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Science Bulletin 2024年第13期69卷 2059-2070页

作者： Chuanliang Wei Zhengran Wang Peng Wang xinlu Zhang xuguang An Jinkui feng Baojuan xi Shenglin xiong School of Chemistry and Chemical Engineering School of Materials Science and EngineeringShandong UniversityJinan 250100China School of Mechanical Engineering Chengdu UniversityChengdu 610106China

The practical application of lithium–sulfur(Li–S)batteries is inhibited by the shuttle effect of lithium polysulfides(LiPSs)and slow polysulfide redox kinetics on the S cathode as well as the uncontrollable growth of dendrites on the Li metal ***,both cathode and anode sides must be considered when modifying LiS ***,two-dimensional(2D)ultrathin CoSe_(2)nanobelts are in situ grown on 2D n-doped Mxene nanosheets(CoSe_(2)@n-Mxene)via one-step solvothermal process for the first *** to its unique 2D/2D structure,CoSe_(2)@n-Mxene can be processed to crumpled nanosheets by freeze-drying and flexible and freestanding films by vacuum *** crumpled CoSe_(2)@nMxene nanosheets with abundant active sites and inner spaces can act as S hosts to accelerate polysulfide redox kinetics and suppress the shuttle effect of LiPSs owing to their strong adsorption ability and catalytic conversion effect with ***,the CoSe_(2)@n-Mxene film(CoSe_(2)@nMF)can act as a current collector to promote uniform Li deposition because it contains lithiophilic CoSe_(2)and n *** the systematic effect of CoSe_(2)@n-Mxene on S cathode and Li metal anode,the electrochemical and safety performance of Li–S batteries are ***_(2)@nMF also shows excellent storage performances in flexible energy storage devices.

关键词： Ultrathin CoSe_(2)nanobelts n-doped Mxene nanosheets In situ growth Flexible Mxene-based films Li-S batteries

Effect of Mn content on microstructure and properties of AlCrCuFeMnx high-entropy alloy

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China Foundry 2024年第2期21卷 147-158页

作者： ning Wang Kai Ma Qiu-da Li Yu-dong Yuan Yan-chun Zhao Li feng School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China State Key Laboratory of Advanced Processing and Reuse of nonferrous Metals Lanzhou 730050China CnnC nuclear Power Operation and Management Co. Ltd.Haiyan 314300ZhejiangChina

AlCrCuFeMnx(x=0,0.5,1,1.5,and 2)high-entropy alloys were prepared using the vacuum arc melting *** microstructure and mechanical properties of AlCrCuFeMnxwere analyzed and tested by xRD,SEM,TEM,nanoindentation,and electronic universal *** results indicate that the AlCrCuFeMnxhigh-entropy alloy exhibits a dendritic structure,consisting of dendrites with a BCC structure,interdendrite regions with an FCC structure,and precipitates with an ordered BCC structure that form within the ***(Mn)has a strong affinity for dendritic,interdendritic,and precipitate structures,allowing it to easily enter these *** an increase in Mn content,the size of the precipitated nanoparticles in the dendritic region initially increases and then ***,the area fraction initially decreases and then ***,the alloy’s strength and wear resistance decrease,while its plasticity *** Al Cr Cu Fe Mn1.5alloy boasts excellent mechanical properties,including a hardness of 360 HV and a wear rate of 2.4×10^(-5)mm^(3)·n^(-1)·mm^(-1).It also exhibits impressive yield strength,compressive strength,and deformation rates of 960 MPa,1,700 MPa,and 27.5%,respectively.

关键词： high-entropy alloys microstructure mechanical properties wear resistance strengthening mechanisms

Efficient nitrate electroreduction over Mn-doped Cu catalyst via regulating n-containing intermediates adsorption configuration

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Science China Chemistry 2024年第6期67卷 1969-1975页

作者： Limin Wu Shunhan Jia Libing Zhang Ruhan Wang Jiaqi feng xiaofu Sun Buxing Han Beijing national Laboratory for Molecular Sciences CAS Laboratory of Colloid and Interface and ThermodynamicsCAS Research/Education Center for Excellence in Molecular SciencesCenter for Carbon Neutral ChemistryInstitute of ChemistryChinese Academy of SciencesBeijing100190China School of Chemical Sciences University of Chinese Academy of SciencesBeijing100049China College of Chemical Engineering and Environment China University of PetroleumBeijing102249China Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular EngineeringEast China Normal UniversityShanghai200062China

The electrochemical reduction of nO_(3)^(-)to nH_(3)holds promise for economic and environmental benefits,presenting an energyefficient alternative to the traditional Haber-Bosch ***,challenges exist due to its sluggish kinetics,multiple intermediates,and various reaction *** this study,Mn-doped-Cu catalyst was synthesized and employed for electrochemical nO_(3)^(-)-to-nH_(3)*** doping of Mn into Cu resulted in exceptional performance,achieving a FE of 95.8%and an nH_(3)yield rate of 0.91 mol g^(-1)h^(-1)at-0.6 V in a neutral electrolyte at low nO_(3)^(-)*** experimental studies and theoretical calculations revealed that the Mn dopant enhanced the kinetic rate of nO_(2)~--to-nH_(3)and induced a distinct configuration of**** alteration decreased the energy barrier of*nO-to-*nOH,consequently promoting the conversion of nO_(3)^(-)-to-nH_(3).

关键词： nitrate reduction electrocatalysis ammonia synthesis n-intermediate green chemistry

Removal of pathogenic indicator microorganisms during partial nitrification:the role of free nitrous acid

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Frontiers of Environmental Science & Engineering 2024年第3期18卷 93-102页

作者： Jiaojiao xu xiaotian Chen Rui Tang Jingwei feng Shoujun Yuan Wei Wang Zhen-Hu Hu Anhui Engineering Laboratory of Rural Water Environment and Resource School of Civil EngineeringHefei University of TechnologyHefei 230009China Hefei 168 High School Hefei 230025China Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power Shanghai University of Electric PowerShanghai 200090China

Digested wastewater contains pathogenic microorganisms and high ammonia concentrations,which can pose a potential risk to public *** removal of pathogens and nitrogen is crucial for the post-treatment of digested *** nitrification-anammox is an energy-saving nitrogen removal *** nitrous acid(FnA),an intermediate product of partial nitrification,has the potential to inactivate ***,the efficiency and mechanisms of FnA-related inactivation in pathogens during partial nitrification remains *** this study,Enterococcus and Escherichia coli(***)were selected to investigate the efficiency and mechanisms of FnA-related inactivation in partial nitrification *** results revealed that 83%±13%and 59%±27%of *** and Enterococcus were removed,respectively,in partial nitrification process at FnA concentrations of 0.023−0.028 mg/*** the concentration of FnA increased from 0 to 0.5 mg/L,the inactivation efficiencies of *** and Enterococcus increased from 0 to 99.9%and 89.9%,*** exhibited a higher resistance to FnA attack compared to ***.3D-laser scanning microscopy(3D-LSM)and scanning electron microscopy(SEM)revealed that FnA exposure caused the surface collapse of *** and Enterococcus,as well as visible pore formation on the surface of *** cells.4',6-Diamidino-2-phenylindole dihydrochloride n-hydrate(DAPI)/propidium iodide(PI)and biomolecule leakage confirmed that inactivation of *** and Enterococcus occurred due to breakdown of cell walls and cell *** findings indicate that partial nitrification process can be used for the removal of residual pathogenic microorganisms.

关键词： Partial nitrification Free nitrous acid Pathogenic indicator microorganism Inactivation Cell structure

Extended light absorption and accelerated charge migration in ultrathin twisted carbon nitride nanoplates for efficient solar hydrogen production

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Science China Chemistry 2024年第7期67卷 2215-2223页

作者： Yanmin Zou Shiyao Li Dandan Zheng Jianyong feng Sibo Wang Yidong Hou Guigang Zhang State Key Laboratory of Photocatalysis on Energy and Environment College of ChemistryFuzhou UniversityFuzhou 350108China College of Environment and Safety Engineering Fuzhou UniversityFuzhou 350108China Collaborative Innovation Center of Advanced Microstructures National Laboratory of Solid State MicrostructuresCollege of Engineering and Applied SciencesNanjing UniversityNanjing 210093China

Polymeric carbon nitride has been widely developed as a promising photocatalyst for solar hydrogen production via photocatalytic water ***,pristine carbon nitride prepared by traditional solid-state polymerization usually encounters issues such as rapid carrier recombination and insufficient absorption of visible light below 460 ***,poly(heptazine imide)with a distinctive nanoplate structure was synthesized in a binary molten salt of naCl–CaCl_(2).The salt template allows the formation of the thin nanoplate structure,which promotes the charge separation and ***,the intercalation of Ca^(2+)ions between the conjugated layers endows the activation of n–π*electron transition due to the distortion of in-plane heptazine ***,the optimized poly(heptazine imide)nanoplates achieve an apparent quantum efficiency of up to 17.3%at 500 nm for photocatalytic hydrogen production from *** work shares new idea for rational control of the optical absorption and charge carrier dynamics of poly(heptazine imide).

关键词： photocatalysis poly heptazine imide nanoplates ion intercalation hydrogen production

Pd/n-doped carbon dots@dendritic mesoporous silica nanospheres:A highly efficient catalyst for the hydrogenation of 4-nitrophenol

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nano Research 2024年第9期17卷 7967-7974页

作者： Weiruo Liu Yanbin Zhu Jiwei Wang Haisong feng Yunpu Zhai Wei Li Dongyuan Zhao College of Chemistry Zhengzhou University100 Kexue AvenueZhengzhou 450001China Department of Chemistry Laboratory of Advanced MaterialsShanghai Key Laboratory of Molecular Catalysis and Innovative Materialsand State Key Laboratory of Molecular Engineering of PolymersFudan UniversityShanghai 200433China State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China

Highly dispersed Pd/n-doped carbon dots(Pd/nCDs)were successfully immobilized in the mesoporous channels of amino-functionalized dendritic mesoporous silica nanospheres(nMS).The synthesized Pd/nCDs@nMS catalyst exhibits outstanding performance in the catalytic reduction of 4-nitrophenol(4-nP),achieving a turnover frequency of 1461.8 mol·molPd^(-1)·h^(-1),with the conversion rate remaining above 80%after 11 *** and density functional theory calculations reveal that the nCDs significantly affect the electronic structure of Pd nanoparticles,leading to changes in the energy barriers for the adsorption of 4-nP at the Pd sites and the conversion of 4-nP reaction intermediates,which is a key factor contributing to the catalytic *** study offers a new strategy for synthesizing carbon-dot-modified metal-based catalysts.

关键词： palladium nanoparticles nitrogen-doped carbon dots dendritic mesoporous silica catalytic hydrogenation 4-nitrophenol reduction

Ionic liquids inhibit the dynamic transition fromα-helices toβ-sheets in peptides

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Fundamental Research 2024年第4期4卷 777-784页

作者： Ju Liu Yanlei Wang feng Huo Hongyan He Beijing Key Laboratory of Ionic Liquids Clean Process State Key Laboratory of Mesoscience and EngineeringCAS Key Laboratory of Green Process and EngineeringInstituteof Process EngineeringChineseAcademyof SciencesBeijing100190China Longzihu new Energy Laboratory Zhengzhou Institute of Emerging Industrial TechnologyHenan UniversityZhengzhou 450000China University of Chinese Academyof Sciences Beijing100049China

Abnormalities in the transition betweenα-helices andβ-sheets(α-βtransition)may lead to devastating neurodegenerative diseases,such as Parkinson's syndrome and Alzheimer's *** liquids(ILs)are potential drugs for targeted therapies against these diseases because of their excellent bioactivity and designability of ***,the mechanism through which ILs regulate the aα-βtransition remains ***,a combination of GPU-accelerated microsecond molecular dynamics simulations,correlation analysis,and machine learning was used to probe the dynamicalα-βtransition process induced by ILs of 1-alkyl-3-methylimidazolium chloride([C_(n)mim]cl)and its molecular ***,the cation of [C_(n)mim]+in ILs can spontaneously insert into the peptides as free ions(n≤10)and clusters(n≥11).Such insertion can significantly inhibit theα-β,transition and the inhibiting ability for the clusters is more significant than that of free ions,where[Ciomim]+and[C_(12)mim]+can reduce the maximumβ-sheet content of the peptide by 18.5% and 44.9%,***,the correlation analysis and machine learning method were used to develop a predictive model accounting for the influencing factors on theα-βtransition,which could accurately predict the effect of ILs on theα-β***,these quantitative results may not only deepen the understanding of the role of ILs in theα-βtransition but also guide the development of the IL-based treatments for related diseases.

关键词： α-βtransition Moleculardynamics simulation lonic liquids Machine learning Membrane channel protein

Mechanism of local solidification time variations with melt rate during vacuum arc remelting process of 8Cr4Mo4V high-strength steel

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Journal of Iron and Steel Research International 2024年第2期31卷 377-388页

作者： Tao Pan Hong-chun Zhu Zhou-hua Jiang Hua-bing Li Rui Zhang Hao feng School of Metallurgy Northeastern UniversityShenyang110819LiaoningChina State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang110819LiaoningChina

A 2D axisymmetric numerical model was established to investigate the variations of molten pool with different melt rates during the vacuum arc remelting of 8Cr4Mo4V high-strength steel,and the ingot growth was simulated by dynamic mesh *** results show that as the ingot grows,the molten pool profile changes from shallow and flat to V-shaped,and both the molten pool depth and the mushy width ***,the variation of both the molten pool shape and the mushy width melt rate is clarified by the thermal equilibrium *** melt rate increases,both the molten pool depth and the mushy width *** is caused by the increment in sensible heat stored in the ingot due to the limitation of the cooling capacity of the *** nonlinear increment in sensible heat leads to a nonlinear increase in the mushy *** addition,as melt rate increases,the local solidification time(LST)of ingot decreases obviously at first and then *** melt rate is controlled in a suitable range,LST is the lowest and the secondary dendrite arm spacing of the ingot is the smallest,which can effectively improve the compactness degree of 8Cr4Mo4V high-strength steel.

关键词： 8Cr4Mo4V high-strength steel Vacuum arc remelting process Melt rate Molten pool Local solidification time

Comparing the temperature sensitivity of organic matter decomposition in oxic and oxygen-deprived soils

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Soil Ecology Letters 2024年第1期6卷 29-32页

作者： Zhenhui Jiang xin Wang Ting Liu xiaojuan feng State Key Laboratory of Vegetation and Environmental Change Institute of BotanyChinese Academy of SciencesBeiing 100093China University of Chinese Academy of Sciences Bejing 100049China State Key Laboratory of Subtropical Silviculture Zhejiang A&F UniversityHangzhou 311300China Henan Key Laboratory of Ecological Environment Protection and Restoration of Yellow River Basin Yellow River Institute of Hydraulic ResearchZhengzhou 450003China

no consistent variation was found in soil respiration Q10 under various O2 *** C quality had a strong effect on Q10 in oxic soils.n limitation had a large impact on Q10 in soils under O2 *** studies on the temperature sensitivity(Q10)of soil organic matter(SOM)decomposition mainly focus on aerobic ***,varia-tions and determinants of Q10 in oxygen(O2)-deprived soils remain *** we incubated three grassland soils under oxic,suboxic,and anoxic conditions subjected to varying temperatures to compare variations in Q10 in relation to changing *** consistent variation was found in Q10 under various O2 *** analysis of edaphic properties demon-strated that substrate carbon quality showed a strong influence on Q10 in oxic soils,whereas nitrogen limitation played a more important role in suboxic and anoxic *** results suggest that substrate carbon quality and nitrogen limitation may play roles of varying importance in determining the temperature sensitivity of SOM decomposition under various O2 conditions.

关键词： oxygen-limited conditions temperature sensitivity soil respiration carbon substrate nitrogen limitation

Metabolites isolated from Penicillium HDS-Z-1E, an endophytic fungal strain isolated from Taxus cuspidata and their activation effect of catalase

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Chinese Herbal Medicines 2024年第2期16卷 227-230页

作者： Chuan Tang Rui Gao xiaoyuan Tang Yu Zhang Weixing feng Baomin feng xuan Lu College of Life and Health Dalian UniversityDalian 116622China

Objective:To study the compounds isolated from Penicillium HDS-Z-1E,an endophytic fungal strain isolated from Taxus cuspidata and their activation effect of catalase(CAT).Methods:The chemical constituents were isolated from Penicillium HDS-Z-1E,by using silica gel,Sephadex LH-20 and *** structural elucidations of five metabolites were elucidated on the basis of spectroscopic including 1 H-nMR,13C-nMR,HMBC and *** activation sites of catalase have been investigated by molecular ***:Five metabolites,compounds(1–5)were isolated from Penicillium HDS-Z-1E and identified as 4-hydroxy-4-methyltetrahydro-2H-pyran-2-one(1),4-hydroxymethyl-5,6-dihydro-pyran-2-one(2),5,6-dihydro-2-oxo-2H-pyran-4-carboxylic(3),n-acetyl-hydrazinobenzoic acid(4),and methyl 2-(2,5-dihydroxyphenyl)acetate(5).Conclusion:Compound 3 is a new *** 3 and 4 may have potential activators of catalase,providing a theoretical basis for the development of CAT activators.

关键词： catalase activators 5,6-dihydro-2-oxo-2H-pyran-4-carboxylic molecular simulation penicillium Taxus cuspidata Sieb.et Zucc