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Geometric-constrained multi-view image matching method based on semi-global optimization

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Geo-Spatial Information Science 2018年第2期21卷 115-126页

作者： Wenhao Zhao Li Yan Yunsheng Zhang School of Geodesy and Geomatics Wuhan UniversityWuhanChina National Geomatics Center of China BeijingChina School of Geosciences and Info-Physics Central South UniversityChangshaChina

Targeting at a reliable image matching of multiple remote sensing images for the generation of digital surface models,this paper presents a geometric-constrained multi-view image matching method,based on an energy minimization framework.By employing a geometrical constraint,the cost value of the energy function was calculated from multiple images,and the cost value was aggregated in an image space using a semi-global optimization approach.A homography transform parameter calculation method is proposed for fast calculation of projection pixel on each image when calculation cost values.It is based on the known interior orientation parameters,exterior orientation parameters,and a given elevation value.For an efficient and reliable processing of multiple remote sensing images,the proposed matching method was performed via a coarse-to-fine strategy through image pyramid.Three sets of airborne remote sensing images were used to evaluate the performance of the proposed method.Results reveal that the multi-view image matching can improve matching reliability.Moreover,the experimental results show that the proposed method performs better than traditional methods.

关键词： Image matching multiview images semi-global optimization digital surface model(DSM)

Paths towards enhanced electrochemical CO2 reduction

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National Science Review 2020年第1期7卷 7-9页

作者： wenhao Ren Chuan zhao School of Chemistry University of New South Wales

Anthropogenic COemissions engender a severe threat to the global ecosystem and consequently are a growing concern associated with traditional means of energy production. Direct electrocatalytic reduction of COinto energyrich fuels and value-added chemical feedstocks provides a promising route to realize a carbon-neutral energy cycle, and at the same time, store the electricity generated from intermittent renewable-energy

关键词： Cu Paths towards enhanced electrochemical CO2 reduction

A new inter‑system double‑difference RTK model applicable to both overlapping and non‑overlapping signal frequencies

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Satellite Navigation 2023年第3期4卷 82-91页

作者： Wenhao Zhao Genyou Liu Ming Gao Bo Zhang Shengjun Hu Minghui Lyu State Key Laboratory of Geodesy and Earth’s Dynamics Innovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhan 430077China University of Chinese Academy of Sciences Beijing 100049China Aerospace Information Research Institute Chinese Academy of SciencesBeijing 100094China

Aiming at the problem that the traditional inter-system double-difference model is not suitable for non-overlapping signal frequencies,we propose a new inter-system double-difference model with single difference ambiguity estimation,which can be applied for both overlapping and non-overlapping signal frequencies.The single difference ambiguities of all satellites and Differential Inter-System Biases(DISB)are first estimated,and the intra-system double difference ambiguities,which have integer characteristics,are then fixed.After the ambiguities are successfully fixed,high-precision coordinates and DISB can be obtained with a constructed transformation matrix.The model effectively avoids the DISB parameter filtering discontinuity caused by the reference satellite transformation and the low precision of the reference satellite single difference ambiguity calculated with the code.A zero-baseline using multiple types of receivers is selected to verify the stability of the estimated DISB.Three baselines with different lengths are selected to assess the positioning performance of the model.The ionospheric-fixed and ionospheric-float models are used for short and medium-long baselines,respectively.The results show that the Differential Inter-System Code Biases(DISCB)and Differential Inter-System Phase Biases(DISPB)have good stability regardless of the receivers type and the signal frequency used and can be calibrated to enhance the strength of the positioning model.The positioning results with three baselines of different lengths show that the proposed inter-system double-difference model can improve the positioning accuracy by 6–22%compared with the intra-system double-difference model which selects the reference satellite independently for each system.The Time to First Fix(TTFF)of the two medium-long baselines is reduced by 30%and 29%,respectively.

关键词： Global navigation satellite systems Real-time Inter-system biases Ambiguity resolution Medium-long baselines

U-Pb Zircon Ages and Geochemistry of the Metasedimentary Rocks from the Foping Area in the South Qinling Belt:Evidence for Early Devonian Amalgamation between North China and South China Blocks

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Journal of Earth Science 2023年第4期34卷 1112-1127页

作者： Ruiying Zhang wenhao Ao Yan zhao State Key Laboratory of Continental Dynamics Department of GeologyNorthwest UniversityXi􀆳an 710069China

The provenance and tectonic implications of Late Paleozoic sedimentary rocks in the South Qinling Belt(SQB) provide important clues for understanding the timing and mechanism of the collision between North China Block(NCB) and South China Block(SCB).Here we report new LAICP-MS zircon U-Pb ages and geochemical composition of metasedimentary rocks from the Foping area in the SQB.The results indicate that the depositional age of the Wenquan Group can be limited to the Early Devonian by the youngest U-Pb age of 398 Ma,whereas those of the quartz schist from the Changjiaoba Group could be constrained after the Carboniferous by the youngest206Pb/238U peak age of 306 Ma.Therefore,much of the previously-assumed “Neoarchaean or Paleoproterozoic” strata,including the Wenquan and Changjiaoba groups,were actually deposited in the Late Paleozoic.Based on analysis and comparison of the detrital zircon ages of the Devonian tectonic units in the SQB,we found that most prominent peak ages of detrital zircons from metasedimentary rocks in the Foping area shared similar characteristics with others.They mainly derived from the North Qinling Belt and South Qinling Belt-Yangtze Block,with a minor source probably from the North China Block,implying that the Shangdan Ocean between NCB and SCB had closed in the Early Devonian.Combined with regional geological background and geochemical data,we inferred that these Devonian strata formed in the foreland basin after the amalgamation of the North China Block and South China Block.

关键词： detrital zircon geochronology geochemistry Devonian sedimentation South Qinling belt forelandbasin geochemistry.

Long-Term Reproducibility of SIMS Zircon U-Pb Geochronology

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Journal of Earth Science 2022年第1期33卷 17-24页

作者： Wenhao Zhao Qiuli Li Yu Liu Guoqiang Tang Xiaoxiao Ling Jiao Li Xianhua Li State Key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China Innovation Academy for Earth Science Chinese Academy of SciencesBeijing 100029China

Secondary ion mass spectrometry(SIMS) zircon U-Pb dating has been widely used to confine the absolute ages of the magmatic or metamorphic events and to distinguish multiple events.Here,a data set consisting of the zircon standards dating data(~15 000 Ple?ovice and ~8 000 Qinghu items) accumulated for more than 8 years using the CAMECA IMS 1280 HR of the Institute of Geology and Geophysics,Chinese Academy of Sciences(IGGCAS) is compiled to evaluate the long-term external reproducibility.With Ple?ovice zircon as the calibration standard and Qinghu zircon as an unknown sample,the analytical uncertainties for single-spot(n = 7 723) and session analyses(n = 691,with more than 7 single spot analyses in one session) are 2.6% and 0.9%(2 RSD,relative standard deviation),respectively.It means that single-spot U-Pb dating for a standard-level zircon sample could vary 5.2% at 95% confidence level,while the average value(n > 7) for each session may vary 1.8%.Thus,these values should be considered as the minimum uncertainty when comparing single spot and individual session analysis results for multiple dating works on a certain geological event.

关键词： zircon U-Pb dating SIMS uncertainty reproducibility

Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy

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Chinese Chemical Letters 2024年第4期35卷 532-538页

作者： wenhao Yan Shuaiya Xue Xuerui zhao Wei Zhang Jian Li Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education College of Chemistry and Chemical EngineeringNorthwest Normal UniversityLanzhou 730070China

In an era where the concept of green development is deeply rooted, magnesium(Mg) alloy as a light metal has a long-term development prospect in the process of energy saving, emission reduction and environmental improvement. However, anti-corrosion performance of Mg alloy is poor due to the high chemical activity and low equilibrium potential, which limits the development of Mg alloy products.Herein, three-dimensional mesopore hollow polypyrrole spheres(MHPS) were prepared, and the MHPS was inserted into the middle of the stacked hexagon boron nitride(h-BN) lamellae, which allowed the hBN to be separated forming a further composite with abundant pore structure. Subsequently, the MHPS/hBN-OH composite was uniformly sprayed on the Mg alloy surface via simple spraying method to form the superhydrophobic surface(SHS). Finally, the slippery liquid infused porous surface(SLIPS) was successfully fabricated by applying drops of silicone lubricant on the superhydrophobic coating surface. After a series of characterization and testing, the results showed that the stacking of h-BN lamellae was significantly reduced after h-BN was successfully embedded by MHPS. In addition, the fabricated SLIPS have excellent self-cleaning, mechanical stability, anti-icing and anti-corrosion properties. Therefore, the method of embedding polymer microspheres not only offers a new strategy for h-BN exfoliation, but also the successful prepared SLIPS largely retards the corrosion of Mg alloy while providing new ideas for the development of SLIPS.

关键词： Anti-corrosion Mg alloy Hexagon boron nitride Polypyrrole SLIPS

Highly active CoP-CO_(2)N confined in nanocarbon enabling efficient electrocatalytic immobilizing-conversion of polysulfide targeting high-rate lithium-sulfur batteries

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Journal of Energy Chemistry 2022年第12期75卷 250-259,I0006页

作者： Xiaojun zhao Tianqi Gao wenhao Ren Chuan zhao Zhi-Hong Liu Linbo Li School of Metallurgical Engineering Xi'an University of Architecture and TechnologyXi'an 710055ShaanxiChina School of Chemistry and Chemical Engineering Shaanxi Normal UniversityXi’an 710062ShaanxiChina School of Chemistry University of New South WalesSydneyNSW 2052Australia

Lithium-sulfur batteries suffer from poor cycling stability because of the intrinsic shuttling effect of intermediate polysulfides and sluggish reaction kinetics,especially at high rates and high sulfur loading.Herein,we report the construction of a CoP-CO_(2)N@N-doped carbon polyhedron uniformly anchored on three-dimensional carbon nanotubes/graphene(CoP-CO_(2)N@NC/CG)scaffold as a sulfur reservoir to achieve the trapping-diffusion-conversion of polysulfides.Highly active CoP-CO_(2)N shows marvelous catalytic effects by effectively accelerating the reduction of sulfur and the oxidation of Li_(2)S during the discharging and charging process,respectively,while the conductive NC/CG network with massive mesoporous channels ensures fast and continuous long-distance electron/ion transportation.DFT calculations demonstrate that the CoP-CO_(2)N with excellent intrinsic conductivity serves as job-synergistic immobilizing-conversion sites for polysulfides through the formation of P…Li/N…Li and Co…S bonds.As a result,the S@CoP-CO_(2)N@NC/CG cathode(sulfur content 1.7 mg cm^(-2))exhibits a high capacity of988 mAh g^(-1)at 2 C after 500 cycles,which is superior to most of the electrochemical performance reported.Even under high sulfur content(4.3 mg cm^(-2)),it also shows excellent cyclability with high capacity at 1 C.

关键词： CoP-CO_(2)N@NC/CG Trapping-diffusion-conversion High-rate DFT calculation Li-S battery

The marriage of dual-acceptor strategy and C-H activation polymerization:naphthalene diimide-based n-type polymers with adjustable molar mass and decent performance

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Science China Chemistry 2023年第2期66卷 548-561页

作者： Ying-Han zhao wenhao Li Tao Shen Yan zhao Yunqi Liu Yang Wang Laboratory of Molecular Materials and Devices Department of Materials ScienceFudan UniversityShanghai200438China Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing100190China

The development of readily accessible high-mobility n-type semiconducting polymers is in great demand for realizing highperformance p-n junction-based organic electronics.In this study,we demonstrate that with the combination of dual-acceptor strategy and C-H direct arylation polymerization(DAr P),unipolar n-type semiconducting polymers can be conveniently synthesized.By tuning the monomer concentration,three dual-acceptor polymers,namely,poly(naphthalene diimide-alt-dithiophenyl pyrrolopyrrole-dione)(PNDI-DPP),poly(naphthalene diimide-alt-dithiophenyl isoindigo)(PNDI-IID),and poly(naphthalene diimide-alt-dithiophenyl bezothiadiazole)(PNDI-BT)can be obtained via C-H activation with decent number average molecular weight of~10 to 30 kg mol^(-1)and relatively narrow polydispersity index of~2.In addition,these polymers are defect-free in nature as evidenced by the nuclear magnetic resonance.Moreover,we attribute the different molar masses of the three copolymers under the same DAr P condition to the differentα-C-H acidity,which may stem from different electronwithdrawing capability of the hydrogenated acceptor units.Furthermore,the influence of the hydrogenated acceptor monomers on the optical,electrochemical and charge transporting properties is comprehensively studied.Among the three dual-acceptor polymers,PNDI-BT demonstrates the highest electron mobilities of up to 0.6 cm^(2)V^(-1)s^(-1)in unipolar n-type organic transistors because of its relatively planar backbone,larger overlaps of the lowest unoccupied molecular orbital and strong H-aggregation.Note that the transistor performance of PNDI-BT synthesized via C-H activation in this study is at least comparable to the one made by conventional C(sp^(2))-C(sp^(2))Stille or Suzuki cross-coupling polymerization.This study demonstrates the presented protocol can be a useful platform for sustainable and convenient synthesis of high-performance n-type semiconducting polymers.

关键词： n-type polymers C-H activation dual-acceptor strategy naphthalene diimide organic thin-film transistors

A core–shell Ni/SiO_(2)@TiO_(2) catalyst for highly selective one-step synthesis of 2-propylheptanol from n-pentanal

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Chinese Journal of Chemical Engineering 2022年第6期35卷 104-112页

作者： Hualiang An Rui Wang wenhao Wang Daolai Sun Xinqiang zhao Yanji Wang Hebei Provincial Key Laboratory of Green Chemical Technology and Efficient Energy Saving Tianjin Key Laboratory of Chemical Process SafetySchool of Chemical Engineering and TechnologyHebei University of TechnologyTianjin 300130China

One-step synthesis of 2-propylheptanol(2-PH)from n-pentanal via a reaction integration of n-pentanal self-condensation and successive hydrogenation is of great significance for it can simplify process flow and reduce energy consumption.The key to promotion of 2-PH selectivity is to enhance the competitiveness of n-pentanal self-condensation with respect to its direct hydrogenation.For this purpose,a core–shell structured Ni/SiO_(2)@TiO_(2) catalyst was designed and prepared.With the precise architecture of this core–shell structured catalyst,n-pentanal can be firstly in contact with TiO_(2) to 2-propyl-2-heptenal(2-PHEA)while the direct hydrogenation to n-pentanol can be effectively inhibited,and then 2-PHEA diffuses into the core of Ni/SiO_(2) and is hydrogenated to 2-PH.The spatial threshold of the core–shell catalyst significantly enhanced its catalytic performance;a 2-PH selectivity of 77.9%was reached with a 100%npentanal conversion.The 2-PH selectivity is much higher than that obtained by employing Ni/TiO_(2) catalyst.Furthermore,the reaction kinetics of one-step synthesis of 2-PH from n-pentanal catalyzed by Ni/SiO_(2)@TiO_(2) was studied and its kinetic model was established which is useful for reactor design and scale-up.

关键词： Reaction integration n-Pentanal 2-Propylheptanol Core-shell structure Reaction kinetics