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Particuology 2024年第8期91卷 106-117页

作者： Junchao xu Zhipeng Zhang Li Lv Yunfei Zhang yiming Xie Huaqiang chu School of Energy and Environment Anhui University of TechnologyMaanshan243002China College of Mechanical and Electrical Engineering China Jiliang UniversityHangzhou310018China

Water vapor nucleation on particle's surface plays an important role in dust removal,cloud formation,and particle ***,the selectivity of nucleation sites and the nucleation characteristic of water molecule on the particle's surface are still unclear,especially for the aggregated *** this paper,the effects of particle wettability and aggregation modes on the selectivity of nucleation sites and the nucleation characteristics were investigated using molecular dynamics *** results were compared with our earlier experimental *** illustrates how the contact angle of clusters,the growth velocity,and the growth duration are all influenced by the interaction coefficient between water and ***,the nucleation sites of water molecules on the particle aggregation surface exhibit a definite *** primary indicator of this selectivity is the preferential nucleation of water molecules at the interfaces of linear chain aggregation particles,at the inner side of non-linear chain aggregation particles,and at the centers of ring *** results are in good agreement with our previous experimental *** significantly,additional research has revealed that subcritical-size clusters typically aggregate on two-particle surfaces spacing when the spacing smaller than the critical cluster size.

关键词： Heterogeneous nucleation Water molecule Wettability Aggregation modes Molecule dynamics

Sulfide-melt inclusions in mantle xenoliths of Hannuoba,china

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Chinese science Bulletin 1999年第2期44卷 166-170页

作者： xu jiuhua , chu xuelei , zhou yiming , du yuanfuuniversity of science and technology beijing, beijing 100083. china china University of Geosciences( beijing) , beijing 100083. china The Research Center of Mineral Resources Exploration , beijing 100101, china Institute of Geology, Chinese Academy of sciences, beijing 100029, china University of science and technology beijing Beijing China china University of Geosciences (beijing) Beijing China The Research Center of Mineral Resources Exploration Beijing China Institute of Geology Chinese Academy of Sciences Beijing China

Sulfide fluid incluision study on mantle xenoliths of Hannouba has been carried out by EPMA analysis. It is indicated that the Ni/Fe ratios of metal sulfides in sulfide-melt inclusions from Hannuoba seem to be related to host rocks. These data of lherzolite （pentlandite） are obviously higher than those of olivine pyroxenite （mainly pentlandite, partly pyrrhotine）. The LRM analysis shows that sulfur （H2S+SO2） occupies larger proportion in gas composition of CO2 fluid inclusions, generally more than mol 20 %. This may be related to sulfide inclusions which are frequently found.

关键词： mantle xenolith sulfide-melt inclusion EPMA.

One-pot Synthesis of MoO_(3)/PI Composite with Enhanced Photocatalytic Performance for Oxidative Coupling of Amines to Imines

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china Petroleum Processing & Petrochemical technology 2024年第2期26卷 57-71页

作者： Zhao Wenjie du Chengxin Song Yu zhou Yafen Wang Qing zhou Limei xu Bin Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province College of Chemistry and Chemical EngineeringChina West Normal UniversityNanchongChina Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education Sichuan University of Science&EngineeringZigongChina

Organic-inorganic MoO_(3)/PI(MoPI)composites were prepared using a simple one-pot thermal copolymerization *** resulting composites exhibited enhanced photocatalytic activity for the selective oxidation of benzylamine to N-benzylidene benzylamine(N-BDBA)in ambient air under simulated solar light irradiation compared to pristine MoO_(3) or polyimide(PI).In particular,the MoPI composite with a 0.3:1 molar ratio of Mo to melamine,referred to as MoPI-0.3,demonstrated the best performance in the photo-oxidation of benzylamine,achieving a benzylamine conversion of 95%with a N-BDBA selectivity exceeding 99%after 3 h *** enhanced photocatalytic activity of the MoPI-0.3 catalyst was attributed to the formation of a direct Z-scheme heterojunction between MoO_(3) and PI,facilitating more efficient separation of the photoinduced electrons and ***,the MoPI-0.3 composite maintained considerably high activity over four consecutive cycles,highlighting its good stability and ***,the MoPI-0.3 composite could photo-oxidize benzylamine derivatives and heterocyclic amines to their corresponding imines,demonstrating the universal applicability of this composite catalyst.

关键词： MoO3/PI composite photocatalysis amine oxidation imine

High-performance wearable bimetallic nanowire-assisted composite foams for efficient electromagnetic interference shielding,infrared stealth,and piezoresistive sensing

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Nano Research 2024年第7期17卷 6757-6765页

作者： Tianyi Hang Lijie zhou Chenhui xu yiming Chen Jiahui Shen Jiajia Zheng Pingan Yang Xiping Li Heng Luo Guoxiu Tong Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance technology and Equipment of Zhejiang Province College of EngineeringZhejiang Normal UniversityJinhua 321004China School of Automation Chongqing University of Posts and TelecommunicationsChongqing 400065China State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China Key Laboratory of the Ministry of Education for Advanced Catalysis Materials College of Chemistry and Materials ScienceZhejiang Normal UniversityJinhua 321004China

With the accelerated development of modern detection and communication technology,the multifunctional wearable materials with excellent electromagnetic interference(EMI)shielding,infrared stealth,and human monitoring for improving military combat capability have received extensive *** this work,the lightweight melamine foam(MF)@silver nanowires(AgNWs)-iron nanowires(FeNWs)(AgFe-MF)was fabricated by a vacuum-assisted dip-coating *** to the porous structure and synergistic electrical and magnetic losses,this lightweight(0.115 g/cm^(3))composite foam with an ultra-low filler content(0.62 vol.%)exhibited an ideal EMI shielding efficiency of 38.4 *** the other hand,the AgFe-MF realized a powerful multifunctional *** surface saturation temperature of the AgFe-MF reached 94.2℃under a low applied voltage of 1.8 V and remained extremely fast heating and cooling response and terrific working stability,resulting in excellent infrared stealth and camouflage ***,taking virtues of the elastic porous conductive architecture,the AgFe-MF was utilized as a piezoresistive sensor exhibiting board compressive interval of 0–1.62 kPa(50%strain)with a good sensitivity of 0.57 kPa^(−1).This work will provide new ideas and insights for developing multifunctional wearable devices in the fields of EMI shielding,thermal management,and piezoresistive sensing.

关键词： metal nanowires porous foams electromagnetic interference shielding infrared stealth wearable sensors

Bimetallic NiCoP catalysts anchored on phosphorus-doped lignin-based carbon for robust oxygen evolution performance

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Rare Metals 2024年第7期43卷 3084-3095页

作者： Ling-Ying-Zi Xiong Bo-Wen Liu Lei du Yue-Kuan zhou xu-Liang Lin Huan Wang Guangdong Engineering technology Research Center for Sensing Materials&Devices Guangzhou Key Laboratory of Sensing Materials&DevicesSchool of Chemistry and Chemical EngineeringGuangzhou UniversityGuangzhou 510006China School of Chemical Engineering and Light Industry Guangdong University of TechnologyGuangzhou 510006China Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center Jieyang 515200China Sustainable Energy and Environment Thrust Function HubThe Hong Kong University of Science and Technology(Guangzhou)Guangzhou 511400China Division of Emerging Interdisciplinary Areas Department of Mechanical and Aerospace EngineeringThe Hong Kong University of Science and TechnologyHong Kong 999077China State Key Lab of Pulp and Paper Engineering South China University of TechnologyGuangzhou 510640China

Oxygen evolution reaction(OER)catalysts are the key core materials that determine the performance of fuel cells,metal-air batteries,electrolytic water decomposition,and other *** this work,a green lignin-based non-precious metal OER catalyst was prepared by a simple ***,c arboxylated lignin was used to complex Ni and Co in situ,and then they were placed with sodium hypophosphite in the same tube furnace for upstream and downstream high-temperature calcination to construct a lignin carbon-based Ni-Co bimetallic OER catalyst(NiCoP@C).The synthesized catalyst is a porous bimetallic phosphide with a three-dimensional network structure and high-density electrochemical active ***@C exhibited favorable catalytic activity for the oxygen evolution reaction(OER)with overpotential of 280 mV at 10 mA·cm~(-2)and a Tafel slope of 77 mV·dec~(-1).Additionally,it exhibited remarkable durability during *** functional theory(DFT)calculations revealed that by leveraging the distinctive structure of transition metal phosphide nanoparticles incorporated into a reticulated substrate,the NiCoP@C catalyst offered an increased number of active sites for OER catalysis,significantly enhancing its stability during practical *** present study broadens the utilization pathways of biomass to"turn waste into treasure,"aligning the development concept of green sustainable development.

关键词： Oxygen evolution reaction Lignin Carbon-based catalyst Nickel-cobalt bimetal Metal phosphide

Quantifying the contribution of activity patterns to PM_(2.5)exposure inequity between urban and rural residents by a novel method

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Building Simulation 2024年第8期17卷 1323-1333页

作者： Wei du Zhanpeng Cui Jinze Wang Yuqiong Wang Yungui Li Xiaoan Li Yan zhou Tao Jiang Kang Mao Xianbiao Lin Jianwu Shi Dengzhou Gao yiming Qin Yunnan Provincial Key Laboratory of Soil Carbon Sequestration and Pollution Control Faculty of Environmental Science&EngineeringKunming University of Science&TechnologyKunming 650500China Laboratory of Earth Surface Processes College of Urban and Environmental SciencesPeking UniversityBeijing 100871China Department of Environmental Engineering Southwest University of Science and TechnologyMianyang 621010China NHC Key Laboratory of Nuclear technology Medical Transformation Mianyang Central HospitalSchool of MedicineUniversity of Electronic Science and Technology of ChinaMianyang 621000China State Key Laboratory of Environmental Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China Key Laboratory of Marine Chemistry Theory and technology Ministry of EducationOcean University of ChinaQingdao266100China Key Laboratory for Humid Subtropical Eco-Geographical Processes of the Ministry of Education School of Geographical SciencesFujian NormalUniversityFuzhou350117China School of Energy and Environment City University of Hong KongHong KongChina

PM_(2.5)pollution variations in different microenvironments would result in PM_(2.5)exposure inequity between rural and urban *** this study,the real-time PM_(2.5)exposure of urban and rural residents in china was examined based on portable PM_(2.5)sensors together with activity patterns derived from questionnaire surveys,with a focus on students and senior citizens who are sensitive to air *** results showed that PM_(2.5)exposure varied significantly among different resident groups,with higher PM_(2.5)exposure of rural residents than those of urban ***_(2.5)exposure peaks mostly occurred during(Accompanied)cooking activities owing to strong *** and resting were the main activities that affected PM_(2.5)exposures of different resident groups,accounting for 60.7%-94.5%of total daily ***,the long duration of sleeping makes it the predominant activity contributing to PM 25 exposure *** is necessary to obtain point-to-point respiratory volume(respiratory rate)data when measuring real-time PM_(2.5)exposure data and incorporate respiratory volume(respiratory rate)into the analysis of PM_(2.5)*** the first time,this study quantified the PM_(2.5)exposure inequality based on a novel method and can provide useful information for further studies on the exposure inequity.

关键词： PM_(2.5)exposure environmental inequity activity pattern urban and rural difference

Tuning interaction strength between CeO_(2) and iridium to promote CO oxidation over Ir/TiO_(2)

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Journal of Rare Earths 2024年第4期42卷 651-659页

作者： Lu Dai Binghua Li Yuhan Peng Xianwei Hao Runquan xuan Hua Huang yiming Bi Liping xu Yanhui Zhang Yun Guo Fangqi du Li Wang Hui Wang technology Center China Tobacco Zhejiang Industrial Co.Ltd.Hangzhou310024China Research Institute of Industrial Catalysis East China University of Science and TechnologyShanghai200237China

The interaction between support and noble metal plays a crucial role in heterogeneous catalysis ***,how to tune metal support interactions to optimize the activity still needs further ***_(2) was introduced to promote CO oxidation ove r Ir/TiO_(2) by adjusting the interaction strength between iridium(Ir)and CeO_(2).The strong interaction between Ir and CeO_(2) blocks CO adsorption and causes low CO oxidation ***,introducing CeO_(2) on Ir/TiO_(2) produces localized interaction between Ir and CeO_(2),which can tune the surface electronic state of Ir,so a"volcano curve"relationship between CO oxidation activity and electronic state is *** amount of CeO_(2) on Ir/TiO_(2)(Ir/Ce_(0.2)Ti)leads to CO complete oxidization at 22℃,and a new pathway for CO oxidation was *** study demonstrates that the utilization of tuning interaction strength between active metal and support is a potential method to increase the catalytic activity.

关键词： CO oxidation CeO_(2) Localized interaction Interaction strength Supported Ir catalysts Rareearths

Technologies and studies of gas exchange in two-stroke aircraft piston engine:A review

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Chinese Journal of Aeronautics 2024年第1期37卷 24-50页

作者： Yu zhou xueyu LI Shuiting DING Shuai ZHAO Kun ZHU Longtao SHAO Farong du Gerui WANG Zheng xu Research Institute of Aero-Engine Beihang UniversityBeijing 100191China Aircraft/Engine Integrated System Safety beijing Key Laboratory Beijing 100191China School of Transportation science and Engineering Beihang UniversityBeijing 100191China Civil Aviation University of china Tianjin 300300China Aero Engine Academy of china Beijing 101304China School of Energy and Power Engineering Beihang UniversityBeijing 100191China Beihang Hangzhou Innovation Institute Yuhang Hangzhou 310052China

The in-cylinder gas exchange process is crucial to the power performance of two-stroke aircraft piston engines,which is easily influenced by complex factors such as high-altitude performance variation and in-cylinder flow *** paper reviews the development history and characteristics of gas exchange types,as well as the current state of theory and the validation methods of gas exchange technology,while also discusses the trends of cutting-edge technologies in the *** paper provides a theoretical foundation for the optimization and engineering design of gas exchange systems and,more importantly,points out that the innovation of gas exchange types,the modification of theoretical models,and the technology of variable airflow organization are the key future research directions in this field.

关键词： Aircraft piston engine Aircraft power systems Gas exchange High-altitude performance In-cylinder flow Two-stroke Unmanned Aerial Vehicles(UAVs)

Behavior of Non-metallic Inclusions in Centrifugal Induction Electroslag Castings

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Journal of University of science and technology beijing 2001年第2期8卷 91-94页

作者： Xichun Chen, Jie Fu, Deguang zhou, Weiguo xu (Metallurgy School, University of science and technology beijing, beijing 100083. china) Univ Sci & Technol beijing Met Sch Beijing 100083 Peoples R China

In order to know the behavior of non-metallic inclusions in centrifugal induction electroslag castings (CIESC), non-metallic inclusions in 5CrMnMo and 4Cr5MoSiV1 were qualitatively and quantitatively analyzed. The largest size of inclusions in the casting and the thermodynamic possibility of TiN precipitation in steel were also calculated. The results show that sulfide inclusions are evenly distributed and the content is low. The amount of oxide inclusions in CIESC: 4Cr5MoSiV1 steel is close to the ESR steel and lower than that in the EAF steel, and there are some differences along radial direction. Nitride inclusions are fine and the diameter of the largest one is 3-1 mum. With the increase of the centrifugal machine's rotational speed, the ratio of round inclusions increases and the ratio of sharp inclusions decreases. According to the experiment and the calculation results, it is pointed out that the largest diameter of non-metallic inclusions in the CIESC 4Cr5MoSiV1 casting is only 6.6 mum, and [N%][Ti%] in 4Cr5MoSiV1 steel should be controlled less than 4.4x 10(-5) in order to further reduce the amount and size of TiN inclusions.

关键词： centrifugal induction electroslag casting non-metallic inclusions 4Cr5MoSiV1 steel 5CrMnMo steel TiN precipitation

Trace Pd alloyed with Au to boost Au/uncalcined TS-1 catalyzed propane hydro-oxidation to acetone

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Nano Research 2024年第8期17卷 7182-7193页

作者： Jinwei Sun Zhihua Zhang Erchuan Yang Wei du Fan Liu Kesheng xu Yuxia Zhong xuezhi duan Xinggui zhou State Key Laboratory of Chemical Engineering School of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China

Selective oxidation of propane to acetone(AC)with H_(2) and O_(2) provides a direct route to convert low-cost propane into valueadded ***,the catalytic activity of conventional Au/Ti-based catalysts is constrained by the high energy barrier for H_(2) ***,uncalcined TS-1 supported Au-Pd bimetallic catalysts were prepared,and the relationship between the active-site structure and corresponding performance in the selective oxidation of propane with H_(2) and O_(2) in the gas phase was systematically *** contrast to the liquid-phase reaction,trace Pd alloyed with Au triggered an increase in both catalytic activity and selectivity,in which Au_(20)-Pd_(1)/TS-1-B catalyst exhibited excellent activity(170 gAC·h^(−1)·kgcat^(−1))and AC selectivity(90.6%),much higher than those of the Au/TS-1-B catalyst(AC formation rate of 100 gAC·h^(−1)·kgcat^(−1)and AC selectivity of 86.3%).It was found that Pd was gradually isolated into monomers with the increase of Au/Pd molar ratio,and the synergy between Pd single atoms and Au improved the catalytic performance via enhancing hydrogen dissociation and modulating the electronic structure of ***,the reaction conditions were optimized based on the kinetics studies and the Au_(20)-Pd_(1)/TS-1-B catalyst exhibited enhanced H_(2) selectivity(45%)and long-term stability(over 130 h).The insights gained here can offer valuable guidance for the design of Au-Pd catalysts applicable to other gas-phase oxidation reactions.

关键词： propane selective oxidation acetone hydrogen dissociation Au-Pd alloy synergy