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An ionic liquid-assisted strategy for enhanced anticorrosion of low-energy PEO coatings on magnesium–lithium alloy

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Journal of Magnesium and Alloys 2024年第6期12卷 2380-2396页

作者： You Zhang Chuping chen Haoyue Tian Shuqi Wang chen wen Fei chen College of New Materials and Chemical Engineering Hydrogen Energy Research CentreBeijing Institute of Petrochemical TechnologyBeijing 102617China Key Laboratory of Advanced Structure-Function Integrated Materials and Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China Beijing Spacecrafts China Academy of Space TechnologyBeijing 100190China

A low-energy plasma electrolytic oxidation(LePEO)technique is developed to simultaneously improve energy efficiency and *** liquids(1-butyl-3-methylimidazole tetrafluoroborate(BmimBF_(4)))as sustainable corrosion inhibitors are chosen to investigate the corrosion inhibition behavior of ionic liquid(ILs)during the LePEO process for LA91 magnesium-lithium(Mg-Li)*** show that the ionic liquid BmimBF_(4)participates in the LePEO coating formation process,causing an increment in coating thickness and surface *** low conductivity of the ionic liquid is responsible for the voltage and breakdown voltage increases during the LePEO with IL process(LePEO-IL).After adding BmimBF_(4),corrosion current density decreases from 1.159×10^(−4)A·cm^(−2)to 8.143×10^(−6)A·cm^(−2).The impedance modulus increases to 1.048×10^(4)Ω·cm^(−2)and neutral salt spray remains intact for 24 *** superior corrosion resistance of the LePEO coating assisted by ionic liquid could be mainly attributed to its compact and thick barrier layer and physical absorption of ionic *** ionic liquid-assisted LePEO technique provides a promising approach to reducing energy consumption and improving film performance.

关键词： Magnesium-lithium alloy Plasma electrolytic oxidation Low energy Ionic liquid Corrosion resistance

Rational design and energy catalytic application of high-loading single-atom catalysts

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Rare Metals 2024年第10期43卷 4844-4866页

作者： Zi-Wei Deng Yue Liu Jie Lin wen-Xing chen Energy and Catalysis Center School of Materials Science and EngineeringBeijing Institute of Technology Ningbo Institute of Materials Technology and Engineering Chinese Academy of Science

It is well known that single-atom catalysts(SACs)have become a hot topic in the field of catalysis due to their advantages such as 100% metal atom utilization efficiency,high catalytic activity and selectivity compared with conventional catalysts and nanocatalysts. However, the isolated metal atoms on SACs have thermodynamic instability and tend to agglomerate, which limit their catalytic ***, it is of great significance to synthesize stable and high-loading single-atom catalysts(HLSACs). In this paper,we review the research progress of HLSACs from two aspects:design and application. Firstly, we comprehensively introduce the synthesis strategies of HLSACs, namely, top-down and bottom-up methods. Secondly, we overview the application status of HLSACs in three fields: electrocatalysis, thermal catalysis and photocatalysis. Finally, we summarize the development prospects and challenges of HLSACs.

关键词： Design Electrocatalysis High-loading single-atom catalysts Photocatalysis Thermal catalysis

How Do Chinese Exporting Firms Respond to Environment-related Notifications?A Green Innovation Perspective

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China & World Economy 2024年第5期32卷 1-27页

作者： wen chen Yinzi Fan School of Economics Xiamen UniversityChina

Environment-related notifications play an important role in the coordinated development of trade and environment *** this paper,we examine how Chinese exporting enterprises responded to environment-related notifications implemented by the US through green innovation *** notifications significantly encouraged exporting firms to increase green innovation,as evidenced particularly by the number of green utility model patents *** effect was most pronounced in non-foreign-invested enterprises,high-total-factor-productivity firms,technology-intensive industries,and nongreen *** notifications also increased the probability of enterprises exiting the market while reducing the probability of new enterprises entering *** innovation motivation of surviving firms was higher than that of the new *** analysis also suggests that environment-related notifications had a crowding-out effect on other innovation rather than a leverage *** study offers important empirical evidence that helps enterprises to respond to green non-tariff measures effectively,enrich the existing literature,and provide practical guidance for both policymaking and corporate development.

关键词： difference-in-differences environment-related notification green innovation.tradeandenvironment JELcodes:F13 F14 O33

The centrosymmetric to non-centrosymmetric transformation induced by alkaline-earth cations producing infrared nonlinear optical AeMn_(6)Ga_(6)S_(16)(Ae=Ca,Sr)

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Science China Chemistry 2024年第9期67卷 2941-2948页

作者： Yang-Ping Zhang Shao-Min Pei wen-Fa chen Bin-wen Liu Xiao-Ming Jiang Guo-Cong Guo State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China School of Physical Science and Technology Shanghai Tech UniversityShanghai 201210China

Non-centrosymmetric(NCS)structure is an indispensable prerequisite for second-order nonlinear optical(NLO)***,the mainstream approach for designing new NCS structures still relies on chemical substitution,necessitating an urgent infusion of fresh *** this work,two isomorphic sulfides AeMn_(6)Ga_(6)S_(16)(Ae=Ca,1;Sr,2)are afforded by modifying the skeleton of centrosymmetric(CS)Mn_(2)Ga_(2)S_(5) via introducing strong electropositive alkaline-earth ***,the incorporation of Ca^(2+)/Sr^(2+)cations allows the elementary[MnGaS_(9)]_(∞)chains to reconfigure into bumpy[MnS_(6)]-[GaS_(4)]layers in a new engagement manner,thus enabling the conversion from CS to NCS *** modifications cause not only strong second-harmonic generation(SHG)responses(~1.5×benchmark AgGaS_(2)@1,700 nm),but also significantly feasible bandgaps(2.60-2.64 e V)compared to the sulfide Mn_(2)Ga_(2)S_(5)(1.36 e V),which ultimately facilitate ultrahigh laser-induced damage thresholds(4.4-6.6×AgGaS_(2)@1,064 nm for compounds 1 and 2).The present study offers an ingenious approach for the transformation of CS to NCS structure.

关键词： second-harmonic generation non-centrosymmetrical structure NLO functional motif solid-state method

Boosting the electrochromic properties by large V_(2)O_(5)nanobelts interlayer spacing tuned via PEDOT

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Chinese Chemical Letters 2024年第9期35卷 408-413页

作者： Haohao Sun wenxuan Wang Yuli Xiong Zelang Jian wen chen State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Sanya Science and Education Innovation Park of Wuhan University of Technology Sanya 572000China

Vanadium pentoxide(V_(2)O_(5))with a layered structure is of great interest in the field of electrochromic(EC)due to its abundance of color ***,there are still a series of problems such as slow ion diffusion,poor electronic conductivity and cyclic stability in the reaction ***,we successfully prepared a stable and fast multi-color electrochromic material V_(2)O_(5)-PEDOT by a simple“one-pot”*** layer space of V_(2)O_(5)could be tuned by 3,4-ethylenedioxythiophene(named V_(2)O_(5)-PEDOT)during the dissolution and recrystallization of vanadium *** expanded layer spacing facilitates rapid ion insertion and *** serves as an internal conductive pillar to improve the overall conductivity of the *** obtained intercrossing structure of the nanobelts shortens the ion diffusion distance and ensures electrolyte *** V_(2)O_(5)-PEDOT exhibits the fast response time(1.1 s for coloration and 3.5 s for bleaching at 422 nm),high optical contrast(ΔT=45%at 422 nm andΔT=35.2%at 1000 nm),great coloration efficiency(CE=97.1 cm2/C),and high cyclic stability(86%preserved after 3000 cycles).The electrochromic devices(ECD)were successfully assembled by using V_(2)O_(5)-PEDOT films as ion storage layers and electrochromic layers,demonstrating remarkable performance.

关键词： Vanadium oxide PEDOT Nanobelts Interlayer spacing Electrochromic

Applications of single-cell RNA sequencing in spermatogenesis and molecular evolution

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Zoological Research 2024年第3期45卷 575-585页

作者： wen-Bo chen Meng-Fei Zhang Fan Yang Jin-Lian Hua College of Veterinary Medicine Shaanxi Centre of Stem Cells Engineering&TechnologyNorthwest A&F UniversityYanglingShaanxi 712100China Key Laboratory of Livestock Biology Northwest A&F UniversityYanglingShaanxi 712100China

Spermatogenic cell heterogeneity is determined by the complex process of spermatogenesis ***,effectively revealing the regulatory mechanisms underlying mammalian spermatogenic cell development and differentiation via traditional methods is *** in technology have led to the emergence of many single-cell transcriptome sequencing protocols,which have partially addressed these *** this review,we detail the principles of 10x Genomics technology and summarize the methods for downstream analysis of single-cell transcriptome sequencing ***,we explore the role of single-cell transcriptome sequencing in revealing the heterogeneity of testicular ecological niche cells,delineating the establishment and disruption of testicular immune homeostasis during human spermatogenesis,investigating abnormal spermatogenesis in humans,and,ultimately,elucidating the molecular evolution of mammalian spermatogenesis.

关键词： Single-cell RNA sequencing(scRNA-seq) Spermatogenesis Molecular evolution Sertoli cell

Lipase and photodecarboxylase coexpression: A potential strategy for alkane-based biodiesel production from natural triglycerides

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Chinese Journal of Chemical Engineering 2024年第3期67卷 238-246页

作者： Yong-Yi Zeng Xin-Yi Xu Jin-Xuan Xie wen-Li chen Lan Liu Xin-Jian Yin Bi-Shuang chen School of Marine Sciences Sun Yat-Sen UniversityZhuhai 519080China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519080China

Alkane-based biodiesel is considered the next generation of biodiesel owing to its potential environmental benefits and the fact that it exhibits much higher specific caloric values than traditional ***,the formidable obstacle impeding the commercialization of this cutting-edge fuel alternative lies in the cost associated with its *** this study,an engineered strain Escherichia coli(***)showcasing harmonized coexpression of a lipase(from Thermomyces lanuginosus lipase,TLL)and a fatty acid photodecarboxylase(from Chlorella variabilis,CvFAP)was first constructed to transform triglycerides into *** potential of *** BL21(DE3)/pRSFDuet-1-TLL-CvFAP for alkane synthesis was evaluated with tripalmitin as a model substrate under various process *** a comprehensive examination of the reaction parameters,the scope of the biotransformation was expanded to‘real’substrates(vegetable oils).The results showed that bioderived oils can be transformed into alkanes with high yields(0.80-10.20 mmol·L^(-1))under mild conditions(35℃,pH 8.0,and 36 h)and blue light *** selected processes were performed on an increased lab scale(up to 100 ml)with up to 24.77 mmol·L^(-1) tripalmitin,leading to a yield of 18.89 mmol·L^(-1) *** the employment of a method for efficiently producing alkanes under mild conditions and a simple procedure to isolate alkanes from the reaction system,the utilization of sustainable biomass as a fundamental feedstock emerges as the primary solution to lower the cost of alkane-based ***,this study proposes a readily implementable and highly effective approach for alkane-based biodiesel production.

关键词： Alkane-based biodiesel Renewable biomass Co-overexpression Lipase Photodecarboxylase

Promising interlayer sensitization strategy for the construction of high-performance blue hyperfluorescence OLEDs

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Light(Science & Applications) 2024年第7期13卷 1372-1382页

作者： Jianghui Wang Peng Zou Letian chen Zhentao Bai Hao Liu wen-cheng chen Yanping Huo Ben Zhong Tang Zujin Zhao State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640China. School of Chemical Engineering and Light Industry Guangdong University of TechnologyGuangzhou 510006China. School of Science and Engineering Shenzhen Institute of Aggregate Science and TechnologyThe Chinese University of Hong KongShenzhenGuangdong 518172China

Multi-resonance thermally activated delayed fluorescence(MR-TADF)materials are promising candidates for organic light-emitting diodes(OLEDs)with narrow electroluminescence(EL)*** researches focus on fabricating hyperfluorescence OLEDs to improve EL efficiencies of MR-TADF emitters by co-doping them with TADF sensitizers in a single host ***,in many cases,the polarity of the single host could be not suitable for both blue MRTADF emitters and blue TADF sensitizers,resulting in broadened EL spectra in high-polar hosts or decreased EL efficiencies in low-polar ***,we wish to report an efficient sensitization strategy for blue MR-TADF emitters by constructing an interlayer-sensitizing configuration,in which the blue TADF sensitizers and blue MR-TADF emitters are separated into two closely aligned host layers with high polarity and low polarity,*** on this strategy,efficient blue hyperfluorescence OLEDs are realized and verified by employing various TADF sensitizers and different MR-TADF emitters,furnishing outstanding external quantum efficiencies of up to 38.8%and narrow EL *** results validate the feasibility and universality of this interlayer sensitization strategy,which provides an effective alternative to high-performance blue hyperfluorescence OLEDs.

关键词： OLEDs interlayer sensitization

Graph Accelerators—A Case for Sparse Data Processing

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Journal of Computer Science & Technology 2024年第2期39卷 243-244页

作者：陈文光 Department of Computer Science and Technology Tsinghua UniversityBeijing 100084China

Graph is a powerful sparse data structure that intuitively represents entities and their *** graph traversal algorithms such as Breadth-First Search(BFS),Single-Source Shortest Path(SSSP),PageRank,and Weakly Connected Components(WCC)have extensive applications in social network analysis,risk management for finance,and recommendation ***,graph processing in CPUs and GPUs is not very efficient due to its irregular memory *** people have proposed software approaches to speed up graph processing,such as PowerGraph,PowerLyra,and Shentu,which address load imbalance issues by replicating high-degree *** and GridGraph attempt to improve memory access locality by scanning the edge list of graphs while localizing the range of vertices accessed in a *** and Gemini provide adaptive dual compute modes(bottom-up and topdown),which are particularly effective for BFS-like algorithms such as BFS and ***,pure software approaches have their limitations,and it is desired to see how hardware could be employed to accelerate graph processing.

关键词： intuitive desired limitations