检索结果-南通市图书馆

Application of ionic liquids as a catalyst in the synthesis of polyvinyl butyral(PVB) polymer

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2016年第1期27卷 145-148页

作者： xi-xi Qin Zhi-lin Cheng College of Chemistry and Chemical Engineering Yangzhou University

Polyvinyl butyral（PVB） polymer was successfully synthesized using ionic liquid（IL） catalyst. The synthesis of PVB was achieved by acetalization of polyvinyl alcohol（PVA） and butyraldehyde（BA） in the presence of [HMIM]~＋HSO_4^-IL catalyst. The FT-IR,~1H NMR, DSC, GPC and SEM characterizations were used to analyze the structure and properties of PVB. The effects of the concentration of PVA in water and the number of reuse cycles on the acetalization degree were investigated. The results indicated that the maximum acetalization degree of PVB obtained using [HMIM]~＋HSO_4^-IL catalyst was up to 72%. The comparison of the commercial PVB and the PVB obtained using [HMIM]~＋HSO_4^-IL catalyst showed that the self-made PVB has a larger molecular weight, higher viscosity, and higher acetalization degree than the commercial PVB.

关键词： Ionic liquids Catalyst PVB Acetalization degree

Study on friction performance of graphene-based semi-solid grease

在线全文

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2014年第9期25卷 1305-1307页

作者： Zhi-lin Cheng xi-xi Qin College of Chemistry and Chemical Engineering Yangzhou University

The graphene-based semi-solid grease with low friction coefficient was prepared by highly dispersed mixing method. The friction testing result showed that the friction coefficient of the graphene oxidebased semi-solid grease reduced from ca. 0.105 of graphite-based one to ca. 0.075, approximately 30% decreasing. Further, the graphene-based semi-solid grease shows the more outstandingly lubricating property, and the friction coefficient approximately drops to the range of between 0.04 and 0.06. By comparing with the graphite-based grease, the friction coefficient decreases about 40%-60% and the wear reduced over 50%.

关键词： Graphene Friction Wear Grease

Revolutionizing breast cancer detection:Advances in fluorescent probe technology

在线全文

学校读者我要写书评

暂无评论

Nano Research 2025年第1期18卷 653-674页

作者： Qian Gao lin Tang Jun Zhan Yiyuan Xue Feng Luo State Key Laboratory of Oral Diseases&National Center for Stomatology&National Clinical Research Center for Oral Diseases West China Hospital of StomatologySichuan UniversityChengdu 610041China Emergency Obstetrics and Gynecology West China Second University HospitalSichuan UniversityChengdu 610041China Department of Obstetrics and Gynecology West China Second University HospitalSichuan UniversityChengdu 610041China Department of Prosthodontics West China School of StomatologySichuan UniversityChengdu 610041China

With the increasing incidence of breast cancer globally,there is an urgent demand for enhanced diagnostic and therapeutic *** comprehensive review explores advancements in fluorescent probe technology for breast cancer imaging and early *** probes offer unparalleled sensitivity and specificity in detecting cancer biomarkers,enabling early diagnosis and delineation of tumor margins during *** categorize these probes into molecular,nano,ratiometric,the second near-infrared window(NIR-II),and multifunctional varieties,each with unique capabilities for targeting specific cancer *** review highlights recent innovations in probe design,emphasizing their applications in pathogenesis studies,drug development,precision medicine,and fluorescence-guided *** their promising clinical potential,challenges such as safety,biomarker targeting accuracy,system compatibility,and clinical translation *** these hurdles is crucial for the integration of fluorescent probes into standard cancer care,aiming to improve treatment outcomes and patient quality of life.

关键词： breast cancer fluorescent probes imaging early diagnosis biomarker

Anaerobic oxidation of methane coupled to sulfate reduction: Consortium characteristics and application in co-removal of H_2S and methane

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental Sciences 2019年第2期31卷 238-248页

作者： lin Li Song Xue Jingru xi State Key Laboratory of Environmental Aquatic Chemistry Research Center for Eco-Environmental SciencesChinese Academy of Sciences National Engineering Laboratory for VOCs Pollution Control Material & Technology University of Chinese Academy of Sciences State Key Laboratory of Applied Microbiology Southern China Guangdong Institute of MicrobiologyGuangdong Academy of Sciences

Anaerobic sludge from a sewage treatment plant was used to acclimatize microbial colonies capable of anaerobic oxidation of methane(AOM) coupled to sulfate reduction. Clone libraries and fluorescence in situ hybridization were used to investigate the microbial ***-reducing bacteria(SRB)(e.g., Desulfotomaculum arcticum and Desulfobulbus propionicus)and anaerobic methanotrophic archaea(ANME)(e.g., Methanosaeta sp. and Methanolinea sp.)coexisted in the enrichment. The archaeal and bacterial cells were randomly or evenly distributed throughout the consortia. Accompanied by sulfate reduction, methane was oxidized anaerobically by the consortia of methane-oxidizing archaea and SRB. Moreover, CH_4 and SO_4^(2-) were consumed by methanotrophs and sulfate reducers with CO_2 and H_2S as products. The H_3CSH produced by methanotrophy was an intermediate product during the process. The methanotrophic enrichment was inoculated in a down-flow biofilter for the treatment of methane and H_2S from a landfill site. On average, 93.33% of H_2S and 10.71% of methane was successfully reduced in the biofilter. This study tries to provide effective method for the synergistic treatment of waste gas containing sulfur compounds and CH_4.

关键词： Anaerobic methane oxidation Sulphate reduction Microbial population 13C isotope-labelling Potential pathway Landfill gas

Treadmill exercise in combination with acousto-optic and olfactory stimulation improves cognitive function in APP/PS1 mice through the brain-derived neurotrophic factor-and Cygb-associated signaling pathways

在线全文

学校读者我要写书评

暂无评论

Neural Regeneration Research 2025年第9期20卷 2706-2726页

作者： Biao xiao Chaoyang Chu Zhicheng lin Tianyuan Fang Yuyu Zhou Chuxia Zhang Jianghui Shan Shiyu Chen Liping Li Department of Physiology and Pharmacology Health Science CenterNingbo UniversityNingboZhejiang ProvinceChina Ningbo Key Laboratory of Behavioral Neuroscience Health Science CenterNingbo UniversityNingboZhejiang ProvinceChina Key Laboratory of Addiction Research of Zhejiang Province NingboZhejiang ProvinceChina

A reduction in adult neurogenesis is associated with behavioral abnormalities in patients with Alzheimer's ***,enhancing adult neurogenesis represents a promising therapeutic approach for mitigating disease symptoms and ***,nonpharmacological interventions aimed at inducing adult neurogenesis are currently *** individual non-pharmacological interventions,such as aerobic exercise,acousto-optic stimulation,and olfactory stimulation,have shown limited capacity to improve neurogenesis and cognitive function in patients with Alzheimer's disease,the therapeutic effect of a strategy that combines these interventions has not been fully *** this study,we observed an age-dependent decrease in adult neurogenesis and a concurrent increase in amyloid-beta accumulation in the hippocampus of amyloid precursor protein/presenilin 1 mice aged 2-8 *** deposition became evident at 4 months,while neurogenesis declined by 6 months,further deteriorating as the disease ***,following a 4-week multifactor stimulation protocol,which encompassed treadmill running(46 min/d,10 m/min,6 days per week),40 Hz acousto-optic stimulation(1 hour/day,6 days/week),and olfactory stimulation(1 hour/day,6 days/week),we found a significant increase in the number of newborn cells(5'-bromo-2'-deoxyuridine-positive cells),immature neurons(doublecortin-positive cells),newborn immature neurons(5'-bromo-2'-deoxyuridine-positive/doublecortin-positive cells),and newborn astrocytes(5'-bromo-2'-deoxyuridine-positive/glial fibrillary acidic protein-positive cells).Additionally,the amyloid-beta load in the hippocampus *** findings suggest that multifactor stimulation can enhance adult hippocampal neurogenesis and mitigate amyloid-beta neuropathology in amyloid precursor protein/presenilin 1 ***,cognitive abilities were improved,and depressive symptoms were alleviated in amyloid precursor protein/presenilin 1 mice

关键词： acousto-optic stimulation adult neurogenesis Alzheimer's disease amyloid precursor protein/presenilin 1 mice amyloid-beta deposition brain cell apoptosis cognitive impairment depression-like behavior involuntary treadmill exercise olfactory stimulation serum metabolites

A strategy to achieve efficient green-emission dual-mode luminescence of Yb^(3+),Er^(3+) doped NaBiF_(4)

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2021年第8期40卷 2040-2048页

作者： Jin-Hui xie Jue Wang Gui-Hua Qiu xi-Bing Li wen-Tao Huang Rui-Rong Zhang Tong lin Li-xi Wang Qi-Tu Zhang College of Materials Science and Engineering Nanjing Tech UniversityNanjing210009China Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites Nanjing210009China Shandong Institute of Non-metallic Material Jinan250031China

A series of hexagonal phase NaBiF_(4):x Yb^(3+),y Er^(3+) were successfully synthesized by solvothermal *** morphology,phase structure,up-conversion luminescence and down-conversion luminescence properties of Yb^(3+) and Er^(3+) doping concentration and the energy transfer mechanism were *** shows that the doping of Yb^(3+) and Er^(3+) does not cause the phase transition of NaBiF_(4),but influences its *** the NaBiF_(4):Yb^(3+),Er^(3+),Yb^(3+) can transfer energy with Er^(3+),enhancing up-conversion green *** Yb^(3+) doping concentration increasing,the up-conversion red-green ratio will increase while the down-conversion intensity of the green emission decreases and that of the red emission *** the potential application of Na BiF4:x Yb^(3+),y Er^(3+) phosphors in optical illumination,the thermal stability was carried out.

关键词： NaBiF_(4) Dual-mode luminescence Energy transfer High temperature fluorescence

Nanostructuring of Mg-Based Hydrogen Storage Materials:Recent Advances for Promoting Key Applications

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2023年第7期15卷 30-56页

作者： Li Ren Yinghui Li Ning Zhang Zi Li xi lin wen Zhu Chong Lu wenjiang Ding Jianxin Zou National Engineering Research Center of Light Alloys Net Forming and State Key Laboratory of Metal Matrix Composites Shanghai Engineering Research Center of Mg Materials and Applications and School of Materials Science and EngineeringCenter of Hydrogen ScienceShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Instrumental Analysis Center of SJTU Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

With the depletion of fossil fuels and global warming,there is an urgent demand to seek green,low-cost,and high-efficiency energy *** has been considered as a potential candidate to replace fossil fuels,due to its high gravimetric energy density(142 MJ kg^(-1)),high abundance(H_(2)O),and ***,due to its low volume density,effective and safe hydrogen storage techniques are now becoming the bottleneck for the"hydrogen economy".Under such a circumstance,Mg-based hydrogen storage materials garnered tremendous interests due to their high hydrogen storage capacity(~7.6 wt%for MgH_(2)),low cost,and excellent ***,the high thermodynamic stability(ΔH=-74.7 kJ mol^(-1)H_(2))and sluggish kinetics result in a relatively high desorption temperature(>300℃),which severely restricts widespread applications of MgH_(2).Nano-structuring has been proven to be an effective strategy that can simultaneously enhance the ab/de-sorption thermodynamic and kinetic properties of MgH_(2),possibly meeting the demand for rapid hydrogen desorption,economic viability,and effective thermal management in practical ***,the fundamental theories,recent advances,and practical applications of the nanostructured Mg-based hydrogen storage materials are *** synthetic strategies are classified into four categories:free-standing nano-sized Mg/MgH_(2)through electrochemical/vapor-transport/ultrasonic methods,nanostructured Mg-based composites via mechanical milling methods,construction of core-shell nano-structured Mg-based composites by chemical reduction approaches,and multi-dimensional nano-sized Mg-based heterostructure by nanoconfinement *** applying these strategies,near room temperature ab/de-sorption(6 wt%)has been achieved in nano Mg/MgH_(2)*** perspectives on the future research and development of nanostructured hydrogen storage materials are also provided.

关键词： Mg-based hydrogen storage materials Nanostructure Hydrogen storage Thermodynamics Kinetics On-board hydrogen storage

Ru/NiMnB spherical cluster pillar for highly proficient green hydrogen electrocatalyst at high current density

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 397-408页

作者： Md Ahasan Habib Shusen lin Mehedi Hasan Joni Sumiya Akter Dristy Rutuja Mandavkar Jae-Hun Jeong Jihoon Lee Department of Electronic Engineering College of Electronics and Information Kwangwoon University

Advanced OER/HER electrocatalytic alternatives are crucial for the wide adaptation of green hydrogen ***,Ru/NiMnB spherical cluster pillar （SCP）,denoted as Ru/NiMnB,is synthesized using a combination of electro-deposition and hydrothermal *** investigation of Ru doping in the NiMnB matrix revealed significant improvements in electrocatalytic *** Ru/NiMnB SCPs demonstrate superior OER/HER activity with low overpotentials of 150 and 103 mV at 50mA/cm2in 1 M KOH,making them highly competitive with state-of-the-art ***,the Ru/NiMnB SCPs exhibit a low 2-E cell voltage of 2.80 V at ultra-high current density of 2,000 m A/cm2in 1 M KOH,outperforming the standard benchmark electrodes of RuO2||Pt/C,thereby positioning Ru/NiMnB as one of the best bifunctional *** SCPs exhibit exceptional high-current characteristics,stability and corrosion resistance,as evidenced by continuous operation at 1,000 mA/cm2high-current density for over 150 h in 6 M KOH at elevated temperatures under harsh industrial *** a small amount of Ru incorporation significantly enhances the electrocatalytic performances of NiMnB,attributed to increased active sites and improved intrinsic properties such as conductivity,adsorption/desorption capability and reaction ***,Ru/NiMnB SCPs present a promising bi-functional electrode concept for efficient green H2production.

关键词： Advanced electrocatalyst High current Corrosion resistance Industrial requirement

Isolation of peroxisomes from tissues and cells by differential and density gradient centrifugation

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

中国病理生理杂志 2015年第10期 1898-1899页

作者： lin Yuan-xi SONG xin-ai WANG Ya-wen Department of Physiology and Pathophysiology Xi'an Jiaotong University School of Medicine

The investigation of unique functional and structural aspects of peroxisomes(POs)requires the preparation of highly purified frac-tions of this *** this report,differential centrifugation separation of POs from of tissues and cells and purification by density gradient ultracentrifugation were *** were purified by different ways:(1)Metrizamide gradient *** the light

关键词：