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26-electrons redox-active polyoxovanadate clusters for aqueous zincion batteries

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Nano Research 2024年第5期17卷 4047-4054页

作者： Yimin Xing wen Yan Haiyang wu Peng Huang Chao Wang Chao Lai School of Chemistry and Materials Science Jiangsu Normal UniversityXuzhou 221116China

Aqueous zinc-ion batteries(ZIBs)are attaining increasing attention for their high safety and low *** significant progresses in realizing high-performance cathode material for ZIBs,simultaneously endowing them with high capacity and fast-charging capability,the long-term cycling stability remains a major unsolved *** this work,a polyoxovanadate cluster of(NH_(4))_(8)[V_(19)O_(41)(OH)_(9)]·11H_(2)O(NOV)is defined as a cathode material for ZIBs that contains mixed-valence vanadium sites(V^(4+)and V^(5+)).A maximum of 26 electrons can be accommodated in one[V_(19)O_(41)(OH)_(9)]^(8-){V_(19)O_(50)}cluster,contributing to the high theoretical specific capacity of 328 mA·h·g^(-1).The Ti_(3)C_(2)T_(x) MXene nanosheets are incorporated into NOV with the help of ionic liquid(IL)linkers to restrain the dissolution of vanadium species and facilitate electron transport across the *** interfacial bonding,anion exchange,and electrostatic interactions among NOV and MXene are provided by IL *** nanohybrid of NOV-IL-MXene endows excellent contact between MXene and NOV,thereby enhanced charge transfer is observed at ***,the as-synthesized NOV-IL-MXene cathodes exhibit high discharge capacity of 413 mA·h·g^(-1) at 0.2 A·g^(-1) even at high mass loading of 5.2 mg·cm^(-2),remarkable rate performance of 182 mA·h·g^(-1) at 10 A·g^(-1),and impressive cycling stability of 94%capacity retention after 2000 *** work opens up new opportunities to develop advanced polyoxovanadate hybrid cathodes for low-cost and high-performance aqueous ZIBs.

关键词： polyoxovanadate MXene composite materials cathodes zinc-ion batteries

A regression approach for seismic first-break picking

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Petroleum Science 2024年第3期21卷 1584-1596页

作者： Huan Yuan San-Yi Yuan Jie wu wen-Jing Sang Yu-He Zhao CNPC Key Laboratory of Geophysical Exploration China University of Petroleum(Beijing)Beijing 102249China Research Institute of Petroleum Exploration&Development—Northwest(NWGI) Key Laboratory of reservoir characterization of CNPCPetroChinaLanzhou 730020GansuChina

The picking efficiency of seismic first breaks(FBs)has been greatly accelerated by deep learning(DL)***,the picking accuracy and efficiency of DL methods still face huge challenges in low signal-to-noise ratio(SNR)*** address this issue,we propose a regression approach to pick FBs based on bidirectional long short-term memory(Bi LSTM)neural network by learning the implicit Eikonal equation of 3D inhomogeneous media with rugged topography in the target *** employ a regressive model that represents the relationships among the elevation of shots,offset and the elevation of receivers with their seismic traveltime to predict the unknown FBs,from common-shot gathers with sparsely distributed *** from image segmentation methods which automatically extract image features and classify FBs from seismic data,the proposed method can learn the inner relationship between field geometry and *** addition,the predicted results by the regressive model are continuous values of FBs rather than the discrete ones of the binary *** picking results of synthetic data shows that the proposed method has low dependence on label data,and can obtain reliable and similar predicted results using two types of label data with large *** picking results of9380 shots for 3D seismic data generated by vibroseis indicate that the proposed method can still accurately predict FBs in low SNR *** subsequent stacked profiles further illustrate the reliability and effectiveness of the proposed *** results of model data and field seismic data demonstrate that the proposed regression method is a robust first-break picker with high potential for field application.

关键词： First-break picking Low signal-to-noiseratio Regression BiLSTM Traveltime Geometry Noisy seismic data

Single-atom Ag-loaded carbon nitride photocatalysts for efficient degradation of acetaminophen:The role of Ag-atom and O_(2)

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Journal of Environmental Sciences 2024年第5期139卷 12-22页

作者： Yi Yuan wen-Long Wang Zhi-Wei Wang Jin Wang Qian-Yuan wu Key Laboratory of Microorganism Application and Risk Control of Shenzhen Guangdong Provincial Engineering Research Center for Urban Water Recycling and Environmental SafetyInstitute of Environment and EcologyShenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China Shenzhen Environmental Science and New Energy Technology Engineering Laboratory Tsinghua-Berkeley Shenzhen InstituteShenzhen 518055China College of Materials Science and Engineering Shenzhen UniversityShenzhen 518071China

Carbon nitride has been extensively used as a visible-light photocatalyst,but it has the disadvantages of a low specific surface area,rapid electron-hole recombination,and relatively low light *** this study,single-atom Ag was successfully anchored on ultrathin carbon nitride(UTCN)via thermal polymerization,the catalyst obtained is called *** Ag hardly changed the carbon nitride's layered and porous physical *** exhibited efficient visible-light photocatalytic performances in the degradation of various recalcitrant pollutants,eliminations of 85% were achieved by visible-light irradiation for *** with Ag improved the photocatalytic performance of UTCN by narrowing the forbidden band gap from 2.49 to 2.36 e V and suppressing electron-hole pair *** addition,Ag doping facilitated O_(2) adsorption on UTCN by decreasing the adsorption energy from -0.2 to -2.22 e V and favored the formation of O_(2)^(·-).Electron spin resonance and radical-quenching experiments showed that O_(2)^(·-)was the major reactive species in the degradation of Acetaminophen(paracetamol,APAP).

关键词： Ag single atom Carbon nitride Photocatalysis Visible light Adsorption energy Reactive species

Asymptotic normality of error density estimator in stationary and explosive autoregressive models

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Applied Mathematics(A Journal of Chinese Universities) 2024年第1期39卷 140-158页

作者： wu Shi-peng YANG wen-zhi GAO Min HU Shu-he School of Mathematical Sciences&School of Big Data and Statistics Anhui UniversityHefei 230601China School of Statistics Shanxi University of Finance and EconomicsTaiyuan030006China

In this paper,we consider the limit distribution of the error density function estima-tor in the rst-order autoregressive models with negatively associated and positively associated random *** mild regularity assumptions,some asymptotic normality results of the residual density estimator are obtained when the autoregressive models are stationary process and explosive *** order to illustrate these results,some simulations such as con dence intervals and mean integrated square errors are provided in this *** shows that the residual density estimator can replace the density\estimator"which contains errors.

关键词： explosive autoregressive models residual density estimator asymptotic distribution association sequence

Janus Quasi‑Solid Electrolyte Membranes with Asymmetric Porous Structure for High‑Performance Lithium‑Metal Batteries

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Nano-Micro Letters 2024年第6期16卷 221-232页

作者： Zerui Chen Wei Zhao Qian Liu Yifei Xu Qinghe Wang Jinmin Lin Hao bin wu Institute for Composites Science Innovation(InCSI)and State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China

Quasi-solid electrolytes(QSEs)based on nanoporous materials are promising candidates to construct high-performance Limetal batteries(LMBs).However,simultaneously boosting the ionic conductivity(σ)and lithium-ion transference number(t^(+)) of liquid electrolyte confined in porous matrix remains ***,we report a novel Janus MOFLi/MSLi QSEs with asymmetric porous structure to inherit the benefits of both mesoporous and microporous *** Janus QSE composed of mesoporous silica and microporous MOF exhibits a neat Li^(+) conductivity of 1.5.10^(–4)S cm^(−1) with t^(+) of 0.71.A partially de-solvated structure and preference distribution of Li^(+)near the Lewis base O atoms were depicted by MD ***,the nanoporous structure enabled efficient ion flux regulation,promoting the homogenous deposition of Li^(+).When incorporated in Li||Cu cells,the MOFLi/MSLi QSEs demonstrated a high Coulombic efficiency of 98.1%,surpassing that of liquid electrolytes(96.3%).Additionally,NCM 622||Li batteries equipped with MOFLi/MSLi QSEs exhibited promising rate performance and could operate stably for over 200 cycles at 1 *** results highlight the potential of Janus MOFLi/MSLi QSEs as promising candidates for next-generation LMBs.

关键词： Metal-organic frameworks Mesoporous silicas Quasi-solid electrolytes Janus structure Lithium-metal battery

Neural Modified Extended State Observer for Autonomous Maritime Transportation Vehicles with Actuator Faults and Unmatched Nonlinearities

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Guidance, Navigation and Control 2024年第1期4卷 41-61页

作者： Yutao wu Zehui Mao bin Jiang College of Automation Engineering Nanjing University of Aeronautics and Astronautics Nanjing 210016 P.R.China

This paper investigates extended state observer design problem for autonomous maritime transportation vehicles consisting of multiple unmanned aerial vehicles(UAVs)and unmanned surface vehicles(USVs)via the cooperation–competition *** two coordinate transformations,the dynamic model of UAVs and USVs is transformed into a standard secondorder heterogeneous multi-agent system in unified earth-fixed *** order to recover the unavailable velocities,unpredictable fault,total disturbance as well as to estimate the heterogeneous match/unmatched nonlinearities,neural network(NN)is incorporated into the design process of the modified distributed extended state observer(MESO).Based on the Lyapunov stability analysis,it is proved that all the error signals are uniformly ultimately bounded(UUB)and the bounds could be arbitrarily small by choosing appropriate *** results verify the effectiveness of the proposed method.

关键词： UAVs-USVs neural network extended state observer signed graph

Upconverting and downshifting circularly polarized luminescence in a superstructural helix

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Science China Chemistry 2024年第8期67卷 2571-2577页

作者： Honghan Ji bin wu Enquan Tian Chao Ren Xue Jin Liangliang Zhu Pengfei Duan CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology(NCNST)Beijing 100190China State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular ScienceFudan UniversityShanghai 200438China University of Chinese Academy of Sciences Beijing 101408China

The modulation of circularly polarized luminescence(CPL) has become an increasingly prominent area of research. In this study,we propose a unique “one-excitation-to-three-emissions” CPL system through the co-assembly of an upconversion system,incorporating one sensitizer(Pt(II) mesotetraphenyl tetrabenzoporphyrine, Pt TPBP) and two annihilators(R/S-DPA and R/SBDP) within liquid crystals. The chiral nature of the annihilators induces a transformation of the nematic liquid crystal into chiral nematic liquid crystals(N*LC), establishing an excellent chiral matrix. Upon the incorporation of the sensitizer Pt TPBP and subsequent excitation at 635 nm, the system demonstrates two independent triplet–triplet annihilation photon upconversion(TTA-UC) with the emission in blue and yellow, aided by thermally activated triplet–triplet energy transfer(TTET). This is accompanied by the simultaneous generation of upconverting circularly polarized luminescence(UC-CPL) and downshifting near-infrared circularly polarized luminescence(DS-CPL) originating from the residual luminescence of Pt TPBP. Remarkably,fine-tuning the ratio between the two annihilators allows the TTA-UC system to exhibit multicolor CPL emission with an amplified luminescence dissymmetry factor(glum, reaching up to 0.6). Our study unveils a previously unreported “one-excitation-to-three-emissions” system and provides a versatile strategy for modulating CPL emissions, surpassing conventional methodologies.

关键词： circularly polarized luminescence triplet–triplet annihilation upconversion near-infrared emission chiral nematic liquid crystal luminescence dissymmetry factor

Evaluation of the binding affinity and antioxidant activity of phlorizin to pepsin and trypsin

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Food Science and Human Wellness 2024年第1期13卷 392-400页

作者： Jing Zhang Lan Tang Xia Hu Zhen Zeng wen wu Fang Geng Hui Li Di wu Meat Processing Key Laboratory of Sichuan Province School of Food and Biological EngineeringChengdu UniversityChengdu 610106China School of Chemical Engineering Sichuan UniversityChengdu 610065China

Phlorizin(PHL)is a natural compound with strong antioxidant properties mainly found in *** this paper,the interaction mechanism of PHL with pepsin and trypsin was comparatively evaluated by computer simulation,fluorescence spectra,circular dichroism(CD),and Fourier transform infrared(FT-IR)spectra at a molecular *** spectra showed that PHL quenches the pepsin/trypsin by static *** parameters indicated that PHL binds to pepsin mainly through hydrogen bonds and van der Waals forces,and that of trypsin was electrostatic *** ground state complexes PHL and protease have a moderate affinity of 105 L/mol PHL binds more strongly to trypsin than to *** and FT-IR spectra results showed that pepsin/trypsin decreased theβ-sheet content and slightly changed its secondary structure upon *** experimental results are mutually verified with the predicted computer-aid simulation *** PHL and trypsin binding,the antioxidant capacity of PHL was ***,the antioxidant capacity of PHL was decreased after binding to *** work elucidates the binding of PHL binding mechanisms to pepsin/trypsin and provides useful information for the digestion of PHL to improve the application of PHL in food processing.

关键词： Interaction Phlorizin Pepsin Trypsin Antioxidation

Construction of spinel/biochar film/honeycomb monolithic catalyst for photothermal catalytic oxidation of VOCs

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Frontiers of Chemical Science and Engineering 2024年第9期18卷 61-71页

作者： Xikai Lu Chunyan Zhang Meng wu wenjie Liu bin Xue Chao Yao Xiazhang Li National-Local Joint Engineering Research Center of Biomass Refining and High-quality Utilization Changzhou UniversityChangzhou 213164China Department of Materials Science and Engineering University of DelawareDelaware CityDE 19716USA

Photothermal catalytic oxidation emerges as a promising method for the removal of volatile organic compounds(VOCs).Herein,via sol-gel impregnation method,spinel CuMn_(2)O_(4)was coated on attapulgite honeycombs with integrating biochar(BC)film as the second carrier,using chestnut shell as complexation *** mass ratios of CuMn_(2)O_(4)to chestnut shell was modulated to investigate the catalytic toluene degradation *** indicated that the monolithic CuMn_(2)O_(4)/BC/honeycomb catalyst demonstrated superior photothermal catalytic toluene degradation with a low T90(temperature at 90%degradation)of 263°C when the mass ratio of CuMn_(2)O_(4)to biomass was 1:*** addition of BC film substantially increased the honeycomb's specific surface area and improved the photothermal conversion of spinel,leading to enhanced photothermal catalytic *** study presents a cost-effective strategy for eliminating industrial VOCs using clay-biomass based monolithic catalyst.

关键词： CuMn_(2)O_(4) biochar photothermal catalysis attapulgite honeycomb volatile organic compound