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Advances in selective conversion of carbohydrates into 5-hydroxymethylfurfural

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Green Energy & Environment 2024年第9期9卷 1384-1406页

作者： Jie Liang Jianchun Jiang Tingting Cai Chao liu Jun Ye Xianhai Zeng Kui Wang Institute of Chemical Industry of Forest Products Chinese Academy of Forestry National Engineering Lab.for Biomass Chemical Utilization Co-Innovation Center of Efficient Processing and Utilization of Forest Resources Nanjing Forestry University College of Energy State Key Laboratory of Physical Chemistry of Solid Surfaces Xiamen University

Converting carbohydrates into 5-hydroxymethylfurfural(5-HMF) is an attractive and promising route for value-added utilization of agricultural and forestry biomass resource. As an important platform compound, 5-HMF possesses high active furan structure with hydroxymethyl and aldehyde group for production of various bio-chemicals and materials, meanwhile, which suffer from low stability and poor yield during the industrial biorefinery process. Hence, selective production of 5-HMF with high-yield and low-cost has attracted extensive attention from scientific and industrial researchers. This review sorted and described the latest advanced research on solvent and catalyst system, as well as energy field effect for production of 5-HMF with different feedstock in detail, emphatically discussing the solvent effect and its synergistic effect with other aspects. Besides, the future prospects and challenges for production of 5-HMF from carbohydrates were also presented, which provide a profound insight into industrial 5-HMF process with economic and environmental feature.

关键词： 5-Hydroxymethylfurfural Biorefinery Solvent Selectivity Carbohydrate

Reviewing electrochemical stability of ionic liquids-/deep eutectic solvents-based electrolytes in lithium-ion,lithium-metal and post-lithium-ion batteries for green and safe energy

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Green Energy & Environment 2024年第6期9卷 966-991页

作者： Yu Chen Shuzi liu Zixin Bi Zheng Li Fengyi Zhou Ruifen Shi Tiancheng Mu Department of Chemistry and Material Science Langfang Normal UniversityNO.100 Aimin West RoadLangfangHebei065000China Department of Chemistry Renmin University of ChinNO.59 Zhongguancun StreetHaidian DistrictBeijing100872China

Sustainable energy is the key issue for the environment protection,human activity and economic *** liquids(ILs)and deep eutectic solvents(DESs)are dogmatically regarded as green and sustainable electrolytes in lithium-ion,lithium-metal(e.g.,lithium-sulphur,lithium-oxygen)and post-lithium-ion(e.g.,sodium-ion,magnesium-ion,and aluminum-ion)*** electrochemical stability of ILs/DESs is one of the prerequisites for green,sustainable and safe energy;while easy electrochemical decomposition of ILs/DESs would be contradictory to the concept of green chemistry by adding the cost,releasing volatile/hazardous by-products and hindering the ***,(1)are ILs/DESs-based electrolytes really electrochemically stable when they are not used in batteries?(2)are ILs/DESs-based electrolytes really electrochemically stable in real batteries?(3)how to design ILs/DESs-based electrolytes with high electrochemical stability for batteries to achieve sustainability and green development?Up to now,there is no summary on this topic,to the best of our ***,we review the effect of chemical structure and non-structural factors on the electrochemical stability of ILs/DESs in simulated *** importantly,electrochemical stability of ILs/DESs in real lithium-ion,lithium-metal and post-lithium-ion batteries is concluded and ***,the strategies to improve the electrochemical stability of ILs/DESs in lithium-ion,lithium-metal and post-lithium-ion batteries are *** review would provide a guide to design ILs/DESs with high electrochemical stability for lithium-ion,lithium-metal and postlithium-ion batteries to achieve sustainable and green energy.

关键词： Green solvents Decomposition Sustainable chemistry Lithium-oxygen batteries Lithium-sulphur batteries Sodium-ion batteries

Organo-mineral complexes in soil colloids:Implications for carbon storage in saline-alkaline paddy soils from an eight-year field experiment

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Pedosphere 2024年第1期34卷 97-109页

作者： Mengmeng CHEN Shirong ZHANG Lu liu Baojian CHANG Yuyi LI Xiaodong DING College of Resources and Environment Qingdao Agricultural UniversityQingdao 266109China Jingke High-tech Institute of Environmental Sciences Co. LtdBeijing 100094China Institute of Agricultural Resources and Regional Planning Chinese Academy of Agricultural SciencesBeijing 100081China

The combination of organic carbon(OC) and reactive minerals is a crucial mechanism of soil carbon(C) storage, which is regulated by the formation of organo-mineral complexes on the surface of soil colloids. The effect of organic fertilizer on the storage mechanism of OC in soil colloids was studied through an 8-year field experiment, which included four treatments: i) no fertilization(control, CK), ii) only mineral N, P, and K fertilization(NPK), iii) NPK plus a low level(450 kg C ha^(-1)year^(-1)) of organic fertilization(NPKC1), and iv) NPK plus a high level(900 kg C ha^(-1)year^(-1)) of organic fertilization(NPKC2). The main results indicated that organic fertilizer addition significantly increased the content of aromatic-C, which was 158.7% and 140.0% higher in soil colloids than in bulk soil in the NPKC1 and NPKC2 treatments, respectively. X-ray photoelectron spectroscopy further demonstrated that the relative proportion of C=C group on the surface of soil colloids was increased by 20.1% and 19.1% in the NPKC1 and NPKC2 treatments, respectively,compared with the CK. In addition, compared with the NPK treatment, the content of reactive minerals(such as Fe and Al oxides) significantly increased with organic fertilization, which was positively correlated with C=C group in soil colloids. This indicates that aromatic-C may be retained by the formation of aromatic-mineral complexes with reactive minerals in soil colloids. Organic fertilization also significantly increased OC storage efficiency(OCSE), which was significantly higher in the NPKC1 treatment than in the NPKC2 treatment. Therefore, a moderate amount of organic fertilizer application is a better agronomic practice to increase OCSE and OC storage in saline-alkaline paddy soils.

关键词： aromatic-C aromatic-mineral complex organic fertilization reactive mineral soil organic carbon water-dispersible colloid

Study of interfacial transition zones between magnesium phosphate cement and Portland cement concrete pavement

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Journal of Traffic and Transportation Engineering(English Edition) 2024年第3期11卷 523-537页

作者： Fei liu Baofeng Pan Changjun Zhou Ge Li Xiaocun Wang Jiaquan Li Faculty of Infrastructure Engineering Dalian University of TechnologyDalian 116024China Tongren City Transportation Bureau Tongren 554300China Beijing Civil Aviation Design and Research Institute of China Design Group Beijing 101318China

The Portland cement concrete pavement(PCCP)often suffers from different environmental distresses and vehicle load failure,resulting in slab corner fractures,potholes,and other *** repair has become one of the effective ways to open traffic *** this study,a novel type of rapid repair material,basalt fiber reinforced polymer modified magnesium phosphate cement(BFPMPC),is used to rapidly repair ***,the mechanical properties and characteristics of the repair interfaces which are named interfacial transition zones(ITZs)formed by BFPMPC and cement concrete are focused on as a decisive factor for the performance of the rapid *** changing trend of the elastic moduli was studied by nanoindentation experiments in the ITZs with the deconvolution analysis that the elastic moduli of certain kinds of substances can be *** experimental results show that the elastic modulus of ITZ-1 with a width of about20μm can be regarded as 0.098 times of the aggregate,and 0.51 times of the ordinary Portland cement(OPC)*** BFPMPC-OPC mortar ITZ has roughly the same mechanical properties as the ITZ between aggregate and BFPMPC.A multi-scale representative two-dimensional model was established by random aggregate and a two-dimensional extended finite element method(XFEM)to study the mechanical properties of the repair *** simulation results show that the ITZ formed by the interface of BFPMPC and OPC mortar and basalt aggregate is the most vulnerable to failure,which is consistent with the nano-indentation experimental results.

关键词： Portland cement concrete pavement Interfacial transition zone Magnesium phosphate cement Repair interface Nanoindentation Mechanical properties and characteristics

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三维弹性体夹芯的夹芯板振动计算方法研究

船舶力学 2024年第6期28卷 925-941页

作者：张彤彤王纬波刘媛慧吴健吴文伟中国船舶科学研究中心船舶振动噪声重点实验室江苏无锡214082

目前夹芯结构由于其轻质、减振、隔声等优良性能,已在隔声壁板、减振结构设计等领域得到广泛的应用。夹芯板在低频振动中通常易于表现为弯曲振动模式,但夹芯板面板材料和芯材材料的性能往往差别较大,在中高频段易产生较为丰富的振动模式... 详细信息

目前夹芯结构由于其轻质、减振、隔声等优良性能,已在隔声壁板、减振结构设计等领域得到广泛的应用。夹芯板在低频振动中通常易于表现为弯曲振动模式,但夹芯板面板材料和芯材材料的性能往往差别较大,在中高频段易产生较为丰富的振动模式,因此建立一种适用于各个频段的夹芯板振动理论预报方法是十分必要的。本文发展了一种新的夹芯板振动理论计算方法,对夹芯板的芯材应用三维弹性力学理论,面板应用薄板理论。本文建立的理论方法可综合体现夹芯板弯曲变形模式和膨胀变形模式,容许夹芯板产生法向形变,可显著提高中高频夹芯板的振动预报计算精度。通过算例将本文理论方法的计算结果与其它理论计算方法和有限元计算的结果进行了对比,证明了本文理论方法的有效性和优势。

关键词：夹芯板振动弹性力学

Cerium refinement of grains and primary carbides during solidification of Cr_(4)Mo_(4)V bearing steel

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Journal of Rare Earths 2024年第4期42卷 783-792页

作者： weifeng liu Jianqiang Wang Mingyue Sun Bin Xu Jiahao Yao Qunbo Fan Dianzhong Li Chongqing Innovation Center Beijing Institute of TechnologyChongqing401135China Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang110016China

The effect of cerium(Ce)on the solidification microstructure of Cr_(4)Mo_(4)V bearing steel was investigated via a combined experimental and theoretical *** a trace amount(0.056 wt%)of Ce addition,the coarse columnar grains in as-cast microstructure transform into equiaxed ones,and the average diameter is reduced from 56 to 27μ*** network-like and bulky primary MC and M2C carbides at the interdendritic regions become disconnected and refined,and their volume percentage decreases from4.15 vol%to 2.1 vol%.Ce-inclusions acting as heterogeneous nucleation agents of prior-austenite grains and Ce atoms segregating at grain boundaries,both contribute to the refinement of *** calculations reveal that primary carbides are precipitated afterγ-austenite forms near the end of the solidification *** modification of primary carbides in size and amount is mainly attributed to the isolated remaining melt separated by refinedγ-austenite grains in which the nucleation of carbides is promoted,while the growth is restrained owing to the less segregation of alloying elements.

关键词： Cr_(4)Mo_(4)V bearing steel Rare Earths Grains Primary carbides Refinement

Experimental and numerical analyses of the effect of fibre content on the close-in blast performance of a UHPFRC beam

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Defence Technology（防务技术） 2024年第1期31卷 242-261页

作者： Junbo Yan Qiyue Zhang Yan liu Yingliang Xu Zhenqing Shi Fan Bai Fenglei Huang State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Chongqing Innovation Center Chongqing 401120China

Limited research has been conducted on the influences of fiber content on close-in blasting characteristics for ultrahigh-performance fiber-reinforced concrete(UHPFRC)*** paper aims to address this knowledge gap through experimental and mesoscale numerical *** were conducted on ten UHPFRC beams built with varying steel fiber volumetric fractions subjected to close-in explosive ***,this study considered other parameters,such as the longitudinal reinforcement type and *** the case of UHPFRC beams featuring normal-strength longitudinal reinforcement of diametersΦ12,Φ16,andΦ20,a reduction in maximum displacement by magnitudes of19.6%,19.5%,and 17.4%was observed,respectively,as the volumetric fractions of fiber increased from1.0%to 2.5%.In addition,increasing the longitudinal reinforcement ratio and using high-strength steel longitudinal reinforcement both significantly reduced the deformation characteristics and increase the blasting resistances of UHPFRC ***,the effects on the local crushing and spalling damage were not significant.A mesoscale finite element model,which considers the impacts of fiber parameters on UHPFRC beam behaviors,was also established and well correlated with the test ***,parametric analyses were further conducted to examine the impacts of the steel fiber content and length and the hybrid effects of various types of microfibers and steel fibers on the blasting performance of UHPFRC beams.

关键词： Blast performance Close-in blast Fiber content Mesoscale approach UHPFRC beams

A high Li-ion diffusion kinetics in multidimensional and compact-structured electrodes via vacuum filtration casting

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Journal of Energy Chemistry 2024年第6期93卷 368-376,I0010页

作者： Jieqiong Li Ting Ouyang Lu liu Shu Jiang Yongchao Huang M.-Sadeeq Balogun College of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan UniversityChangsha 410082HunanChina Institute of Environmental Research at Greater Bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006GuangdongChina

Manufacturing process,diffusion co-efficient and areal capacity are the three main criteria for regulating thick electrodes for lithium-ion batteries(LIBs).However,simultaneously regulating these criteria for LIBs is desirable but remains a significant *** this work,niobium pentoxide(Nb_(2)O_(5))anode and lithium iron phosphate(LiFePO_(4))cathode materials were chosen as the model materials and demonstrate that these three parameters can be simultaneously modulated by incorporation of micro-carbon fibers(MCF)and carbon nanotubes(CNT)with both Nb_(2)O_(5) and LFP via vacuum filtration *** as-prepared MNC-20 anode and MLC-20 cathode achieves high reversible areal capacity of≈5.4 m A h cm^(-2)@0.1 C and outstanding Li-ion diffusion coefficients of≈10~(-8)cm~2 s~(-1)in the half-cell *** assembled MNC-20‖MLC-20 full cell LIB delivers maximum energy and power densities of244.04 W h kg^(-1)and 108.86 W kg^(-1),*** excellent electrochemical properties of the asprepared thick electrodes can be attributed to the highly conductive,mechanical compactness and multidimensional mutual effects of the MCF,CNT and active materials that facilitates rapid Li-ion diffusion ***,electrochemical impedance spectroscopy(EIS),symmetric cells analysis,and insitu Raman techniques clearly validates the enhanced Li-ion diffusion kinetics in the present architecture.

关键词： Thick electrodes Carbon nanotubes Li-ion diffusion co-efficient Vacuum filtration technique High areal capacity Lithium-ion batteries

Theoretical study on the effect of H_(2)O on the formation mechanism of NO_(x) precursors during indole pyrolysis

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Frontiers of Chemical Science and Engineering 2024年第6期18卷 99-112页

作者： Ziqi Wang Jun Shen Xuesong liu Sha Wang Shengxiang Deng Hai Zhang Yun Guo School of Mechanical and Automotive Engineering Shanghai University of Engineering ScienceShanghai 201620China School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai 200240China

The incineration technology of kitchen waste is one of the effective technologies to achieve the resource utilization of municipal solid *** is an important stage of *** is a rich initial product in the pyrolysis process of kitchen waste,and the presence of H_(2)O has a significant impact on the decomposition of indole to form NO_(x) ***,this study uses density functional theory method to study the effect of H_(2)O on the thermal decomposition of indole to produce NH_(3),HNCO,and *** H_(2)O participates in the reaction,it can provide oxidative groups to generate a new product HNCO,which is different from the previous findings by indole pyrolysis without the presence of H_(2)***,this study theoretically proves that NH_(3) is easier to form than *** is consistent with the phenomenon that NH_(3) release is higher than HCN release in pyrolysis *** addition,compared with the individual pyrolysis of indole,the participation of H_(2)O reduces the energy barriers for the formation of NH_(3) and HCN during indole pyrolysis,thereby promoting the formation of NH_(3) and HCN.

关键词： indole pyrolysis H_(2)O NO_(x)precursors DFT