检索结果-南通市图书馆

Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO2 photoreduction

Science China Chemistry 2025年第01期 201-208页

作者： Hui-Feng Wang wen-jie Shi Yu-Xin Yang Bao-Xia Dong Tong-Bu Lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou University Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology

Dinuclear metal synergistic catalysis （DMSC） has been proved powerful in boosting CO2reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework （MOF）,obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center （M-In）,three MOFs with dinuclear homometallic catalytic centers （MM-In）,and three MOFs with dinuclear heterometallic catalytic centers (MM’-In,M/M’=Co（II）,Ni（II）,Zn（II）).It was found that all these MOFs can serve as catalysts for photochemical CO2reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g-1h-1,which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO2reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO2reduction.

关键词：

来源：

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Recent progress in metal-organic frameworks(Part II—material application)

引用

Science China Chemistry 2025年

作者： Jiandong Pang wentao Jiang Xue-wen Zhang Hao-Long Zhou Yuxiu Sun Wei Gong Bin Wang Fuyin Ma Linwei He Long Chen Qiang Chen He-Qi Zheng Yuanjing Cui wen-jie Shi Chao Zhang Mei Wang Yue-Biao Zhang jie-Peng Zhang Chongli Zhong Yong Cui Shuao Wang Jian-Rong Li Guodong Qian Tong-Bu Lu Huan Pang Xian-He Bu Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology School of Chemistry and Chemical Engineering Yangzhou University School of Materials Science and Engineering Nankai University School of Physical Science and Technology ShanghaiTech University MOE Key Laboratory of Bioinorganic and Synthetic Chemistry GBRCE for Functional Molecular Engineering School of Chemistry IGCMESun Yat-sen University Department of Chemistry Shantou University School of Chemical Engineering and Technology Tiangong University School of Chemistry and Chemical Engineering Shanghai Jiao Tong University State Key Laboratory of Radiation Medicine and Protection School for Radiological and Interdisciplinary Sciences Soochow University College of Materials Science & Engineering Beijing University of Technology State Key Laboratory of Silicon and Advanced Semiconductor Materials Cyrus Tang Center for Sensor Materials and ApplicationsSchool of Materials Science & Engineering Zhejiang University

As a class of functional crystalline porous materials, metal-organic frameworks(MOFs) gained rapid development in the past three decades and a large number of MOFs with ordered structures, high surface areas, and functionalized channels have been investigated. MOFs and MOF-derived/composite materials show great potential in many application fields. In this review, we discussed the main applications of MOFs and MOF-derived/composite materials in small molecule storage, separation, luminescence, sensing, multitype catalysis, and energy storage. In addition, challenges and problems in the future research of MOFsrelated fields are also discussed.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

环糊精聚合物在食品分析样品前处理中的应用

引用

分析测试学报 2025年第1期44卷 34-42页

作者：王楠王媛宗帅赵文杰河南工业大学化学化工学院河南郑州450001 宁夏计量质量检验检测研究院宁夏银川750411

环糊精聚合物(CDPs)是由环糊精(CD)分子以化学键合等手段构筑的含有多个环糊精单元的高分子衍生物,不仅很好地保留了环糊精的包络识别性能,还兼具聚合物优良的机械强度、稳定性和化学可调性等优点。CDPs在样品前处理中具有广泛的应用潜... 详细信息

环糊精聚合物(CDPs)是由环糊精(CD)分子以化学键合等手段构筑的含有多个环糊精单元的高分子衍生物,不仅很好地保留了环糊精的包络识别性能,还兼具聚合物优良的机械强度、稳定性和化学可调性等优点。CDPs在样品前处理中具有广泛的应用潜力,选择性吸附与分离、高效去除污染物、可再生性与环保性等特性为其在环境保护、食品安全等领域的应用提供了有力支持。该文概括了不同的CDPs的合成方法及其在食品分析样品前处理领域的重要作用,通过与固相微萃取、磁性固相萃取、搅拌棒萃取等技术结合,CDPs能够有效地分离和富集食品中的目标分析物(如农药残留、食品添加剂和天然香味成分等)。并总结与展望了CDPs的发展现状和未来发展趋势。

关键词：环糊精环糊精聚合物样品前处理食品分析选择性吸附

来源：

维普期刊数据库

同方期刊数据库博看期刊评论

在线全文

学校读者我要写书评

暂无评论

Adaptive fuzzy controller for a class of strict-feedback nonaffine nonlinear systems

引用

Journal of Systems Engineering and Electronics 2011年第6期22卷 967-974页

作者： jie wen Changsheng Jiang College of Science Nanjing University of Aeronautics and Astronautics Nanjing 210016 P. R. China College of Automation Engineering Nanjing University of Aeronautics and Astronautics Nanjing 210016 E R. China

A robust adaptive fuzzy control scheme is presented for a class of strict-feedback nonaffine nonlinear systems with modeling uncertainties and external disturbances by using a backstepping *** logic systems are employed to approximate the unknown parts of the desired virtual controls,and the approximation errors of fuzzy systems are only required to be *** function tanh（·） is introduced to avoid problems associated with sgn（·）.The tracking error is guaranteed to be uniformly ultimately bounded with the aid of an additional adaptive compensation ***＇s circuit system and R o¨ssler system are presented to illustrate the feasibility and effectiveness of the proposed control technique.

关键词： fuzzy control nonaffine system backstepping approach Chua's circuit system Ro ¨ssler system tanh function.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Performance Analysis and Improvement of Flat Torque Converters Using DOE Method

引用

Chinese Journal of Mechanical Engineering 2018年第4期31卷 101-109页

作者： Guang-Qiang Wu jie Chen wen-jie Zhu School of Automotive Studies Tongji University Institute of Industrial Science The University of Tokyo

Automotive torque converters have recently been designed with an increasingly narrower profile for the purpose of achieving a smaller axial size and reducing weight. Design of experiment(DOE) and computational fluid dynamics(CFD) techniques are applied to improve the performance of a flat torque converter. Four torque converters with different flatness ratios(0.204, 0.186, 0.172, and 0.158) are designed and simulated first to investigate the effects of flatness ratio on their overall performance, including efficiency, torque ratio, and impeller torque factor. The simulation results show that the overall performance tends to deteriorate as the flatness ratio decreases. Then a parametric study covering six geometric parameters, namely, inlet and outlet angles of impeller, turbine, and stator is carried out. The results demonstrate that the inlet and outlet angles play an important role in determining the performance characteristics of a torque converter. Furthermore, the relative importance of the six design parameters is investigated using DOE method for each response(stall torque ratio and peak efficiency). The turbine outlet angle is found to exert the greatest influence on both responses. After DOE analysis, an optimized design for the flat torque converter geometry is obtained. Compared to the conventional product, the width of the optimized flat torque converter torus is reduced by about 20% while the values of stall torque ratio and peak efficiency are only decreased by 0.4% and 1.7%, *** proposed new optimization strategy based on DOE method together with desirability function approach can be used for performance enhancement in the design process of flat torque converters.

关键词： Torque converter Flatness ratio Computational fluid dynamics(CFD) Parametric study Design of experiment(DOE)

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Cachazo-Svrcek-Witten rules for tree-level gluonic amplitudes revisited

引用

Science China(Physics,Mechanics & Astronomy) 2022年第4期65卷 20-31页

作者： wen-jie Zhang Jun-Bao Wu Chuan-jie Zhu Center for Joint Quantum Studies and Department of Physics School of ScienceTianjin UniversityTianjin 300350China Peng Huanwu Center for Fundamental Theory Hefei 230026China College of Mathematics and Physics Science Hunan University of Arts and ScienceChangde 415000China

We provide a new proof of Cachazo-Svrcek-Witten rules for tree-level gluonic *** a key step,we explicitly demonstrate the cancellation of spurious poles originating from the maximally helicity violating vertices in these *** achieve this,we introduce specially-defined two-off-shell-line sub-amplitudes and examine their residues at spurious poles.

关键词： general properties of perturbation theory perturbative calculations dualities in gauge field theories

来源：

维普期刊数据库

同方期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Coupling potential and viscous flow models with domain decomposition for wave propagations

引用

Journal of Hydrodynamics 2022年第5期34卷 826-848页

作者： wen-jie Zhong wen-tao Wang De-cheng Wan Computational Marine Hydrodynamics Lab(CMHL) School of Naval ArchitectureOcean and Civil EngineeringShanghai Jiao Tong UniversityShanghai200240China China Ship Scientific Research Center Wuxi214082China

Either potential flow or viscous flow based model may be flawed for numerical wave *** two-way coupling of potential and viscous flow models with the domain decomposition utilizing respective strengths has been a trending research *** contrast to existing literatures in which closed source potential models were used,the widely used open source OceanWave3D,OpenFOAM-v2012 are used in the present *** innovative overlapping two-way coupling strategy is developed utilizing the ghost points in *** guarantee computational stability,a relaxation zone used both for outlet damping and data transfer is built over the overlapping region in *** free surface elevation in the relaxation zone is directly probed in OpenFOAM while the velocity potential is indirectly built upon its temporal variation which is calculated by the free surface boundary condition using the probed *** coupling is achieved based on the fourth-order Runge-Kutta(RK)*** two-and three-dimensional tests including linear,nonlinear,irregular,and multi-directional irregular waves,are *** effectiveness of the coupling procedure in bidirectional data transfer is fully demonstrated,and the model is validated to be accurate and efficient,thus providing a competitive alternative for ocean wave simulations.

关键词： Domain decomposition numerical wave tank potential/viscous flow coupling irregular waves wave-structure interaction

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Comparison of time optimal control for two level quantum systems

引用

Journal of Systems Engineering and Electronics 2014年第1期25卷 95-103页

作者： Shuang Cong jie wen Xubo Zou Department of Automation University of Science and Technology of China Key Laboratory of Quantum Information University of Science and Technology of ChinaChinese Academy of Sciences

The time optimal problem for a two level quantum sys-tem is studied. We compare two different control strategies of bang-bang control and the geometric control, respectively, es-pecial y in the case of minimizing the time of steering the state from North Pole to South Pole on the Bloch sphere with bounded control. The time performances are compared for different param-eters by the individual numerical simulation experiments, and the experimental results are analyzed. The results show that the ge-ometric control spends less time than the bang-bang control does.

关键词： geometric control bang-bang control time optimal,comparison,

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

CMAGAN:classifier-aided minority augmentation generative adversarial networks for industrial imbalanced data and its application to fault prediction

引用

Advances in Manufacturing 2024年第3期12卷 603-618页

作者： wen-jie Wang Zhao Liu Ping Zhu School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai200240People’s Republic of China National Engineering Research Center of Automotive Power and Intelligent Control Shanghai Jiao Tong UniversityShanghai200240People’s Republic of China School of Design Shanghai Jiao Tong UniversityShanghai200240People’s Republic of China

Class imbalance is a common characteristic of industrial data that adversely affects industrial data mining because it leads to the biased training of machine learning *** address this issue,the augmentation of samples in minority classes based on generative adversarial networks(GANs)has been demonstrated as an effective *** study proposes a novel GAN-based minority class augmentation approach named classifier-aided minority augmentation generative adversarial network(CMAGAN).In the CMAGAN framework,an outlier elimination strategy is first applied to each class to minimize the negative impacts of ***,a newly designed boundary-strengthening learning GAN(BSLGAN)is employed to generate additional samples for minority *** incorporating a supplementary classifier and innovative training mechanisms,the BSLGAN focuses on learning the distribution of samples near classification ***,it can fully capture the characteristics of the target class and generate highly realistic samples with clear ***,the new samples are filtered based on the Mahalanobis distance to ensure that they are within the desired *** evaluate the effectiveness of the proposed approach,CMAGAN was used to solve the class imbalance problem in eight real-world fault-prediction *** performance of CMAGAN was compared with that of seven other algorithms,including state-of-the-art GAN-based methods,and the results indicated that CMAGAN could provide higher-quality augmented results.

关键词： Class imbalance Minority class augmentation Generative adversarial network(GAN) Boundary strengthening learning(BSL) Fault prediction

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Amorphous phase stability of NbTiAlSiNx high-entropy films

引用

Rare Metals 2018年第8期37卷 682-689页

作者： wen-jie Sheng Xiao Yang jie Zhu Cong Wang Yong Zhang State Key Laboratory for Advanced Metals and Materials University of Science and Technology Beijing Beijing 100083China Center for Condensed Matter and Materials Physics Departmentof Physics Beihang University Beijing 100191 China

In this study, high-entropy films with the compo- sition of NbTiA1SiNx were prepared by a reactive direct current （DC） magnetron sputtering technique, with different nitrogen flow rates （0, 4 and 8 ***^-1）. The microstructures and properties were characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM）, high-resolution transmission electron microscopy （HRTEM）, nano-indenter and spectrophotometer. All of the as-deposited NbTiA1SiNx films are shown to have an amorphous structure, and the films exhibit high thermal stability up to 700℃. The maximum hardness and modulus values of the films reach 20.5 GPa （4 ***-1） and 206.8 GPa （0 ***^-l）, respectively. The films exhibit high absorption of the solar energy in the wavelength of 0.3-2.5 pm, which indicates that NbTiA1SiNx nitride film is a potential candidate solar selective absorbing coating for high-temperature photo-thermal conversion in the concentrated solar power project.

关键词： High-entropy film Sputtering Amorphous Photo-thermal conversion Phase stability

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：