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Recent progress on photoactive nonprecious transition-metal complexes

Science China Chemistry 2025年第1期 46-95页

作者： zhong-Liang Gong Hong-Jie Zhang Yan Cheng Jianxun Liu Yuhan Ai Yaqin Li Zhihui Feng Qiong Zhang Shaolong Gong Yong Chen Chang-Jiang Yao Yuan-Yuan Zhu Liang-Jin Xu Yu-wu zhong CAS Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences State Key Laboratory of Structural Cemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences School of Chemistry and Chemical Engineering Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology State Key Laboratory of Explosion Science and Safety Protection School of Mechatronical Engineering Beijing Institute of Technology College of Chemistry and Molecular Sciences Hubei Key Lab on Organic and Polymeric Optoelectronic Materials Wuhan University School of Chemistry and Chemical Engineering Anhui University Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

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Handedness-inverted polymorphic helical assembly and circularly polarized luminescence of chiral platinum complexes

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Science China Chemistry 2021年第5期64卷 788-799页

作者： zhong-Liang Gong Yu-wu zhong Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of PhotochemistryCAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of Chemical Sciences University of Chinese Academy of SciencesBeijing 100049China

Circularly polarized luminescence(CPL)materials have potential applications in three-dimensional(3D)displays,quantum encryption,and optical *** development of single-component CPL materials with polymorphic assembly and handedness inversion remains a significant ***,we present the access of such materials by controlling the underlying assembly pathway of well-designed chiral emitters.A pair of enantiomeric platinum complexes(R)-1 and(S)-1 decorated with a chiralα-methylbenzyl isocyanide ligand were *** using the mixed-solvent(THF/n-hexane,THF=tetrahydrofuran)or high-concentration condition,these complexes were found to assemble via a cooperative or isodesmic pathway with significantly enhanced yellow or red emission,*** aggregate samples obtained via these conditions show efficient CPL(dissymmery factor|glum|>0.02,emission quantum yieldΦ>20%).Interestingly,different assembly pathway leads to helical nanoribbons or nanofibers with opposite handedness from the complex with the same molecular *** has been unambiguously and consistently manifested by circular dichroism and CPL spectral analysis and transmission electron,scanning electron,and atomic force microscope *** work demonstrates an appealing example of constructing polymorphic helical architectures with highly efficient CPL and inverted handedness thanks to the excellent assembly and emission of platinum complexes.

关键词： self-assembly nanostructures circularly polarized luminescence chiral materials platinum complexes

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Iterative Learning Disturbance Observer Based Attitude Stabilization of Flexible Spacecraft Subject to Complex Disturbances and Measurement Noises

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IEEE/CAA Journal of Automatica Sinica 2021年第9期8卷 1576-1587页

作者： Tongfu He zhong wu School of Instrumentation and Optoelectronics Engineering Beihang UniversityBeijing 100191China

To realize high-precision attitude stabilization of a flexible spacecraft in the presence of complex disturbances and measurement noises,an iterative learning disturbance observer(ILDO)is presented in this ***,a dynamic model of disturbance is built by augmenting the integral of the lumped disturbance as a *** on it,ILDO is designed by introducing iterative learning ***,comparative analyses of ILDO and traditional disturbance observers are carried out in frequency *** demonstrates that ILDO combines the advantages of high accuracy in disturbance estimation and favorable robustness to measurement *** that,an ILDO based composite controller is designed to stabilize the spacecraft ***,the effectiveness of the proposed control scheme is verified by simulations.

关键词： Disturbance observer iterative learning measure-ment noise spacecraft attitude control

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Urea-bridged diferrocene: structural, electrochemical, and spectroelectrochemical studies

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Science China Chemistry 2015年第9期58卷 1444-1450页

作者： zhong-Liang Gong Yu-wu zhong Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Photochemistry Institute of Chemistry Chinese Academy of Sciences

Urea-bridged diferrocene derivatives N,N?-diferrocenylurea(1) and N,N?-dimethyl-N,N?-diferrocenylurea(2) were prepared and characterized. Single-crystal X-ray analysis shows that Compound 1 has a trans-trans linear conformation whereas Compound 2 has a trans-cis conformation. Both compounds display two consecutive redox couples with, respectively, E1/2 of +0.29 and +0.42 V vs. Ag/Ag Cl for 1 and +0.31 and +0.50 V for 2. Spectroelectrochemical studies show the presence of distinct intervalence charge transfer(IVCT) transitions for the one-electron-oxidized mixed-valent Compound 1+, with an estimated electronic coupling parameter of 190 cm?1. By contrast, the one-electron-oxidized Compound 2+ shows much weaker IVCT transitions.

关键词： mixed-valent compounds ferrocene electrochemistry urea spectroelectrochemistry

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Photofunction-Directed Coordination Molecular Engineering

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Chinese Journal of Chemistry 2021年第3期39卷 543-549页

作者： Yu-wu zhong Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of PhotochemistryCAS Research/Education Center for Excellence in Molecular SciencesInstitute of ChemistryChinese Academy of SciencesBeijing 100190China School of Chemical Sciences University of Chinese Academy of SciencesBejjing 100049China

Molecular engineering has emerged as a highly interdisciplinary field of study on function-directed molecular design,material synthesis,and property optimization,accompanied by a deep understanding of the structure-property *** this review,our recent progress on the design and preparations of photofunctional metal complexes and related materials is summarized from the perspective of coordination molecular *** particular,a series of cyclometalated diruthenium complexes with near-infrared(NIR)electrochromic property have been synthesized by engineering the bridging ligand structures.A group of ruthenium-amine conjugated complexes with multistage NIR electrochromism are obtained on the basis of a multicenter *** engineering the ligand structures,a series of new ruthenium and platinum complexes are synthesized to show switchable luminescence in response to various *** addition,photoluminescent ruthenium,iridium,and platinum complexes are assembled to afford micro/nanocrystals with well-defined morphology and luminescent properties.

关键词： Photochemistry Photophysics Transitional metals Metal-metal interactions Conjugation Luminescence

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Six-DOF trajectory optimization for reusable launch vehicles via Gauss pseudospectral method

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Journal of Systems Engineering and Electronics 2016年第2期27卷 434-441页

作者： Zhen Wang zhong wu School of Instrumentation Science and Optoelectronics Engineering Beihang UniversityBeijing 100191China China Institute of Marine Technology&Economy Beijing 100081China

To be close to the practical flight process and increase the precision of optimal trajectory, a six-degree-offreedom（6-DOF） trajectory is optimized for the reusable launch vehicle（RLV） using the Gauss pseudospectral method（GPM）. Different from the traditional trajectory optimization problem which generally considers the RLV as a point mass, the coupling between translational dynamics and rotational dynamics is taken into account. An optimization problem is formulated to minimize a performance index subject to 6-DOF equations of motion, including translational and rotational dynamics. A two-step optimal strategy is then introduced to reduce the large calculations caused by multiple variables and convergence confinement in 6-DOF trajectory optimization. The simulation results demonstrate that the 6-DOF trajectory optimal strategy for RLV is feasible.

关键词： reusable launch vehicle(RLV) trajectory optimization Gauss pseudospectral method(GPM)

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Modification of FGD gypsum in hydrothermal mixed salt solution

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Journal of Environmental Sciences 2006年第1期18卷 170-175页

作者： wu Xiao-qin wu zhong-biao Department of Environmental Engineering Zhejiang University Hangzhou 310027 China Department of Chemical Engineering Wuhan University of Science and Technology Wuhan 430081 China

A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.

关键词： FGD gypsum modification hydrothermal mixed salt solution atmospheric pressure

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Laboratory and field evaluation of asphalt pavement surface friction resistance

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Frontiers of Structural and Civil Engineering 2018年第3期12卷 372-381页

作者： zhong wu Chris ABADIE Louisiana Transportation Research Center 4101 Gourrier Avenue Baton Rouge LA 70808 USA Louisiana Department of Transportation and Development 5080 Florida Blvd Baton Rouge LA 70806 USA

Pavement surface friction is a significant factor for driving safety and plays a critical role in reducing wet- pavement crashes. However, the current asphalt mixture design procedure does not directly consider friction as a requirement. The objective of this study was to develop a surface friction prediction model that can be used during a wearing course mixture design. To achieve the objective, an experimental study was conducted on the frictional characteristics of typical wearing course mixtures in Louisiana. Twelve wearing course mixtures including dense-graded and open-graded mixes with different combinations of aggregate sources were evaluated in laboratory using an accelerated polishing and testing procedure considering both micro- and macro texture properties. In addition, the surface frictional properties of asphalt mixtures were measured on twenty-two selected asphalt pavement sections using different in situ devices including Dynamic Friction Tester （DFT）, Circular Texture Meter （CTM）, and Lock-Wheel Skid Trailer （LWST）. The results have led to develop a procedure for predicting pavement end-of-life skid resistance based on the aggregate blend polish stone value, gradation parameters, and traffic, which is suited in checking whether the selected aggregates in a wearing course mix design would meet field friction requirements under a certain design traffic polishing.

关键词： friction skid resistance polishing PSV LWST micro-texture macro-texture

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Quantum Creation of a Schwarzschild-de Sitter Black Hole

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Chinese Physics Letters 1997年第4期14卷 317-320页

作者： wu zhong-chao Department of Physics Beijing Normal UniversityBeijing 100875

Using the Hartle-Hawking no-boundary proposal for the wave function of the universe,we can study the wave function and probability of a single Schwarzschild-de Sitter black hole created at the birth of the *** black hole originates from a gravitational instanton with conical *** probability of a black hole creation is the exponential of one quarter of the sum of areas of the black hole and cosmological *** quarter of this sum is the total entropy of the universe.

关键词： universe horizon gravitational

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Black Hole Creation at the Birth of the Universe

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Chinese Physics Letters 2000年第2期17卷 154-156页

作者： wu zhong-Chao Department of Physics Beijing Normal UniversityBeijing 100875

We study the quantum creation of black hole pairs in the (anti-)de Sitter space background. These black hole pairs in the Kerr-Newman family are created from constrained instantons. At the Wentzel-Kramers-Brillouin level, for the chargeless and nonrotating case, the relative creation probability is the exponential of (the negative of) the entropy of the universe. Also for the remaining cases of the family, the creation probability is the exponential of (the negative of) one quarter of the sum of the inner and outer black hole horizon areas. In the absence of a general no-boundary proposal for open universes, we treat the creations of the closed and the open universes in the same way.

关键词： universe horizon black

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