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Engineering atomic Rb-N configurations to tune radical pathways for highly selective photocatalytic H2O2 synthesis coupled with biomass valorization

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Journal of Energy Chemistry 2025年第1期100卷 215-225页

作者： Jiaye Li Shuang pan Yihuang Chen Qiong Liu College of Chemistry and Materials Engineering Wenzhou University Guangdong Provincial Key Laboratory of Chemical Measurement and Emergency Test Technology (China) Institute of Analysis Guangdong Academy of Sciences (China National Analytical CenterGuangzhou)

Photocatalytic oxygen reduction for hydrogen peroxide （H2O2） synthesis presents a green and costeffective production ***,achieving highly selective H2O2synthesis remains challenging,necessitating precise control over free radical reaction pathways and minimizing undesirable oxidative ***,we report for the visible light-driven simultaneous co-photocatalytic reduction of O2to H2O2and oxidation of biomass using the atomic rubidium-nitride modified carbon nitride（CNRb）.The optimized CNRb catalyst demonstrates a record photoreduction rate of 8.01 mM h-1for H2O2generation and photooxidation rate of 3.75 mM h-1for furfuryl alcohol to furoic acid,achieving a remarkable solar-to-chemical conversion （SCC） efficiency of up to 2.27%.Experimental characterizations and DfT calculation disclosed that the introducing atomic Rb–N configurations allows for the high-selective generation of superoxide radicals while suppressing hydroxyl free radical *** is because the Rb–N serves as the new alternative site to perceive a stronger connection position for O2adsorption and reinforce the capability to extract protons,thereby triggering a high selective redox product *** study holds great potential in precisely regulating reactive radical processes at the atomic level,thereby paving the way for efficient synthesis of H2O2coupled with biomass valorization.

关键词： Atomic economy Radical pathway regulation Rubidium atom coordination Biomass valorization

Analytical solutions of uniform extended dislocations and tractions over a circular area in anisotropic magnetoelectroelastic bimaterials

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Acta Mechanica Sinica 2013年第1期29卷 73-84页

作者： Y.-f. Zhao x.-C. Shang E. pan Dept. of Civil Engineering University of Akron Dept. of Applied Mechanics University of Science and Technology

In this paper, we derive the analytical solutions in a three-dimensional anisotropic magnetoelectroelastic bimaterial space subject to uniform extended dislocations and tractions within a horizontal circular area. By virtue of the Stroh formalism and fourier transformation, the final expression of solutions in the physical domain contains only line integrals over [0, 2π] rather than infinite integrals. As the reduced cases, the half-space and homogeneous full-space solutions can be directly derived from the present solutions. Also, in terms of material domains, the present solutions can be reduced to the piezoelectric, piezomagnetic, purely elastic materials with different symmetries of material prop- erty. To carry out numerical calculations, Gauss quadrature is adopted. In the numerical examples, the effect of different loading locations on the response at the interface is analyzed. It is shown that, when the magnetic traction or electric dislocation is applied, the physical quantities on the interface may not decrease monotonically as the loading area moves away from the interface. The distributions of different in-plane physical quantities on the upper and lower interfaces under various extended horizontal loadings are compared and the differences are discussed. The work presented in this paper can serve as benchmarks for future numerical studies in related research fields.

关键词： Anisotropic bimaterial space. Magnetoelectroe- lastic Extended dislocations Extended tractions Circular loading Analytic solutions

Nano-phase transformation of composite precipitates in multicomponent Al-Mg-Si(-Sc)alloys

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Journal of Materials Science & Technology 2022年第15期110卷 216-226页

作者： S.B.Wang C.f.pan B.Wei x.Zheng Y.x.Lai J.H.Chen Key Laboratory of LCR Materials and Devices of Yunnan Province National Center for International Research on Photoelectric and Energy MaterialsSchool of Materials and EnergyYunnan UniversityKunming 650091China Collaborative Innovation Center of Renewable Energy Materials and Department of Physics Guangxi UniversityNanning 530004China Center for High-Resolution Electron Microscopy College of Materials Science and EngineeringHunan UniversityChangsha 410082China

Sc-addition can significantly enhance the performance of the micro-alloyed Al-Mg-Si-Sc ***,the mechanisms by which the Sc element modifies the microstructure of the alloys are still unknown in many ***,using atomic-scale transmission electron microscopy and atomic-resolution spectroscopy,we have revealed the microstructural differences between two age-hardened Al-0.5Mg-0.4Si(wt.%)alloys with and without *** first significant effect of Sc-addition on the precipitation microstructure of the Al-Mg-Si-Sc alloy is that Sc-atoms may distribute at theβ"-precipitate/Al-matrix interface and therefore accelerate aging kinetics at the initial stage of *** second significant effect of Sc-addition is that in the transition from theβ"-hardened peak-age stage to theβ′-hardened late stage,Sc-atoms can greatly improve the stability of transitionalβ"/B'/β′composite precipitates by entering the B'-substructures and/or locating at the precipitate/Al *** such Sc-atoms effectively suppressβ"toβ'transformation and cross-sectional coarsening of bothβ"and composite precipitates,leading to much finer precipitate needles with smaller diameter but much larger length,as compared with those precipitate needles formed in the alloy without ***,the alloy with Sc-addition exhibits a much better thermal stability than that without Sc.

关键词： Al alloy Strengthening mechanism Phase transition Transmission electron microscopy

Bullous pemphigoid associated with acquired hemophilia A: A case report

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World Journal of Clinical Cases 2025年第4期13卷 28-33页

作者： Su-Ye Hu Meng-Can Li Zi-Jia Hao xu-Ya Chai Pei-Sai Li Yang Liu Li-xia Liu Ying xu pan-pan Yang Ling-E Li Department of Dermatology Shijiazhuang Traditional Chinese Medicine HospitalShijiazhuang 050051Hebei ProvinceChina Graduate School Hebei University of Traditional Chinese MedicineShijiazhuang 050051Hebei ProvinceChina Department of Pathology Shijiazhuang Traditional Chinese Medicine HospitalShijiazhuang 050051Hebei ProvinceChina

BACKGROUND Acquired hemophilia A (AHA) is a rare and potentially severe bleeding disordercaused by circulating autoantibodies against factor Ⅷ (fⅧ). In approximately50% of the patients, the condition is associated with autoimmune diseases,cancers, medication use, pregnancy, and the post-partum period. Bullous pemphigoid(BP) is a chronic autoimmune subepidermal blistering disease associatedwith tissue-bound and circulating autoantibodies against BP antigens 180 (BP180)and 230 (BP230). AHA-associated BP has a high mortality rate;hence, the understandingof this disease must *** SUMMARY A 69-year-old man presented with erythema, blisters, blood blisters, and crustsaccompanied by severe pruritus for more than 20 days, and ecchymosis andswelling on his left upper arm for 3 days. Pathological examination revealed asubepidermal blister that contained eosinophils. Laboratory tests showed that theBP180 autoantibody levels had increased, isolated activated partial thromboplastintime was notably prolonged (115.6 s), and coagulation fⅧ activity wasextremely low (furthermore, the fⅧ inhibitor titer had greatlyincreased (59.2 Bethesda units). Therefore, the patient was diagnosed as having BP associated with AHA, prescribed 0.05% topical halometasone cream, and transferred to a higher-level hospitalfor effective treatment;however, he died after 2 *** AHA associated BP is rare, dangerous, and has a high mortality rate. Therefore, its timely diagnosis and effectivetreatment are necessary.

关键词： Bullous pemphigoid Acquired hemophilia A Acquired hemophilia A factorⅧ Case report

Strengthening mechanisms in magnesium alloys containing ternary Ⅰ,W and LPSO phases

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Journal of Materials Science & Technology 2018年第7期34卷 1110-1118页

作者： N.Tahreen D.f. Zhang f.S. pan x.Q. Jiang D.Y. Li D.L. Chen Department of Mechanical and Industrial Engineering Ryerson University Toronto Ontario MSB 2K3 Canada College of Materials Science and Engineering Chongqing University Chongqing 400045 China National Engineering Research Center for Magnesium Alloys Chongqing University Chongqing 400044 China Advanced Materials Research Center ChongqingAcademy of Science and Technology Chongqing 401123 China faculty of Materials and Energy Southwest University Chongqing 400715 China Department of Chemical and Materials Engineering University of Alberta Alberta T6G 11-19 Canada

This study was aimed at identifying underlying strengthening mechanisms and predicting the yield strength of as-extruded Mg-Zn-Y alloys with varying amounts of yttrium （Y） element. The addition of Y resulted in the formation of ternary 1 （Mg3YZn6）, W （Mg3Y2Zn3） and LPSO （Mg12YZn） phases which subse- quently reinforced alloys ZM31 ＋ 0.3Y, ZM31 ＋ 3.2Y and ZM31 ＋ 6Y, where the value denoted the amount of Y element （in wt%）. Yield strength of the alloys was determined via uniaxial compression testing, and grain size and second-phase particles were characterized using OM and SEM. In-situ high-temperature xRD was performed to determine the coefficient of thermal expansion （CTE）, which was derived to be 1.38 x 10^-5 K^-1 and 2.35 x 10^-5 K^-1 for W and LPSO phases, respectively. The individual strengthening effects in each material were quantified for the first time, including grain refinement, Orowan looping, thermal mismatch, dislocation density, load-bearing, and particle shearing contributions. Grain refinement was one of the major strengthening mechanisms and it was present in all the alloys studied, irrespective of the second-phase particles. Orowan looping and crE mismatch were the predominant strengthening mechanisms in the ZM31＋0.3Y and ZM31 ＋ 3.2Y alloys containing I and W phases, respectively, while load-bearing and second-phase shearing were the salient mechanisms contributing largely to the superior yield strength of the LPSO-reinforced ZM31 ＋ 6Y alloy.2017 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science ＆ Technology.

关键词： Magnesium alloy I-phase W-phase LPSO phase Strengthening mechanism

Hot Deformation and Work Hardening Behavior of an Extruded Mg–Zn–Mn–Y Alloy

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Journal of Materials Science & Technology 2015年第12期31卷 1161-1170页

作者： N.Tahreen D.f.Zhang f.S.pan x.Q.Jiang D.Y.Li D.L.Chen Department of Mechanical and Industrial Engineering Ryerson University College of Materials Science and Engineering Chongqing University National Engineering Research Center for Magnesium Alloys Chongqing University Advanced Materials Research Center Chongqing Academy of Science and Technology faculty of Materials and Energy Southwest University Department of Chemical and Materials Engineering University of Alberta

The aim of this study was to evaluate the strain hardening and hot deformation behavior of asextruded Mg-Zn-Mn （ZM31） magnesium alloy with varying Y contents （0.3, 3.2, and 6 wt%） via compression testing along the extrusion direction at room temperature, 200℃ and 300 ℃. Texture and phases were identified by x-ray diffraction. Alloy ZM31 ＋ 0.3Y consisted of a mixture of fine equiaxed grains and elon- gated grains with 1-phase （Mg3YZno）; alloy ZM31 ＋ 3.2Y contained 1-phase and W-phase （Mg3Y2Zn3）; alloy ZM31 ＋ 6Y had long-period stacking-ordered （LPSO） x-phase （Mg12YZn） and Mg24Y5 particles. With increasing Y content the basal texture became weakened significantly. While alloys ZM31 ＋ 0.3Y and ZM31 ＋ 3.2Y exhibited a skewed true stress-true stain curve with a three-stage strain hardening feature caused by the occurrence of {1072} extension twinning, the true stress-true stain curve of alloy ZM31 ＋ 6Y was normal due to the dislocation slip during compression. With increasing temperature the extent of skewness decreased. While the compressive yield stress, ultimate compressive stress, strain hardening exponent, and hardening capacity all decreased as the temperature increased, the retention of the high- temperature deformation resistance increased with increasing Y content mainly due to the presence of thermally-stable LPSO x-ohase.

关键词： Magnesium alloy Yttrium effect Temperature effect Strain hardening I and W-phase LPSO x-phase

DEGRADATION BEHAVIORS Of NEW TYPE TiV-BASED HYDROGEN STORAGE ELECTRODE ALLOYS

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Acta Metallurgica Sinica(English Letters) 2006年第1期19卷 68-74页

作者： x.Z. Sun Y. f. Zhu Y. Lin R. Li M.x. Gao H. G. pan Department of Materials Science and Engineering Zhejiang University Hangzhou310027 China

The degradation behaviors of the TiV-based multiphase hydrogen storage alloy Ti0.8Zr0.2V3.2Mn0.64 Cr0.96Ni1.2 during electrochemical cycling in alkaline electrolyte have been studied by xRD, SEM, EIS and AES measurements. xRD analysis indicates that the alloy consists of a C14-type Laves phase and a V-based solid solution. The lattice parameters of both phases are increased after discharged with cycling, which indicates that more irreversible hydrogen remains not discharged in the alloy. It shold be responsible for the decrease of discharge capacity. SEM micrographs show that after 10 electrochemical cycles, a large number of cracks can be observed in the alloy, existing mainly in the V-based solid solution phase. Moreover, after 30 cycles, the alloy particles are obviously pulverized due to the larger expansion and shrinkage of cell volumes during hydrogen absorption and desorption, which induces the fast degradation of the TiV-based hydrogen storage alloys. EIS and AES measurements indicate that some passive oxide film has been formed on the surface of alloy electrode, which has higher charge-transfer resistance, lower hydrogen diffusivity, and less electro-catalytic activity. Therefore it can be concluded that the pulverization and oxidation of the alloy are the main factors responsible for the fast degradation of the TiV-hased hydrogen storage alloys.

关键词： metal hydrides hydrogen storage alloy pulverization degradation

Construction of hybrid Z-scheme graphitic C_(3)N_(4)/reduced TiO_(2) microsphere with visible-light-driven photocatalytic activity

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Journal of Materiomics 2018年第3期4卷 238-246页

作者： C.Zhou N.f.Ye x.H.Yan J.J.Wang J.M.pan D.f.Wang Q.Wang J.x.Zu x.N.Cheng School of Materials Science and Engineering Jiangsu UniversityZhenjiang212013JiangsuChina Institute for Advanced Materials Jiangsu UniversityZhenjiang212013JiangsuChina Institute of Green Materials and Metallurgy Jiangsu UniversityZhenjiang 212013JiangsuChina

A novel Z-scheme graphitic C_(3)N_(4)/reduced TiO_(2)microsphere(g-C_(3)N_(4)/r-TiO_(2))has been successfully synthesized by a solvothermal *** as-prepared samples with different contents of g-C_(3)N_(4)were characterized by x-ray diffraction,electron paramagnetic resonance,scanning electron microscope,UV *** reflectance and photoluminescence *** r-TiO_(2)microspheres are aggregated on the surface of g-C_(3)N_(4)sheets in the as-prepared g-C_(3)N_(4)/r-TiO_(2)*** g-C_(3)N_(4)/r-TiO_(2)catalysts show enhanced photocatalytic activity for the degradation of rhodamine B under visible light *** could be attributed to these influences of oxygen vacancy(changing the band gap of TiO_(2)),the large specific surface area(providing much more active sites for photocatalytic reaction),and the synergetic effect between g-C_(3)N_(4)and r-TiO_(2)(promoting the separation for photoinduced electron-hole pairs).Moreover,the Z-scheme carriers transfer mechanism in the photocatalytic process has been discussed through trapping experiments of active *** work demonstrates the strategies of the construction of Z-scheme carriers transfer system,the introduction of oxygen vacancy and structure designing are beneficial to design materials toward solar energy conversion like contaminant degradation.

关键词： TiO_(2) C_(3)N_(4) Oxygen vacancy Z-scheme heterojunction Photocatalytic performance

Novel ternary Ag/CeVO_4/g-C_3N_4 nanocomposite as a highly efficient visible-light-driven photocatalyst

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Journal of Advanced Ceramics 2018年第1期7卷 50-57页

作者： J.REN Y.Z.WU J.M.pan x.H.YAN M.CHEN J.J.WANG D.f.WANG C.ZHOU Q.WANG x.N.CHENG School of Materials Science and Engineering Jiangsu University Institute for Advanced Materials Jiangsu University Institute of Green Materials and Metallurgy Jiangsu University

The CeVO_4/graphitic C_3N_4 composites have exhibited much enhanced photocatalytic property for degrading methylene blue(MB) pollutant under visible light irradiation compared with single-phase g-C_3N_4 or CeVO_4. The composite S5 obtained from an optimized mass ratio(5%) of CeVO_4 to dicyanamide(DCDA) exhibits the highest photocatalytic activity. Here, ternary Ag/CeVO_4/g-C_3N_4 composites denoted as x%Ag/S5 were prepared by an ultrasonic precipitation method to improve the photocatalytic property of S5. The TEM images show that CeVO_4 and Ag nanoparticles are well distributed on the layered g-C_3N_4, which agree well with the xRD results. The UV spectra show that the 7%Ag/S5 sample has the widest absorption range and the enhanced absorption intensity under visible light irradiation. The corresponding band gap of 7%Ag/S5(2.5 eV) is much lower than that of S5(2.65 eV). The corresponding k value of 7%Ag/S5 is much higher than those of g-C_3N_4 and CeVO_4. The degradation experiments for MB solution suggest that the 7%Ag/S5 sample has the optimal photocatalytic performance, which can degrade MB solution completely within 120 min. The enhanced photocatalytic property of the composites is ascribed to not only the effect of heterojunction structure, but also the surface plasma resonance effect of Ag nanoparticles.

关键词： g-C3N4 CeVO4 Ag nanocomposites photocatalytic performance