检索结果-南通市图书馆

Crystalline-amorphous M@MN_x(M=Co,Fe,Ni)encapsulated in nitrogen-doped carbon for enhanced efficient and durable hydrogen evolution reaction

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第4期43卷 1547-1556页

作者： Yang Yang Xiao-Chuan Duan Shao-Hui Guo xian-ming zhang College of Materials Science and Engineering College of ChemistryKey Laboratory of Interface Science and Engineering in Advanced MaterialsTaiyuan University of TechnologyYuci030600China

Developing earth-abundant electrocatalysts for hydrogen evolution reaction(HER)is important for the sustainable energy ***,efficient and stable heterocatalysts consisting of crystalline-amorphous M@MN_(x)(M=Co,Fe,Ni)encapsulated in N-doped carbon layers supported with N-doped graphene sheets(denoted as M@MN_(x)@NC-NG)are synthesized by facile hydrothermal reaction and nitridation *** the nitriding process,metal ions in M(tzbc)_2(H_(2)O)_4(tzbc=4-(1H-1,2,4-triazol-1-yl)benzoic acid)complexes are reduced to crystalline M cores,accompanied by the formation of amorphous MN_(x)shells;the tzbc ligands are insitu carbonized to form outermost N-doped carbon(NC)layers that connect with inner MN_(x)via M-N-C motifs inherited from the complex precursors and inhibit the transition of MN_(x)from amorphous to crystalline *** Co@CoN_(x)@NC-NG catalyst exhibits excellent HER activity with small overpotentials of 45 and 64 mV at a cathode current density of 10 mA·cm^(-2)and low Tafel slopes of 40 and 85 mV·dec^(-1)in 0.5 mol·L^(-1)H_(2)SO_4 and1.0 mol·L^(-1)KOH electrolytes,*** Co@CoN_(x)@NC-NG retains 97%of the initial overpotential after 100,000 s in both acidic and alkaline *** outstanding HER performance originates from the crystalline-amorphous Co@CoN_(x)that redistributes electrons around the heterointerfaces,facilitating the conversion process of H^(+)/H_(2)O to hydrogen and thereby promoting HER *** outermost NC layers serve as the armor of Co@CoN_(x),and graphene nanosheets act as carriers of egg-like Co@CoN_(x)@NC and conduction paths for electron shuttles,ensuring stable and continuous electrocatalytic hydrogen production.

关键词： Hydrogen evolution reaction Electrocatalysts Iron group metals Heterojunction Crystalline-amorphous structure

Accumulated-state-error-based event-triggered sampling scheme and its application to H∞ control of sampled-data systems

在线全文

学校读者我要写书评

暂无评论

Science China(Information Sciences) 2024年第6期67卷 328-341页

作者： xian-ming zhang Qing-Long HAN Bao-Lin zhang Xiaohua GE Dawei zhang School of Science Computingand Engineering TechnologiesSwinburne University of Technology College of Automation and Electronic Engineering Qingdao University of Science & Technology School of Mathematics Shandong University

This paper is concerned with event-triggered H∞control of sampled-data systems. Its novelties lie in three aspects:（i） A novel accumulated-state-error-based event-triggered scheme is introduced by comparing the integral of the state error from tk to t with the system state sampled at tk. This condition works well due to the fact that the so-called Zeno behaviour does not occur.（ii） A novel Lyapunov functional is constructed to establish a criterion to ensure some certain H∞performance of the closed-loop system. This Lyapunov functional is dependent on the integral of the state error involved in the event-triggered scheme.（iii） Under the event-triggered sampling scheme, suitable state-feedback controllers can be designed rather than be given a priori. Moreover, a self-triggered implementation of the proposed event-triggered sampling scheme is presented as well. Finally, a batch reactor model and an inverted pendulum system are given to demonstrate the effectiveness of the proposed method.

关键词： event-triggered sampling self-triggered implementation $H_\infty$ control looped-functional

同方期刊数据库

Al-containing Ge-rich IWV:rapid synthesis via interzeolite transformation and application in Baeyer-Villiger oxidation

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2024年第7期67卷 2282-2291页

作者： Meichen Jiao Chunmin Jia Hao Xu Peng Wu xian-ming zhang School of Chemistry&Material Science Shanxi Normal UniversityTaiyuan 030006China Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai 200062China School of Chemistry Taiyuan University of TechnologyTaiyuan 030024China

Ge-containing Lewis acidic zeolites are typically synthesized using a conventional hydrothermal strategy from amorphous silica sources,through a long time-and energy-consuming approach limiting their wide *** study reports a rapid synthesis strategy for a series of IWV aluminogermanosilicate zeolites(T-x-Al)with a wide range of Si/Ge molar ratios(5–15)by interzeolite transformation of dealuminated FAU(DA-FAU).Notably,Ge-rich IWV could be obtained with crystallization time as short as one day by the equimolecular Si/Ge ratio *** effect of synthetic parameters was investigated and the obtained T-x-Al samples were characterized by XRD,SEM,EDS,ICP,^(29)Si and^(27)Al MAS NMR,FTIR,and N_(2)physisorption *** with a previously reported IWV germanosilicate(H-3),T-x-Al displayed a better catalytic activity in Baeyer-Villiger(BV)oxidation,attributed to the presence of the active framework Ge sites with the assistance of the extraframework Al *** cyclic catalysis tests revealed that the presence of framework Al species contributed to the stability of the ***,T-x-Al,with 14-membered ring(MR)supercages,outperformed the typical 12-MR Sn-beta catalyst in the BV oxidation of large ketone-like 2-admantanone,indicating a promising potential application in the macromolecular catalytic process.

关键词： Ge-rich IWV interzeolite transformation Al assistance Baeyer-Villiger oxidation

Immobilizing Triphenylamine with Photoredox Inert Sr^(2+)Forming Sr-MOF with Controlled Electron Migration for Photocatalytic Oxidation of Thiols to Disulfides

在线全文

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2024年第10期42卷 1093-1099页

作者： Ying-Xia Wang Fang Zheng Dong-Xia Song Bao-Yue Niu Lu-Qian Deng xian-ming zhang Key Laboratory of Magnetic Molecules and Magnetic Information Materials(Ministry of Education) Schoolof Chemistry and Materials ScienceShanxi Normal UniversityTaiyuanShanxi 030006China Key Laboratory of Interface Science and Engineering in Advanced Material(Ministry of Education) College of ChemistryTaiyuan University of TechnologyTaiyuanShanxi 030024China

The photocatalytic oxidative coupling of thiols is one of the most popular methods to synthesize the *** and its derivatives(TPAs)are promising for the above reaction,but suffer from the easy polymerization and difficult *** overcome these obstacles while controlling the photogenerated electrons transfer directly to target substrates,herein,we constructed one TPA-based metal-organic framework(MOF),(Me_(2)NH_(2))[Sr(TCBPA)]·DMA·3H_(2)O(1),by direct self-assembly of tris(4′-carboxybiphenyl)amine(H_(3)TCBPA)and photoredox inert strontium ion(Sr^(2+)).DFT calculations revealed that the valence band maximum(VBM)and the conduction band minimum(CBM)are mainly located on TCBPA^(3-),successfully inhibiting the undesirable electron migration to metal *** results indicated that 1 displays superior performance than homogeneous H_(3)TCBPA,which may result from the abundant π…π and C—H…π interactions between the well-arranged TCBPA^(3-)and the build-in electric field between the anionic framework and the Me_(2)NH^(2+).This work highlights that immobilizing TPAs into MOFs is one promising approach to designing heterogeneous photocatalysts for the synthesis of disulfides by oxidative coupling of thiols.

关键词： Triphenylamine Metal-organic frameworks Strontium Photooxidation Thiols Disulfides

Metal-organic nanosheet assembly ions sieving membrane for precise lithium ion and anion/solvent separation toward robust lithium metal battery

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2024年

作者： Jian-Qiang Shen Tian-Tian Zhao Ying-Li Song Ling-Juan zhang Ya-Nan Gao Xiao-Nan Cui Peng Zhao xian-ming zhang Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education School of Chemistry & Material ScienceShanxi Normal University College of Chemistry and Chemical Engineering Taiyuan University of Technology

Metal-organic nanosheets （MONs） as a novel material with tunable pore structures and low mass transfer resistance, have emerged as molecular sieves for the separation of gases and liquids. In theory, they can also serve as ion sieves for lithium metal batteries （LMBs）, realizing the high-energy and dendritic free LMBs. However, there are rarely relevant reports, because it is difficult to simultaneously balance efficient ion sieving ability, high ion passing rate and high electrochemical stability. Here, we synthesized a stable ultrathin MON [Zn2（Bim）4]([Zn2（Bim）4] Nanosheet, HBim=benzimidazolate), which can achieve both efficient lithium ion sieving ability, high lithium ion passing rate and high electrochemical stability at the same time. The separator assembled by this MON exhibits high Li+transfer number of 0.81 due to the accurate lithium ion and anion/solvent separation. The battery containing such separator shows high lithium ionic conductivity of 0.74 mS cm-1and low activation energy of 0.099 eV, which can be attributed to the nanometer level thickness and the ion sieving effect. What is more, we realized the application of MONs-based ion sieves in LMBs with intercalation cathodes for the first time. And the LiFePO4|Li battery with as-assembled separator demonstrates improved Coulombic efficiency （> 99%） and significantly extended cycling life （>1600 cycles） with 80%capacity retention.

关键词： lithium sieving membrane metal-organic nanosheets lithium metal battery lithium ion and anion separation lithiumion and solvent separation

Resilient and Safe Platooning Control of Connected Automated Vehicles Against Intermittent Denial-of-Service Attacks

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2023年第5期10卷 1234-1251页

作者： Xiaohua Ge Qing-Long Han Qing Wu xian-ming zhang the School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyMelbourne VIC 3122Australia the School of Engineering and Technology Central Queensland UniversityRockhampton QLD 4701Australia

Connected automated vehicles(CAVs)serve as a promising enabler for future intelligent transportation systems because of their capabilities in improving traffic efficiency and driving safety,and reducing fuel consumption and vehicle emissions.A fundamental issue in CAVs is platooning control that empowers a convoy of CAVs to be cooperatively maneuvered with desired longitudinal spacings and identical velocities on *** paper addresses the issue of resilient and safe platooning control of CAVs subject to intermittent denial-of-service(DoS)attacks that disrupt vehicle-to-vehicle ***,a heterogeneous and uncertain vehicle longitudinal dynamic model is presented to accommodate a variety of uncertainties,including diverse vehicle masses and engine inertial delays,unknown and nonlinear resistance forces,and a dynamic platoon ***,a resilient and safe distributed longitudinal platooning control law is constructed with an aim to preserve simultaneous individual vehicle stability,attack resilience,platoon safety and ***,a numerically efficient offline design algorithm for determining the desired platoon control law is developed,under which the platoon resilience against DoS attacks can be maximized but the anticipated stability,safety and scalability requirements remain ***,extensive numerical experiments are provided to substantiate the efficacy of the proposed platooning method.

关键词： Connected automated vehicles(CAVs) cooperative adaptive cruise control denial-of-service(DoS)attacks resilient control vehicle platooning vehicle-to-vehicle communication

A Scalable Adaptive Approach to Multi-Vehicle Formation Control with Obstacle Avoidance

在线全文

学校读者我要写书评

暂无评论

IEEE/CAA Journal of Automatica Sinica 2022年第6期9卷 990-1004页

作者： Xiaohua Ge Qing-Long Han Jun Wang xian-ming zhang IEEE School of Science Computing and Engineering TechnologiesSwinburne University of TechnologyMelbourneVIC 3122Australia Department of Computer Science and School of Data Science City University of Hong KongChina

This paper deals with the problem of distributed formation tracking control and obstacle avoidance of multivehicle systems(MVSs)in complex obstacle-laden *** MVS under consideration consists of a leader vehicle with an unknown control input and a group of follower vehicles,connected via a directed interaction topology,subject to simultaneous unknown heterogeneous nonlinearities and external *** central aim is to achieve effective and collisionfree formation tracking control for the nonlinear and uncertain MVS with obstacles encountered in formation maneuvering,while not demanding global information of the interaction *** this goal,a radial basis function neural network is used to model the unknown nonlinearity of vehicle dynamics in each vehicle and repulsive potentials are employed for obstacle ***,a scalable distributed adaptive formation tracking control protocol with a built-in obstacle avoidance mechanism is *** is proved that,with the proposed protocol,the resulting formation tracking errors are uniformly ultimately bounded and obstacle collision avoidance is *** simulation results are elaborated to substantiate the effectiveness and the promising collision avoidance performance of the proposed scalable adaptive formation control approach.

关键词： Adaptive control collision avoidance distributed formation control multi-vehicle systems neural networks obstacle avoidance repulsive potential

Two-in-one tecton strategy to construct single crystalline hydrogen-bonded organic framework with high proton conductivity above 100℃

在线全文

学校读者我要写书评

暂无评论

中国科学:化学英文版 2023年第9期66卷 2563-2568页

作者： Xiao-Lu Wang Linfeng Liang Shuai Dou xian-ming zhang Institute of Crystalline Materials Shanxi UniversityTaiyuan 030006China Institute of Urban Environment Chinese Academy of SciencesXiamen 361021China College of Chemistry Taiyuan University of TechnologyTaiyuan 030024China

By tactically integrating two different kinds of proton donors and acceptors into one supramolecular tecton, a new crystalline hydrogen-bonded organic framework(HOF-SXU-1) has been developed. HOF-SXU-1 features a remarkable proton conductivity as high as 6.32 mS cm^(-1) and an extremely low activation energy of 0.16 eV at 160℃ under anhydrous N_(2) *** contrast, under identical conditions, the organic precursors of HOF-SXU-1 only exhibit negligible proton conduction performance, demonstrating that the formation of HOF is crucial for excellent proton conduction performance.

关键词： two-in-one strategy hydrogen-bonded organic framework proton conduction solid state electrolyte

Synergistic effect of Ni^(Ⅱ)and Co/Fe^(Ⅲ)in doped mixed-valence phosphonate for enhancing electrocatalytic oxygen evolution

在线全文

学校读者我要写书评

暂无评论

Green Energy & Environment 2022年第3期7卷 432-439页

作者： Juan-Juan Hou Jian-Tao Yuan Wei zhang Ying-Xia Wang xian-ming zhang Key Laboratory of Magnetic Molecules and Magnetic Information Materials(Ministry of Education) School of Chemistry and Material ScienceShanxi Normal UniversityLinfen041004China

Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor,but only few of pristine metal organophosphonate are directly used for oxygen evolution reaction(OER)***,a mixedvalence iron phosphonate(Fe_(3)-ppat)has been constructed and applied to OER catalysis considered the potential active sites in pillars Fe^(Ⅱ)(-H_(2)O)_(4)(COO)_(2)and inorganic layers Fe^(Ⅲ)(μ_(2)–OH)PO_(3).Specifically,isostructural trimetallic framework Fe_(1.7)Co_(0.3)Ni_(1.0)-ppat possesses a minimum overpotential(291 mV),small Tafel slope(91.65 mV dec^(-1)),and high stability up to 83 *** enhanced catalytic performance could be mainly ascribed to the synergistic effect of Ni^(Ⅱ)equivalent occupancy in pillars and Co/Fe^(Ⅲ)in layers.

关键词： phosphonate stability organo