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Rare Metals 2023年第11期42卷 3630-3637页

作者： Jing Wang Qing-Bin Xu Jin-Xin Liu wei-jun kong Lin-Chun Shi Key Laboratory of Chinese Medicine Resources Conservation State Administration of Traditional Chinese Medicine of the Peoples Republic of ChinaEngineering Research Center of Chinese Medicine Resource of Ministry of EducationInstitute of Medicinal Plant DevelopmentChinese Academy of Medical Sciences and Peking Union Medical CollegeBeijing100193China School of Traditional Chinese Medicine Capital Medical UniversityBeijing100069China

A new kind of UiO-66-NH_(2) and RuO_(2) composite loaded on carbon fiber was prepared by pulsed laser deposition and electrophoretic deposition,which was then utilized as working electrode in developing an electrochemical sensor for ferulic acid *** morphology,composition,chemical valence states of the developed composite were *** electrochemical redox reactions of ferulic acid were explored.

关键词： composite fiber carbon

Aerobic Heterogeneous Palladium-Catalyzed Oxidative Allenic C−H Arylation:Benzoquinone as a Direct Redox Mediator between O_(2)and Pd

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CCS Chemistry 2021年第6期3卷 1127-1137页

作者： wei-jun kong Michaela Reil Lei Feng Man-Bo Li Jan-E.Bäckvall Department of Organic Chemistry Arrhenius LaboratoryStockholm UniversitySE-10691 Stockholm Institute of Physical Science and Information Technology Anhui UniversityHefeiAnhui 230601 Department of Natural Sciences Mid Sweden UniversitySE-85170 Sundsvall

Transitionmetal-catalyzedaerobicoxidativereactions using molecular oxygen as the terminal oxidant play a significant role in organic ***(BQ)has been widely used as an electron-transfer mediator(ETM)in biomimetic palladium-catalyzed aerobic oxidative reactions,but always together with an ETM between O_(2) and BQ,such as a macrocyclic metal ***,we report on a heterogeneous palladium-catalyzed allenic C(sp3)-H arylation with only catalytic amounts of BQ under air without the need of an additional *** ofmultisubstituted 1,3-dienes were synthesized under mild reaction *** studies reveal the bifunctional role of BQ as a ligand for reductive elimination and as an ETM between Pd(0)and O_(2).This new regime of oxidation has important implications for further development of other transition metal-catalyzed aerobic oxidative reactions.

关键词： aerobic oxidation benzoquinone C-H activation heterogeneous palladium

Sharp Isolated Toughness Bound for Fractional(k,m)-Deleted Graphs

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Acta Mathematicae Applicatae Sinica 2025年第1期41卷 252-269页

作者： wei GAO wei-fan WANG Yao-jun CHEN School of Mathematics Hohai UniversityNanjing 210098China Department of Mathematics Zhejiang Normal UniversityJinhua 321004China Department of Mathematics Nanjing UniversityNanjing 210093China

A graph G is a fractional(k,m)-deleted graph if removing any m edges from G,the resulting subgraph still admits a fractional *** k≥2 and m≥1 be ***[2m/k]^(*)=[2m/k]if 2m/k is not an integer,and[2m/k]^(*)=[2m/k]-1 if 2m/k is an *** this paper,we prove that G is a fractional(k,m)-deleted graph if δ(G)≥k+m and isolated toughness meets I(G)>{3-1/m,if k=2 and m≥3,k+[2m/k]^(*)m+1-[2m/k]^(*);***,we show that the isolated toughness bound is tight.

关键词： graph isolated toughness fractional k-factor fractional(k,m)-deleted graph

Pretreatment red blood cell distribution width as a predictive marker for postoperative complications after laparoscopic pancreatoduodenectomy

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World Journal of Gastrointestinal Oncology 2025年第1期17卷 143-157页

作者： Xian-Rang Cao Yin-Long Xu Jia-wei Chai Kai Zheng jun-Jie kong jun Liu Shun-Zhen Zheng Department of Liver Transplantation and Hepatobiliary Surgery Shandong Provincial Hospital Affiliated to Shandong First Medical UniversityJinan 250021Shandong ProvinceChina Department of Breast and Thyroid Surgery Shandong Provincial Maternal and Child Health Care HospitalJinan 250014Shandong ProvinceChina

BACKGROUND Red blood cell distribution width(RDW)is associated with the development and progression of various *** To explore the association between pretreatment RDW and short-term outcomes after laparoscopic pancreatoduodenectomy(LPD).METHODS A total of 804 consecutive patients who underwent LPD at our hospital between March 2017 and November 2021 were retrospectively *** between pretreatment RDW and clinicopathological characteristics and short-term outcomes were *** Patients with higher pretreatment RDW were older,had higher Eastern Cooperative Oncology Group scores and were associated with poorer short-term outcomes than those with normal *** pretreatment RDW was an independent risk factor for postoperative complications(POCs)(hazard ratio=2.973,95%confidence interval:2.032-4.350,P<0.001)and severe POCs of grade IIIa or higher(hazard ratio=3.138,95%confidence interval:2.042-4.824,P<0.001)based on the Clavien-Dino classification *** analysis showed that high pretreatment RDW was an independent risk factor for Clavien-Dino classi-fication grade IIIb or higher POCs,a comprehensive complication index score≥26.2,severe postoperative pancreatic fistula,severe bile leakage and severe *** pretreatment RDW was positively associated with the neutrophil-to-lymphocyte ratio and platelet-to-lymphocyte ratio and was negatively associated with albumin and the prognostic nutritional *** Pretreatment RDW was a special parameter for patients who underwent *** was associated with malnutrition,severe inflammatory status and poorer short-term *** could be a surrogate marker for nutritional and inflammatory status in identifying patients who were at high risk of developing POCs after LPD.

关键词： Biomarker Laparoscopic pancreatoduodenectomy Postoperative complication Red blood cell distribution width Short-term outcomes

Hausdorff Measure of Space Anisotropic Gaussian Processes with Non-stationary Increments

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Acta Mathematicae Applicatae Sinica 2025年第1期41卷 114-132页

作者： jun WANG Zhen-long CHEN wei-jie YUAN Guang-jun SHEN School of Mathematics and Physics Anhui Polytechnic UniversityWuhu 241000China School of Statistics and Mathematics Zhejiang Gongshang UniversityHangzhou 310018China Department of Mathematics Anhui Normal UniversityWuhu 241000China

Let X={X(t),t∈R+} be a centered space anisotropic Gaussian process values in R^(d) with non-stationary increments,whose components are independent but may not be identically *** certain conditions,then almost surely c_(1)≤ϕ-m(X([0,1]))≤c_(2),where ϕ denotes the exact Hausdorff measure associated with function ϕ(s)=s1/α_(k)+Σ_(i=1)k(1-αi/αk)log log 1/s for some 1≤k≤d,(α_(1),…,α_(d))∈(0,1]^(d).We also obtain the exact Hausdorff measure of the graph of X on[0,1].

关键词： Hausdorff measure self-similar Gaussian processes non-stationary increment Lamperti theorem

Approved delivery strategies for biopharmaceuticals

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Chinese Chemical Letters 2025年第2期36卷 69-79页

作者： Makhloufi Zoulikha Zhongjian Chen jun Wu wei He School of Pharmacy China Pharmaceutical University Shanghai Skin Disease Hospital Tongji University School of Medicine Department of Geriatric Cardiology Jiangsu Provincial Key Laboratory of Geriatrics The First Affiliated Hospital of Nanjing Medical University

In recent years, biopharmaceuticals have witnessed remarkable advancements, transforming the landscape of therapeutic interventions. Biopharmaceuticals encompassing therapeutics generated through cutting-edge biotechnological methods have shown promising therapeutic outcomes. However, their clinical success hinges significantly on overcoming drug delivery challenges related to stability, intracellular delivery, immunogenicity, and pharmacokinetic properties. Herein, we provide an overview of various marketed macromolecules, including nucleic acids, and immunotherapeutic agents such as cytokines and monoclonal antibodies, as well as other therapeutic peptides/proteins like enzymes, hormones, and coagulation factors. Our primary focus is on elucidating the delivery challenges associated with these macromolecules and highlighting the pivotal role played by drug delivery platforms in the development of currently marketed products, offering valuable insights for both scientific research and the pharmaceutical industry.

关键词： Biopharmaceuticals Drug delivery Monoclonal antibodies Nucleic acids Proteins

Use of forestry waste as an alternative raw material for generating metallurgical coke

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Journal of Iron and Steel Research International 2025年第1期32卷 25-39页

作者： Lin-bo Qin wei Qin An-yi Wang Ling Shi jun Han College of Resources and Environment Engineering Wuhan University of Science and TechnologyWuhan430081HubeiChina Hubei Key Laboratory of Industrial Fume and Dust Pollution Control Jianghan UniversityWuhan430056HubeiChina Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources Wuhan University of Science and TechnologyWuhan430081HubeiChina

Forestry waste(FW)is a significant renewable energy source in *** substitution of coal blends(BC)with forestry waste to produce metallurgical coke was investigated aiming at expanding alternative resources and reducing CO_(2)emissions in ironmaking *** BC with different ratios of FW were carbonized in a fixed bed reactor,and the physicochemical structure of the coke derived from FW/BC co-carbonization was characterized by Fourier transform infrared spectroscopy,X-ray photoelectron spectroscopy,solid-state^(13)C nuclear magnetic resonance,optical microscopy,and scanning electron *** results reveal that the suitable incorporation of FW in BC is 10 wt.%,and the index of coke quality exhibits a good correlation with the optical anisotropy index and the aromaticity of the as-obtained *** partial substitution of BC with FW exhibits potential benefits for colloid formation,owing to the higher hydrogen in ***,as the substitution ratio of BC with FW increases,it inhibits coke agglomeration due to more tortuous stacked structures formation during volatile releasing ***,it was identified that the substitution of higher BC ratios with FW results in the partial replacement of aromatic carbons by oxygenlinked carbons and aliphatic *** substitution leads to a reduction in the aromaticity of the as-obtained coke.

关键词： Metallurgical coke Forestry waste Coal blend Co-carbonization Chemical structure

P-tuned FeN2 binuclear sites for boosted CO2 electro-reduction

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Journal of Energy Chemistry 2025年第2期101卷 816-824页

作者： Cao Guo Sanshuang Gao jun Li Menglin Zhou Abdukader Abdukayum Qingquan kong Yingtang Zhou Guangzhi Hu School of Materials and Energy Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental Science Yunnan University Xinjiang Key Laboratory of Novel Functional Materials Chemistry College of Chemistry and Environmental Sciences Kashi University School of Mechanical Engineering Chengdu University National Engineering Research Center for Marine Aquaculture Marine Science and Technology College Zhejiang Ocean University

The recycling of CO2through electrochemical processes offers a promising solution for alleviating the greenhouse effect;however,the activation of CO2and desorption of*CO in electrocatalytic CO2reduction（ECR） frequently encounter high energy barriers and competitive hydrogen evolution reactions（HERs）,which are urgent problems that need to be *** this study,a catalyst(P100-Fe-N/C) with homogeneous P-tuned FeN2binuclear sites（N2PFe-FePN2） was successfully synthesised,demonstrating satisfactory performance in the ECR to CO.P100-Fe-N/C attains a peak FECOof 98.01% and a normalized TOF of664.7 h-1at-0.7 VRHE,surpassing the performance of the Fe binuclear catalyst without P and singleatoms *** the MEA cell,a FECOexceeding 90% can still be *** functional theory analysis indicates that the asymmetric coordination configuration induced by the incorporation of P facilitates a reduction in the system's *** modulation of P results in the d-band centre of the catalyst being positioned closer to the Fermi level,which facilitates the interaction of the catalyst with CO2,allowing more electrons to be injected into the CO2molecule at the Fe binuclear sites and inhibiting the *** P-tuned FeN2binuclear sites effectively lower the*CO desorption barrier.

关键词： CO2 reduction reaction DFT calculation Diatomic catalyst Electrocatalysis Heteroatom doping

A Multi-Condition Sequential Network Ensemble for Industrial Energy Storage Prediction Considering the Condition Switching Characteristics

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IEEE/CAA Journal of Automatica Sinica 2025年第2期12卷 369-380页

作者： Tianyu Wang Fan Zhou Yangjie Wu jun Zhao wei Wang IEEE the School of Control Science and Engineering Dalian University of Technology the School of Information Science and Engineering Dalian Polytechnic University

As a crucial storage and buffering apparatus for balancing the production and consumption of byproduct gases in industrial processes, accurate prediction of gas tank levels is essential for optimizing energy system scheduling. Considering that the continuous switching of the pressure and valve status(mechanism knowledge) would bring about multiple working conditions of the equipment, a multi-condition time sequential network ensembled method is proposed. In order to especially consider the time dependence of different conditions, a centralwise condition sequential network is developed, where the network branches are specially designed based on the condition switching sequences. A branch combination transfer learning strategy is developed to tackle the sample imbalance problem of different condition data. Since the condition or status data are real-time information that cannot be recognized during the prediction process, a pre-trained and ensemble learning approach is further proposed to fuse the outputs of the multi-condition networks and realize a transient-state involved prediction. The performance of the proposed method is validated on practical energy data coming from a domestic steel plant, comparing with the state-of-the-art algorithms. The results show that the proposed method can maintain a high prediction accuracy under different condition switching cases, which would provide effective guidance for the optimal scheduling of the industrial energy systems.

关键词： Ensemble learning industrial energy prediction multi-working condition structural deep network transfer learning

EDA-complexes-enabled photochemical synthesis of α-amino acids with imines and tetrabutylammonium oxalate

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Chinese Chemical Letters 2025年第1期36卷 1-2页

作者： Min-Hang Zhou jun Jiang wei-Min He School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001China

The synthesis ofα-amino acid from imines with different carbonyl sources is attractive for both synthetic organic and medicinal chemistry ***,which were easily available from the corresponding ketones and amines,were employed as one of the most ideal ***,cyanation and subsequent hydrolysis were required to install the carboxyl group^([1]).In these cases,the toxicity of the cyanation reagents limited its further synthetic applications in organic ***,metal activation of imine substrates to make the organometallic intermediate and trap CO_(2) to give the desiredα-amino acid were also developed by many groups(Scheme 1A).The utilization of stoiochiometric amounts of metal reagents was required to realize the ***,Yu reported a novel photocatalytic reductive carboxylation protocol for synthesis ofα-amino acid from imines with CO_(2)as the carbonyl source^([2]).

关键词： synthesis carbonyl photochemical