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Rare Metals 2024年第4期43卷 1702-1712页

作者： Xuan Liu Zi-Xia Lin Yin-Biao Shi xiao-Yan Wang Ming-Ye Ding xiao-fei yang College of Science Nanjing Forestry UniversityNanjing210037China Testing Center Yangzhou UniversityYangzhou225009China

Regulating luminescent dynamics of lanthanide-based luminescent materials via external stimuli is of great significance in the fields of optical thermometry and high-level ***,it is still a huge challenge to realize multimodal emissions with tunable color outputs from a single activator in simple structures via smart dynamic control of photon transition ***,we present a mechanistic strategy to achieve multimodal luminescence of Er^(3+)activators with color-switchable outputs in a non-core-shell *** the control of excitation dynamics(λ_(ex)=980,808,1532,377 nm),the population among the intermediate en ergy levels of Er^(3+)and the interaction between Er^(3+)and Yb^(3+)could be precisely modulated through energy transfer and migration processes,leading to the generation of colortunable multimodal luminescence upon diverse excitation modes(non-steady-state,single-/dual-wavelength steady,thermal activation).Inspired by its special luminescent performance,the as-obtained material exhibits great potential in noncontact thermometry,multimodal anticounterfeiting,and high-capacity information encryption by performing a series of proof-of-concept *** findings might provide a conceptual model to modulate the luminescent dynamics in a simple-structured system for the generation of color-adjustable multimodal emissions,which is convenient for the development of advanced luminescent materials toward versatile cuttingedge applications.

关键词： Lanthanide ions Multimodal emission Upconversion Downshifting Anti-counterfeiting Luminescent thermometry

Lignin-reinforced PVDF electrolyte for dendrite-free quasi-solid-state Li metal battery

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Rare Metals 2024年第3期43卷 1006-1016页

作者： Xin-yang Chen Xue-Jie Gao Han-Yan Wu Yu-Long Liu xiao-fei yang Run-Cang Sun Center for Lignocellulosic Chemistry and Biomaterials College of Light Industry and Chemical EngineeringDalian Polytechnic UniversityDalian116034China Division of Energy Storage Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian116023China School of Chemistry Northeast Normal UniversityChangchun130024China

Quasi-solid-state lithium metal batteries(QSSLMBs)assembled with polyvinylidene fluoride(PVDF)are a promising class of next-generation rechargeable batteries due to their safety,high energy density,and superior interfacial ***,PVDF has a series of inherent drawbacks such as low ionic conductivity,ease of crystallization,and hydrophobic character that leading to poor cell *** tackle these issues,a lignin-reinforced PVDF electrolyte is proposed in this work to solve these drawbacks of PVDF and enhance the comprehensive performance of *** lithophilic polar groups of lignin can promote uniform deposition of Li on the *** with the improved mechanical properties can efficiently prevent Li dendrites penetration through the *** addition,more active sites provided by lignin can also enhance Li^(+)transport and lead to a faster electrochemical reaction *** from the ingenious design,Li symmetric cells with 5%lignin-PVDF quasi-solid-state electrolyte can operate for 900 h at a high current density/capacity of 5 mA·cm^(-2)/5 mAh·cm^(-2),while shortcircuiting occurs after 56 h for the counterpart(pure PVDF).Moreover,a full cell of Li/5%lignin-PVDF/LFP cell demonstrates a high capacity of 96.2 mAh·g^(-1)after 2000 cycles at 10 *** work is expected to open up promising opportunities to develop other high-energy/power-density QSSLMBs.

关键词： Quasi-solid-state electrolyte Lignin PVDF Dendrite-free Li metal battery

Synergistic etching and intercalation enables ultrathin Ti_(3)C_(2)T_(x)and Nb_(2)CT_(x)MXene nanosheets

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Rare Metals 2023年第4期42卷 1175-1185页

作者： Qian-Qian Xiong Tahir Muhmood Cheng-xiao Zhao Jing-San Xu xiao-fei yang College of Science Nanjing Forestry UniversityNanjing210037China School of Chemistry and Physics Science and Engineering FacultyQueensland University of TechnologyBrisbaneQLD4001Australia

Transition metal-containing MXene has shown great potential in the promising research fields,and its performance strongly depends on the composition,structure,dimension,and surface ***,rational design and controllable synthesis of ultrathin two-dimensional(2D)MXene nanosheets with uniform surface terminations are of great ***,the use of 2D MXene,particularly in solar-powered photocatalysis and electrocatalysis,is restricted by the formation of thick,multi-layered MXene flakes with a small interlayer spacing produced from the conventional hydrofluoric acid(HF)etching *** this work,we report a few-layer MXene nanosheets by solely employing a mixture of lithium fluoride and hydrochloric acid as the etching *** etching and intercalation technique endows MXene with ultrathin 2D nanostructures;moreover,the use of fluoride salt,rather than harmful HF,offers a safer and environmentally-friendly synthetic route for scalable green production of 2D *** the obtained Ti_(3)C_(2)T_(x)and Nb_(2)CT_(x)nanosheets show a highly efficient photoelectrochemical performance superior to highly stacked MXene *** work highlights a mild,simultaneous etching and delamination strategy for the development of high quality of 2D MXene nanosheets.

关键词： MXene Electrocatalysis Hydrogen evolution reaction(HER) Two-dimensional(2D)nanomaterials

Structure and properties of indium-doped ZnO films prepared by RF magnetron sputtering under different pressures

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Rare Metals 2022年第9期41卷 3239-3243页

作者： Li-Ping Peng A-Ling He Liang Fang xiao-fei yang Research Center of Laser Fusion Chinese Academy of Engineering PhysicsMianyang621900China Department of Applied Physics Chongqing UniversityChongqing400030China Science and Technology Information Center Chinese Academy of Engineering PhysicsMianyang621900China

High conductive and transparent In-doped ZnO thin films were deposited on glass substrates by radio-frequency(RF)magnetron sputtering at 250℃.Argon gas was used as the sputtering gas,and its pressure varies from 0.1 to 4.0 *** influences of deposition pressure on the structural,electrical and optical properties of the films were investigated by means of X-ray diffraction(XRD),scanning electron microscope(SEM)and Hall and transmittance *** optical constant of the films was estimated from transmittance data using a nonlinear programming *** is found that the deposition pressure affects the properties of the films *** film deposited at 2.0 Pa shows the optimal crystal quality with a high transmittance of 85%in the visible range and a low resistivity of 2.4×10^(−3)Ω·cm and can thus be used as a transparent electrode.

关键词： ZnO thin films Transparent conductive oxide Optical constant Magnetron sputtering

Construction of atomic-level charge transfer channel in Bi_(12)O_(17)C_(l2)/MXene heterojunctions for improved visible-light photocatalytic performance

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Rare Metals 2022年第7期41卷 2405-2416页

作者： Song-Song Cui Xuan Liu Yin-Biao Shi Ming-Ye Ding xiao-fei yang College of Science Nanjing Forestry UniversityNanjing 210037China

Exploring efficient co-catalysts to accurately steer the charge separation of semiconductor photocatalysts is highly desired yet remains ***,we tackle the significant challenge by in situ growing the Bi_(12)O_(17)C_(l2)photocatalyst onto two-dimensional(2D)Cl-terminated Ti_(3)C_(2)MXene to construct 2D/2D heterojunction of Bi_(12)O_(17)C_(l2)and Ti_(3)C_(2).Firstly,2D few-layered Ti_(3)C_(2)MXene with chlorine groups has been successfully syn-thesized by Lewis acidic etching strategy with subsequent ultrasonic *** grafting of chlorine terminations on the surface of MXene serves as nucleating centers and growth platform,resulting in the formation of strong interfacial bonds(Bi-Cl-Ti)between Bi_(12)O_(17)C_(l2)and Ti_(3)C_(2).These strong bonds can facilitate the separation and transfer of photo-generated charge carriers between Bi_(12)O_(17)C_(l2)photocatalyst and Ti_(3)C_(2)*** expec-ted,the photocatalytic degradation rate of Bi_(12)O_(17)C_(l2)/Ti_(3)C_(2)hybrids is 9.7 times higher than that of bare Bi_(12)O_(17)C_(l2)*** work not only exhibits a new design concept to effectively steer the charge separation for photocatalysis,but also gives a reference for constructing efficient MXene-based photocatalytic systems.

关键词： Photocatalysis Ti3C2 MXenes Cocatalyst Schottky junction Heterojunction Charge transfer channels

Integrating high-entropy alloy oxides with porous wood architectures for boosted salt-resistant water evaporation

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Rare Metals 2023年第12期42卷 3960-3968页

作者： De-Qi Fan Ye-Mei Liao Xiang Wang Yi Lu Yan Mi xiao-fei yang Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and MaterialsCollege of Chemical EngineeringNanjing Forestry UniversityNanjing 210037China College of Science Nanjing Forestry UniversityNanjing 210037China Key Laboratory of Chemistry and Engineering of Forest Products State Ethnic Affairs CommissionGuangxi Key Laboratory of Chemistry and Engineering of Forest ProductsGuangxi Minzu UniversityNanning 530006China

Solar-driven interfacial desalination technology has recently emerged as a promising way to realize seawater desalination with high energy conversion ***,salt accumulation on solar absorber surface significantly retards desalination rate,especially for highsalinity ***,a vertical Janus-interface saltresistant solar evaporator is constructed for simultaneous efficient solar absorption and stable high-salinity desalination based on the assembly of hydrophilic delignification wood(DW),high-entropy alloy oxides(HEAO),and hydrophobic polydimethylsiloxane(PDMS).

关键词： alloy entropy oxides

3D robust anisotropic diffusion filtering algorithm for sparse view neutron computed tomography 3D image reconstruction

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Nuclear Science and Techniques 2024年第3期35卷 13-29页

作者： yang Liu Teng-fei Zhu Zhi Luo xiao-Ping Ouyang School of Nuclear Science and Engineering North China Electric Power UniversityBeijing 102206China State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China State Key Laboratory of Intense Pulsed Radiation Simulation and Effect Xi’an 710024China

The most critical part of a neutron computed tomography(NCT) system is the image processing algorithm,which directly affects the quality and speed of the reconstructed *** types of noise in the system can degrade the quality of the reconstructed ***,to improve the quality of the reconstructed images of NCT systems,efficient image processing algorithms must be *** anisotropic diffusion filtering(ADF) algorithm can not only effectively suppress the noise in the projection data,but also preserve the image edge structure information by reducing the diffusion at the image ***,we propose the application of the ADF algorithm for NCT image *** compare the performance of different algorithms in NCT systems,we reconstructed images using the ordered subset simultaneous algebraic reconstruction technique(OS-SART) algorithm with different regular terms as image processing *** the iterative reconstruction,we selected two image processing algorithms,the Total Variation and split Bregman solved total variation algorithms,for comparison with the performance of the ADF ***,the filtered back-projection algorithm was used for comparison with an iterative *** reconstructing the projection data of the numerical and clock models,we compared and analyzed the effects of each algorithm applied in the NCT *** on the reconstruction results,OS-SART-ADF outperformed the other algorithms in terms of denoising,preserving the edge structure,and suppressing *** example,when the 3D Shepp–Logan was reconstructed at 25 views,the root mean square error of OS-SART-ADF was the smallest among the four iterative algorithms,at only *** universal quality index,mean structural similarity,and correlation coefficient of the reconstructed image were the largest among all algorithms,with values of 0.9877,0.9878,and 0.9887,respectively.

关键词： NCT OS-SART Sparse-view Anisotropic diffusion filtering

S vacant CuIn_(5)S_(8) confined in a few-layer MoSe_(2) with interlayerexpanded hollow heterostructures boost photocatalytic CO_(2) reduction

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Rare Metals 2022年第1期41卷 144-154页

作者： Li-Juan Chen Ting-Ting Liu Shu-Ming Liu Sheng Cai xiao-xiao Zou Jing-Wen Jiang Zhi-Yuan Mei Gen-Fu Zhao xiao-fei yang Hong Guo School of Materials and Energy Yunnan UniversityKunming 650091China Nanomaterials and Energy Lab Department of Mechanical and Materials EngineeringWestern UniversityLondonON N6A 5B9Canada

The conversion of CO_(2)into CO,CH_(4)and other hydrocarbons through solar energy can alleviate the energy shortage *** design a novel photocatalyst with S defects CuIn_(5)S_(8)@MoSe_(2)hollow *** interlayerexpanded MoSe_(2)can increase the adsorption of *** unique hollow structure can improve the light utilization efficiency and the electron–holes ***_(5)S_(8)with S vacancies in bimetallic sites has high selectivity and photocatalytic reduction of CO_(2)***,S vacant CuIn_(5)S_(8)confined in a few-layers MoSe_(2)with interlayer-expanded hollow heterostructures exhibit super performance for photocatalytic CO_(2)*** 8-h light reaction,the outputs of CO and CH_(4)for the 15.3 wt%CuIn_(5)S_(8)@MoSe_(2)sample containing S vacancies(Vs)are 30.4 and 14.7 lmol·g^(-1),*** mechanism is also investigated in detail through in situ Fourier transform infrared spectroscopy technology.

关键词： Sulfur vacancy CuIn_(5)S_(8) MoSe_(2)heterojunction Photocatalytic CO_(2)reduction

Progress and challenges of electrolyte modulation in aqueous zinc-ion batteries

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Rare Metals 2024年第7期43卷 2940-2967页

作者： Qi-Hang yang Lu-fei Wang xiao-Yu Wang Meng-Meng Zhen Tianjin Key Laboratory of Clean Energy and Pollution Control School of Energy and Environmental EngineeringHebei University of Technology

As a new type of green battery system,aqueous zinc-ion batteries（AZIBs） have gradually become a research hotspot due to their low cost,high safety,excellent stability,high theoretical capacity(820 mAh·g-1) of zinc anode,and low redox potential(-0.76 V *** hydrogen electrode（SHE）).AZIBs have been expected to be an alternative to lithium-ion batteries for large-scale commercial energy storage ***,they are facing thorny issues such as degradation of cycling performance,zinc dendrites,and side *** the same time,these problems cause short cycling life of batteries,thus severely limiting their commercial *** recent years,many more researches have been conducted on the modification of anode and cathode materials of AZIBs,but there is a lack of in-depth discussion on the characteristics and mechanism of electrolyte *** this review,we will make a systematic summary of the current problems with two electrodes in AZIBs,as well as the types and functions of electrolyte ***,we further systematically describe the modulation mechanism of electrolyte additives in the performance of the cathode and *** prospects and development directions of additive modulation strategies for AZIBs electrolytes are prospected.

关键词： Electrolyte additives Aqueous zinc-ion batteries Zinc anode protection Cathode chemistry

Simplified p-i-n Perovskite Solar Cells with a Multifunctional Polyfullerene Electron Transporter

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CHINESE JOURNAL OF POLYMER SCIENCE 2024年第8期42卷 1060-1066页

作者： Wang, fei-fei Liu, Tian-xiao Cui, Ze-Wei Wang, Ling-Yuan Dou, Yun-Jie Shi, xiao-Yu Luo, Si-Wei Hu, xiao-Dong Ren, Zhi-Jun Liu, yang-yang Zhao, Yu Chen, Shang-Shang Nanjing Univ Sch Chem & Chem Engn State Key Lab Coordinat Chem MOE Key Lab High Performance Polymer Mat & Technol Nanjing 210023 Jiangsu Peoples R China

In prevailing p-i-n perovskite solar cells (PSCs), solution-processible fullerene molecules are widely used as electron-transporting layers (ETLs) but they typically suffer from poor uniformity and undesirable stability issues. Additionally, a separate bathocuproine (BCP) layer is needed to block hole transfer, increasing fabrication complexity and cost. Here, we address these limitations by developing a novel polymeric ETL (named PFBCP) synthesized by polymerizing C60 with BCP. This innovative material achieves both efficient electron transport and hole blocking, while its excellent uniformity minimizes interface recombination and enhances stability. Consequently, our blade-coated PSCs utilizing PFBCP achieve a high power conversion efficiency exceeding 22% and retain 91% of initial efficiency after 1200 h of light exposure. This development not only paves the way for commercially viable PSCs but also opens avenues for future ETL design to realize even more efficient and stable PSCs.

关键词： Polyfullerene Perovskite solar cells Electron transporter Stability HIGH-PERFORMANCE LAYER