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Sharp Isolated Toughness Bound for Fractional(k,m)-Deleted Graphs

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Acta Mathematicae Applicatae Sinica 2025年第1期41卷 252-269页

作者： wei GAO wei-fan WANG Yao-jun CHEN School of Mathematics Hohai UniversityNanjing 210098China Department of Mathematics Zhejiang Normal UniversityJinhua 321004China Department of Mathematics Nanjing UniversityNanjing 210093China

A graph G is a fractional(k,m)-deleted graph if removing any m edges from G,the resulting subgraph still admits a fractional *** k≥2 and m≥1 be ***[2m/k]^(*)=[2m/k]if 2m/k is not an integer,and[2m/k]^(*)=[2m/k]-1 if 2m/k is an *** this paper,we prove that G is a fractional(k,m)-deleted graph if δ(G)≥k+m and isolated toughness meets I(G)>{3-1/m,if k=2 and m≥3,k+[2m/k]^(*)m+1-[2m/k]^(*);***,we show that the isolated toughness bound is tight.

关键词： graph isolated toughness fractional k-factor fractional(k,m)-deleted graph

Hausdorff Measure of Space Anisotropic Gaussian Processes with Non-stationary Increments

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Acta Mathematicae Applicatae Sinica 2025年第1期41卷 114-132页

作者： jun WANG Zhen-long CHEN wei-jie YUAN Guang-jun SHEN School of Mathematics and Physics Anhui Polytechnic UniversityWuhu 241000China School of Statistics and Mathematics Zhejiang Gongshang UniversityHangzhou 310018China Department of Mathematics Anhui Normal UniversityWuhu 241000China

Let X={X(t),t∈R+} be a centered space anisotropic Gaussian process values in R^(d) with non-stationary increments,whose components are independent but may not be identically *** certain conditions,then almost surely c_(1)≤ϕ-m(X([0,1]))≤c_(2),where ϕ denotes the exact Hausdorff measure associated with function ϕ(s)=s1/α_(k)+Σ_(i=1)k(1-αi/αk)log log 1/s for some 1≤k≤d,(α_(1),…,α_(d))∈(0,1]^(d).We also obtain the exact Hausdorff measure of the graph of X on[0,1].

关键词： Hausdorff measure self-similar Gaussian processes non-stationary increment Lamperti theorem

Approved delivery strategies for biopharmaceuticals

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Chinese Chemical Letters 2025年第2期36卷 69-79页

作者： Makhloufi Zoulikha Zhongjian Chen jun Wu wei He School of Pharmacy China Pharmaceutical University Shanghai Skin Disease Hospital Tongji University School of Medicine Department of Geriatric Cardiology Jiangsu Provincial Key Laboratory of Geriatrics The First Affiliated Hospital of Nanjing Medical University

In recent years, biopharmaceuticals have witnessed remarkable advancements, transforming the landscape of therapeutic interventions. Biopharmaceuticals encompassing therapeutics generated through cutting-edge biotechnological methods have shown promising therapeutic outcomes. However, their clinical success hinges significantly on overcoming drug delivery challenges related to stability, intracellular delivery, immunogenicity, and pharmacokinetic properties. Herein, we provide an overview of various marketed macromolecules, including nucleic acids, and immunotherapeutic agents such as cytokines and monoclonal antibodies, as well as other therapeutic peptides/proteins like enzymes, hormones, and coagulation factors. Our primary focus is on elucidating the delivery challenges associated with these macromolecules and highlighting the pivotal role played by drug delivery platforms in the development of currently marketed products, offering valuable insights for both scientific research and the pharmaceutical industry.

关键词： Biopharmaceuticals Drug delivery Monoclonal antibodies Nucleic acids Proteins

Use of forestry waste as an alternative raw material for generating metallurgical coke

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Journal of Iron and Steel Research International 2025年第1期32卷 25-39页

作者： Lin-bo Qin wei Qin An-yi Wang Ling Shi jun Han College of Resources and Environment Engineering Wuhan University of Science and TechnologyWuhan430081HubeiChina Hubei Key Laboratory of Industrial Fume and Dust Pollution Control Jianghan UniversityWuhan430056HubeiChina Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources Wuhan University of Science and TechnologyWuhan430081HubeiChina

Forestry waste(FW)is a significant renewable energy source in *** substitution of coal blends(BC)with forestry waste to produce metallurgical coke was investigated aiming at expanding alternative resources and reducing CO_(2)emissions in ironmaking *** BC with different ratios of FW were carbonized in a fixed bed reactor,and the physicochemical structure of the coke derived from FW/BC co-carbonization was characterized by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy,solid-state^(13)C nuclear magnetic resonance,optical microscopy,and scanning electron *** results reveal that the suitable incorporation of FW in BC is 10 wt.%,and the index of coke quality exhibits a good correlation with the optical anisotropy index and the aromaticity of the as-obtained *** partial substitution of BC with FW exhibits potential benefits for colloid formation,owing to the higher hydrogen in ***,as the substitution ratio of BC with FW increases,it inhibits coke agglomeration due to more tortuous stacked structures formation during volatile releasing ***,it was identified that the substitution of higher BC ratios with FW results in the partial replacement of aromatic carbons by oxygenlinked carbons and aliphatic *** substitution leads to a reduction in the aromaticity of the as-obtained coke.

关键词： Metallurgical coke Forestry waste Coal blend Co-carbonization Chemical structure

A Multi-Condition Sequential Network Ensemble for Industrial Energy Storage Prediction Considering the Condition Switching Characteristics

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IEEE/CAA Journal of Automatica Sinica 2025年第2期12卷 369-380页

作者： Tianyu Wang Fan Zhou Yangjie Wu jun Zhao wei Wang IEEE the School of Control Science and Engineering Dalian University of Technology the School of Information Science and Engineering Dalian Polytechnic University

As a crucial storage and buffering apparatus for balancing the production and consumption of byproduct gases in industrial processes, accurate prediction of gas tank levels is essential for optimizing energy system scheduling. Considering that the continuous switching of the pressure and valve status(mechanism knowledge) would bring about multiple working conditions of the equipment, a multi-condition time sequential network ensembled method is proposed. In order to especially consider the time dependence of different conditions, a centralwise condition sequential network is developed, where the network branches are specially designed based on the condition switching sequences. A branch combination transfer learning strategy is developed to tackle the sample imbalance problem of different condition data. Since the condition or status data are real-time information that cannot be recognized during the prediction process, a pre-trained and ensemble learning approach is further proposed to fuse the outputs of the multi-condition networks and realize a transient-state involved prediction. The performance of the proposed method is validated on practical energy data coming from a domestic steel plant, comparing with the state-of-the-art algorithms. The results show that the proposed method can maintain a high prediction accuracy under different condition switching cases, which would provide effective guidance for the optimal scheduling of the industrial energy systems.

关键词： Ensemble learning industrial energy prediction multi-working condition structural deep network transfer learning

EDA-complexes-enabled photochemical synthesis of α-amino acids with imines and tetrabutylammonium oxalate

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Chinese Chemical Letters 2025年第1期36卷 1-2页

作者： Min-Hang Zhou jun Jiang wei-Min He School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001China

The synthesis ofα-amino acid from imines with different carbonyl sources is attractive for both synthetic organic and medicinal chemistry ***,which were easily available from the corresponding ketones and amines,were employed as one of the most ideal ***,cyanation and subsequent hydrolysis were required to install the carboxyl group^([1]).In these cases,the toxicity of the cyanation reagents limited its further synthetic applications in organic ***,metal activation of imine substrates to make the organometallic intermediate and trap CO_(2) to give the desiredα-amino acid were also developed by many groups(Scheme 1A).The utilization of stoiochiometric amounts of metal reagents was required to realize the ***,Yu reported a novel photocatalytic reductive carboxylation protocol for synthesis ofα-amino acid from imines with CO_(2)as the carbonyl source^([2]).

关键词： synthesis carbonyl photochemical

Travelling characteristics of road vehicles on single-level rail-cum-road bridge under the dynamic and aerodynamic impact of travelling trains

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Earthquake Engineering and Engineering Vibration 2025年第1期24卷 235-256页

作者： He Jiajun Lu jun Guo wei Dong Lianjie Bai Xue Li Yongle Southwest Municipal Design&Research Institute of China Chengdu 610299China Southwest Jiaotong University Chengdu 610031China

Aerodynamic and dynamic interference from trains is a key issue of concern for the safety of road vehicles travelling on single-level rail-cum road *** on the wind-road vehicle-train-bridge(WRTB)coupled vibration system developed herein,this study examines the dynamic characteristics when road vehicles meet trains in this *** influence of load combination,vehicle type and vehicle location is analyzed.A method to obtain the aerodynamic load of road vehicles encountering the train at an arbitrary wind speed is *** results show that due to the windproof facilities and the large line distance between the railway and highway,the aerodynamic and dynamic influence of trains on road vehicles is slight,and the vibration of road vehicles depends on the road *** the road vehicles discussed,the bus is the easiest to rollover,and the truck-trailer is the easiest to *** with the aerodynamic impact of trains,the crosswind has a more significant influence on road *** first peak/valley value of aerodynamic loads determines the maximum dynamic response,and the quick method is optimized based on this *** cases show that the optimized method can produce conservative results and can be used for relevant research or engineering applications.

关键词： single-level rail-cum-road bridge vehicle-bridge coupled vibration dynamic characteristic aerodynamic impact road vehicle

Discovery of a new family member of arsenic–vanadium polyoxometalates with high catalytic performance for one-pot coupling of CO2, epoxides and amines

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Tungsten 2025年第1期7卷 80-87页

作者： Fang-Qian Wang Yin Zhang wei-wei Wang Mei-Qian Fu Hong-Bing Mo wei-Dong Yu Chao Liu jun Yan College of Chemistry and Chemical Engineering Central South University junior Education Department Changsha Normal University School of Science Hunan University of Technology and Business

Arsenic-vanadium polyoxometalates（POMs） represent a family of tremendous potential catalysts owing to their peculiar physical and chemical *** in CO2conversion,using POMs to catalyze the conversion of CO2and epoxide into chemical intermediates is the research ***,A new family number of arsenic-vanadium POMs,[N（CH3）4]4[As8V12O38（H2O）]·2H2O({As8V12O38}),was reported and characterized by single-crystal X-ray diffraction,fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy,*** from other allotropicity,{As8V12O38}shows a different structure pattern with an I-43d *** obtained {As8V12O38} was employed as a catalyst for the *** initial catalytic reaction confirmed that {As8V12O38} can catalyze the formation of epoxy carbonate by using 1.01 kPa CO2and epoxide at 70℃.Furtherly,when added amine in the catalytic system,oxazolidinone could be obtained by high yields,which provides an efficient way to convert CO2into profitable ***,a possible catalytic reaction mechanism was proposed by using different characterization analyses.{As8V12O38} first catalyzes the epoxide and CO2to form an epoxy carbonate and then catalyzes epoxy carbonate and benzylamine into oxazolidinone.

关键词： Arsenic CO2 conversion Oxazolidinone Polyoxometalates Vanadium

From waste to wealth:Coal tar residue derived carbon materials as low-cost anodes for potassium-ion batteries

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 464-475页

作者： Zhonghua Lu jun Shen Xin Zhang Lingcong Chao Liang Chen Ding Zhang Tao wei Shoudong Xu College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024China College of Chemistry Taiyuan University of TechnologyTaiyuan 030024China School of Chemical Engineering and Pharmacy Wuhan Institute of TechnologyWuhan 430205China School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China

Carbon materials are widely recognized as highly promising electrode materials for various energy storage system *** tar residues(CTR),as a type of carbon-rich solid waste with high value-added utilization,are crucially important for the development of a more sustainable *** this study,we employed a straightforward direct carbonization method within the temperature range of 700-1000℃to convert the worthless solid waste CTR into economically valuable carbon materials as anodes for potassium-ion batteries(PIBs).The effect of carbonization temperature on the microstructure and the potassium ions storage properties of CTR-derived carbons(CTRCs)were systematically explored by structural and morphological characterization,alongside electrochemical performances *** on the co-regulation between the turbine layers,crystal structure,pore structure,functional groups,and electrical conductivity of CTR-derived carbon carbonized at 900℃(CTRC-900H),the electrode material with high reversible capacity of 265.6m Ah·g^(-1)at 50 m A·g^(-1),a desirable cycling stability with 93.8%capacity retention even after 100 cycles,and the remarkable rate performance for PIBs were ***,cyclic voltammetry(CV)at different scan rates and galvanostatic intermittent titration technique(GITT)have been employed to explore the potassium ions storage mechanism and electrochemical kinetics of *** indicate that the electrode behavior is predominantly governed by surface-induced capacitive processes,particularly under high current densities,with the potassium storage mechanism characterized by an“adsorption-weak intercalation”*** work highlights the potential of CTR-based carbon as a promising electrode material category suitable for high-performance PIBs electrodes,while also provides valuable insights into the new avenues for the high value-added utilization of CTR.

关键词： coal tar residue carbon materials anode potassium-ion batteries high value-added