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Journal of Iron and Steel Research International 2020年第8期27卷 952-963页

作者： Yang-huan Zhang Wei Zhang Ze-ming Yuan wen-gang bu Yan Qi Shi-hai Guo Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010Inner MongoliaChina Department of Functional Material Research Central Iron and Steel Research InstituteBeijing 100081China

Both element substitution and surface modification were utilized to enhance the electrochemical performances of Mg–Ni-based alloys. Nanocrystalline and amorphous -Mg1?xCexNi0.9Al0.1 (x?=?0–0.08)?+?50 wt.% Ni hydrogen storage alloys were synthesized through mechanical milling. The sample alloys show excellent activation property and have good electrochemi-cal hydrogenation and dehydrogenation property at normal temperature. The discharge capacity has a peak value with Ce content varying which is 461.6 mAh/g for 10-h milled alloy, while that of -Ce0.04 alloy augments from 352.6 to 536.9 mAh/g with milling time extending from 5 to 30 h. Cycle stability is conspicuously improved with Ce content and milling duration augment. To be specific, when cycle number is fixed at 100, the capacity retention rate augments from 41% to 72% after Ce dosage rising from 0 to 0.08 for the 10-h milled alloy and from 58% to 76% after milling duration extending from 5 to 30 h for -Ce0.06 alloy. Additionally, the electrochemical kinetics of the alloys own peak values with Ce proportion varying;however, they always rise with milling duration extending.

关键词： Mg–Ni-based alloy Ce replacing Mg Surface modification Mechanical milling Electrochemical performance

Hydrogen Storage Thermodynamics and Dynamics of Nd–Mg–NiBased Nd Mg_(12^-)Type Alloys Synthesized by Mechanical Milling

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Acta Metallurgica Sinica(English Letters) 2016年第6期29卷 577-586页

作者： Yang-Huan Zhang Ze-Ming Yuan wen-gang bu Feng Hu Ying Cai Dong-Liang Zhao Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University ofScience and TechnologyBaotou 014010China Department of Functional Material Research Central Ironand Steel Research InstituteBeijing 100081China

Nanocrystalline and amorphous Nd Mg_（12^-）type Nd Mg_（11）Ni＋ x wt% Ni（x=100, 200） hydrogen storage alloys were synthesized by mechanical milling. The effects of Ni content and milling time on hydrogen storage thermodynamics and dynamics of the alloys were systematically investigated. The gaseous hydrogen absorption and desorption properties were investigated by Sieverts apparatus and differential scanning calorimeter connected with a H_2 detector. Results show that increasing Ni content significantly improves hydrogen absorption and desorption kinetics of the alloys. Furthermore,varying milling time has an obvious effect on the hydrogen storage properties of the alloys. Hydrogen absorption saturation ratio（R^a_（10）; a ratio of the hydrogen absorption capacity in 10 min to the saturated hydrogen absorption capacity） of the alloys obtains the maximum value with varying milling time. Hydrogen desorption ratio（R^d_（20）, a ratio of the hydrogen desorption capacity in 20 min to the saturated hydrogen absorption capacity） of the alloys always increases with extending milling time. The improved hydrogen desorption kinetics of the alloys are considered to be ascribed to the decreased hydrogen desorption activation energy caused by increasing Ni content and milling time.

关键词： NdMg12 alloy Hydrogen storage Mechanical milling Activation energy Kinetics

Structure and electrochemical properties of LaMgNi4-xCox(x=0-0.8)hydrogen storage electrode alloys

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Rare Metals 2018年第3期37卷 249-256页

作者： Tai Yang Ting-Ting Zhai Ze-Ming Yuan wen-gang bu Yan Qi Yang-Huan Zhang Functional Materials Research Institute Central Iron and SteelResearch Institute Beijing 100081 China Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science andTechnology Baotou 014010 China

LaMgNi（4-x）Cox（x = 0-0.8） electrode alloys used for MH/Ni batteries were prepared by induction melting. The structures and electrochemical hydrogen storage properties of the alloys were investigated in detail.X-ray diffraction（XRD） and scanning electron microscopy（SEM） analysis show that LaMgNi4 phase and LaNi5 phase are obtained. The lattice parameters of the two phases increase first and then decrease with Co content *** electrochemical properties of the alloy electrodes were measured by means of simulated battery tests. Results show that the addition of Co does not change the discharge voltage plateau of the alloy electrodes. However, the maximum discharge capacity increases from 319.9 mAh·g^-1（x = 0）to 347.5 mAh·g^-1（x = 0.4） and then decreases to331.7 mAh·g^-1（x = 0.8）. The effects of Co content on electrochemical kinetics of the alloy electrodes were also performed. The high rate dischargeability（HRD） first increases and then decreases with Co content increasing and reaches the maximum value（95.0 %） when x = 0.4. Test results of the electrochemical impedance spectra（EIS）,potentiodynamic polarization curves and constant potential step measurements of the alloy electrodes all demonstrate that when Co content is 0.4 at%, the alloy exhibits the best comprehensive electrochemical properties.

关键词： Hydrogen storage alloy Element substitution Phase structure Electrochemical performances Kinetics

A Comparison Study of Hydrogen Storage Thermodynamics and Kinetics of YMg11Ni Alloy Prepared by Melt Spinning and Ball Milling

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Acta Metallurgica Sinica(English Letters) 2017年第11期30卷 1040-1048页

作者： Yang-Huan Zhang Wei Zhang Jin-Liang Gao Ze-Ming Yuan wen-gang bu Yan Qi Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science and Technology Baotou 014010 China Department of Functional Material Research Central Iron and Steel Research Institute Beijing 100081 China Weishan Cisri-Eare Earth Materials Co. Ltd. Jining 277600China

Melt spinning （MS） and ball milling （BM） were employed to fabricate YMg11Ni alloy, and their structures and hydrogen storage performances were examined. The results reveal that the as-spun and as-milled alloys both exhibit the nanocrystalline and amorphous structure. The as-milled alloy shows a larger hydrogen absorption capacity as compared with the as-spun alloy. More than that, the as-milled alloy exhibits lower onset hydrogen desorption temperature than the as-spun one, which are 549.8 and 560.9 K, respectively. Additionally, the as-milled alloy shows a superior hydrogen desorption property to the as-spun one. On the basis of the time needed by desorbing hydrogen of 3 wt% H2, for the as- milled alloy, it needs 1106, 456, 343, and 180 s corresponding to hydrogen desorption temperatures of 593, 613, 633, and 653 K. However, for the as-spun alloy, the time needed is greater than 2928, 842, 356, and 197 s corresponding to the same temperatures. Hydrogen desorption activation energies of as-milled and as-spun alloys are 98.01 and 105.49 kJ/mol, respectively, which is responsible for that the as-milled alloy possesses a much faster dehydriding rate. By means of the measurement of pressure-composition-temperature （P-C-T） curves, the dehydrogenation enthalpy change of the alloys prepared by MS （△Hoe（MS）） and BM （△Hdc（BM）） is 81.84 and 79.46 kJ/mol, respectively, viz. △Hde（MS）〉 △Hoc（BM）.

关键词： Mg-based alloy Ball milling Melt spinning Hydrogen storage kinetics Comparison

Hydrogen Storage Performances of Nanocrystalline and Amorphous NdMg11Ni+x wt% Ni （x=100, 200） Alloys Synthesized by Mechanical Milling

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Acta Metallurgica Sinica(English Letters) 2019年第9期32卷 1089-1098页

作者： Yang-Huan Zhang Kai-Feng Zhang Ze-Ming Yuan Peng-Peng Wang Ying Cai wen-gang bu Yan Qi Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010China Department of Functional Material Research Central Iron and Steel Research InstituteBeijing 100081China

Nanocrystalline and amorphous NdMg12-type NdMg11Ni+x wt%Ni(x=100,200)alloys were successfully prepared through ball milling(BM).The microstructures and electrochemical properties were systematically studied to get a more comprehensive understanding of the sample *** maximum discharging capacity could be obtained at only two cycles,indicating that as-milled alloys have superior activation *** more the Ni content,the better the electrochemical properties of the as-milled *** be specific,the discharge capacities of x=100 and x=200(BM 20 h)samples are 128.2 and 1030.6 mAh/g at 60 mAh/g current density,respectively,revealing that enhancement of Ni content could significantly improve the discharging capacities of the ***,milling duration obviously influences the electrochemical properties of the *** discharging capacity always rises with milling duration prolonging for the x=100 sample,but that of the(x=200)sample shows a trend of first augment and then *** cycling stability of the(x=100)alloy clearly decreases with extending milling duration,whereas that of the(x=200)alloy first declines and then augments under the same *** addition,the high rate discharge(HRD)abilities of the sample display the maximal values as milling duration *** HRD(HRD=C300/C60×100%)values of the as-milled alloys(x=100,200)are 80.24%and 85.17%,respectively.

关键词： NdMg12 alloy Mechanical milling Electrochemical hydrogen storage performance Dynamic characteristics Activation energy

Hydrogen storage performances of as-milled REMg_(11)Ni(RE=Y, Sm) alloys catalyzed by MoS_2

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Transactions of Nonferrous Metals Society of China 2018年第9期28卷 1828-1837页

作者： Yang-huan ZHANG Wei ZHANG Ze-ming YUAN wen-gang bu Yan QI Xiao-ping DONG Shi-hai GUO Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal Resources Inner Mongolia University of Science and TechnologyBaotou 014010China Department of Functional Material Research Central Iron and Steel Research InstituteBeijing 100081China Department of Mechanical Engineering Hebei UniversityBaoding 071002China

To compare the hydrogen storage performances of as-milled REMg11Ni-5MoS2(mass fraction)(RE=Y,Sm)alloys,which were catalyzed by MoS2,the corresponding alloys were *** hydrogen storage performaces of these alloys were measured by various methods,such as XRD,TEM,automatic Sievert apparatus,TG and *** results reveal that both of the as-milled alloys exhibit a nanocrystalline and amorphous *** RE=Y alloy shows a larger hydrogen absorption capacity,faster hydriding rate,lower initial hydrogen desorption temperature,superior hydrogen desorption property,and lower hydrogen desorption activation energy,which is thought to be the reason of its better hydrogen storage kinetics,as compared with RE=Sm alloy.

关键词： Mg-based alloy ball milling catalyst rare earth element hydrogen storage performance

Effect of Nd content on electrochemical performances of nanocrystalline and amorphous (Mg_(24)Ni_(10)Cu_2)_(100-x)Nd_x(x=0-20) alloys prepared by melt spinning

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Transactions of Nonferrous Metals Society of China 2013年第12期23卷 3668-3676页

作者：张羊换杨泰卜文刚蔡颖张国芳赵栋梁内蒙古科技大学内蒙古自治区白云鄂博矿多金属资源综合利用重点实验室包头014010 钢铁研究总院功能材料研究所北京100081

The nanocrystalline and amorphous Mg2Ni-type alloys with a chemical composition of （Mg24Ni10Cu2）100-xNdx （x=0, 5, 10, 15, 20） were fabricated by melt spinning technology. The effects of spinning rate on the structure and electrochemical hydrogen storage performance of the alloys were investigated. The as-spun Nd-free alloy displays an entire nanocrystalline structure, whereas the as-spun Nd-added alloys hold a nanocrystalline and amorphous structure, suggesting that the addition of Nd facilitates the glass forming of the Mg2Ni-type alloys. Increasing the spinning rate from 0 to 40 m/s gives rise to the discharge capacity growing from 42.5 to 100.6 mA·h/g for the x=0 alloy and from 86.4 to 452.8 mA·h/g for the x=10 alloy. And the cycle stability （S20） rises from 40.2%to 41.1%for the x=0 alloy and from 53.2%to 89.7%for the x=10 alloy, respectively.

关键词： hydrogen storage alloy Mg2Ni-type alloy Nd melt spinning structure

Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

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Science China Chemistry 2025年第01期 201-208页

作者： Hui-Feng Wang wen-Jie Shi Yu-Xin Yang Bao-Xia Dong Tong-bu Lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

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基于云服务接入的温室环境采集终端优化设计

沈阳农业大学学报 2018年第3期49卷 371-377页

作者：李文龙郑文刚卜云龙张馨姚远方北京农业信息技术研究中心北京100097 农业部农业信息软硬件产品质量检测重点实验室北京100097 北京京鹏环球科技股份有限公司北京100094

由于温室环境信息采集需求多样、应用分散设备接入网络困难且为物联网,云服务优先应用领域,使得采用运营商通讯(GSM/GPRS、3G、4G等)的环境数据采集设备在温室生产中应用越来越多,但实际运行过程中依然存在系统能耗高、太阳能温室内充... 详细信息

由于温室环境信息采集需求多样、应用分散设备接入网络困难且为物联网,云服务优先应用领域,使得采用运营商通讯(GSM/GPRS、3G、4G等)的环境数据采集设备在温室生产中应用越来越多,但实际运行过程中依然存在系统能耗高、太阳能温室内充电效率低、铅酸蓄电池供电为主体积大、整体密封性差难以适应高温高湿环境等问题,迫切需要在以上几个方面开展优化设计。开发了低成本、集成度高、低功耗的温室环境感知终端,能够采集常规数字(I2C、1-wire、串口等)、模拟信号传感器(0~5V,4~20m A),灵活选择传感器满足用户对不同监测参数的测量需求并通过GSM/GPRS接入已有的设施农业云服务平台,适合分散,大区域接入、单温室直接网络接入等应用场景。重点在终端能耗管理、防护结构、太阳能供电结构等方面开展优化设计,小功率太阳能电池板采用多角度安装方式,实现延长充电时间超过2h·d^(-1),提高温室内太阳能利用率;将主动通风空气防辐射罩与符合IP67标准防护壳构成一体,适应高温高湿环境,并加速防辐射罩内部与外部气流交换速度,提高温湿度、CO2测量响应速度和精度;低功耗硬件选型配合事件触发唤醒能耗管理模式解决GSM/GPRS通讯能耗问题使终端休眠能耗为44u A,常规应用频率平均功耗达1.1m A,实现无外接供电设备全负荷独立工作近1个月,满足温室环境在线监测需求。该优化设计与应用具有开放性、易用性、低成本、安装便捷等特点,能够提升温室生产监测能力,市场前景广阔。

关键词：温室智能传感器环境监测低功耗设计 GSM/GPRS

Dynamical complexity of Anosov systems driven by a quasi-periodic force

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Science China Mathematics 2025年第1期 89-136页

作者： wen Huang Zeng Lian Kening Lu Department of Mathematics University of Science and Technology of China School of Mathematics Sichuan University

Consider C2Anosov systems on a compact manifold driven by a quasi-periodic *** study their dynamical complexity on various levels from the perspectives of both path-wise dynamics and stochastic *** that these systems are non-wandering（i.e.,every point in the phase space is nonwandering）,we prove a set of results:（1） the existence of abundance of random periodic points;（2） a random Liv?ic theorem;（3） a random Ma?é-Bousch-Conze-Guivarc'h lemma;（4） the existence of strong random ***,a concrete example constructed on a 2-dimensional torus is also given to uncover some interesting phenomena of the systems.

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