UniversityNanjing 210023China Center for Analysis and Prediction of Storms and School of Meteorology The University of OklahomaNorman 73072U.S.A

Assessment of past-climate simulations of regional climate models(RCMs)is important for understanding the reliability of RCMs when used to project future regional ***,we assess the performance and discuss possible causes of biases in a WRF-based RCM with a grid spacing of 50 km,named WRFG,from the North American Regional Climate Change Assessment Program(NARCCAP)in simulating wet season precipitation over the Central United States for a period when observational data are *** RCM reproduces key features of the precipitation distribution characteristics during late spring to early summer,although it tends to underestimate the magnitude of *** dry bias is partially due to the model’s lack of skill in simulating nocturnal precipitation related to the lack of eastward propagating convective systems in the *** in reproducing large-scale circulation and environmental conditions is another contributing *** too weak simulated pressure gradient between the Rocky Mountains and the Gulf of Mexico results in weaker southerly winds in between,leading to a reduction of warm moist air transport from the Gulf to the Central Great *** simulated low-level horizontal convergence fields are less favorable for upward motion than in the NARR and hence,for the development of moist convection as ***,a careful examination of an RCM’s deficiencies and the identification of the source of errors are important when using the RCM to project precipitation changes in future climate scenarios.

关键词： NARCCAP Central United States precipitation low-level jet large-scale environment diurnal variation