检索结果-南通市图书馆

Lifetime-tunable circularly polarized luminescent system based on triplet-to-singlet Förster resonance energy transfer

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第9期67卷 2918-2922页

作者： Zhenyi He Zizhao Huang xiang ma Key Laboratory for Advanced materials and Feringa Nobel Prize Scientist Joint Research Center Institute of Fine ChemicalsSchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

Circularly polarized luminescence(CPL)materials have received widespread attention due to their remarkable performance and broad ***,current CPL material research primarily focuses on tunable color,intensity,and *** CPL with adjustable lifetime remains a significant ***,a series of CPL polymeric materials with tunable lifetime were obtained by employing phosphorescent terephthalic acid and chiral organic small molecule R/S-BNAF(a luminescent binaphthol derivative)to copolymerize with acrylamide in different *** was verified that this performance results from the different energy transfer efficiency between luminophores with varying ratios of the monomers for *** strategy to realize CPL with tunable lifetime by modulating the energy transfer efficiency will provide a new perspective to broaden the applications of CPL materials.

关键词： circularly polarized luminescence tunable lifetime Förster resonance energy transfer room temperature phosphorescence

Multicolor Circularly Polarized Luminescence of a Single-Component System Revealing Multiple Information Encryption

在线全文

学校读者我要写书评

暂无评论

CCS Chemistry 2024年第2期6卷 518-527页

作者： Ying Hu Zizhao Huang Itamar Willner xiang ma Key Laboratory for Advanced materials and Feringa Nobel Prize Scientist Joint Research Center Frontiers Science Center for Materiobiology and Dynamic ChemistrySchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237 Institute of Chemistry The Center for Nanoscience and NanotechnologyThe Hebrew University of JerusalemJerusalem 91904

Metal-free materials with multicolor tunable circularly polarized luminescence(CPL)are attractive because of their potential applications in information storage and ***,we designed two enantiomers composed of chiral dialkyl glutamides and achiral vibration-induced emission(VIE)moiety,which can switch on CPL after a simple gelation *** is noteworthy that the CPL colors vary in different solvents,and this is attributed to various self-assembly-induced microstructures,in which the VIE moiety is restrained to different ***,a multidimensional code system composed of a quick response code,a ultraviolet(UV)light-activated color code,and a CPL information figure was *** our satisfaction,the system possesses multiple information-storage *** orthogonal anticounterfeiting and CPLenhanced encryption functions also improve the system information encryption *** brief,this study provides a practical example of CPL applied to information security and an effective approach to obtain a single-component color-tunable CPL material with multiple information storage and encryption functions as well.

关键词： circularly polarized luminescence information storage and encryption multicolor tunable single component vibration-induced emission

Data driven reduced modeling for fluidized bed with immersed tubes based on PCA and Bi-LSTM neural networksAuthor links open overlay panel

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Particuology 2024年第8期91卷 1-18页

作者： Jiabin Fang Wenkai Cu Huang Liu Huixin Zhang Hanqing Liu Jinjia Wei xiang ma Nan Zheng School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'anShaanxi 710049China

The fast and accurate reduced-order modeling of fluidized beds is a challenging task in the field of fluid dynamics,owing to their high dimensionality and nonlinear dynamic *** this study,a nonintrusive reduced order modeling method,the reduced order model based on principal component analysis and bidirectional long short-term memory networks(PBLSTM ROM),was developed to capture complex spatio-temporal dynamics of fluidized *** combining principal component analysis and Bidirectional long-short-term memory networks,the PBLSTM ROM effectively extracted dynamic evolution information without any prior knowledge of governing equations,enabling reduced-order modeling of unsteady flow *** PBLSTM ROM was validated using the solid volume fraction and gas velocity flow fields of a fluidized bed with immersed tubes,showing superior performance over both the PLSTM and PANN ROMs in accurately capturing temporal changes in the fluidization fields,especially in the region near immersed tubes where severe fluctuations ***,the PBLSTM ROM improved the simulation speed by five orders of magnitude compared to traditional computational fluid dynamics *** findings suggest that the PBLSTM ROM presents a promising approach for analyzing the complex fluid flows in engineering practice.

关键词： Reduced order modeling Fluidized bed Deep learning Bi-LSTM

Larger in-plane upper critical field and superconducting diode effect observed in topological superconductor candidate InNbS_(2)nanoribbons

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano Research 2024年第7期17卷 6686-6694页

作者： Bo Zheng Changlong Wang Xukun Feng Xiaozhen Sun Shasha Wang Dawei Qiu xiang ma Ruimin Li Guanglei Cheng Lan Wang Yalin Lu Peng Li Shengyuan A.Yang Bin xiang Department of materials Science and Engineering CAS Key Lab of Materials for Energy ConversionAnhui Laboratory of Advanced Photon Science and TechnologyUniversity of Science and Technology of ChinaHefei 230026China Research Laboratory for Quantum materials Singapore University of Technology and DesignSingapore 487372Singapore School of Microelectronics University of Science and Technology of ChinaHefei 230052China CAS Key Laboratory of Microscale magnetic Resonance and School of Physical Sciences University of Science and Technology of ChinaHefei 230026China Lab of Low Dimensional magnetism and Spintronic Devices School of PhysicsHefei University of TechnologyHefei 230009China Research Laboratory for Quantum materials IAPMEUniversity of MacaoMacaoChina

Recently,the coexistence of topology and superconductivity has garnered considerable ***,the dimensionality of these materials is crucial for the realization of topological quantum ***,the naturally grown materials,especially with one-dimensional feature that exhibits the coexistence of topology and superconductivity,still face challenges in terms of experimental realization and scalability,which hinders the fundamental research development and the potential to revolutionize quantum ***,we report the first experimental synthesis of quasi-one-dimensional InNbS_(2)nanoribbons that exhibit the coexistence of topological order and superconductivity via a chemical vapor transport ***,the inplane upper critical field of InNbS_(2)nanoribbons exceeds the Pauli paramagnetic limit by more than 2.2 times,which can be attributed to the enhanced spin-orbit coupling and the weakened interlayer interaction between the NbS_(2)layers induced by the insertion of In atoms,making InNbS_(2)exhibit spin-momentum locking similar to that of monolayer NbS_(2).Moreover,for the first time,we report the superconducting diode effect in a quasi-one-dimensional superconductor system without any inherent geometric *** measured maximum efficiency is manifested as 14%,observed atμ0H≈±60 mT,and we propose that the superconducting diode effect can potentially be attributed to the presence of the nontrivial topological *** work provides a platform for studying exotic phenomena in condensed matter physics and potential applications in quantum computing and quantum information processing.

关键词： topological order superconductivity nanoribbon superconducting anisotropy superconducting diode

Effect of low-degree astigmatism on the objective visual quality

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

International Journal of Ophthalmology(English edition) 2024年第6期17卷 1086-1093页

作者： Ling-Ying Ye Shu-Feng Li Jing-Jing Zuo Jin Li Hui-xiang ma National Clinical Research Center for Ocular Diseases Eye HospitalWenzhou Medical UniversityWenzhou 325027Zhejiang ProvinceChina

AIM:To evaluate the effect of low-degree astigmatism on objective visual quality through the Optical Quality Analysis System(OQAS).METHODS:This study enrolled 46 participants(aged 23 to 30y,90 eyes)with normal or corrected-to-normal *** cylindrical lenses(0,0.5,0.75,1.0,and 1.25 D)were placed at the axial direction(180°,45°,90°,and 135°)in front of the eyes with the best correction to form 16 types of regular low-degree *** was used to detect the objective visual quality,recorded as the objective scattering index(OSI),OQAS values at contrasts of 100%,20%,and 9%predictive visual acuity(OV100%,OV20%,and OV9%),modulation transfer function cut-off(MTFcut-off)and Strehl ratio(SR).The mixed effect linear model was used to compare objective visual quality differences between groups and examine associations between astigmatic magnitude and objective visual quality ***:Apparent negative relationships between the magnitude of low astigmatism and objective visual quality were *** increase of OSI per degree of astigmatism at 180°,45°,90°,and 135°axis were 0.38(95%CI:0.35,0.42),0.50(95%CI:0.46,0.53),0.49(95%CI:0.45,0.54)and 0.37(95%CI:0.34,0.41),*** decrease of MTFcut-off per degree of astigmatism at 180°,45°,90°,and 135°axis were-10.30(95%CI:-11.43,-9.16),-12.73(95%CI:-13.62,-11.86),-12.75(95%CI:-13.79,-11.70),and-9.97(95%CI:-10.92,-9.03),*** the same astigmatism degree,OSI at 45°and 90°axis were higher than that at 0°and 135°axis,while MTFcut-off were ***:Low astigmatism of only 0.50 D can significantly reduce the objective visual quality.

关键词： low-degree astigmatism objective visual quality Optical Quality Analysis System

MnS–MnO heterogeneous nanocube@N,S-doped carbon as a highly efficient bifunctional water splitting electrocatalyst

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第5期43卷 1977-1988页

作者： Xue-Qian Wang xiang-Ying ma Wang-Zhi Wu Hui-Bing He Nan-Nan Wang Ren-Ji Zheng Shao-Jian ma Yan-Qiu Zhu Pei-Kang Shen Jin-Liang Zhu School of Resources Environment and MaterialsState Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite StructuresCollege of Chemistry and Chemical EngineeringGuangxi UniversityNanning 530004China School of Chemistry and Chemical Engineering Guangxi MinzuUniversity Nanning 530006 China School of Minerals Processing and Bioengineering Central South UniversityChangsha 410083China

A stable,efficient,and economical bifunctional electrolytic catalyst would be incredibly beneficial for the development of hydrogen production by electrocatalytic water *** this study,we synthesized a novel MnS–MnO heterogeneous nanocube@N,S-doped carbon(MnS–MnO@NSC).MnS–MnO nanocubes possess rich heterogeneous interfaces and plentiful catalytic active sites to promote electrochemical reactions,while the N,S-doped carbon shell possesses excellent conductivity and catalytic properties and protects the ***–MnO@NSC exhibited excellent electrochemical properties as an effective bifunctional electrocatalyst for the hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in KOH *** the HER,the overpotential was as low as 124 mV at a current density of 10 ma·cm^(-2)while in the OER,it was only 340 mV at 100 ma·cm^(-2)under the same *** addition,a MnS–MnO@NSC||MnS–MnO@NSC electrolyzer exhibited almost comparable activity and higher steadiness than those exhibited by the state-of-the-art Pt/C||RuO_(2)/C system for full water splitting in KOH solution.

关键词： manganese sulfide manganese oxide Doped carbon Heterogeneous nanocube Water splitting

Diversification of interfaces triggered hydrogen storage properties enhancement

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第5期43卷 2324-2330页

作者： Jia-Xin Zhang Xin Ding Rui-Run Chen xiang-Feng ma Wen-Chao Cao Yong Zhang Jing-Jie Guo National Key Laboratory for Precision Hot Processing of Metals Harbin Institute of TechnologyHarbin 150001China

Dual effects of grain refinement and alloying are achieved and the mechanism of"diverse interfaces reinforcement"for hydrogen storage Mg alloys is first *** interface reinforced Mg-Y-Zn-Al alloy for hydrogen storage is *** work figures out that the adventurous Al-rich phase exhibits an ordered face-centered cubic(FCC)structure with composition of(31±2)at%Y-(28±1)at%Zn-(41±3)at%Al,i.e.,Y_(3)Zn_(3)Al_(4),and an incoherent interface between Y3Zn3Al4phase and Mg substrate is observed.

关键词： hydrogen alloying alloy

Surface engineering of Li-and Mn-rich layered oxides for superior Li-ion battery

在线全文

学校读者我要写书评

暂无评论

Tungsten 2024年第1期6卷 259-268页

作者： Lu-xiang ma Tian-Dong Chen Chun-Xi Hai Sheng-De Dong Xin He Qi Xu Hang Feng AXin Ji-Tao Chen Yuan Zhou College of materials and Chemistry and Chemical Engineering Chengdu University of TechnologyChendu 610000China Qinghai Building and materials Research Co. LtdXining 810000China Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China

The Li-and Mn-rich layered oxides(R-LNCM)are considered as promising cathode materials for high-energy density lithium-ion batteries(LIBs).However,the interface side reaction aggravates the voltage and capacity fading between cathode material and electrolyte at high voltage,which severely hinders the practical application of LIB ***,lithium polyacrylate(LiPAA)as the binder and coating agent is applied to suppress the voltage and capacity fading of R-LNCM *** flexible LiPAA layers with high elasticity are capable of impeding cathode cracks on the particle surface via mechanical stress ***,superior voltage and capacity fading suppression on R-LNCM electrode is finally *** a result,LiPAA-R-LNCM cathode exhibits a remarkable specific capacity of 186 ma·h·g^(-1)with~73%retention at 1℃after ***,the corresponding average discharge potential is maintained to~3.1 V with only~0.4 V falling.

关键词： LiPAA interphase layer Interface side reaction Cathode cracks Capacity and voltage fading suppression Liand Mn-rich cathode

mainchain conformation ordering self-assembly tailored room temperature phosphorescence emission

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2024年

作者： Yuzhu Li Yumeng Gao Feng Tian Yu Wang Yuan Yao Shaoliang Lin xiang ma Binbin Xu Shanghai Key Laboratory of Advanced Polymeric materials Key Laboratory for Ultrafine Materials of Ministry of Education School of Materials Science and Engineering East China University of Science and Technology Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences Key Laboratory for Advance materials and Feringa Noble Prize Scientist Joint Research Centre Frontiers Science for Materiobiology and Dynamic Chemistry School of Chemistry and Molecular Engineering East China University of Science & Technology

Developing organic room-temperature phosphorescence(RTP) materials with a wide range of tunable-emission is significant in expanding the applications of RTP materials. Herein, we rationally designed amphiphilic alternating copolymers poly(1,2-bis(4-alkoxyphenyl)ethane-1,2-dione-alt-(ethylene glycol)x)(P(Bz-alt-EGx)) that combined the advantage of alternating benzil and EGxskeleton, and tunable mainchain conformation. Through a mainchain conformation ordering assembly(COA) process, P(Bz-alt-EGx) self-assembled into well-defined platelets, and such assemblies emitted blue RTP at ca. 425 nm due to the ordered folded-chain conformation and confined microenvironment. In contrast, traditional self-assembly(TA) of P(Bz-alt-EGx) obtained less ordered aggregates, such as asymmetric worms, vesicles, and rod-like micelles. The resultant less ordered aggregates exhibited yellow-green RTP at ca. 550 nm. The wide-tuning RTP emission in solution(between blue and yellow-green, over125 nm) is realized using the P(Bz-alt-EGx) alternating copolymers under the treatment of different self-assembly *** study uncovers a new strategy to tailor the RTP emission through different self-assembly pathways and holds great promise for the fabrication of advanced optical materials.

关键词：