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Chinese Journal of Chemistry 2020年第4期38卷 367-371页

作者： Penghui Li Yingyong Wang yunwei Wang guoqiang Jin xiang-yun guo Xili Tong State Key Laboratory of Coal Conversion Institute of Cool ChemistryChinese Academy of SciencesTaiyuanShanxi 030001China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China School of Petrochemical Engineering Changzhou UniversityChangzhouJiangsu 213164Chino

Summary of main observation and conclusion Selective hydrogenation of a,B-unsaturated carbonyls into saturated carbonyls is important to obtain remunerative ***,it is still a challenge to achieve high activity and selec tivity under mild ***,Pd,Ir and bimetallic Pd-Ir nanoparticles were uniformly deposited with high dispersity on the surface of SIC by a facile impregnation method,*** as prepared Pd/SIC catalysts eficiently hydrogenate cinnamaldehyde to hydrocinnamaldehyde at room temperature and atmospheric pressure,and the activity of Pd/SiC is observed further enhanced by adding Ir component(conversion of 100%).In addition,the dependence of Pd-lr catalyst activity on Pd/Ir molar ratio *** a synergistic effect between Ir and Pd,which originates from the electron transfer between Pd and Ir.

关键词： Palladium Hydrogenation uniformly

Study on Reduction of β-Aromatic Amino Substituted Triazolyl Ketene Compounds

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Chinese Chemical Letters 2003年第5期14卷 471-474页

作者： Yang Zhou LI Jun Ran CHENG Qing Min WANG xiang yun guo Run Qiu HUANG Institute and State Key Laboratory of Elemento-organic Chemistry Nankai UniversityTianjin 300071

A series of b-aromatic amino substituted triazolyl ketenes were reduced at different conditions to enols and saturated alcohols, respectively. The preliminary biological tests showed that some of them exhibit good fu... 详细信息

关键词： Triazole reduction fungicidal activity.

Photocatalytic C–X borylation of aryl halides by hierarchical SiC nanowire-supported Pd nanoparticles

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Chinese Journal of Catalysis 2020年第2期41卷 357-363页

作者： Zhi-Feng Jiao Ji-Xiao Zhao Xiao-Ning guo xiang-yun guo State Key Laboratory of Coal Conversion Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001ShanxiChina Institut für Anorganische Chemie and Institute for Sustainable Chemistry&Catalysis with BoronJulius-Maximilians-Universit?t WürzburgAm Hubland97074 WürzburgGermany School of Petrochemical Engineering Changzhou UniversityChangzhou 213164JiangsuChina Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Hierarchical Si C nanowire-supported Pd nanoparticles showed high photocatalytic activity for the C–X(X = Br, I) borylation of aryl halides at 30 °C. The Si C/Pd Mott-Schottky contact enhances the rapid transfer of the photogenerated electrons from Si C to the Pd nanoparticles. As a result, the concentrated energetic electrons in the Pd nanoparticles can facilitate the cleavage of C–I or C–Br bonds, which normally requires high-temperature thermal processes. We show that the present Pd/Si C photocatalyst is capable of catalyzing the transformation of a large variety of aryl halides to their corresponding boronate esters under visible light irradiation, with excellent yields.

关键词： Boronate esters Carbon-halogen activation Hierarchical SiC nanowires Pd nanoparticles Photocatalysis

WAVES GENERATED BY A 3D MOVING BODY IN A TWO LAYER FLUID OF FINITE DEPTH

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Journal of Hydrodynamics 2005年第1期17卷 92-101页

作者： ZHUWei YOUyun-xiang MIAOguo-ping ZHAOFeng ZHANGJun SchoolofNavalArchitecture OceanandCivilEngineeringShanghaiJiaotongUniversityShanghai200030China ChinaShipScientificResearchCenter Wuxi214082China

This paper is concerned with the waves generated by a 3 D body advancing beneath the free surface with constant speed in a two layer fluid of finite depth. By applying Green’s theorem, a layered integral equation system based on the Rankine source for the perturbed velocity potential generated by the moving body was derived with the potential flow theory. A four node isoparametric element method was used to treat with the solution of the layered integral equation system. The surface and interface waves generated by a moving ball were calculated numerically. The results were compared with the analytical results for a moving source with constant velocity.

关键词： internal waves two-layer fluid Rankine source wave-making wave pattern

Simultaneous laparoscopic excision for rectal carcinoma and synchronous hepatic metastasis

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Chinese Medical Journal 2011年第19期124卷 2990-2992页

作者： CHEN Kai-yun xiang guo-an WANG Han-ning XIAO Fang-lian Department of General Surgery the Second People＇s Hospital of Guangdong Province Guangzhou Guangdong 510317 China

Background Rectal carcinoma patients are often accompanied by hepatic metastasis. The aim of this study was to evaluate the therapeutic efficacy of simultaneous laparoscopic excision for rectal carcinoma with synchronous hepatic *** A total of 41 patients with rectal carcinoma and synchronous hepatic metastasis detected by CT scan were included in this study. Among them, 23 patients underwent laparoscopic surgery and 18 patients underwent traditional open surgery to simultaneously remove the rectal tumor and hepatic metastasis lesions. All patients received postoperative adjuvant chemotherapy. All the patients were followed up from 36 to 72 months （mean 45.3 months）.Results All the operations were performed successfully and no patient was turned to open surgery in laparoscopic group. The mean blood loss, the mean postoperative hospital stay, the mean blood transfusion and the mean intestinal functional recovery time showed a significant difference between the two groups （P〈0.05）. The 1-, 3- and 5-year survival rates were 82.6%, 43.5% and 8.6% in the laparoscopic group, without significant difference compared with the open group （77.8%, 38.9% and 0）（P〉0.05）.Conclusions Simultaneous laparoscopic excision for rectal carcinoma and synchronous hepatic metastasis is safe and effective with similar survival achieved by the traditional open abdominal surgery.

关键词： rectal tumor metastasis laparoscope hepatectomy

Pd@Ir-LOD multienzyme utilizing endogenous lactate consumption cooperates with photothermal for tumor therapy

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Nano Research 2024年第1期17卷 270-281页

作者： Zichen Ye yun Li Jingchao Li Xinyan Hu Jinyang Zheng Gongxin Zhang Sijin xiang Tianbao Zhu Zhide guo Xiaolan Chen State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials and Engineering Research Center for Nano-Preparation Technology of Fujian ProvinceCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China State Key Laboratory of Molecular Vaccinology and Molecular Diagnostics&Center for Molecular Imaging and Translational Medicine School of Public Health Xiamen UniversityXiamen 361102China The High Educational Key Laboratory for Biomedical Engineering&Key Laboratory of Fire Retardant Materials of Fujian Province Department of BiomaterialsCollege of MaterialsXiamen UniversityXiamen 361102China

Lactic acid(LA)plays a major role in the occurrence,development,and spread of *** by its high accumulation in tumor site,a novel lactate oxidase(LOD)conjugated two-dimensional Pd@Ir nanoplatform(Pd@Ir-LOD,PIL)was fabricated to combine cascade reaction with photothermal for tumor *** detail,the overexpressed LA in tumor microenvironment(TME)was a key factor to activate the PIL-based cascade reaction:(1)Plenty of H_(2)O_(2)could be generated from LA by the catalysis of LOD with O_(2);(2)potent·OH was produced from H_(2)O_(2)due to the peroxidase(POD)-like activity of PIL;(3)meantime,PIL’s catalase(CAT)-like activity could decompose part H_(2)O_(2)into O_(2)to achieve the purpose of LA cyclic ***,the reduced glutathione(GSH)scavenging capability of PIL might protect the produced reactive oxygen species(ROS)from being cleared to further improve the cascade therapeutic *** importantly,PIL had excellent photothermal conversion efficiency(37.35%)and manifested a surprising temperature rising effect in *** together,the decreasing LA concentration,accumulation of high-toxic ROS,the depletion of GSH together with the higher intra-tumoral temperature potently enhanced in vivo antitumor ***,a promising therapeutic tactic based on PIL integrating endogenous LA consumption,chemodynamic therapy(CDT),and photothermal therapy(PTT)has been put forward.

关键词： lactate oxidase chemodynamic therapy photothermal therapy cascade reaction tumor microenvironment

Precise determination of the pole position of the exotic Z_(c)(3900)

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Science China(Physics,Mechanics & Astronomy) 2024年第9期67卷 84-90页

作者： yun-Hua Chen Meng-Lin Du Feng-Kun guo School of Mathematics and Physics University of Science and Technology BeijingBeijing 100083China School of Physics University of Electronic Science and Technology of ChinaChengdu 611731China CAS Key Laboratory of Theoretical Physics Institute of Theoretical PhysicsChinese Academy of SciencesBeijing 100190China School of Physical Sciences University of Chinese Academy of SciencesBeijing 100049China Peng Huanwu Collaborative Center for Research and Education Beihang UniversityBeijing 100191China

We perform a unified description of the experimental data of the π^(+)π^(-)and J/ψπ^(±)invariant mass spectra for e^(+)e^(-)→J/ψπ^(+)π^(-)and the D^(0)D^(*-)mass spectrum for e^(+)e^(-)→D^(0)D^(*-)π^(+)at e^(+)e^(-)center-of-mass energies 4.23 and 4.26 *** analysis takes into account open-charm meson loops that contain triangle singularities,the J/ψπ-DD^(*)coupled-channel interaction respecting unitarity,and the strong ππ-KK final state interaction using dispersion *** analysis leads to a precise determination of the Z_(c)(3900)pole with the pole mass and width(3880.7±1.7_(stat)±22.4_(syst))MeV and(35.9±1.4_(stat)±15.3_(syst))MeV,respectively,and hints at that the DD^(*)molecular and non-molecular components are of similar importance in the Z_(c)(3900)formation.

关键词： exotic hadrons dispersion relations final state interaction triangle singularity

Effect of slag composition on kinetic behavior of deep deoxidation of 5 wt.% Si high-silicon austenitic stainless steel

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Journal of Iron and Steel Research International 2024年第8期31卷 1873-1885页

作者： Guan-xiong Dou Han-jie guo Jing guo Xue-cheng Peng Qing-yun Chen School of Metallurgical and Ecological Engineering University of Science and Technology Beijing(USTB)Beijing 100083China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials Beijing 100083China

Based on a thermodynamic study of 5 wt.%Si high-silicon austenitic stainless steel(SS-5Si)smelting using CaF_(2)-CaO-Al_(2)0_(3)-Mg-Si0_(2) slag to obtain a low oxygen content of less than 10×10^(-4) wt.%,a kinetic mass transfer model for deep deoxidation was established through laboratory studies,and the effects of slag components and temperature on deoxidation during the slag-steel reaction process of sS-5Si were systematically *** experimental data verified the accuracy of the model *** results showed that the final oxygen content in the steel at 1873 K was mainly controlled by the oxygen content derived from the activity of SiO_(2) regulated by the[Si]-[O]equilibrium reaction in the slag system;in particular,when the slag basicity R(R=w(CaO)/w(SiO2),where w(CaO)and w(SiO_(2))are the contents of CaO and SiO_(2) in the slag,respectively)is 3,the Al2O3 content in the slag needs to be less than 2.7%.The mass transfer rate equation for the kinetics of the deoxidation reaction revealed that the mass transfer of oxygen in the liquid metal is the rate-controlling step under different slag conditions at 1873 K,and the oxygen transfer coefficient ko.m increases with increasing the slag basicity from 4.0×10^(-6)m s^(-1)(R=1)to 4.3×10^(-5) m s^(-1)(R=3).ko.m values at R=2 and R=3 are almost the same,indicating that high slag basicity has little *** integral of the mass transfer rate equation for the deoxidation reaction of SS-5Si under different slag conditions is *** total oxygen content of the molten steel decreases with increasing basicity from an initial content of 22×10^(-4) to 3.2×10^(-4) wt.%(R=3),consistent with the change in ko.m with slag *** R=2,the slag-steel reaction takes 15 min to reach equilibrium(w[O]=5.5×10^(-4) wt.%),whereas at R=3,the slag-steel reaction takes 30 min to reach equilibrium(w[0]=3.2×10^(-4) wt.%).Considering the depth of deoxidation and reaction time of SS-5Si smelting,it is recommended the slag b

关键词： Slag-steel reaction Kinetics Rate-controlling step Deep deoxidation Transfer coefficient

Synergistic effect of gradient Zn content and multiscale particles on the mechanical properties of Al-Zn-Mg-Cu alloys with coupling distribution of coarse-fine grains

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International Journal of Minerals,Metallurgy and Materials 2024年第6期31卷 1392-1405页

作者： Liangliang Yuan Mingxing guo Yi Wang yun Wang Linzhong Zhuang Institute of Effectiveness Evaluation of Flying Vehicle Beijing 100085China State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology BeijingBeijing 100083China Beijing Laboratory of Metallic Materials and Processing for Modern Transportation University of Science and Technology BeijingBeijing 100083China

This study investigated the influence of graded Zn content on the evolution of precipitated and iron-rich phases and grain struc-ture of the alloys,designed and developed the Al–8.0Zn–1.5Mg–1.5Cu–0.2Fe(wt%)alloy with high strength and *** the increase of Zn content,forming the coupling distribution of multiscale precipitates and iron-rich phases with a reasonable matching ratio and dispersion distribution characteristics is *** phenomenon induces the formation of cell-like structures with alternate distribu-tion of coarse and fine grains,and the average plasticity–strain ratio(characterizing the formability)of the pre-aged alloy with a high strength is up to *** reveal the evolution and influence mechanisms of multiscale second-phase particles and the corresponding high formability mechanism of the *** developed coupling control process exhibits considerable potential,revealing remarkable improvements in the room temperature formability of high-strength Al–Zn–Mg–Cu alloys.

关键词： Al–Zn–Mg–Cu alloy iron-rich phase high formability microstructure mechanisms

An Intelligent Framework for Resilience Recovery of FANETs with Spatio-Temporal Aggregation and Multi-Head Attention Mechanism

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Computers, Materials & Continua 2024年第5期79卷 2375-2398页

作者： Zhijun guo yun Sun YingWang Chaoqi Fu Jilong Zhong Air Traffic Control and Navigation College Air Force Engineering UniversityXi’an710000China Institute of Systems Engineering Academy of Military ScienceBeijing100101China Equipment Management and UAV Engineering College Air Force Engineering UniversityXi’an710038China Defense Innovation Institute Academy of Military ScienceBeijing100071China

Due to the time-varying topology and possible disturbances in a conflict environment,it is still challenging to maintain the mission performance of flying Ad hoc networks(FANET),which limits the application of Unmanned Aerial Vehicle(UAV)swarms in harsh *** paper proposes an intelligent framework to quickly recover the cooperative coveragemission by aggregating the historical spatio-temporal network with the attention *** mission resilience metric is introduced in conjunction with connectivity and coverage status information to simplify the optimization model.A spatio-temporal node pooling method is proposed to ensure all node location features can be updated after destruction by capturing the temporal network *** with the corresponding Laplacian matrix as the hyperparameter,a recovery algorithm based on the multi-head attention graph network is designed to achieve rapid *** results showed that the proposed framework can facilitate rapid recovery of the connectivity and coverage more effectively compared to the existing *** results demonstrate that the average connectivity and coverage results is improved by 17.92%and 16.96%,respectively compared with the state-of-the-art ***,by the ablation study,the contributions of each different improvement are *** proposed model can be used to support resilient network design for real-time mission execution.

关键词： Resilience cooperative mission FANET spatio-temporal node pooling multi-head attention graph network