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CdS/LaFeO_(3) heterojunctions with improved optical properties for visible-light catalytic applications

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Journal of Rare Earths 2024年第5期42卷 879-888,I0003页

作者： Jiaqi Wei Wen Zhu xuelian xu Xiao xu Junjiang Zhu Hubei Key Laboratory of Biomass Fibers and Eco-dyeing&Finishing College of Chemistry and Chemical EngineeringWuhan Textile University ChemistryWuhan430200China

Construction of heterojunctions is a normal and effective strategy to improve the photocatalytic performances of semiconductors,through which both the lifetime and the redox ability of electrons/holes can be improved,as co mpared to the respective *** this basis,we constructed Z-scheme CdS/LaFeO_(3) heterojunctions(CdS/LFO),by in-situ growing different amounts of CdS on the surface of LaFeO_(3),for photocatalytic degradation of tetracycline hydrochloride(TC)in aqueous solution at room *** crystal structure,surface morphology and optoelectronic properties of the COS/LFO heterojunctions were systemically characterized to correlate the reaction *** tests indicate that the CdS/LFO heterojunctions exhibit promising activity for TC degradation under visible light irradiation(λ≥420 nm),with 85%TC conversion obtained at reaction time of 45 min,which is 3.4 and 1.9 times higher than that of CdS and LaFeO_(3).The CdS/LFO heterojunctions are also stable in the reaction and can be reused for four cycles with no appreciable activity *** applicability of CdS/LFO to photocatalytic degradation of organic dyes,as well as the reaction mechanism,was also explored.

关键词： LaFeO_(3) CdS Photocatalytic degradation Tetracycline hydrochloride Reaction mechanism Rare earths

绝经后女性铁蓄积与骨代谢及机体炎症反应的相关性研究

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中国骨质疏松杂志 2019年第5期25卷 649-655页

作者：程千刘起富金铭赵国阳徐又佳上海交通大学医学院附属同仁医院上海200050 江苏大学附属医院江苏镇江212000 山东省青州市人民医院山东潍坊262500 苏州大学附属第二医院江苏苏州215000

目的研究绝经后女性铁蓄积与骨代谢及机体炎症反应的相关性。方法将117名绝经后女性体检者按照骨密度(bone mineral density,BMD)值分成3组:骨量正常组(T≥-1)、骨量减少组(-2.5 详细信息

目的研究绝经后女性铁蓄积与骨代谢及机体炎症反应的相关性。方法将117名绝经后女性体检者按照骨密度(bone mineral density,BMD)值分成3组:骨量正常组(T≥-1)、骨量减少组(-2.5

关键词：铁蓄积骨代谢炎症反应骨质疏松骨密度

Study on force chain evolution of rice straw with different length during vibrational compression

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Particuology 2024年第2期85卷 310-322页

作者： Han Tang Wenlong xu Guixuan Zhu Changsu xu Jinwu Wang College of Engineering Northeast Agricultural UniversityHarbin150030China

This paper explores the mechanism of force chain evolution and voidage change under vibrational and non-vibrational compression conditions of rice straw of different *** were used to explore the force chain evolution and voidage variation mechanism under different *** re-sults show that under non-vibrational compression,the strong force chain passes from top to bottom in vertical direction and from center to periphery in tangential *** vibrational compression,the force chain passes from top and bottom to center in vertical direction and the force chain evolves from outer ring to interior and exterior in tangential *** number of strong chains,voidage and standard deviation of the mean pressure under vibratory compression are lower than the values under non-vibratory *** promotes stress transfer and enhancement,velocity enhancement and density *** study analyzes the mechanical properties of different lengths straw during vibrational and non-vibrational compression from a detailed viewpoint.

关键词： Straw compression Voidage Discrete element method Mechanical properties Force chain transmission

ARPES investigation of the electronic structure and its evolution in magnetic topological insulator MnBi2+2nTe4+3n family

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National Science Review 2024年第2期11卷 81-93页

作者： Runzhe xu Lixuan xu Zhongkai Liu Lexian Yang Yulin Chen State Key Laboratory of Low Dimensional Quantum Physics Department of PhysicsTsinghua University School of Physical Science and Technology Shanghai Tech University and CAS-Shanghai Science Research Center Shanghai Tech Laboratory for Topological Physics Frontier Science Center for Quantum Information Collaborative Innovation Center of Quantum Matter Department of Physics Clarendon LaboratoryUniversity of Oxford

In the past 5 years,there has been significant research interest in the intrinsic magnetic topological insulator family compounds MnBi2+2nTe4+3n（where n=0,1,2…）.In particular,exfoliated thin films of MnBi2Te4have led to numerous experimental breakthroughs,such as the quantum anomalous Hall effect,axion insulator phase and high-Chern number quantum Hall effect without Landau ***,despite extensive efforts,the energy gap of the topological surface states due to exchange magnetic coupling,which is a key feature of the characteristic band structure of the system,remains experimentally *** electronic structure measured by using angle-resolved photoemission （ARPES） shows significant deviation from ab initio prediction and scanning tunneling spectroscopy measurements,making it challenging to understand the transport results based on the electronic *** paper reviews the measurements of the band structure of MnBi2+2nTe4+3nmagnetic topological insulators using ARPES,focusing on the evolution of their electronic structures with temperature,surface and bulk doping and film *** aim of the review is to construct a unified picture of the electronic structure of MnBi2+2nTe4+3ncompounds and explore possible control of their topological properties.

关键词： magnetic topological insulator MnBi2Te4 electronic structure angle-resolved photoemission spectroscopy

Cationic starch microparticles with integrated antibacterial and hemostatic performance

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Science China Technological Sciences 2024年第10期67卷 3235-3246页

作者： SU Yang NIU MengXin xu KaiDong xu Chen YANG PeiLang HU Yang xu Fu-Jian Key Lab of Biomedical Materials of Natural Macromolecules (Beijing University of Chemical Technology Ministry of Education)Beijing Laboratory of Biomedical MaterialCollege of Materials Science and EngineeringBeijing University of Chemical Technology Department of Burn Ruijin Hospital Affiliated to Shanghai Jiao Tong University School of Medicine

It is urgently demanded to develop biomaterials with balanced hemostatic/antibacterial ability and facile preparation methods. In this work, cationic starch microparticles(MSQP), prepared by the facile grafting of microporous starch particles(MS) with tunable quaternized polyethyleneimine, were readily constructed as promising hemostatic materials for integrated antibacterial and hemostatic performance. The cationic grafts not only endowed MSQP with good antibacterial ability, but also benefited from biocompatible MS to achieve favorable biocompatibility. Moreover, in vitro results confirmed the superior hemostatic property of MSQP2(with the medium content of cationic grafts) among three MSQP and pristine MS. After investigating the bloodmaterial interactions of MSQP/MS, the procoagulant mechanism of MSQP2 was revealed that the optimal amount of cationic grafts achieves highly balanced plasma-protein adhesion, platelet adhesion and blood coagulation system. In vivo artery-injury model further demonstrated the superior hemostatic performance of MSQP2 for potential severe hemorrhage. This work sheds light on the design of cationic polymer-based biomaterials for balanced antibacterial and hemostatic functions.

关键词： hemostasis antibacterial cationic polymer microparticles

Optimal design for rubber concrete layered periodic foundations based on the analytical approximations of band gaps and mapping relations

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Earthquake Engineering and Engineering Vibration 2024年第3期23卷 593-608页

作者： Wu Qiaoyun xu Zhifeng xu Peishan Zeng Wenxuan Chen xuyong School of Civil Engineering and Architecture Wuhan Institute of TechnologyWuhan 430073China State Key Laboratory for Health and Safety of Bridge Structures Wuhan 430034China Wuhan Urban Construction Group Co. Ltd.Wuhan 430022China

The seismic performance of rubber concrete-layered periodic foundations are significantly influenced by their design,in which the band gaps play a paramount *** at providing better designs for these foundations,this study first proposes and validates the analytical formulas to approximate the bounds of the first few band *** addition,the mapping relations linking the frequencies of different band gaps are ***,an optimal design method for these foundations is developed,which is validated through an engineering *** is demonstrated that ensuring the superstructure’s resonance zones are completely covered by the corresponding periodic foundation’s band gaps can achieve satisfactory vibration attenuation effects,which is a good strategy for the design of rubber concrete layered periodic foundations.

关键词： periodic foundation band gap vibration attenuation seismic isolation optimal design

Coupling effect on the thermal hazard assessment of hazardous chemical materials via calorimetric technologies and simulation approaches

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Defence Technology（防务技术） 2024年第2期32卷 644-654页

作者： Yabei xu Jiankun Shao Wei Wang Shengliang xu Dongping Chen State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China Science and Technology on Aerospace Chemical Power Laboratory Hubei Institute of Aerospace ChemotechnologyXiangyang 441003China

The coupling effect of heat absorption and release exists in the thermal decomposition of a few chemical ***,the impact of the above coupling on thermal hazard assessment is not considered in the literature *** this work,nitroguanidine(NQ)and 1,3,5-trinitro-1,3,5-triazine(RDX)are selected as representative materials to explore the influence of the coupling effect on the thermal hazard assessment of chemical *** linear heating experiments of NQ and RDX are carried out by a microcalorimeter and synchronous thermal *** thermal decomposition curves are decoupled by advanced thermokinetics *** thermal decomposition and kinetic parameters before and after decoupling are *** results of TG experiment show that both NQ and RDX began to lose mass during the endothermic *** endothermic melting and exothermic decomposition of NQ and RDX are coupled within this *** coupling effect has different degrees of influence on its initial decomposition temperature and safety *** with the parameters in the coupling state,the initial decomposition temperature and adiabatic induction period after decoupling *** self-accelerating decomposition temperature increases,and internal thermal runaway time *** the thermal hazard assessment of chemical materials with coupling effects,the calculated parameters after decoupling should be taken as an important safety index。

关键词： Calorimetric technologies Kinetics Thermal hazard Phase transformation Thermal decomposition

Gluing Affine Vortices

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Acta Mathematica Sinica,English Series 2024年第1期40卷 250-312页

作者： Guang Bo xu Department of Mathematics Rutgers UniversityHill Center-Busch Campus 110 Frelinghuysen RoadPiscatawayNJ 08854-8019USA

We provide an analytical construction of the gluing map for stable affine vortices over the upper half plane with the Lagrangian boundary *** result is a necessary ingredient in studies of the relation between gauged ... 详细信息

关键词： Affine vortices gauged linear sigma model adiabatic limit symplectic reduction

Image Recognition Model of Fraudulent Websites Based on Image Leader Decision and Inception-V3 Transfer Learning

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China Communications 2024年第1期21卷 215-227页

作者： Shengli Zhou Cheng xu Rui xu Weijie Ding Chao Chen Xiaoyang xu Information Department of Zhejiang Police College Hangzhou 310053China Hangzhou Dianzi University Hangzhou 310018China Big Data Laboratory of Zhejiang Police College Hangzhou 310053China Hangzhou Public Security Bureau Hangzhou 310002China

The fraudulent website image is a vital information carrier for telecom *** efficient and precise recognition of fraudulent website images is critical to combating and dealing with fraudulent *** research on image recognition of fraudulent websites is mainly carried out at the level of image feature extraction and similarity study,which have such disadvantages as difficulty in obtaining image data,insufficient image analysis,and single identification *** study develops a model based on the entropy method for image leader decision and Inception-v3 transfer learning to address these *** data processing part of the model uses a breadth search crawler to capture the image ***,the information in the images is evaluated with the entropy method,image weights are assigned,and the image leader is *** model training and prediction,the transfer learning of the Inception-v3 model is introduced into image recognition of fraudulent *** selected image leaders to train the model,multiple types of fraudulent websites are identified with high *** experiment proves that this model has a superior accuracy in recognizing images on fraudulent websites compared to other current models.

关键词： fraudulent website image leaders telecom fraud transfer learning