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Experimental Study on the Molten Salt at Micron Scale during the Melting Process

Journal of Thermal Science 2024年第1期33卷 70-85页

作者： TIAN Ziqian LIAO Zhirong xu Chao fang Yongzhe JIANG Kaijun YUAN Mengdi Key Laboratory of Power Station Energy Transfer Conversion and System Ministry of Education of ChinaSchool of Energy Power and Mechanical EngineeringNorth China Electric Power UniversityBeijing 102206China

The investigation of the melting behaviors of the molten salt at micron scale during the melting process is critical for explaining the solid-liquid phase transition *** this paper,a novel experimental system and analysis method were proposed to study the melting process with three heating rates in the range of1-10℃/min of the solar salt at micron *** solid-liquid boundary morphology and phase transition kinetics of molten salt particles were focused ***,the correlations between liquid fraction,temperature and time under different heating rates were *** solid-liquid boundary morphology was depicted by the visualized experimental set-up,and the instantaneous liquid volume fraction during the non-isothermal phase transition was ***,the correlation between temperature and liquid volume fraction was proposed to reveal the evolution of the solid-liquid boundary with temperature at different heating ***,the non-isothermal phase transition kinetic equation was established by introducing a constant parameter(V_(a,b)),and more kinetic parameters such as 1g V_(a,b) and-lg V_(a,b)/b were *** results showed that the exponent b is not sensitive to the heating rate with a range of 3-5 for solar salt ***,the heating rate influences the value of V_(a,b) and presents a positive ***,the non-isothermal phase transition kinetic equations at different heating rates in the range of 1-10℃/min can be quickly predicted by the proposed improved experimental test *** study could fill the research insufficiency and provide significant guidance for future research on the solid-liquid transition mechanism of molten salts at micron scale.

关键词： molten salt non-isothermal phase transition solid-liquid boundary morphology liquid volume fraction micron scale melting process

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Single-atom catalysis for advanced oxidation and reduction systems in water decontamination

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Rare Metals 2024年第8期43卷 3576-3606页

作者： Jie Teng Jin-Hui xu wen-Xin Sun xue-Feng Liu Xia xu Guo-Shuai Liu School of Urban Construction Changzhou UniversityChangzhou 213164China School of Environmental and Civil Engineering Jiangnan UniversityWuxi 214122China

Water scarcity is an escalating global crisis,posing a severe threat to populations ***,exploring various materials to remove emerging contaminants from freshwater sources has garnered significant *** this regard,single-atom catalysis(SACs) has emerged as a catalyst of scientific progress in water purification and treatment methodologies during recent *** exhibit exceptional catalytic activity,selectivity and stability,due to their near-perfect atom utilization,highly unsaturated coordination environment and uniform reaction ***,a comprehensive and critical review encompassing the successful integration of SACs into water purification processes needs to be *** review aims to accentuate recent trends by presenting the synthesis,structure,and environment and energy application-relevant properties of *** results show that a comprehensive and multi-perspective summary of the advantages of SACs in environmental remediation can have significant benefits,such as fast kinetics,costeffectiveness,*** oxidation and reduction processes of SACs and functional SACs materials in water purification were ***,the last section is devoted to the current research gaps and further perspectives on the application of SACs in water treatment,which are summarized and analyzed.

关键词： Single-atom catalysis Water treatment Oxidation Reduction

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In-situ analysis and genetic investigation of Li-bearing minerals in McDermitt clay-type lithium deposit,Nevada,USA

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Acta Geochimica 2024年第3期43卷 478-488页

作者： Yi Cui Hanjie wen Zhengbing Zhou Kunyue Ling Lin xu Shirong Liu Fei xu School of Earth Sciences East China University of TechnologyNanchang 330013China State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China School of Earth Sciences and Resources Chang’an UniversityXi’an 710054China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China State Key Laboratory of Ore Deposit Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China State Key Laboratory of Environmental Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China

Clay-type Li deposits are poised to play a pivotal role in addressing the surging global demand for *** McDermitt clay-type Li deposit,located in Nevada,is the largest Li deposit in the United States,with Li hosted by a clay-rich sequence of smectite-dominated intervals and illite-dominated intervals,***,the occurrence of Li and the genesis of Li-bearing minerals within smectite-dominated intervals have not been thoroughly investigated in previous ***,we studied the mineralogy,the in-situ Li distribution,and the bonding environments of Li within the smectite intervals using a combination of instru-mental techniques including scanning electron microscope,transmission electron microscope,time-of-flight secondary ion mass spectrometry,and nuclear magnetic *** results indicate that the smectite exhibits low crystallinity characteristics of lacustrine clay authigenesis and is com-monly found tofill the interstices among volcanic minerals or envelop them;Li is mainly hosted by Mg-smectite rather than the volcanic *** the tuffaceous sediment samples,the volcanic glass has undergone a transformation,resulting in its complete disappearance and alteration into clay *** to the octahedral sites of Mg-smectite bounded in Li,it is referred to be *** interpret that the hectorite’s precipitation occurs in a high saline-alkaline water environment,a result of McDermitt *** conclusion can be supported by the coexistence of spherulitic calcite and ***,this study confirms hectorite as the main Li-bearing mineral and increases the understanding of the genetic model of hectorite formation in intracontinental caldera basins.

关键词： McDermitt caldera Lithium occurrence Tuffaceous sediments Mineralogy Hectorite neoformation

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Cation-Dipole Interaction-Induced Coacervate Underwater Adhesives in Natural Seawater

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Chinese Journal of Polymer Science 2024年第7期42卷 984-991,I0009页

作者： xu-Fei Liu Chong-Rui Zhang Hua-wen Peng Qiang Zhao Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan430074China

Significant progress has been made in wet adhesives for low salinity water,but exploration of general ionic adhesives for natural seawater is less developed because the high salinity could weaken interfacial bonding and shields electrostatic interactions,resulting in adhesion ***,the design of adhesives for natural seawater represents challenges less ***,a cationic polyelectrolyte(PECHIA)containing imidazolacetonitrile unit was explored to prepare adhesives enabled by natural *** combining the ion shielding effect with the“cation-dipole”interactions between PECHIA chains,aqueous solution of the PECHIA underwent coacervation and self-crosslinking in natural seawater,allowing for underwater adhesion to various substrates in *** instantaneous lap-shear and tensile adhesion strengths are 47 and 119 kPa,respectively,while the cured adhesive shows~739 k Pa tensile adhesion in natural *** design of PECHIA enables wet adhesives viable for applications in the diversified scenarios of natural seawater.

关键词： Coacervate Underwater adhesives Seawater Cation-dipole interaction

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SGT-Net: A Transformer-Based Stratified Graph Convolutional Network for 3D Point Cloud Semantic Segmentation

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Computers, Materials & Continua 2024年第6期79卷 4471-4489页

作者： Suyi Liu Jianning Chi Chengdong Wu fang xu Xiaosheng Yu Faculty of Robot Science and Engineering Northeastern UniversityShenyang110167China State Key Laboratory of Robotics Shenyang Institute of AutomationChinese Academy of SciencesShenyang110016China Institutes for Robotics and Intelligent Manufacturing Chinese Academy of SciencesShenyang110169China SIASUN Robot&Automation Co. Ltd.Shenyang110169China

In recent years,semantic segmentation on 3D point cloud data has attracted much *** 2D images where pixels distribute regularly in the image domain,3D point clouds in non-Euclidean space are irregular and inherently ***,it is very difficult to extract long-range contexts and effectively aggregate local features for semantic segmentation in 3D point cloud *** current methods either focus on local feature aggregation or long-range context dependency,but fail to directly establish a global-local feature extractor to complete the point cloud semantic segmentation *** this paper,we propose a Transformer-based stratified graph convolutional network(SGT-Net),which enlarges the effective receptive field and builds direct long-range ***,we first propose a novel dense-sparse sampling strategy that provides dense local vertices and sparse long-distance vertices for subsequent graph convolutional network(GCN).Secondly,we propose a multi-key self-attention mechanism based on the Transformer to further weight augmentation for crucial neighboring relationships and enlarge the effective receptive *** addition,to further improve the efficiency of the network,we propose a similarity measurement module to determine whether the neighborhood near the center point is *** demonstrate the validity and superiority of our method on the S3DIS and ShapeNet *** ablation experiments and segmentation visualization,we verify that the SGT model can improve the performance of the point cloud semantic segmentation.

关键词： 3D point cloud semantic segmentation long-range contexts global-local feature graph convolutional network dense-sparse sampling strategy

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Thermodynamic geometry of the RN-Ad S black hole and non-local observables

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Communications in Theoretical Physics 2024年第2期76卷 137-144页

作者： Chao Wang Bin Wu Zhen-Ming xu wen-Li Yang Institute of Physics Shaanxi University of TechnologyHanzhong 723000China School of Physics Northwest UniversityXi'an 710127China Institute of Modern Physics Northwest UniversityXi'an 710127China Shaanxi Key Laboratory for Theoretical Physics Frontiers Xi'an 710127China Peng Huanwu Center for Fundamental Theory Xi'an 710127China

This paper studies the thermodynamic geometry of the Reissner–Nordstr?m-anti-de Sitter(RN-AdS)black hole via detection of the non-local observables in the dual field theory,including the entanglement entropy and equal-time two-point correlation *** the dimensional analysis,we construct the principle of corresponding states of black hole *** a result,our findings can be applied to black holes with different Ad S *** this sense,the probe of the thermodynamic geometry of the RN-Ad S black hole though the non-local observables in dual field theory has been confirmed numerically.

关键词： black hole thermodynamic thermodynamic geometry phase transition non-local observables

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Design study of charge-stripping scheme of heavy ion beams for HIAF-BRing

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Nuclear Science and Techniques 2024年第5期35卷 30-41页

作者： Jun-Jie Zhang Zhi-You xu Jin-Quan Zhang wen-wen Ge Liang-Ting Sun Huan-Yu Zhao Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China

Charge strippers play an essential role in heavy-ion accelerators by stripping the projectile ions to higher charge states to enhance the acceleration efficiency downstream of the *** the high-energy mode of the booster ring(BRing)of the high-intensity heavy-ion accelerator facility,the pre-accelerated ions from the iLinac will be stripped by a carbon foil to higher charge states and then injected into the *** key parameters of the stripper and stripped ions were calculated,and the influence of stripping on the beam quality was *** get high stripping efficiencies,the foil thicknesses and resultant charge state distributions for the typical ions were determined by the code *** equilibrium thickness was obtained for the U beam,while the stripper thicknesses for the Xe and Kr beams were determined based on a compromise between the stripped charge states and the stripping *** energy loss,energy straggling,and emittance growth due to stripping have a non-negligible impact on the transport of the stripped beams and the injection of the ***,these parameters were simulated by *** addition,the foil’s temperature evolution,which greatly affects the foil lifetime,was simulated by *** maximum temperature of the foil bombarded by the U and Xe beams with the nominal parameters will exceed the safe value in terms of the impact of evaporation on the foil’s *** the foil temperature constraint,the highest tolerable beam intensity and the injected ion number into the ring were derived for different beam *** results of this paper will present important reference data for the optimization design and commissioning of the beamline and injection to the BRing for the stripped ions.

关键词： High-intensity heavy-ion accelerator facility Charge stripper Energy spread Thermal analysis Emittance growth Injection turns

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Machine learning-based performance predictions for steels considering manufacturing process parameters:a review

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Journal of Iron and Steel Research International 2024年第7期31卷 1555-1581页

作者： Wei fang Jia-xin Huang Tie-xu Peng Yang Long Fu-xing Yin Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and EngineeringHebei University of TechnologyTianjin 300132China Institute of New Materials Guangdong Academy of ScienceGuangzhou 510651GuangdongChina

Steels are widely used as structural materials,making them essential for supporting our lives and ***,further improving the comprehensive properties of steel through traditional trial-and-error methods becomes challenging due to the continuous development and numerous processing parameters involved in steel *** address this challenge,the application of machine learning methods becomes crucial in establishing complex relationships between manufacturing processes and steel *** review begins with a general overview of machine learning methods and subsequently introduces various performance predictions in steel *** classification of performance pre-diction was used to assess the current application of machine learning model-assisted *** important issues,such as data source and characteristics,intermediate features,algorithm optimization,key feature analysis,and the role of environmental factors,were summarized and *** insights will be beneficial and enlightening to future research endeavors in this field.

关键词： Steel Manufacturing process Machine learning Performance prediction Algorithm

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Superatom-assembled boranes,carboranes,and low-dimensional boron nanomaterials based on aromatic icosahedral B_(12)and C_(2)B_(10)

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Nano Research 2024年第7期17卷 6734-6740页

作者： Qiao-Qiao Yan Yan-fang Wei Qiang Chen Yue-wen Mu Si-Dian Li Institute of Molecular Science Shanxi UniversityTaiyuan 030006China

Using the experimentally known aromatic icosahedral superatoms I_(h)B_(12)H_(12)2−and D_(5d)1,12-C_(2)B_(10)H_(12)as building blocks and based on extensive density functional theory calculations,we predict herein a series of core–shell superpolyhedral boranes and carboranes in a bottom-up approach,including the high-symmetry Th B_(12)@B_(152)H_(72)2−(2),C2h C_(2)B_(10)@B_(152)H_(72)(3),D_(3d)B_(12)@B_(144)H_(66)(4),I_(h)B_(12)@C_(24)B_(12)0H_(72)2−(6),and D_(5d)C_(2)B_(10)@C_(24)B_(12)0H_(72)(7).More interestingly,the superatom-assembled linear D2h B_(36)H_(32)^(2−)(8),close-packed planar D_(3d)B_(84)H_(60)^(2−)(10),and nearly close-packed core−shell D_(3d)B_(12)@B144H_(6)6(4)can be extended periodically to form the one-dimensional(1D)α-rhombohedral borane nanowire B_(12)H_(10)(Pmmm)(9),two-dimensional(2D)α-rhombohedral monolayer borophane B_(12)H_(6)(P m1)(11),and the experimentally known three-dimensional(3D)α-rhombohedral boron(R m)(12)which can be viewed as an assembly of the monolayer B_(12)H_(6)(11)staggered in vertical direction,setting up a bottom-up strategy to form low-dimensional boron-based nanomaterials from their borane“seeds”via partial or complete *** bonding analyses indicate that the high stability of these nanostructures originates from the spherical aromaticity of their icosahedral B_(12)or C_(2)B_(10)structural units which possess the universal skeleton electronic configuration of 1S21P61D101F8 following the Wade’s n+1 *** infrared(IR)and Raman spectra of the most-concerned neutral B_(12)@B144H_(6)6(4)and C_(2)B_(10)@C_(24)B_(12)0H_(72)(7)are computationally simulated to facilitate their experimental characterizations.

关键词： superatom-assembling bottom-up approach density functional theory superpolyhedral boranes superpolyhedral carboranes borophanes

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Protective effect of Fu Brick tea on high-fat diet-induced metabolic syndrome: Relevant to protecting the intestinal barrier and regulating the gut microbiota

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Food Science and Human Wellness 2024年

作者： wenwen fang fang Zhou Kuofei Wang Shuai wen Hongzhe Zeng Hao xu Jingyi Tang Jian-an Huang Zhonghua Liu Key Laboratory of Tea Science of Ministry of Education，National Research Center of Engineering and Technology for Utilization of Botanical Functional Ingredients，Key Laboratory for Evaluation and Utilization of Gene Resources of Horticultural Crops， Ministry of Agriculture and Rural Affairs of China， Hunan Agricultural University

This study investigated the therapeutic effects on metabolic syndrome (MetS) and the impact on the intestinal barrier and gut microbiota of Fu brick tea aqueous extracts (FTE) on metabolic syndrome (MetS) in rats fed with a high-fat diet (HFD). Here， the results showed that FTE supplement significantly reduced HFD-induced weight gain， adiposity， dyslipidemia， fasting blood glucose (PBG) increment， and non-alcoholic fatty liver disease (NAFLD). Moreover， FTE supplement resulted in a decline in lipopolysaccharide (LPS) level and attenuation of colonic inflammation and oxidative stress to protect the intestinal barrier function. FTE supplement also maintained the intestinal barrier integrity by improving histological appearance and promoting ZO-1， Occludin， and Claudin-1 protein expression levels. Meanwhile， FTE supplement alleviated the gut microbiota dysbiosis by enhancing the Firmicutes/Bacteroidetes (F/B) ratio and stimulating the colonization of probiotic bacteria such as Akkermansia， Lactobacillus， Adlercreutzia， and Bacteroides. These findings collectively suggest that Fu brick tea could alleviate MetS and Mets-associated traits with the mechanism relevant to the protection of intestinal barrier and gut microbiota regulation.

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