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Construction of iron manganese metal-organic framework-derived manganese ferrite/carbon-modified graphene composites toward broadband and efficient electromagnetic dissipation

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International Journal of Minerals,Metallurgy and Materials 2025年第3期32卷 546-555页

作者： Baohua liu shuai liu Zaigang Luo Ruiwen shu School of Chemical and Blasting Engineering Anhui Province Key Laboratory of Specialty PolymersAnhui University of Science and TechnologyHuainan 232001China Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining Anhui University of Science and TechnologyHuainan 232001China

The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge ***-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW *** this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis *** results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ***,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption ***,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was ***,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.

关键词： metal-organic frameworks graphene magnetic composites morphology regulation electromagnetic dissipation

Improving Multi-task GNNs for Molecular Property Prediction via Missing Label Imputation

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Machine Intelligence Research 2025年第1期22卷 131-144页

作者： Fenyu Hu Dingshuo Chen Qiang liu shu Wu University of Chinese Academy of Sciences Beijing100190China Center for Research on Intelligent Perception and Computing State Key Laboratory of Multimodal Artificial Intelligence SystemsInstitute of AutomationChinese Academy of SciencesBeijing100190China

The prediction of molecular properties is a fundamental task in the field of drug ***,graph neural networks(GNNs)have been gaining prominence in this *** a molecule tends to have multiple correlated properties,there is a great need to develop the multi-task learning ability of ***,limited by expensive and time-consuming human annotations,collecting complete labels for each task is *** a result,most existing benchmarks involve many missing labels in training data,and the performance of GNNs is impaired due to the lack of sufficient supervision *** overcome this obstacle,we propose to improve multi-task molecular property prediction by missing label ***,a bipartite graph is first introduced to model the molecule-task co-occurrence ***,the imputation of missing labels is transformed into predicting missing edges on this bipartite *** predict the missing edges,a graph neural network is devised,which can learn the complex molecule-task co-occurrence *** that,we select reliable pseudo labels according to the uncertainty of the prediction *** with enough and reliable supervision information,our approach achieves state-of-the-art performance on a variety of real-world datasets.

关键词： Graph classification imbalance learning prediction bias mixture of experts multiview representations

Functional ternary salt construction enabling an in-situ Li3N/LiF-enriched interface for ultra-stable all-solid-state lithium metal batteries

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Journal of Energy Chemistry 2025年第2期101卷 68-75页

作者： Hong-Yan liu Xin-Yu liu Nan Zhang Peng-Fei Wang Zong-Lin liu Jie shu Ting-Feng Yi School of Materials Science and Engineering Northeastern University Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province School of Resources and Materials Northeastern University at Qinhuangdao Faculty of Materials Science and Chemical Engineering and Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province Ningbo University

Poly（ethylene oxide）-based polymer all-solid-state lithium metal batteries（ASSLBs） have received widespread attention due to their low cost,good process ability,and high energy ***,the growth of Li dendrites within polymer solid-state electrolytes damages the reversibility of Li anodes and still impedes their widespread *** efficient strategy is to construct a superior solid electrolyte ***,a stable interface enriched with Li3N and LiF is in-situ formed between Li anode and a terna ry salt *** terna ry salt electrolyte is innovatively designed by introducing lithium bis（trifluoromethane sulfonyl）imide（LiTFSI）,lithium bis（fluorosulfonyl）imide（LiFSI）,and LiNO3to poly（ethylene oxide） *** characterization indicates that LiNO3and LiFSI contribute to forming a Li3N-LiF-enriched interface and meanwhile LiTFSI ensures excellent ***,among various Li compound components,Li3N has high ionic conductivity,which is beneficial for reducing overpotential,while LiF has high interfacial energy which can enhance nucleation energy and suppress the formation of Li *** experimental results show that ASSLBs coupled with LiFePO4cathode display extremely excellent cycle stability approximately 2200 cycles at 2 C,with a final and corresponding discharge specific capacity of 96.7 mA h g-1. Additionally,a schematic illustration of the working mechanism for the Li3N-LiF interface is proposed.

关键词： All-solid-state lithium metal batteries In-situ SEI Lithium dendrite PEO (LiTFSI) Solid electrolyte

Different fates of Sb(Ⅲ)and Sb(V)during the formation of jarosite mediated by Acidithiobacillus ferrooxidans

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Journal of Environmental Sciences 2025年第1期147卷 342-358页

作者： Lu Chen Yirong Wang Hongchang liu Yuhang Zhou Zhenyuan Nie Jinlan Xia Wensheng shu School of Minerals Processing and Bioengineering Central South UniversityChangsha 410083China Key Lab of Biometallurgy of Ministry of Education of China Central South UniversityChangsha 410083China School of Life Sciences South China Normal UniversityGuangzhou 510631China

Secondary iron-sulfate minerals such as jarosite,which are easily formed in acid mine drainage,play an important role in controlling metal *** this work,the typical iron-oxidizing bacterium Acidithiobacillus ferrooxidans ATCC 23270 was selected to synthesize jarosite in the presence of antimony ions,during which the solution behavior,synthetic product composition,and bacterial metabolism were *** results show that in the presence of Sb(V),Fe^(2+)was rapidly oxidized to Fe^(3+)by *** and Sb(V)had no obvious effect on the biooxidation of Fe^(2+)under the current experimental *** presence of Sb(Ⅲ)inhibited bacterial growth and Fe^(2+)*** the group with Sb(Ⅲ),products with amorphous phaseswere formed 72 hr later,whichwere mainly ferrous sulfate and pentavalent antimony oxide,and the amorphous precursor was finally transformed into a more stable crystal *** the group with Sb(V),the morphology and structure of jarosite were changed in comparison with those without *** biomineralization process was accompanied by the removal of 94%Sb(V)to form jarosite containing the Fe-Sb-O *** transcriptome analysis shows differential effects of Sb(Ⅲ)and Sb(V)on bacterial *** expression levels of functional genes related to cell components were much more downregulated for the group with Sb(Ⅲ)butmuch more regulated for that with Sb(V).Notably,cytochrome c and nitrogen fixation-relevant genes for the A.f_Fe^(2+)_Sb(Ⅲ)group were enhanced significantly,indicating their role in Sb(Ⅲ)*** study is of great value for the development of antimony pollution control and remediation technology.

关键词： Jarosite Acidithiobacillus ferrooxidans Bacterial iron oxidation Sb(Ⅲ)and Sb(V)transformation Transcriptome analysis

Optimizing frequency allocation for superconducting quantum processors with frequency-tunable qubits

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Science China(Physics,Mechanics & Astronomy) 2025年第2期68卷 23-36页

作者： Bi-Ying Wang Wuxin liu xiangyu Chen shu Xu Jiangyu Cui Man-Hong Yung Quantum Science Center of Guangdong-Hong Kong-Macao Greater Bay Area(Guangdong) Shenzhen518129China Shenzhen Institute for Quantum Science and Engineering Southern University of Science and TechnologyShenzhen518055China International Quantum Academy Shenzhen518048China Guangdong Provincial Key Laboratory of Quantum Science and Engineering Southern University of Science and TechnologyShenzhen518055China Shenzhen Key Laboratory of Quantum Science and Engineering Southern University of Science and TechnologyShenzhen518055China

As superconducting quantum processors scale,a key challenge is maintaining high coherence times and fidelity control over numerous *** propose an automatic frequency allocation method for frequency-tunable qubits that equally considers coherence-limited fidelity and crosstalk-induced control errors during the allocation *** employing a weighted average of the objective functions for coherence time and crosstalk,we numerically calculate gate fidelity to establish an open-loop optimization for determining suitable weight *** results in an efficient objective function for frequency *** apply our method to frequency-tunable transmon qubits with tunable couplers,both theoretically and *** numerical results demonstrate significant advantages,including substantial reductions in gate errors and faster operation times,especially at higher qubit ***,our approach successfully achieves approximately 99.9%single-qubit fidelity on a nine-qubit chip.

关键词： frequency allocation transmon qubits superconducting processors

Fabrication of flake-like NiCo_(2)O_(4)/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber

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International Journal of Minerals,Metallurgy and Materials 2025年第3期32卷 556-565页

作者： Konghu Tian Hang Yang Chao Zhang Ruiwen shu Qun Shao Xiaowei liu Kaipeng Gao The First Affiliated Hospital of Anhui University of Science and Technology(Huainan First People’s Hospital) Huainan 232001China Analysis and Test Center Anhui University of Science and TechnologyHuainan 232001China School of Materials Science and Engineering Anhui University of Science and TechnologyHuainan 232001China School of Chemical and Blasting Engineering Anhui University of Science and TechnologyHuainan 232001China

Carbon-based foams with a three-dimensional structure can serve as a lightweight template for the rational design and control-lable preparation of metal oxide/carbon-based composite microwave absorption *** this study,a flake-like nickel cobaltate/re-duced graphene oxide/melamine-derived carbon foam(FNC/RGO/MDCF)was successfully fabricated through a combination of solvo-thermal treatment and high-temperature *** indicated that RGO was evenly distributed in the MDCF skeleton,providing ef-fective support for the load growth of FNC on its *** S3,the FNC/RGO/MDCF composite prepared by solvothermal method for 16 h,exhibited a minimum reflection loss(RL_(min))of-66.44 dB at a thickness of 2.29 *** the thickness was reduced to 1.50 mm,the optimal effective absorption bandwidth was 3.84 *** of the absorption mechanism of FNC/RGO/MDCF revealed that its excellent absorption performance was primarily attributed to the combined effects of conduction loss,multiple reflection,scattering,in-terface polarization,and dipole polarization.

关键词： carbon foam reduced graphene oxide flake-like nickel cobaltate microwave absorbing materials

Predicting the efficiency of arsenic immobilization in soils by biochar using machine learning

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Journal of Environmental Sciences 2025年第1期147卷 259-267页

作者： Jin-Man Cao Yu-Qian liu Yan-Qing liu shu-Dan Xue Hai-Hong Xiong Chong-Lin Xu Qi Xu Gui-Lan Duan State Key Lab of Urban and Regional Ecology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Henan Institute of Advanced Technology Zhengzhou UniversityZhengzhou 450052China University of Chinese Academy of Sciences Beijing 100049China

Arsenic(As)pollution in soils is a pervasive environmental *** immobilization offers a promising solution for addressing soil As *** efficiency of biochar in immobilizing As in soils primarily hinges on the characteristics of both the soil and the ***,the influence of a specific property on As immobilization varies among different studies,and the development and application of arsenic passivation materials based on biochar often rely on empirical *** enhance immobilization efficiency and reduce labor and time costs,a machine learning(ML)model was employed to predict As immobilization efficiency before biochar *** this study,we collected a dataset comprising 182 data points on As immobilization efficiency from 17 publications to construct three ML *** results demonstrated that the random forest(RF)model outperformed gradient boost regression tree and support vector regression models in predictive *** importance analysis and partial dependence plots based on the RF model were conducted to identify the most crucial factors influencing As *** findings highlighted the significant roles of biochar application time and biochar pH in As immobilization efficiency in ***,the study revealed that Fe-modified biochar exhibited a substantial improvement in As *** insights can facilitate targeted biochar property design and optimization of biochar application conditions to enhance As immobilization efficiency.

关键词： Biochar Arsenic immobilization Soil Machine learning

Iron scrap derived nano zero-valent iron/biochar activated persulfate for p-arsanilic acid decontamination with coexisting microplastics

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Journal of Environmental Sciences 2025年第5期151卷 733-746页

作者： Zihan shu Hailan Yang shujing Ye Hong Li Zhiming Yang Chuang Li Xiaofei Tan Shaobo liu Hou Wang College of Environmental Science and Engineering Hunan University and Key Laboratory of Environmental Biology and Pollution Control(Hunan University)Ministry of EducationChangsha 410082China Shenzhen Research Institute of Hunan University Shenzhen 518055China School of Resources Environment and MaterialsGuangxi UniversityNanning 530004China College of Resources and Environment University of Chinese Academy of SciencesBeijing 101408China School of Architecture and Art Central South UniversityChangsha 410083China School of Metallurgy and Environment Central South UniversityChangsha 410083China

P-arsanilic acid(AA)has received widespread attention because of its conversion to more toxic inorganic arsenic compounds(arsenate and arsenite)in the natural *** removal process and mechanisms with co-existence of microplastics remain *** this study,biochar loaded with nano zero-valent iron(nZVI)particles(ISBC)was prepared by using iron scrap obtained from a steel works and wood chips collected from a wood processing *** advanced oxidation system of sodium persulfate(PDS)activated by ISBC was applied for AA degradation and inorganic arsenic control in aqueous *** than 99%of the AA was completely degraded by the ISBC/PDS system,and the As(III)on AA was almost completely oxidized to As(V)and finally removed by ***_(3)−inhibited the removal of AA by the ISBC/PDS system,while Cl^(−)had a dual effect that showing inhibition at low concentrations yet promotion at high *** effect of microplastics on the degradation of AA by the ISBC/PDS system was further investigated due to the potential for combined microplastic and organic arsenic contamination in rural/remote *** were found to have little effect on AA degradation in the ISBC/PDS system,while affect the transport of inorganic arsenic generated from AA ***,this study provides new insights and methods for efficient removal of p-arsanilic acid from water with coexisting microplastics.

关键词： P-arsanilic acid Biochar Arsenate and arsenite Microplastics

China Liver Transplant Registry plays an important role in liver transplantation

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Hepatobiliary & Pancreatic Diseases International 2025年第1期24卷 14-17页

作者： Zhe Yang Jian-Peng liu Jun-Li Chen shu-Sen Zheng Department of Hepatobiliary and Pancreatic Surgery Department of Liver Transplantation Shulan(Hangzhou)Hospital Division of Hepatobiliary Pancreatic Surgery the First Affiliated Hospital Zhejiang University School of Medicine Key Laboratory of Combined Multi-organ Transplantation Ministry of Public Health the First Affiliated Hospital Zhejiang University School of Medicine National Center for Healthcare Quality Management in Liver Transplant

In China, liver transplantation is an important discipline in the field of organ transplantation. China Liver Transplant Registry (CLTR) is a scientific project that has been set up to advance surgical techniques and procedures and to improve both short-and long-term post-transplant follow-up and outcome of the liver recipients. CLTR also serves as a robust data support platform for the National Liver Transplant Quality Control Center in the quest to upscale its quality control protocols. The mission of CLTR is to register all liver transplantation activities in the mainland of China and to conduct scientific analyses of the collected data. The huge number of compiled cases and the scientific research conducted over the past decade based on this database drastically revolutionized the clinical practice in the country. All CLTR activities and projects will be a guarantee to foster progresses of liver transplantation in China in a more scientific way, to standardize the systematic care in the field of liver transplantation.

关键词： Transplant registry China Liver Transplant Registry Liver transplantation Hepatocellular cancer