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Construct a 3D microsphere of HMX/B/Al/PTFE to obtain the high energy and combustion reactivity

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Defence Technology（防务技术） 2024年第2期32卷 45-54页

作者： Jian Wang Jie Chen Yaofeng mao Yongjun Deng wei Cao Fude Nie Jun Wang Institute of Chemical Materials China Academy of Engineering PhysicsMianyang 621999PR China Shock and Vibration of Engineering Materials and Structures Key Lab of Sichuan Province Mianyang 621010PR China

Metal(aluminum and boron)based energetic materials have been wildly applied in various fields including aerospace,explosives and micro-devices due to their high energy ***,the low combustion efficiency and reactivity of metal fuels,especially boron(B),severely limit their practical ***,multi-component 3D microspheres of HMX/B/Al/PTFE(HBA)have been designed and successfully prepared by emulsion and solvent evaporation method to achieve superior energy and combustion *** reactivity and energy output of HBA are systematically measured by ignitionburning test,constant-volume explosion vessel system and bomb *** to the increased interfacial contact and reaction area,HBA shows higher flame propagation rate,faster pressurization rate and larger combustion heat of 29.95 cm/s,1077 kPa/s,and 6164.43 J/g,which is 1.5 times,3.5 times,and 1.03 times of the physical mixed counterpart(HBA-P).Meanwhile,HBA also shows enhanced energy output and reactivity than 3D microspheres of HMX/B/PTFE(HB)resulting from the high reactivity of *** reaction mechanism of 3D microspheres is comprehensively investigated through combustion emission spectral and thermal analysis(TG-DSC-MS).The superior reactivity and energy of HBA originate from the surface etching of fluorine to the inert shell(Al_(2)O_(3) and B_(2)O_(3))and the initiation effect of Al to *** work offers a promising approach to design and prepare high-performance energetic materials for the practical applications.

关键词： HMX/B/Al/PTFE 3D microspheres Surface etching Reaction mechanism

Single Particle Colorimetric Acid Phosphatase Activity Assay with CeO_(2)-modified Gold Nanoparticles

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Chemical Research in Chinese Universities 2024年第2期40卷 320-325页

作者： ZHU Tang Jiayao YUAN Xiang mao Guojiang wei Lin XIAO Lehui Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research National and Local Joint Engineering Laboratory for New Petrochemical Materials and Fine Utilization of ResourcesCollege of Chemistry and Chemical EngineeringHunan Normal UniversityChangsha410081P.R.China Henan Key Laboratory of Organic Functional Molecule and Drug Innovation Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine ChemicalsKey Laboratory of Green Chemical Media and ReactionsMinistry of EducationSchool of Chemistry and Chemical EngineeringHenan Normal UniversityXinxiang453007P.R.China College of Chemistry and Chemical Engineering Central South UniversityChangsha410083P.R.China

Acid phosphatase(ACP)is a ubiquitous phosphatase in living *** abnormal variation of ACP is related to various ***,we propose a colorimetric method based on CeO_(2)-modified gold core shell nanoparticles(Au@CeO_(2)NPs)to analyze ACP activity with high sensitivity and *** this design,2-phospho-L-ascorbic acid trisodium salt(AAP)is dephosphorylated by ACP and produces reductive ascorbic acid(AA),which makes the CeO_(2)shell decomposition.A remarkable blue shift of localized surface plasmon resonance peak(LSPR,from yellow to green)along with the scattering intensity ratio changes from individual Au@CeO_(2)NPs are *** activity can be quantified by calculating the ratio changes of individual Au@CeO_(2)*** assay reveals limit of detection(LOD)of 0.044 mU/mL and the linear range of 0.05–5.0 mU/mL,which are much lower than most of spectroscopic measurements in bulk ***,the recovery measurements in real samples are satisfactory and the capacity for practical application is *** a consequence,Au@CeO_(2)NPs used in this assay will find new applications for the ultrasensitive detection of enzyme activity.

关键词： Single particle imaging Dark field Gold nanoparticle Enzyme activity Colorimetric detection

A novel method for simulating nuclear explosion with chemical explosion to form an approximate plane wave: Field test and numerical simulation

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第6期16卷 2137-2153页

作者： wei Ming Xiaojie Yang Yadong mao Xiang Wang Manchao He Zhigang Tao College of Civil and Architecture Engineering North China University of Science and TechnologyTangshan063210China State Key Laboratory for Tunnel Engineering China University of Mining and Technology-BeijingBeijing100083China School of Mechanics and Civil Engineering China University of Mining and Technology-BeijingBeijing100083China

A nuclear explosion in the rock mass medium can produce strong shock waves,seismic shocks,and other destructive effects,which can cause extreme damage to the underground protection *** the increase in nuclear explosion power,underground protection engineering enabled by explosion-proof impact theory and technology ushered in a new *** paper proposes to simulate nuclear explosion tests with on-site chemical explosion tests in the form of multi-hole ***,the mechanism of using multi-hole simultaneous blasting to simulate a nuclear explosion to generate approximate plane waves was *** plane pressure curve at the vault of the underground protective tunnel under the action of the multi-hole simultaneous blasting was then obtained using the impact test in the rock mass at the *** to the peak pressure at the vault plane,it was divided into three regions:the stress superposition region,the superposition region after surface reflection,and the approximate plane stress wave zone.A numerical simulation approach was developed using PFC and FLAC to study the peak particle velocity in the surrounding rock of the underground protective cave under the action of multi-hole *** time-history curves of pressure and peak pressure partition obtained by the on-site multi-hole simultaneous blasting test and numerical simulation were compared and analyzed,to verify the correctness and rationality of the formation of an approximate plane wave in the simulated nuclear *** comparison and analysis also provided a theoretical foundation and some research ideas for the ensuing study on the impact of a nuclear explosion.

关键词： Approximate plane wave Multi-hole simultaneous blasting Chemical explosion Nuclear explosion Pressure sensor inclusion

Dual-channel mechano-phosphorescence:a combined locking effect with twisted molecular structures and robust interactions

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Light(Science & Applications) 2024年第4期13卷 738-746页

作者： Zongliang Xie Zhu mao Hailan Wang Yuxin Xiao Xiayu Zhang Tao Yu Zhongfu An wei Huang Frontiers Science Center for Flexible Electronics Xi’an Institute of Flexible Electronics&Xi’an Institute of Biomedical Materials and EngineeringNorthwestern Polytechnical University127 West Youyi RoadXi’an 710072China. Research&Development Institute of Northwestern Polytechnical University in Shenzhen Shenzhen 518100China. Shenzhen Institutes of Advanced Electronic Materials Shenzhen 518100China. Key Laboratory of Flexible Electronics&Institute of Advanced Materials Nanjing Tech University30 South Puzhu RoadNanjing 211816China

Organic mechanoluminescence materials,featuring dual emission and ultralong phosphorescence characteristics,exhibit significant potential for applications in real-time stress sensing,pressure-sensitive lighting,advanced security marking techniques,and material breakage ***,due to immature molecular design strategies and unclear luminescence mechanisms,these materials remain rarely *** this study,we propose a valuable molecular design strategy to achieve dual-channel *** introducing the arylphosphine oxide group into a highly twisted molecular framework,enhanced intra-and intermolecular interactions could be achieved within rigid structures,leading to dual-channel mechanoluminescence with greatly promoted ultralong *** investigations reveal the substantial boosting effect of intra-and intermolecular interactions on mechanoluminescence and ultralong phosphorescence properties by locking the highly twisted molecular *** work provides a concise and guiding route to develop novel smart responsive luminescence materials for widespread applications in material science.

关键词： channel luminescence locking

Software Defect Prediction Method Based on Stable Learning

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Computers, Materials & Continua 2024年第1期78卷 65-84页

作者： Xin Fan Jingen mao Liangjue Lian Li Yu wei Zheng Yun Ge College of Aerospace Engineering Nanjing University of Aeronautics and AstronauticsNanjing210012China School of Software Nanchang Hangkong UniversityNanchang330029China Software Testing and Evaluation Center Nanchang Hangkong UniversityNanchang330029China

The purpose of software defect prediction is to identify defect-prone code modules to assist software quality assurance teams with the appropriate allocation of resources and *** previous software defect prediction studies,transfer learning was effective in solving the problem of inconsistent project data ***,target projects often lack sufficient data,which affects the performance of the transfer learning *** addition,the presence of uncorrelated features between projects can decrease the prediction accuracy of the transfer learning *** address these problems,this article propose a software defect prediction method based on stable learning(SDP-SL)that combines code visualization techniques and residual *** method first transforms code files into code images using code visualization techniques and then constructs a defect prediction model based on these code *** the model training process,target project data are not required as prior *** the principles of stable learning,this paper dynamically adjusted the weights of source project samples to eliminate dependencies between features,thereby capturing the“invariance mechanism”within the *** approach explores the genuine relationship between code defect features and labels,thereby enhancing defect prediction *** evaluate the performance of SDP-SL,this article conducted comparative experiments on 10 open-source projects in the PROMISE *** experimental results demonstrated that in terms of the F-measure,the proposed SDP-SL method outperformed other within-project defect prediction methods by 2.11%-44.03%.In cross-project defect prediction,the SDP-SL method provided an improvement of 5.89%-25.46% in prediction performance compared to other cross-project defect prediction ***,SDP-SL can effectively enhance within-and cross-project defect predictions.

关键词： Software defect prediction code visualization stable learning sample reweight residual network

A visual analysis approach for data imputation via multi-party tabular data correlation strategies

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Frontiers of Information Technology & Electronic Engineering 2024年第3期25卷 398-414页

作者： Haiyang ZHU Dongming HAN Jiacheng PAN Yating wei Yingchaojie FENG Luoxuan WENG Ketian mao Yuankai XING Jianshu LV Qiucheng WAN wei CHEN The State Key Lab of CAD&CG Zhejiang UniversityHangzhou 310058China Wuchan Zhongda Digital Technology Co. Ltd.Hangzhou 310020China Zhejiang Metals and Materials Co. Ltd.Hangzhou 310005China

Data imputation is an essential pre-processing task for data governance,aimed at filling in incomplete ***,conventional data imputation methods can only partly alleviate data incompleteness using isolated tabular data,and they fail to achieve the best balance between accuracy and *** this paper,we present a novel visual analysis approach for data *** develop a multi-party tabular data association strategy that uses intelligent algorithms to identify similar columns and establish column correlations across multiple ***,we perform the initial imputation of incomplete data using correlated data entries from other ***,we develop a visual analysis system to refine data imputation *** interactive system combines the multi-party data imputation approach with expert knowledge,allowing for a better understanding of the relational structure of the *** significantly enhances the accuracy and eficiency of data imputation,thereby enhancing the quality of data governance and the intrinsic value of data *** validation and user surveys demonstrate that this method supports users in verifying and judging the associated columns and similar rows using theirdomain knowledge.

关键词： Data governance Data incompleteness Data imputation Data visualization Interactive visual analysis

Synergy of sodium doping and nitrogen defects in carbon nitride for promoted photocatalytic synthesis of hydrogen peroxide

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Chinese Chemical Letters 2024年第8期35卷 324-329页

作者： Fabrice Nelly Habarugira Ducheng Yao wei Miao Chengcheng Chu Zhong Chen Shun mao College of Environmental Science and Engineering State Key Laboratory of Pollution Control and Resource ReuseTongji UniversityShanghai 200092China Baowu Water Technology Co. Ltd.Research InstituteShanghai 201999China

Photocatalytic synthesis of hydrogen peroxide has gradually become a promising method for in-situ pro-duction of hydrogen peroxide,which relies on sustainable solar ***,the commonly used photocatalyst,i.e.,carbon nitride(CN),still suffers from the drawbacks of narrow light absorption range and fast charge ***,we report a facile method to introduce nitrogen defects into carbon nitride together with sodium *** adjusting the ratio of sodium dicyandiamide,the band gap of carbon nitride can be controlled,while the carrier separation and transfer ability of carbon nitride is *** modified CN with sodium doping and nitrogen defect(SD-CN)demonstrates outstanding H_(2)O_(2)pro-duction performance(H_(2)O_(2)yield rate of 297.2μmol L^(−1)h^(−1))under visible light irradiation,which is approximately 9.8 times higher than that of pristine *** work deepens the understanding of the coordinated effect of structural defect and element doping of carbon nitride on the photocatalytic H_(2)O_(2)production performance,and provides new insight into the design of photocatalytic system for efficient production of H_(2)O_(2).

关键词： Photocatalysis H_(2)O_(2)evolution Sodium doping Nitrogen defect Metal-free catalyst

Ambient electrocatalytic synthesis of urea by co-reduction of NO_(3)^(-) and CO_(2) over graphene-supported In_(2)O_(3)

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Chinese Chemical Letters 2024年第3期35卷 538-543页

作者： Yini mao Yong Jiang Hao Liu Yimin Jiang Ming Li wei Su Rongxing He Key Laboratory of Luminescence Analysis and Molecular Sensing(Southwest University) Ministry of EducationCollege of Chemistry and Chemical EngineeringSouthwest UniversityChongqing 400715China Key Laboratory of Beibu Gulf Environment Change and Resources Utilization(Nanning Normal University) Ministry of EducationCollege of Chemistry and Life ScienceNanning Normal UniversityNanning 530000China

Urea plays a vital role in the sustainable development of mankind as it is one of the most important nitrogen *** synthesis of urea is accompanied by a high level of energy consumption while electrocatalytic methods suffer from low yields and poor *** work achieves efficient synthesis of urea by designing the graphene-In_(2)O_(3)electrocatalysts for the co-activated reduction of nitrate and carbon dioxide,where the formation rate of urea,Faraday efficiency(FE)and carbon selectivity at-0.35 V *** can reach 357.47μg mg^(-1)h^(-1),10.46%and~100%,***,the key intermediates in the C–N coupling reaction are demonstrated to be*NH_(2)and*CO_(2),which is of novelty compared to previous *** work may provide inspiration for subsequent studies on the reaction mechanism of the electrochemical synthesis of urea,as well as theoretical guidance for the sustainable synthesis of some other important chemical substances.

关键词： Graphene-supported In_(2)O_(3) Dispersion effect Efficient C-N coupling Key intermediate Urea

Boosting high-rate Li-ion storage properties by La(Ⅲ)ion doping in spinel(Co_(0.2)Cr_(0.2)Fe_(0.2)Mn_(0.2)Ni_(0.2))_(3)O_(4)high-entropy oxide anode

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Journal of Advanced Ceramics 2024年第6期13卷 769-779页

作者： Shijie Chen Mengfan Bao Yanggang Jia Pengpeng Wang Dan wei Yuhuan Guo Jie Tan Aiqin mao Advanced Ceramics Research Center School of Materials Science and EngineeringAnhui University of TechnologyMa’anshan 243032China Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials(Anhui University of Technology) Ministry of EducationMa’anshan 243032China

The present work aims to create lattice distortion and optimize the surface oxygen vacancy(OV)concentration in a model spinel(Co_(0.2)Cr_(0.2)Fe_(0.2)Mn_(0.2)Ni_(0.2))_(3)O_(4)high-entropy oxide(HEO)through a heteroatom La^(3+)doping *** demonstrated,La^(3+)with a large radius can be doped successfully into the spinel lattice of(Co_(0.2)Cr_(0.2)Fe_(0.2)Mn_(0.2)Ni_(0.2))_(3)O_(4),thereby not only causing lattice distortion to increase oxygen vacancies but also refining crystalline grains and improving the specific *** with the(Co_(0.2)Cr_(0.2)Fe_(0.2)Mn_(0.2)Ni_(0.2))_(3)O_(4)anode,the(La_(0.01)CoCrFeMnNi)_(3/5.01)O_(4) anode with moderate doping exhibits excellent cycling performance(1228 mAh·g^(−1)after 400 cycles at 0.2 A·g^(−1))and yields an increase of 75%rate capability at 3 A·g^(−1)(420 mAh·g^(−1)at 3 A·g^(−1)).The desirable kinetic transport of electrons and diffusion of Li+within the moderately La^(3+)-doped anode and the synergistic interfacial pseudocapacitive behavior satisfy the redox reaction at a high rate,thus increasing rate capability.

关键词： lithium-ion battery(LIB) anode lattice distortion high-entropy oxide(HEO) high-rate performance La^(3+)doping oxygen vacancy(OV)