检索结果-南通市图书馆

Constructing a 700 Wh kg^(-1)-level rechargeable lithium-sulfur pouch cell

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2023年第1期76卷 181-186,I0005页

作者： Qian Cheng Zi-xian Chen xi-yao li li-Peng Hou Chen-xi Bi Xue-Qiang Zhang Jia-Qi Huang Bo-Quan li School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

lithium–sulfur(li–S)batteries are considered as highly promising energy storage devices because of their ultrahigh theoretical energy density of 2600 Wh kg^(-1).The highest practical energy density of li–S batteries reported at pouch cell level has exceeded 500 Wh kg^(-1),which significantly surpasses that of lithium-ion ***,a 700 Wh kg^(-1)-level li–S pouch cell is successfully *** pouch cell is designed at 6 Ah level with high-sulfur-loading cathodes of 7.4 mgScm^(-2),limited anode excess(50μm in thickness),and lean electrolyte(electrolyte to sulfur ratio of 1.7 gelectrolyteg^(-1)S).Accordingly,an ultrahigh specific capacity of 1563 m A h g^(-1)is achieved with the addition of a redox comediator to afford a practical energy density of 695 Wh kg^(-1)based on the total mass of all *** pouch cell can operate stably for three cycles and then failed due to rapidly increased polarization at the second discharge *** to failure analysis,electrolyte exhaustion is suggested as the key limiting *** work achieves a significant breakthrough in constructing high-energy-density li–S batteries and propels the development of li–S batteries toward practical working conditions.

关键词： lithium–sulfur batteries Pouch cell High energy density lithium polysulfides

A post-modification strategy to precisely construct dual-atom sites for oxygen reduction electrocatalysis

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第3期90卷 511-517,I0012页

作者： Juan Wang xinyan liu Chang-xin Zhao Yun-Wei Song Jia-Ning liu xi-yao li Chen-xi Bi xin Wan Jianglan Shui Hong-Jie Peng Bo-Quan li Jia-Qi Huang School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Materials Science and Engineering Beihang UniversityBeijing 100191China

Dual-atom catalysts(DACs) afford promising potential for oxygen reduction electrocatalysis due to their high atomic efficiency and high intrinsic ***,precise construction of dual-atom sites remains a *** this work,a post-modification strategy is proposed to precisely fabricate DACs for oxygen reduction ***,a secondary metal precursor is introduced to the primary single-atom sites to introduce direct metal-metal interaction,which ensures the formation of desired atom pair structure during the subsequent pyrolysis process and allows for successful construction of *** as-prepared FeCo-NC DAC exhibits superior oxygen reduction electrocatalytic activity with a half-wave potential of 0,91 V *** hydrogen ***-air batteries equipped with the FeCo-NC DAC demonstrate higher peak power density than those with the Pt/C *** importantly,this post-modification strategy is demonstrated universal to achieve a variety of dual-atom *** work presents an effective synthesis methodology for precise construction of catalytic materials and propels their applications in energy-related devices.

关键词： Dual-atom catalysts Electrocatalysis Oxygen reduction reaction Post-modification Zinc–air batteries

Boosting sulfur redox kinetics by a pentacenetetrone redox mediator for high-energy-density lithium-sulfur batteries

在线全文

学校读者我要写书评

暂无评论

Nano Research 2023年第6期16卷 8253-8259页

作者： Yan-Qi Peng Meng Zhao Zi-xian Chen Qian Cheng Yiran liu xi-yao li Yun-Wei Song Bo-Quan li Jia-Qi Huang School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

lithium-sulfur(li-S)battery is considered as a promising energy storage system due to its ultrahigh theoretical energy density of 2,600 Wh·kg^(−1).Redox mediation strategies have been proposed to promote the sluggish sulfur redox ***,the applicability of redox mediators in practical high-energy-density li-S batteries has seldomly been *** this work,5,7,12,14-pentacenetetrone(PT)is proposed as an effective redox mediator to promote the sulfur redox kinetics under practical working conditions.A high initial specific discharge capacity of 993 mAh·g^(−1) is achieved at 0.1 C with high-sulfur-loading cathodes of 4.0 mgS·cm^(−2)and low electrolyte/sulfur(E/S)ratio of 5μL·mg_(S)^(−1).More importantly,practical li-S pouch cells with the PT mediator realize an actual initial energy density of 344 Wh·kg^(−1)and cycle stably for 20 cycles wih a high capacity retention of 88%.This work proposes an effective redox mediator and further verifies the redox mediation strategy for practical high-energydensity li-S batteries.

关键词： lithium-sulfur batteries lithium polysulfides redox mediation sulfur redox kinetics pouch cells

A three-way electrolyte with ternary solvents for high-energy-density and long-cycling lithium-sulfur pouch cells

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

SusMat 2024年第2期4卷 1-12页

作者： Zheng li Legeng Yu Chen-xi Bi xi-yao li JinMa xiang Chen Xue-Qiang Zhang Aibing Chen Haoting Chen Zuoru Zhang li-Zhen Fan Bo-Quan li Cheng Tang Qiang Zhang Tsinghua Center for Green Chemical Engineering Electrification Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyDepartment of Chemical EngineeringTsinghua UniversityBeijingChina School of Materials Science and Engineering Beijing Institute of TechnologyBeijingChina Institute of Advanced Materials and Technology University of Science and TechnologyBeijingChina Shanxi Research Institute for Clean Energy Tsinghua UniversityTaiyuanChina Center for Next-Generation Energy Materials and School of Chemical Engineering Sungkyunkwan UniversityJangan-GuSuwon-SiGyeonggi-DoRepublic of Korea College of Chemical and Pharmaceutical Engineering Hebei University of Science and TechnologyShijiazhuangChina Ordos Carbon Neutral Research and Application Co. Ltd.Kangbashi DistrictOrdos CityInner MongoliaChina Institute for Carbon Neutrality Tsinghua UniversityBeijingChina

lithium–sulfur(li–S)batteries promise high-energy-density potential to exceed the commercialized lithiumion batteries but suffer from limited cycling lifespan due to the side reactions between lithium polysulfides(liPSs)and li metal ***,a three-way electrolyte with ternary solvents is proposed to enable high-energy-density and long-cycling li–S pouch ***,ternary solvents composed of 1,2-dimethoxyethane,di-isopropyl sulfide,and 1,3,5-trioxane are employed to guarantee smooth cathode kinetics,inhibit the parasitic reactions,and construct a robust solid electrolyte interphase,*** cycling lifespan of li–S coin cells with 50μm li anodes and 4.0 mg cm^(−2) sulfur cathodes is prolonged from88 to 222 cycles using the three-way ***-heterogeneous solvation structure of liPSs and organic-rich solid electrolyte interphase are identified to improve the cycling stability of li metal ***,a 3.0 Ah-level li–S pouch cell with the three-way electrolyte realizes a high energy density of 405 Wh kg^(−1) and undergoes 27 *** affords a three-way electrolyte recipe for suppressing the side reactions of liPSs and inspires rational electrolyte design for practical high-energy-density and long-cycling li–S batteries.

关键词： lithium metal anodes lithium-sulfur batteries pouch cells solid electrolyte interphase three-way electrolyte

Geochemistry and detrital zircon records of the Ruyang-Luoyu groups,southern North China Craton:Provenance,crustal evolution and Paleo-Mesoproterozoic tectonic implications

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Geoscience Frontiers 2020年第2期11卷 679-696页

作者： xi-yao li Sanzhong li Tong-Shan Wang Yunpeng Dong xiao-Guang liu Shu-Juan Zhao Kun Wang Jiao-Peng Sun li-Ming Dai Yan-Hui Suo Key Lab of Submarine Geosciences and Prospecting Techniques MOEand Institute for Advanced Ocean StudyCollege of Marine GeosciencesOcean University of ChinaQingdao 266100China State Key Laboratory of Continental Dynamics Northwest UniversityXi’an 710069China Laboratory for Marine Mineral Resources Qingdao National Laboratory for Marine Science and TechnologyQingdao 266237China Research Institute of Petroleum Exploration and Development PetroChinaBeijing 100083China

Paleo-to Mesoproterozoic sedimentary rocks in the southern margin of the North China Craton(NCC)are represented by the Ruyang and Luoyu *** studied the sedimentary rocks from the Yunmengshan and Beidajian formations of the Ruyang Group and the Cuizhuang and Sanjiaotang formations of the Luoyu *** zircon grains from these formations have U–Pb age populations of 3.64–3.31 Ga,2.96–2.86 Ga,2.72–2.59 Ga,2.56–2.47 Ga,2.45–2.0 Ga,1.99–1.85 Ga and 1.84–1.65 *** geochemical features of the sedimentary rocks suggest that some of the sediments were sourced from intermediate to felsic magmatic *** age groups of the detrital zircon are roughly consistent with the tectono-thermal events in the southern margin of the *** Hf isotopic compositions of detrital zircon from the sedimentary rocks in Ruyang and Luoyu groups suggest that significant crustal growth and reworking of the NCC took place during the Neoarchean and early-to mid-Paleoproterozoic,while crustal reworking at the Paleoarchean and late-Paleoproterozoic,and crustal growth at the *** suggest the depositional times of the Ruyang Group and Luoyu Group are constrained to no older than 1.75–1.7 Ga and 1.7–1.65 Ga,*** of late-Paleoproterozoic basins related to the strike slip and extrusion tectonics that cross-cut the NCC during the late Paleoproterozoic(linked the Yanshan–liaoxi regions of the northern NCC.

关键词： Detrital zircon North China craton Proterozoic Tectonics U–Pb ages Hf isotope

Promoting the sulfur redox kinetics by mixed organodiselenides in high-energy-density lithium-sulfur batteries

在线全文

学校读者我要写书评

暂无评论

eScience 2021年第1期1卷 44-52页

作者： Meng Zhao xi-yao li xiang Chen Bo-Quan li Stefan Kaskel Qiang Zhang Jia-Qi Huang School of Materials Science and Engineering Beijing Institute of TechnologyBeijing 100081China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Department of Inorganic Chemistry Technische Universität DresdenBergstr.66Dresden 01069Germany

lithium-sulfur(li-S)batteries are considered as a highly promising energy storage system due to their ultrahigh theoretical energy ***,the sluggish kinetics of the complex multi-electron sulfur redox reactions seriously hinders the actual battery performance especially under practical working *** redox mediation,through elaborately designing the additive molecules,is an effective approach to promote the sulfur redox *** a promoter of mixed organodiselenides(mixed-Se)is proposed to comprehensively improve the sulfur redox kinetics following the redox comediation ***,diphenyl diselenide promotes the liquid-liquid conversion between polysulfides and the solid-liquid conversion regarding lithium sulfide oxidation to polysulfides,while dimethyl diselenide enhances the liquid-solid conversion regarding lithium sulfide ***,the mixed-Se promoter endows a high discharge capacity of 1002 mAh g^(−1)with high sulfur loading of 4.0 mg cm^(−2),a high capacity retention of 81.6%after 200 cycles at 0.5 C,and a high actual energy density of 384 Wh kg^(−1)at 0.025 C in 1.5 Ah-level li-S pouch *** work affords an effective kinetic promoter to construct high-energy-density li-S batteries and inspires molecular design of kinetic promoters toward targeted energy-related redox reactions.

关键词： lithium-sulfur batteries Sulfur redox kinetics Organodiselenide lithium polysulfides Redox comediation

FUBP3 mediates the amyloid-β-induced neuronal NLRP3 expression

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Neural Regeneration Research 2025年第7期20卷 2068-2083页

作者： Jing yao Yuan li xi liu Wenping liang Yu li liyong Wu Zhe Wang Weihong Song The National Clinical Research Center for Geriatric Disease Xuanwu HospitalCapital Medical UniversityBeijingChina Department of Neurology The First Affiliated Hospital of Zhengzhou UniversityZhengzhouHenan ProvinceChina Department of Neurosurgery Xuanwu HospitalCapital Medical UniversityBeijingChina Department of Pediatrics The Second Affiliated Hospital and Yuying Children’s HospitalKey Laboratory of Alzheimer’s Disease of Zhejiang ProvinceInstitute of AgingWenzhou Medical UniversityWenzhouZhejiang ProvinceChina Oujiang Laboratory(Zhejiang Laboratory for Regenerative Medicine Visionand Brain Health)WenzhouZhejiang ProvinceChina

Alzheimer's disease is characterized by deposition of amyloid-β,which forms extracellular neuritic plaques,and accumulation of hyperphosphorylated tau,which aggregates to form intraneuronal neurofibrillary tangles,in the *** NLRP3 inflammasome may play a role in the transition from amyloid-βdeposition to tau phosphorylation and *** NLRP3 is primarily found in brain microglia,and tau is predominantly located in neurons,it has been suggested that NLRP3 expressed by microglia indirectly triggers tau phosphorylation by upregulating the expression of pro-inflammatory ***,we found that neurons also express NLRP3 in vitro and in vivo,and that neuronal NLRP3 regulates tau *** biochemical methods,we mapped the minimal NLRP3 promoter and identified FUBP3 as a transcription factor regulating NLRP3 expression in *** primary neurons and the neuroblastoma cell line Neuro2A,FUBP3 is required for endogenous NLRP3 expression and tau phosphorylation only when amyloid-βis *** the brains of aged wild-type mice and a mouse model of Alzheimer's disease,FUBP3 expression was markedly increased in cortical *** analysis suggested that FUBP3 plays a role in neuron-mediated immune *** also found that FUBP3 trimmed the 5′end of DNA fragments that it bound,implying that FUBP3 functions in stress-induced *** findings suggest that neuronal NLRP3 may be more directly involved in the amyloid-β-to–phospho-tau transition than microglial NLRP3,and that amyloid-βfundamentally alters the regulatory mechanism of NLRP3 expression in *** that FUBP3 was only expressed at low levels in young wild-type mice and was strongly upregulated in the brains of aged mice and Alzheimer's disease mice,FUBP3 could be a safe therapeutic target for preventing Alzheimer's disease progression.

关键词： 5′end trimming Alzheimer's disease amyloid-beta amyloid-β-dependent transcription FUBP3 inflammasome inflammation neuron NLRP3 tau transcription factor

Effects of thrombolytic drugs and a selective endothelin-1 receptor antagonist on acute pulmonary thromboembolism in dogs

在线全文

学校读者我要写书评

暂无评论

Chinese Medical Journal 2010年第4期123卷 395-400页

作者： HAN li li Qing-yun ZHOU ling WANG xi BAO Zhi-yao li Min WAN Huan-ying SHI Guo-chao Department of Respiratory Medicine Ruijin Hospital Shanghai Jiao Tong University School of Medicine Shanghai 200025 China

Background It has been shown that neurohumoral factors other than mechanical obstruction are involved in the pathophysiology of acute pulmonary thromboembolism （APTE）. The aim of this study was to investigate the effects of thrombolytic drugs, a selective endothelin-1 receptor （ET-1 R） antagonist alone or their combination on APTE in a canine model. Methods Twenty dogs were randomly assigned to five groups： sham, model, urokinase （UK）, BQ123, and combination （UK plus BQ123）. The dogs in the sham group underwent sham surgery. APTE was induced in the other four groups by intravenous injection of autologous blood clots. Dogs in the UK, BQ123 and combination groups received UK, BQ123 （a selective ET-1R antagonist）, or UK plus BQ123, respectively. The dogs in the model group were given saline. Mean pulmonary artery pressure （mPAP）, serum concentrations of ET-1, thromboxane （TXB2）, and tumor necrosis factor （TNF）-α were determined at different time points following the induction of APTE. Results UK and BQ123 alone markedly decreased mPAP in APTE. By comparison, the reduction was more significant in the combination group. Compared with the sham group （（-0.90±0.61） mmHg）, mPAP increased by （7.44±1.04）, （3.42±1.12） and （1.14±0.55） mmHg in the model group, UK alone and BQ123 alone groups, respectively, and decreased by （2.24±0.67） mmHg in the combination group （P 〈0.01）. Serum ET-1 concentrations in the BQ123 and combination groups were （52.95±8.53） and （74.42±10.27） pg/ml, respectively, and were significantly lower than those in the model and UK groups （（84.56±7.44） and （97.66±8.31） pg/ml respectively; P 〈0.01）. Serum TNF-α concentrations were significantly lower in the BQ123 group than in the model, UK and combination groups （P 〈0.05）. Conclusions Our results indicate that the selective ET-1R antagonist BQ123 not only reduces the increase of mPAP and serum ET-1 level, but also inhibits the production of TNF-α, and attenuates the local inflammatory response induced by APTE.

关键词： acute pulmonary thromboembolism thrombolytics endothelin-1 receptor antagonist pulmonary artery pressure

A Hybrid Approach for Pavement Crack Detection Using Mask R-CNN and Vision Transformer Model

在线全文

学校读者我要写书评

暂无评论

Computers, Materials & Continua 2025年第1期82卷 561-577页

作者： Shorouq Alshawabkeh li Wu Daojun Dong yao Cheng liping li Faculty of Engineering China University of GeosciencesWuhan430074China

Detecting pavement cracks is critical for road safety and infrastructure *** methods,relying on manual inspection and basic image processing,are time-consuming and prone to *** deep-learning(DL)methods automate crack detection,but many still struggle with variable crack patterns and environmental *** study aims to address these limitations by introducing the Masker Transformer,a novel hybrid deep learning model that integrates the precise localization capabilities of Mask Region-based Convolutional Neural Network(Mask R-CNN)with the global contextual awareness of Vision Transformer(ViT).The research focuses on leveraging the strengths of both architectures to enhance segmentation accuracy and adaptability across different pavement *** evaluated the performance of theMaskerTransformer against other state-of-theartmodels such asU-Net,TransformerU-Net(TransUNet),U-NetTransformer(UNETr),SwinU-NetTransformer(Swin-UNETr),You Only Look Once version 8(YoloV8),and Mask R-CNN using two benchmark datasets:Crack500 and *** findings reveal that the MaskerTransformer significantly outperforms the existing models,achieving the highest Dice SimilarityCoefficient(DSC),precision,recall,and F1-Score across both ***,the model attained a DSC of 80.04%on Crack500 and 91.37%on DeepCrack,demonstrating superior segmentation accuracy and *** high precision and recall rates further substantiate its effectiveness in real-world applications,suggesting that the Masker Transformer can serve as a robust tool for automated pavement crack detection,potentially replacing more traditional methods.

关键词： Pavement crack segmentation transportation deep learning vision transformer Mask R-CNN image segmentation