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Genome-wide adenine n6-methylation map reveals epigenomic regulation of lipid accumulation in nannochloropsis

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Plant Communications 2024年第3期5卷 106-122页

作者： Yanhai Gong Qintao Wang Li wei Wensi Liang Lianhong Wang nana Lv Xuefeng Du Jiashun Zhang Chen Shen Yi xin Luyang Sun Jian Xu Single-Cell Center CAS Key Laboratory of BiofuelsShandong Key Laboratory of Energy GeneticsQingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdaoChina Shandong Energy Institute QingdaoChina Qingdao new Energy Shandong Laboratory QingdaoChina University of Chinese Academy of Sciences Beijing 100049China Laboratory for Marine Biology and Biotechnology Qingdao National Laboratory for Marine Science and TechnologyQingdao 266237China

Epigenetic marks on histones and DnA,such as DnA methylation at n6-adenine(6mA),play crucial roles in gene expression and genome maintenance,but their deposition and function in microalgae remain largely ***,we report a genome-wide 6mA map for the model industrial oleaginous microalga nannochloropsis oceanica produced by single-molecule real-time *** in 0.1%of adenines,6mA sites are mostly enriched at the AGGYV motif,more abundant in transposons and 30 untranslated re-gions,and associated with active ***,6mA gradually increases in abundance along the direction of gene transcription and shows special positional enrichment near splicing donor and transcrip-tion termination *** expressed genes tend to show greater 6mA abundance in the gene body than do poorly expressed genes,indicating a positive interaction between 6mA and general transcription ***,knockout of the putative 6mA methylase nO08G00280 by genome editing leads to changes in methylation patterns that are correlated with changes in the expression of molybdenum cofactor,sulfate transporter,glycosyl transferase,and lipase genes that underlie reductions in biomass and oil *** contrast,knockout of the candidate demethylase nO06G02500 results in increased 6mA levels and reduced *** the epigenomic players and their roles in biomass productivity and lipid metabolism lays a foundation for epigenetic engineering of industrial microalgae.

关键词： adenine n6-methylation industrial oleaginous microalgae nannochloropsis oceanica transcriptional regulation epigenomics

Hydrogen production from hydrolysis of naBH_(4) solution over Co-Fe-B@g-C_(3)n_(4)/nF thin film catalyst

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Rare Metals 2024年第6期43卷 2648-2659页

作者： Yan Wang Jia-xin Ma Jian Ren Di Zhang Feng-Yan Xu Ke Zhang Zhong-Qiu Cao Qiu-Ju Sun Guo-De Li Shi-wei Wu Hong-Hui Chen College of Chemistry and Chemical Engineering Shenyang Normal UniversityShenyang 110034China Experimental Center Shenyang Normal UniversityShenyang 110034China Hunan Shande Energy Storage new Materials Research Institute Limited Company Changde 415000China

In this study,the double loaded Co-Fe-B@g-C_(3)n_(4)/nF(nF:ni foam)thin film catalysts were prepared for the first time via chemical deposition method at room *** optimizing the reducing agent concentration to 0.9 mol·L^(-1),the as-obtained Co-Fe-B@g-C_(3)n_(4)/nF exhibited the twisted ribbon structure with more distinct three-dimensional hierarchy and the smaller particle size,showing the good catalytic property for the hydrolysis of naBH_(4)*** H_(2)generation rate of Co-Fe-B@g-C_(3)n_(4)/nF and binary Co-B@g-C_(3)n_(4)/nF under visible light irradiation surpassed the value under natural *** apparent activation energy of Co-Fe-B@g-C_(3)n_(4)/nF(45.0 kJ·mol^(-1))under visible light irradiation was obviously reduced when compared with the natural condition(48.4 kJ·mol^(-1))and binary Co-B@g-C_(3)n_(4)/nF(60.6 kJ·mol^(-1))under visible light ***,the catalytic performance of the optimized Co-Fe-B@g-C_(3)n_(4)/nF thin film catalyst was superior to most of the reported non-noble metal and even noble metal ***,it illustrated that the catalytic H_(2)production performance of Co-Fe-B@g-C_(3)n_(4)/nF thin film was distinctly improved after the introduction of light and multicomponent recombination.

关键词： Sodium borohydride Co-Fe-B@g-C_(3)n_(4)/nF catalyst Chemical deposition Hydrogen production

Polyoxometalates-derived ternary metal oxides electrocatalyst for n_(2) reduction under ambient conditions

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Tungsten 2024年第2期6卷 428-437页

作者： Meng-Le Yang Zhong-xin Jin Xi-Xian Cao xin-Ming Wang Hui-Yuan Ma Hai-Jun Pang Gui-xin Yang The School of Material Science and Chemical Engineering Harbin University of Science and TechnologyHarbin 150040China

Accelerating the breaking of the nitrogen nonpolar bond(n≡n)is an important factor to improve the effi ciency of the electro-catalytic nitrogen reduction reaction(e-nRR).In this work,polyoxometalates-derived FeMo-based ternary oxide materials MoO_(2)-Mo_(4)O_(11)-FeMoO_(4)@X(abbreviated as MoFeO@X,X represents the synthesis temperature of 650,750 and 850℃)were designed and synthesized for e-nRR under ambient *** scanning electron microscopy images of MoFeO@750 show an ellipsoidal-like structure(0.86×0.6μm).The relatively large specifi c surface area,formation of multiple interfaces,together with the synergistic eff ect of iron and molybdenum bimetals,would make MoFeO@X catalyst more easily absorb and activate n_(2)in the ***,the synthesized MoFeO@750 shows an optimal nH_(3)production rate of 16.57μg·h^(−1)·mg cat.^(−1)and Faradaic effi ciency of 12.33%at−0.3 V versus reversible hydrogen electrode(ν***),with outstanding electrochemical and structural stability.

关键词： Polyoxometalates Electrocatalytic nitrogen reduction reaction Ternary oxide Electrocatalyst

A highly reduced Mo_(74) polyoxometalate featuring high proton conductivity accessed by building block strategy

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Science China Chemistry 2024年第3期67卷 862-868页

作者： Shi-Yi Liu Xue-xin Li wei-Chao Chen Kui-Zhan Shao xin-Long Wang Chao Qin Zhong-Min Su Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Department of ChemistryNortheast Normal UniversityChangchun 130024China State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical ChemistryCollege of ChemistryJilin UniversityChangchun 130021China

Highly reduced polyoxometalates(POMs) are predicted to be used as rather high energy density materials;however,it still suffers from the limited cluster species and reduction *** we demonstrate that it is possible to employ the building block strategy to generate a highly reduced polyoxomolybdate(C_(2)H_(8)n)_(14)(nH_(4))_(4)H_(14)[Mo_(48)-ⅤMo_(26)ⅥO_(202)(OH)_(12)(SO_(4))_(6)]·46H_(2)O(Mo_(74)).The fundamental Mo-based{Mo_x}(x=4,5,and 6) building blocks,which are templated by tetra-coordinated anions{MoO_(4)}or{SO_(4)},not only lay foundation for the formation of Mo_(74) featuring an unprecedented reduction ratio of 65%,but also give rise to SBBs-mediated(secondary building blocks) supramolecular dense packing interactions among the isolated Mo_(74) clusters that are favorable for proton ***,high proton conductivity(2.04×10^(-2)S cm^(-1)) had been realized at 50℃ and 90% relative humidity,revealing one of the well-known POMs-based crystalline proton conducting *** result highlights that this building block approach possesses great potential in producing highly reduced POM systems that can achieve controllable reduced ratio and desirable properties.

关键词： polyoxometalate building block molybdenum highly reduced state proton conduction

Facile Semiconductor p-n Homojunction nanowires with Strategic p-Type Doping Engineering Combined with Surface Reconstruction for Biosensing Applications

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nano-Micro Letters 2024年第10期16卷 15-30页

作者： Liuan Li Shi Fang wei Chen Yueyue Li Mohammad Fazel Vafadar Danhao Wang Yang Kang xin Liu Yuanmin Luo Kun Liang Yiping Dang Lei Zhao Songrui Zhao Zongzhi Yin Haiding Sun iGan Laboratory School of MicroelectronicsUniversity of Science and Technology of ChinaHefei 230026People's Republic of China Department of Obstetrics and Gynecology The First Affiliated Hospital of Anhui Medical UniversityNo 218 Jixi RoadHefei 230022People's Republic of China Department of Electrical and Computer Engineering McGill University3480 University StreetMontrealQC H3A 0E9Canada Union Hospital Tongji Medical CollegeHuazhong University of Science and TechnologyNo 1277 Jiefang Ave.Wuhan 430022People's Republic of China

Photosensors with versatile functionalities have emerged as a cornerstone for breakthroughs in the future optoelectronic systems across a wide range of *** particular,emerging photoelectrochemical(PEC)-type devices have recently attracted extensive interest in liquid-based biosensing applications due to their natural electrolyte-assisted operating ***,a PEC-type photosensor was carefully designed and constructed by employing gallium nitride(Gan)p-n homojunction semiconductor nanowires on silicon,with the p-Gan segment strategically doped and then decorated with cobalt-nickel oxide(ConiO_(x)).Essentially,the p-n homojunction configuration with facile p-doping engineering improves carrier separation efficiency and facilitates carrier transfer to the nanowire surface,while ConiO_(x)decoration further boosts PEC reaction activity and carrier dynamics at the nanowire/electrolyte ***,the constructed photosensor achieves a high responsivity of 247.8 mA W^(-1)while simultaneously exhibiting excellent operating ***,based on the remarkable stability and high responsivity of the device,a glucose sensing system was established with a demonstration of glucose level determination in real human *** work offers a feasible and universal approach in the pursuit of high-performance bio-related sensing applications via a rational design of PEC devices in the form of nanostructured architecture with strategic doping engineering.

关键词： p-n Gan nanowires Strategic p-doping Surface decoration Photoelectrochemical sensor Glucose sensing

Stable α-CsPbI3 with extremely red emission for expanding the color gamut

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Science China(Information Sciences) 2024年第5期67卷 311-317页

作者： Yong ZHAnG xin wei Lei GAO weijie ZHAO Changjiu SUn Junli wei Mingjian YUAn Zhenhua nI Junpeng LU Hongwei LIU School of Physics and Key Laboratory of MEMS of the Ministry of Education Southeast University Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education) Renewable Energy Conversion and Storage Center (RECAST) College of Chemistry Nankai University Jiangsu Key Lab on Opto-Electronic Technology School of Physics and TechnologyNanjing Normal University

The wider color gamut represents the better reproducibility of the real natural colors. Perovskite materials exhibit promising potential in full-color wide-gamut displays because of the wide tunability and high saturability of their photon emission. However, the full-color wide gamut(>100% Rec.2020) has not been constructed due to the lack of the extreme red primary color(～700 nm). Herein, the widest color gamut is realized, whereinα-CsPbI3 is used to generate the extreme red primary color. An in-situ encapsulation approach is advised to stabilizeα-CsPbI3 at room temperature by means of polyvinylpyrrolidone(PVP).Theα-CsPbI3 encapsulated by PVP(denoted as P-CPI) shows highly saturated(FWHM(full width at half maximum) ～28 nm) and extremely(～697 nm) red emission. The green emission is provided by P-CPBr(CsPbBr3 with PVP) which is also synthesized using the universal in-situ encapsulation approach. With the assistance of a commercial Ga n chip, the RGB gamut is extended to the widest(151% nTSC, 113%Rec.2020).

关键词： all-inorganic perovskite wide color gamut LED display carrier recombination

Accelerated heterogenous ring-opening polymerization towards well-defined helical poly(n-allyl alanine)with clickable side chains

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Science China Chemistry 2024年第6期67卷 2056-2062页

作者： Anyao Ma xin Wang Sunting Xuan Zhengbiao Zhang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou215123China State Key Laboratory of Radiation Medicine and Protection Soochow UniversitySuzhou215123China

Well-defined poly(n-allyl alanine)has been synthesized by heterogenous ring-opening polymerization(HROP)of less reactive n-allyl-alanine n-carboxyanhydride,using acetic acid as the catalyst and benzylamine as the initiator,in non-polar ***,the polymerization exhibited typical features of living polymerization though both monomer(liquid)and polymer(solid)have minimal solubility in *** obtained polymer showed a stable helix structure independent of the temperatures screened,as evidenced by circular dichroism ***,the preliminary study demonstrated that the side chains can be post-functionalized through thiol-ene click chemistry with quantitative ***,this work provides guidance for the development of accelerated HROP of other liquid monomers bearing low ***,the helical and functionalizable poly(n-allyl alanine)could be a useful“clickable platform”for the design of variable biomaterials via efficient click chemistry.

关键词： heterogenous ring-opening polymerization controlled polymerization stable helix clickable n-substituted polypeptide di-substituted polypeptoid

An integrable generalization of the Fokas–Lenells equation:Darboux transformation, reduction and explicit soliton solutions

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Chinese Physics B 2024年第7期33卷 117-124页

作者：魏姣耿献国王鑫 School of Mathematics and Statistics Zhengzhou UniversityZhengzhou 450001China School of Mathematics and Information Science Zhongyuan University of TechnologyZhengzhou 450007China

Under investigation is an integrable generalization of the Fokas–Lenells equation, which can be derived from the negative power flow of a 2 × 2 matrix spectral problem with three potentials. Based on the gauge transformation of the matrix spectral problem, one kind of Darboux transformation with multi-parameters for the three-component coupled Fokas–Lenells system is constructed. As a reduction, the n-fold Darboux transformation for the generalized Fokas–Lenells equation is obtained, from which the n-soliton solution in a compact Vandermonde-like determinant form is given. Particularly,the explicit one-and two-soliton solutions are presented and their dynamical behaviors are shown graphically.

关键词： Darboux transformation soliton solutions generalized Fokas–Lenells equation

Rational design of Ce-doped CdS/n-rGO photocatalyst enhanced interfacial charges transfer for high effective degradation of tetracycline

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Journal of Materials Science & Technology 2024年第6期173卷 137-148页

作者： Huijie Wang Yang Wan Binrong Li Jian Ye Jiahao Gan Jiejing Liu xin Liu Xianghai Song weiqiang Zhou xin Li Pengwei Huo Institute of Green Chemistry and Chemical Technology School of Chemistry&Chemical EngineeringJiangsu UniversityZhenjiang 212013China national and Local Joint Engineering Laboratory of Municipal Sewage Resource Utilization Technology School of Environmental Science and EngineeringSuzhou University of Science and TechnologySuzhou 215009China Institute of Biomass Engineering Key Laboratory of Energy Plants Resource and UtilizationMinistry of Agriculture and Rural AffairsSouth China Agricultural UniversityGuangzhou 510642China

The charge carrier separation efficiency and the adsorption capacity of the photocatalyst usually affect the degradation rate of ***,Cerium-doped leaf-like CdS(Ce-CdS)modified with ultrathin n-doped rGO(n-rGO)composites were successfully constructed(Ce-CdS/n-rGO)to investigate the removal efficiency of tetracycline(TC).X-ray photoelectron spectroscopy(XPS)and photoelectrochemical results revealed that Ce ions doped in CdS acting as the electron capture sites facilitated the interfacial charge *** calculation(DFT)results indicated that the interfacial effect between Ce-CdS and ultrathin n-rGO promoted the transfer of photogenerated electrons under the synergistic effect between the doping and interface modification *** optimized Ce5-CdS/n-rGO20 composites had the maximum TC removal capability(94.5%)and maintained a stable cycling *** addition,the adsorption-driven photocatalytic degradation pathway of TC was studied through mass spectrometry(MS)and in-situ Fourier transform infrared spectroscopy(in-situ FTIR).This study will provide an effective strategy for the construction of efficient photocatalytic composites for wastewater treatment.

关键词： Interfacial charges transfer Adsorption-driven photocatalytic degradation Synergistic effect Doping strategy Leaf-like CdS