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Research progress on catalysts for organic sulfur hydrolysis: Review of activity and stability

Chinese Journal of Chemical Engineering 2024年第7期71卷 203-216页

作者： Bingning wang xianzhe.wang Song Yang Chao Yang Huiling Fan Ju Shangguan State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan 030024China Shanxi Engineering Center of Civil Clean Fuel Taiyuan University of TechnologyTaiyuan 030024China College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024China College of Environmental Science and Engineering Taiyuan University of TechnologyTaiyuan 030024China

The removal of organic sulfur through catalytic hydrolysis is a significant area of research in the field of *** review provides an overview of recent advancements in catalytic hydrolysis technology of organic sulfur,including the activity,stability,and atmosphere effects of hydrolysis *** emphasis is on strategies for enhancing hydrolysis activity and anti-oxygen poisoning property of *** modification,metal doping and nitrogen doping have been found to improve the activity of *** components modification is the most commonly used method,the formation of oxygen vacancies through metal doping and creation of nitrogen basic sites through nitrogen doping also contribute to the hydrolysis of organic *** strategies for anti-oxygen poisoning are discussed in a systematic *** structural regulation of catalysts is beneficial for the desorption and diffusion of hydrogen sulfide(H_(2)S),thereby effectively inhibiting its *** doping and the addition of electronic promoters such as transition metals can protect active sites and decrease the number of active oxygen *** methods have been proven to enhance the anti-poisoning performance of ***,this article summarizes how different atmospheres affect the activity of hydrolysis *** objective of this review is to pave the way for the development of efficient,stable and widely used catalysts for organic sulfur hydrolysis.

关键词： Organic sulfur Hydrolysis Catalysts Activity Stability

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In situ protonation in a locally flexible porous coordination polymer for enhancing proton-carrier loading and proton conductivity

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Science China Chemistry 2024年第10期67卷 3432-3437页

作者： xianzhe Wei Jincheng Liu Yan Su Weitao wang Guixiang wang Gen Zhang Ping wang Cheng Gu State Key Laboratory of Luminescent Materials and Devices Institute of Polymer Optoelectronic Materials and DevicesSouth China University of Technology College of Polymer Science and Engineering State Key Laboratory of Polymer Materials EngineeringSichuan University Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education School of Chemistry and Chemical EngineeringNanjing University of Science and Technology

Designing efficient proton-conductive materials is crucial in fuel cells. Yet, it remains a substantial challenge because of the issues in proton mobility, proton-carrier amount, and orientation of proton host materials. Herein, we report an in-situ protonation strategy to produce a locally flexible porous coordination polymer(PCP) to enhance the proton-carrier loading and proton conductivity. The local dipole flipping of the ligand allows effective proton exchange with low activation energy, promoting interpore proton transport through the pore apertures and pore walls. The protonation induces substantial charges to the frameworks and enhances the interaction with proton carriers, thereby increasing the loading of the proton carriers. By this design strategy, the resulting PCP exhibits enhanced phosphoric acid loading and extraordinary proton conductivities under both aqueous and anhydrous conditions compared to its isoreticular analog that features rigidity without proton-exchange *** work provides a new avenue for designing proton-conductive materials that combine structural dynamics with performance merits.

关键词： porous coordination polymers in-situ protonation local flexibility proton-exchange mechanism proton conduction

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Evolving landscape of treatments targeting the microenvironment of liver metastases in non-small cell lung cancer

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Chinese Medical Journal 2024年第9期137卷 1019-1032页

作者： Lingling Zhu xianzhe Yu Xiaojun Tang Chenggong Hu Lei Wu Yanyang Liu Qinghua Zhou Lung Cancer Center Lung Cancer InstituteWest China HospitalSichuan UniversityChengduSichuan 610041China Key Laboratory of Drug Targeting and Drug Delivery Systems Ministry of EducationWest China School of PharmacyCollege of Polymer Science and EngineeringSichuan UniversityChengduSichuan 610041China Department of Gastrointestinal Surgery Chengdu Second People’s HospitalChengduSichuan 610041China Department of Critical Care Medicine West China HospitalSichuan UniversityChengduSichuan 610041China Core Facility of West China Hospital Sichuan UniversityChengduSichuan 610041China Department of Medical Oncology Cancer CenterWest China HospitalSichuan UniversityChengduSichuan 610041China

Liver metastases(LMs)are common in lung *** substantial advances in diagnosis and treatment,the survival rate of patients with LM remains low as the immune-suppressive microenvironment of the liver allows tumor cells to evade the immune *** impact of LMs on the outcomes of immune checkpoint inhibitors in patients with solid tumors has been the main focus of recent translational and clinical *** evidence indicates that the hepatic microenvironment delivers paracrine and autocrine signals from non-parenchymal and parenchymal ***,these microenvironments create pre-and post-metastatic conditions for the progression of ***,we reviewed the epidemiology,physiology,pathology and immunology,of LMs associated with non-small cell lung cancer and the role and potential targets of the liver microenvironment in LM in each phase of ***,we reviewed the current treatment strategies and challenges that should be overcome in preclinical and clinical *** approaches target liver elements as the basis for future clinical trials,including combinatorial interventions reported to resolve hepatic immune suppression,such as immunotherapy plus chemotherapy,immunotherapy plus radiotherapy,immunotherapy plus anti-angiogenesis therapy,and surgical resection.

关键词： Non-small cell lung cancer Liver metastasis Combination therapy Immune checkpoint inhibitors Immune tolerance Immunotherapy

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Exploring Antarctic subglacial lakes with RECoverable Autonomous Sonde(RECAS):Design and first field tests

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Science China(Technological Sciences) 2024年第6期67卷 1866-1878页

作者： SUN YouHong PAVEL Talalay LI YuanSheng YU HaiBin wang DongLiang LI GuoPing XU LiPing GONG Da wang JiXin wang JianHua wang Ting ZHANG Nan wang ZhiGang CHEN YanJi LIU YunChen LI YaZhou PENG ShiLin SHI JianGuang AN ChunLei GE Qun XU Jing NI XiaoKang CUI QiFeng JIANG Qiang MIKHAIL Sysoev Yang Yang wang RuSheng WEI xianzhe.wang Yu ZHU TianXin DENG ZhiPeng ALEXEY Markov LI Bing FAN XiaoPeng Polar Research Center Jilin UniversityChangchun130000China School of Engineering and Technology China University of GeosciencesBeijing100083China Polar Research Institute of China Shanghai200120China College of Electronics and Information Hangzhou Dianzi UniversityHangzhou310018China Aerospace System Engineering Shanghai Shanghai201109China Nanjing Institute of Astronomical Optics&Technology National Astronomical ObservatoriesChinese Academy of SciencesNanjing210000China National Ocean Technology Center Tianjin300000China

Conducting scientific drilling on subglacial lakes and obtaining samples of subglacial lake water holds great significance in unraveling the formation and evolution of Antarctic subglacial lakes and early Earth's life *** various approaches to access and directly sample subglacial water and sediments,clean access and exploration of subglacial lakes remain *** address this concern,Jilin University has developed the RECoverable Autonomous Sonde(RECAS)*** technology enables sampling and in-situ detection of subglacial lake water while being isolated from the surface,thus minimizing the risk of *** tests,including downward and upward drilling,long-running,remote-control,and cold-environment assessments,were conducted to validate the sonde's principle and *** the 38th Chinese National Antarctic Research Expedition,CHINARE(2021–2022 season),the RECAS prototype underwent testing on the flank region of Dalk glacier,10 km from Zhongshan Station in *** boreholes with depths of 200.3,183.2,and 133.5 m were successfully drilled,with the refrozen meltwater sealing the boreholes during the *** 600 mL of melted water samples were collected from each *** the drilling tests,all systems of the RECAS prototype performed within the expected ranges.

关键词： subglacial lake thermal drilling water sampling Antarctic autonomous sonde

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环境规制下中国工业绿色转型的创新类型选择

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浙江大学学报（工学版） 2024年第1期58卷 188-196页

作者：刘海英蔡先哲大连海事大学航运经济与管理学院辽宁大连116026

为了解决严格环境规制背景下工业企业如何选择适宜的绿色技术创新类型来实现工业绿色转型的问题,采用包含非期望产出的超效率与基于松弛值测算(SBM)相结合的SBM模型,测算中国30个省份2008—2020年的工业环境效率,以该效率表征工业绿色... 详细信息

为了解决严格环境规制背景下工业企业如何选择适宜的绿色技术创新类型来实现工业绿色转型的问题,采用包含非期望产出的超效率与基于松弛值测算(SBM)相结合的SBM模型,测算中国30个省份2008—2020年的工业环境效率,以该效率表征工业绿色转型水平.通过面板门槛模型,探究不同环境规制强度下绿色技术创新类型对工业绿色转型的影响机理.结果表明,整体上,2008—2020年中国工业环境效率处于波动上升态势,区域间的效率差距整体上呈微幅减小的趋势.不同绿色技术创新的环境效应存在显著差异,其中强调工艺和产品的过程导向型绿色技术创新是实现工业绿色转型的关键.随着环境规制强度的加大,过程导向型绿色技术创新的正向环境效应会加大,结果导向型绿色技术创新的负向环境效应会降低.

关键词：绿色技术创新环境规制工业绿色转型超效率SBM模型面板门槛模型

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Remodel the perifollicular microenvironment via Minoxidil-loaded microneedle patch and cold atmospheric plasma for treating androgenetic alopecia

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Nano Research 2024年第7期17卷 6411-6419页

作者： Hao Chen xianzhe Tang Yueye Huang Chen Chen Yuheng Yang Chaojie Hao Wenqi Xie Tingjing Huang Xiaofeng Cheng Qingnan Xu Shicong Huang Zhi Ye Xucong Lin Zhaowei Chen Zhitong Chen MOE Key Laboratory for Analytical Science of Food Safety and Biology and New Cornerstone Science LaboratoryCollege of ChemistryFuzhou UniversityFuzhou 350108China Institute of Biomedical and Health Engineering Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China Advanced Therapeutic Center National Innovation Center for Advanced Medical DevicesShenzhen 518000China Department of Chemistry University College LondonLondon WC1H 0AJUK Engineering Technology Research Center on Reagent and Instrument for Rapid Detection of Product Quality and Food Safety in Fujian Province College of ChemistryFuzhou UniversityFuzhou 350108China Key Laboratory of Biomedical Imaging Science and System Chinese Academy of SciencesShenzhen 518055China

Androgenetic alopecia(AGA)is a chronic and progressive form of hair loss characterized by vascular degeneration in the perifollicular microenvironment,leading to cell apoptosis and eventual loss of hair follicles(HFs).Traditional therapeutic formulations,such as Minoxidil(MXD)tincture,have limitations in reshaping the perifollicular microenvironment and exhibit limited ***,we report a multi-synergistic therapeutic platform for high-performance hair regeneration *** platform combines microneedle(MN)patches loaded with MXD-encapsulated nanostructured lipid carriers(MXD-NLC-MNs)and cold atmospheric plasma(CAP).The MNs’mechanical strength enables efficient transdermal delivery of MXD to the targeted dermal papilla cells,promoting cell ***,in collaboration with MXD,the mechanical stimulation exerted by MN application synergistically upregulates the expression of vascular endothelial growth factor,leading to ***,the transient microchannels in the skin created by MNs facilitate the transdermal delivery of CAPgenerated nitric oxide(NO)to the sites of HF lesions,whereby the synergistic interaction between MXD and NO boosts perifollicular ***,the perifollicular microenvironment can be effectively reshaped to accelerate hair regeneration in AGA murine *** multi-synergistic combination therapy strategy would hold great promise for effectively treating AGA and promoting hair regrowth.

关键词： nanomedicine androgenetic alopecia microneedle cold atmospheric plasma drug delivery

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Cookie Baking Process Optimization and Quality Analysis Based on Food 3D Printing

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Journal of Northeast Agricultural University(English Edition) 2024年第1期31卷 61-73页

作者： Liu Chenghai Li Jingyi Wu Chunsheng Zhao Xinglong Zheng xianzhe College of Engineering Northeast Agricultural UniversityHarbin 150030China Jiamusi Branch of Heilongjiang Academy of Agricultural Machinery Engineering Jiamusi 154005HeilongjiangChina Innovation and Entrepreneurship Center of Northeast Agricultural University Harbin 150030China

In order to obtain better quality cookies, food 3D printing technology was employed to prepare cookies. The texture, color, deformation, moisture content, and temperature of the cookie as evaluation indicators, the influences of baking process parameters, such as baking time, surface heating temperature and bottom heating temperature, on the quality of the cookie were studied to optimize the baking process parameters. The results showed that the baking process parameters had obvious effects on the texture, color, deformation, moisture content, and temperature of the cookie. All of the roasting surface heating temperature, bottom heating temperature and baking time had positive influences on the hardness, crunchiness, crispiness, and the total color difference(ΔE) of the cookie. When the heating temperatures of the surfac and bottom increased, the diameter and thickness deformation rate of the cookie increased. However,with the extension of baking time, the diameter and thickness deformation rate of the cookie first increased and then decreased. With the surface heating temperature of 180 ℃, the bottom heating temperature of 150 ℃, and baking time of 15 min, the cookie was crisp and moderate with moderate deformation and uniform color. There was no burnt phenomenon with the desired quality. Research results provided a theoretical basis for cookie manufactory based on food 3D printing technology.

关键词： food 3D printing baking process cookie quality analysis optimization of process parameter

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Zircon U-Pb-Hf and trace element signatures reveal the petrogenesis of the Jiuyishan granitic complex， South China: Implications for W-Sn and rare metal mineralization

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Journal of Earth Science 2024年

作者： Wenzhou Xiao Chaoyun Liu Kaixuan Tan xianzhe Duan Qinglin Sui Kaituo Shi Peng Feng Mabrouk Sami Quan Ou Hunan Key Laboratory of Rare Metal Minerals Exploitation and Geological Disposal of Wastes， School of Resource Environment and Safety Engineering， University of South China Fundamental Science on Radioactive Geology and Exploration Technology Laboratory， East China University of Technology Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring， Ministry of Education， School of Geosciences and Info-Physics， Central South University Geology Department， Faculty of Science， Minia University State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation， Institute of Sedimentary Geology， Chengdu University of Technology

The Jiuyishan granitic complex， located in the Nanling Range， South China， is composed of five granitic plutons （Xuehuading， Jinjiling， Pangxiemu， Shaziling and Xishan）. Zircon U-Pb dating of four plutons （Jinjiling， Pangxiemu， Shaziling and Xishan） yielded similar ages of approximately 153 Ma， indicating indistinguishable ages within error. Three plutons except the Shaziling pluton， have consistent εNd（t）（-7.8 to -5.8） and εHf（t）（-9.1 to -2.2） values， which are similar to those of the lower crustal granulitic metasedimentary and meta-igneous rocks in South China. Comparing to other three plutons， the Shaziling pluton has consistent εHf（t）（-7.4 to -6.8） and εHf（t）（-7.5 to -4.7） values and shows similar source， but the Shaziling mafic microgranular enclaves （MMEs） show variable εHf（t）（-14.2 to 4.8） values， indicating a remarkable mantle magma injection of the Shaziling pluton. Zircon Ce/Sm-Yb/Gd， whole-rock CaO-P2O5and CaO-TiO2linear trends revealed that from the Xishan to the Shaziling and from the Jinjiling to the Pangxiemu granites， they experienced apatite and titanite fractionation， respectively. Zircon Th， U， Nb， Ta， Hf， Ti， Y， P and rare earth element （REE） contents and whole-rock Sr， Ba and Rb contents also show that the Shazling， Xishan， Jinjiling and Pangxiemu granites followed a discontinuous evolutionary series， but the Pangxiemu granites exhibit highly evolved nature. Four main controlling factors of W-Sn and rare metal mineralization in granitic rocks were discussed， and we found that the mineralization in Jiuyishan granitic complex was mainly controlled by the fractionation degree and crystallization temperature， but were rarely affected by oxygen fugacity and mantle material input. The Pangxiemu granites show particularly higher Rb and Ta contents than the other three plutons， implying that the ore deposits developed in the Jiuyishan complex were directly related to the most evolved Pangxiemu pluton， with the occurrence of Rb and Ta as the most l

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面向旋转载体的卫星导航天线相位缠绕问题与分析

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航空兵器 2024年第3期31卷 66-71页

作者：王俊瞿辰旭董先哲北京交通大学电子信息工程学院北京100044

为解决卫星导航接收机在小口径旋转导弹应用中无法实现载波连续跟踪问题,本文通过分析小口径旋转导弹接收的卫星导航信号特点,研究载体旋转对接收信号幅度和载波相移的影响,建立载体旋转状态下接收信号的幅度变化模型和载波相移模型,提... 详细信息

为解决卫星导航接收机在小口径旋转导弹应用中无法实现载波连续跟踪问题,本文通过分析小口径旋转导弹接收的卫星导航信号特点,研究载体旋转对接收信号幅度和载波相移的影响,建立载体旋转状态下接收信号的幅度变化模型和载波相移模型,提出了天线相位缠绕会引入额外的载波相移并改进原有的系统模型。依据信号模型进行系统仿真,并搭建了试验环境以证明相位缠绕对载波相位测量引入的误差不可忽略。试验结果表明,本文所改进的相位缠绕系统模型与实测数据均方根误差为11.13°,为卫星导航接收机实现载波跟踪进行精确的相位补偿提供理论依据,进而为提高高速旋转载体卫星导航性能提供理论支撑。

关键词：旋转载体卫星导航幅度变化模型载波相移模型相位缠绕导弹

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The reformation of catalyst:From a trial-and-error synthesis to rational design

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Nano Research 2024年第4期17卷 3261-3301页

作者： Ligang wang Jiabin Wu Shunwu wang Huan Liu Yao wang Dingsheng wang Department of Chemistry Tsinghua UniversityBeijing 100084China

The appropriate catalysts can accelerate the reaction rate and effectively boost the efficient conversion of various molecules,which is of great importance in the study of chemistry,chemical industry,energy,materials and environmental ***,efficient,environmentally friendly,and easy to operate synthesis methods have been used to prepare various types of *** previous studies have reported the synthesis and characterization of the aforementioned catalysts,more still remain in trial and error methods,without in-depth consideration and improvement of traditional synthesis ***,we comprehensively summarize and compare the preparation methods of the trial-and-error synthesis strategy,structure–activity relationships and density functional theory(DFT)guided catalysts rational design for nanomaterials and atomically dispersed *** also discuss in detail the utilization of the nanomaterials and single atom catalysts for converting small molecules(H_(2)O,O_(2),CO_(2),N_(2),etc.)into value-added products driven by electrocatalysis,photocatalysis,and ***,the challenges and outlooks of mass preparation and production of efficient and green catalysts through conventional trial and error synthesis and DFT theory are featured in accordance with its current development.

关键词： trial-and-error synthesis structure–activity relationships density functional theory(DFT)guidance nanomaterials atomically dispersed catalysts

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