检索结果-南通市图书馆

Numerical simulation of granular silicon growth and silicon fines formation process in polysilicon fluidized bed

在线全文

学校读者我要写书评

暂无评论

Particuology 2024年第4期87卷 74-86页

作者： Guangkai Gu Guoqiang Lv wenhui Ma Shanlin Du Boqiang Fu Faculty of Metallurgical and Energy Engineering Kunming University of Science and TechnologyKunming 650093China State Key Laboratory of Complex Nonferrous Metal Resources Cleaning Utilization in Yunnan Province Kunming 650093China

Operating conditions strongly affect the yield and quality of polysilicon in a polysilicon fluidized bed.In this study,a new model of polysilicon fluidized bed was established using the Euler-Euler model coupled with population balance model(PBM),which was combined with fluid flow,heat,and mass transfer models,while considering the scavenging effect of silicon fines.The effects of different operating conditions on the deposition and formation rates of silicon fines were investigated.Results show that the model can correctly describe the particle growth process in the fluidized bed of polysilicon.The silicon fines and the interphase velocity difference show"N"-and"M"-shaped distributions along the axial direction,respectively.The particle temperature and concentration near the wall are higher than those in the central region.The decomposition of silane in the bottom region of the bed is dominated by het-erogeneous deposition.The scavenging of silicon fines occurs in the dilute-phase region.The effects of operating conditions,i.***.inlet gas temperature,silane composition,and gas velocity,on the reactor performance were also explored comprehensively.Increasing the inlet gas composition and velocity enhances the formation rates of solid silicon and fines.Increasing the inlet gas temperature promotes the growth of solid silicon and inhibits the formation of silicon fines.High fluidization ratio,low inlet silane concentration,and high inlet gas temperature enhance the selectivity of silicon growth.

关键词： Polysilicon fluidized bed Particle growth Fines CFD Population balance model(PBM)

Insights into Nano-and Micro-Structured Scaffolds for Advanced Electrochemical Energy Storage

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano-Micro Letters 2024年第7期16卷 187-230页

作者： Jiajia Qiu Yu Duan Shaoyuan Li Huaping Zhao wenhui Ma Weidong Shi Yong Lei Fachgebiet Angewandte Nanophysik Institut Für Physik and IMN MacroNanoTechnische Universit.t Ilmenau98693 IlmenauGermany Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization Faculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093People’s Republic of China School of Chemistry and Chemical Engineering Jiangsu UniversityZhenjiang 212013People’s Republic of China School of Science and Technology Pu’er UniversityPu’er 665000People’s Republic of China

Adopting a nano-and micro-structuring approach to fully unleashing the genuine potential of electrode active material benefits in-depth understandings and research progress toward higher energy density electrochemical energy stor-age devices at all technology readiness levels.Due to various challenging issues,especially limited stability,nano-and micro-structured(NMS)electrodes undergo fast electrochemical performance degradation.The emerging NMS scaffold design is a pivotal aspect of many electrodes as it endows them with both robustness and electrochemical performance enhancement,even though it only occupies comple-mentary and facilitating components for the main mechanism.However,extensive efforts are urgently needed toward optimizing the stereoscopic geometrical design of NMS scaffolds to minimize the volume ratio and maximize their functionality to fulfill the ever-increasing dependency and desire for energy power source supplies.This review will aim at highlighting these NMS scaffold design strategies,summariz-ing their corresponding strengths and challenges,and thereby outlining the potential solutions to resolve these challenges,design principles,and key perspectives for future research in this field.Therefore,this review will be one of the earliest reviews from this viewpoint.

关键词： Nano-and micro-structured Interconnected porous Scaffolds Electrode design Electrochemical energy storage

Inhibitory Effect of Vibrio neocaledinocus sp. and Pseudoalteromonas piscicida Dual-Species Biofilms on the Corrosion of Carbon Steel

在线全文

学校读者我要写书评

暂无评论

Acta Metallurgica Sinica(English Letters) 2022年第4期35卷 551-562页

作者： Masoumeh Moradi Jianlin Li wenhui liu Dake Xu Fuhui Wang Shenyang National Laboratory for Materials Science Northeastern UniversityShenyang 110819China Key Laboratory for Anisotrotropy and Texture of Materials(Ministry of Education) School of Materials Science and EngineeringNortheastern UniversityShenyang 110819China

Multi-species biofilms are found in various bacterial habitats and have industrial relevance. These complex bacterial communities have synergetic effects, unlike a single species. Therefore, it is critical to evaluate these complex communities as a whole. Here, the inhibitory eff ect of single-and dual-species biofilms of Vibrio neocaledinocus sp. and Pseudoalteromonas piscicida for A36 carbon steel corrosion was investigated. The results demonstrated that the synergistic interactions of the monoculture increased the overall biomass production of the dual-species biofilm, but the growth rate was reduced in the presence of the dual-species culture due to a lack of nutrients. Field emission scanning electron microscopy images also confirmed the development of biofilms—they became more homogenized via exposure time in both the mono-and dual-species cultures. The corrosion resistance of A36 carbon steel positively increased because of the dual-species interactions. This reached the highest value after four weeks of exposure. The highest corrosion inhibition e fficiency of 99.8% was achieved in the dual-species cultures. Microbial community analysis revealed the high relative abundance of Pseudoalteromonas piscicida during the initial days of exposure, demonstrating the dominant role of this bacterium in the biofilm structure.

关键词： Dual-species biofilm Steel alloys Corrosion inhibitory Electrochemical analysis Cooperative interaction

Accumulation mechanism of mantle-derived helium resources in petroliferous basins, eastern China

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2022年第12期65卷 2322-2334页

作者： Xiaofeng WANG Quanyou liu wenhui liu Dongdong ZHANG Xiaofu LI Dong ZHAO State Key Laboratory of Continental Dynamics Department of GeologyNorthwest UniversityXi’an 710069China State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing 100083China Institute of Energy Peking UniversityBeijing 100871China Petroleum Exploration and Production Research Institute SINOPECBeijing 100083China

A series of marginal-sea basins and fault-depression basins were formed in eastern China under the background of subduction of the West Pacific plate.Different types of helium-rich natural gas reservoirs(He>1000 ppm,1 ppm=1μmol mol^(-1))have been found in these basins:helium-rich CO_(2)gas reservoirs,helium-rich N_(2)gas reservoirs,and helium-rich hydrocarbon gas reservoirs.Based on the analysis of gas geochemical data,the source and accumulation mechanism of helium in these heliumrich natural gas reservoirs were discussed.Helium-rich natural gas has relatively high 3He/4He ratios(0.88-4.91 Ra,average 2.82 Ra).The ^(3)He/^(4)He ratio characteristics of mantle xenoliths and mantle-derived CO_(2)gas reservoirs indicate that the helium in these helium-rich natural gas reservoirs is mainly mantle-derived(>70%).The original mantle volatile is mainly CO_(2)with a low helium concentration(Helium in the gas reservoir is mainly related to the dissolution and mineralization of CO_(2).During this process,the CO_(2)/3He ratio decreases from 2×10^(9)to approximately 2×10^(6).As CO_(2)dissolves and mineralizes,the concentration of conservative gases(He and N_(2))increases in the remaining CO_(2)gas proportionally to the loss of CO_(2).Large amounts of carbonate minerals,such as dawsonite,which are relatively enriched in 13C,are found in CO_(2)reservoirs in eastern China.The relative enrichment of^(12)C in residual CO_(2)gas is important evidence of the dissolution and mineralization of CO_(2).The relative abundance of mantle-derived helium and N_(2)gas increases thousands of times during the dissolution and mineralization of CO_(2),which is the main accumulation mechanism of mantle-derived helium-rich CO_(2)gas reservoirs and helium-rich N_(2)gas reservoirs.Helium-rich gas from the mantle is mixed with alkane gas generated by organic matter in the sedimentary basin to form helium-rich hydrocarbon gas reservoirs.

关键词： Mantle-derived helium ^(3)He/4He ratio,Helium resources,Helium-rich natural gas,Accumulation mechanism

Unveiling the mechanical response and accommodation mechanism of pre-rolled AZ31 magnesium alloy under high-speed impact loading

在线全文

学校读者我要写书评

暂无评论

Journal of Magnesium and Alloys 2022年第4期10卷 1096-1108页

作者： Xiao liu Hui Yang Biwu Zhu Yuanzhi Wu wenhui liu Changping Tang Key Laboratory of High Temperature Wear Resistant Materials Preparation Technology of Hunan Province Hunan University of Science and TechnologyXiangtanHunan 411201China Research Institute of Automobile Parts Technology Hunan Institute of TechnologyHengyangHunan 421002China

Split Hopkinson pressure bar(SHPB)tests were conducted on pre-rolled AZ31 magnesium alloy at 150–350℃ with strain rates of 2150s-1,3430s^(-1) and 4160s-1.The mechanical response,microstructural evolution and accommodation mechanism of the pre-rolled AZ31 magnesium alloy under high-speed impact loading were investigated.The twin and shear band are prevailing at low temperature,and the coexistence of twins and recrystallized grains is the dominant microstructure at medium temperature,while at high temperature,dynamic recrystallization(DRX)is almost complete.The increment of temperature reduces the critical condition difference between twinning and DRX,and the recrystallized temperature decreases with increasing strain rate.The mechanical response is related to the competition among the shear band strengthen,the twin strengthen and the fine grain strengthen and determined by the prevailing grain structure.The fine grain strengthen could compensate soften caused by the temperature increase and the reduction of twin and shear band.During high-speed deformation,different twin variants,introduced by pre-rolling,induce different deformation mechanism to accommodate plastic deformation and are in favor for non-basal slip.At low temperature,the high-speed deformation is achieved by twinning,dislocation slip and the following deformation shear band at different deformation stages.At high temperature,the high-speed deformation is realized by twinning and dislocation slip of early deformation stage,transition shear band of medium deformation stage and DRX of final deformation stage.

关键词： Mechanical response Pre-twinning Accommodation mechanism Pre-rolled AZ31 magnesium alloy High-speed impact loading

CircPMS1 promotes proliferation of pulmonary artery smooth muscle cells,pulmonary microvascular endothelial cells,and pericytes under hypoxia

在线全文

学校读者我要写书评

暂无评论

Animal Models and Experimental Medicine 2024年第3期7卷 310-323页

作者： Xiaoyi Hu Shang Wang Hui Zhao Yaqin Wei Ruowang Duan Rong Jiang wenhui Wu Qinhua Zhao Sugang Gong Lan Wang Jinming liu Ping Yuan Department of Cardio-Pulmonary Circulation Shanghai Pulmonary HospitalSchool of MedicineTongji UniversityShanghaiChina Institute of Bismuth Science University of Shanghai for Science and TechnologyShanghaiChina Department of Geriatrics Shanghai Institute of GeriatricsHuadong HospitalFudan UniversityShanghaiChina Department of Anesthesiology Shanghai Pulmonary HospitalSchool of MedicineTongji UniversityShanghaiChina

Background:Circular RNAs(circRNAs)have been recognized as significant regulators of pulmonary hypertension(PH);however,the differential expression and function of circRNAs in different vascular cells under hypoxia remain unknown.Here,we identified co-differentially expressed circRNAs and determined their putative roles in the proliferation of pulmonary artery smooth muscle cells(PASMCs),pulmonary microvascular endothelial cells(PMECs),and pericytes(PCs)under hypoxia.Methods:Whole transcriptome sequencing was performed to analyze the differential expression of circRNAs in three different vascular cell types.Bioinformatic analysis was used to predict their putative biological function.Quantitative real-time polymerase chain reaction,Cell Counting Kit-8,and EdU Cell Proliferation assays were carried out to determine the role of circular postmeiotic segregation 1(circPMS1)as well as its potential sponge mechanism in PASMCs,PMECs,and PCs.Results:PASMCs,PMECs,and PCs exhibited 16,99,and 31 differentially expressed circRNAs under hypoxia,respectively.CircPMS1 was upregulated in PASMCs,PMECs,and PCs under hypoxia and enhanced the proliferation of vascular cells.CircPMS1may upregulate DEP domain containing 1(DEPDC1)and RNA polymerase II subunit D expression by targeting microRNA-432-5p(miR-432-5p)in PASMCs,upregulate MAX interactor 1(MXI1)expression by targeting miR-433-3p in PMECs,and upregulate zinc finger AN1-type containing 5(ZFAND5)expression by targeting miR-3613-5p in PCs.Conclusions:Our results suggest that circPMS1 promotes cell proliferation through the miR-432-5p/DEPDC1 or miR-432-5p/POL2D axis in PASMCs,through the miR-433-3p/MXI1 axis in PMECs,and through the miR-3613-5p/ZFAND5 axis in PCs,which provides putative targets for the early diagnosis and treatment of PH.

关键词： circular postmeiotic segregation 1 circular RNAs hypoxia pulmonary hypertension vascular cells

Two material removal modes in chemical mechanical polishing:mechanical plowing vs.chemical bonding

在线全文

学校读者我要写书评

暂无评论

Friction 2024年第5期12卷 897-905页

作者： Yuan WU Liang JIANG wenhui LI Jiaxin ZHENG Yushan CHEN Linmao QIAN Tribology Research Institute State Key Laboratory of Rail Transit Vehicle SystemSouthwest Jiaotong UniversityChengdu610031China

With the rapid development of semiconductors,the number of materials needed to be polished sharply increases.The material properties vary significantly,posing challenges to chemical mechanical polishing(CMP).Accordingly,the study aimed to classify the material removal mechanism.Based on the CMP and atomic force microscopy results,the six representative metals can be preliminarily classified into two groups,presumably due to different material removal modes.From the tribology perspective,the first group of Cu,Co,and Ni may mainly rely on the mechanical plowing effect.After adding H_(2)O_(2),corrosion can be first enhanced and then suppressed,affecting the surface mechanical strength.Consequently,the material removal rate(MRR)and the surface roughness increase and decrease.By comparison,the second group of Ta,Ru,and Ti may primarily depend on the chemical bonding effect.Adding H_(2)O_(2)can promote oxidation,increasing interfacial chemical bonds.Therefore,the MRR increases,and the surface roughness decreases and levels off.In addition,CMP can be regulated by tuning the synergistic effect of oxidation,complexation,and dissolution for mechanical plowing,while tuning the synergistic effect of oxidation and ionic strength for chemical bonding.The findings provide mechanistic insight into the material removal mechanism in CMP.

关键词： Chemical mechanical polishing corrosion wear material removal mode mechanical plowing chemical bonding

Tunable quantum anomalous Hall effects in ferromagnetic van der Waals heterostructures

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

National Science Review 2024年第3期11卷 100-107页

作者： Feng Xue Yusheng Hou Zhe Wang Zhiming Xu Ke He Ruqian Wu Yong Xu wenhui Duan Beijing Academy of Quantum Information Sciences State Key Laboratory of Low Dimensional Quantum Physics Department of Physics Tsinghua University Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices Center for Neutron Science and Technology School of Physics Sun Yat-sen University State Key Laboratory of Surface Physics Key Laboratory of Computational Physical Sciences and Department of PhysicsFudan University Frontier Science Center for Quantum Information Department of Physics and Astronomy University of California-Irvine Tencent Quantum Laboratory Tencent Technology(Shenzhen)Co.Ltd RIKEN Center for Emergent Matter Science(CEMS) Institute for Advanced Study Tsinghua University

The quantum anomalous Hall effect（QAHE） has unique advantages in topotronic applications, but it is still challenging to realize the QAHE with tunable magnetic and topological properties for building functional devices. Through systematic first-principles calculations, we predict that the in-plane magnetization induced QAHE with Chern numbers C = ±1 and the out-of-plane magnetization induced QAHE with high Chern numbers C = ±3 can be realized in a single material candidate, which is composed of van der Waals（vdW）coupled Bi and MnBi2Te4monolayers. The switching between different phases of QAHE can be controlled in multiple ways, such as applying strain or（weak） magnetic field or twisting the vdW materials. The prediction of an experimentally available material system hosting robust, highly tunable QAHE will stimulate great research interest in the field. Our work opens a new avenue for the realization of tunable QAHE and provides a practical material platform for the development of topological electronics.

关键词： quantum anomalous Hall effect topological quantum phase transition van der Waals heterostructures tunable Chern number high Chern number

High mechanical strength Si anode synthesis with interlayer bonded expanded graphite structure for lithium-ion batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第6期93卷 253-263,I0007页

作者： wenhui Lai Jong Hak Lee Lu Shi Yuqing liu Yanhui Pu Yong Kang Ong Carlos Limpo Ting Xiong Yifan Rao Chorng Haur Sow Barbaros Ozyilmaz Department of Material Science&Engineering National University of SingaporeSingapore 117575Singapore Center for Advanced 2D Materials National University of SingaporeSingapore 117546Singapore Department of Physics National University of SingaporeSingapore 117551Singapore Institute forFunctional Intelligent Materials National University of SingaporeSingapore 117544Singapore

Despite advancements in silicon-based anodes for high-capacity lithium-ion batteries,their widespread commercial adoption is still hindered by significant volume expansion during cycling,especially at high active mass loadings crucial for practical use.The root of these challenges lies in the mechanical instability of the material,which subsequently leads to the structural failure of the electrode.Here,we present a novel synthesis of a composite combining expanded graphite and silicon nanoparticles.This composite features a unique interlayer-bonded graphite structure,achieved through the application of a modified spark plasma sintering method.Notably,this innovative structure not only facilitates efficient ion and electron transport but also provides exceptional mechanical strength(Vickers hardness:up to658 MPa,Young's modulus:11.6 GPa).This strength effectively accommodates silicon expansion,resulting in an impressive areal capacity of 2.9 mA h cm^(-2)(736 mA h g^(-1)) and a steady cycle life(93% after 100cycles).Such outsta nding performance is paired with features appropriate for large-scale industrial production of silicon batteries,such as active mass loading of at least 3.9 mg cm^(-2),a high-tap density electrode material of 1.68 g cm^(-3)(secondary clusters:1.12 g cm^(-3)),and a production yield of up to 1 kg per day.

关键词： Lithium-ion battery Silicon anode Spark plasma sintering Interlayer bonding Mechanical strength Tap density