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Remote-controlled module-assisted synthesis of O-(2-[^(18)F]fluoroethyl)-L-tyrosine as tumor PET tracer using two different radiochemical routes

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Nuclear Science and Techniques 2006年第3期17卷 148-153页

作者： WANG Ming-wei YIN Duan-Zhi ZHANG Lan ZHOU wei WANG yong-xian Radiopharmaceutical Centre Shanghai Institute of Applied Physics the Chinese Academy of Sciences Shanghai 201800 China

The positron-emitter fluorine-18 labeled amino acid O-(2-[18F]fluoroethyl)-L-tyrosine ([18F]FET) has shown very promising perspectives for brain tumor diagnosis with positron emission tomography (PET). There have been two existing preparation routes of [18F]FET named direct nucleophilic radiofluorination of protected L-tyrosine and radiofluoroalkylation of unprotected L-tyrosine, respectively. A general module was designed specifically for the routine synthesis of [18F]FET, which could be suitable for the present two chemical methods with simple modifica- tions. The fluorinated intermediates and the final product were separated and purified using solid phase extraction (SPE) on the Sep-Pak silica plus cartridge instead of the time-consuming high performance liquid chromatography (HPLC) procedures. The total synthesis time was about 50—60 min with good radiochemical yield (about 20—40%, no-decay-corrected) and good radiochemical purity (more than 97%) for both the synthetic methods.

关键词： PET 氟化作用合成模块正电子发射亲质子

Investigation on the structural feature of Shengli lignite

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International Journal of Mining Science and Technology 2018年第2期28卷 335-342页

作者： Zhang Yang-Yang Zong Zhi-Min Sun Yi-Bing Liu Fang-Jing Li wei-Tu Wang Ya-Nan wei xian-yong Key Laboratory of Coal Processing & Efficient Utilization Ministry of Education China University of Mining & Technology

The extraction residue from Shengli lignite was sequentially dissolved in cyclohexane, benzene, methanol, ethanol, and isopropanol in an autoclave at 320℃ to afford soluble portions(SPs) 1–5(SP_1-SP_5) and the final residue(FR). The total yield of SP_1-SP_5 is ca. 55.1%. The FR was subjected to ruthenium ioncatalyzed oxidation and the resulting products were isolated from the reaction mixture and *** the esterified products and SP_1-SP_5 were analyzed with a gas chromatograph/mass *** total, 342 compounds were identified in SP_1-SP_5. They can be classified into normal alkanes, branched alkanes, alkenes, alkanedienes, arenes, alkanols, methylcycloalkanes, alkenols, alkylbenzenemethanols,arenols, anisol and substituted anisols, polymethyldihydrobenzofurans, arenofurans, dibenzofurans,ethoxymethylbenzenes, aldehydes, ketones, esters, nitrogen-containing organic compounds, sulfurcontaining organic compounds, and other compounds. Among the compounds, arenols are predominant in SP_1 and SP_2 and the main compounds in SP_3, while the main compounds in SP_4 and SP_5 are esters and arenes, respectively. According to the esterified products identified, the products from the FR oxidation can be grouped into non-benzene ring carboxylic acids(NBCAs) and benzenepolycarboxylic acids(BPCAs). The total yield of BPCAs is much higher than that of NBCAs, suggesting that the FR is rich in condensed aromatic moieties.

关键词： Lignite Arenols Esters Arenes Condensed aromatic moieties

GC/MS Analysis of Fractional Extraction of Fusain from Tongting Bituminous Coal in CS_2

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Journal of China University of Mining and Technology 2006年第1期16卷 8-12页

作者： QIN Zhi-hong JIANG Chun SUN Hao ZONG Zhi-min JIANG Bing wei xian-yong School of Chemical Engineering and Technology China University of Mining ＆ Technology Xuzhou Jiangsu 221008 China

Fusain from Tongting (Huaibei, Anhui Province) bituminous (FTTB) coal was fractionally extracted using Soxhlet extractor with CS2. Then the extracts were analyzed with GC/MS. Comparison of experimental data between FTTB coal and clarain from Tongting bituminous (CTTB) coal was carried out. The results show that the kinds of small molecule components detected by GC/MS of FTTB are less than those of CTTB. Long-chain alkanes exist mostly in the extracts of fusain. Macromolecular networks are predominant in the FTTB coal mainly composed of inertinite in the coal petrography. The size of micropores in the FTTB coal is relatively small, and the development of micropores is relatively low. Thus the content of aromatic compounds with affinity for micropores is relative low in FTTB, while the content of long-chain alkanes with affinity for macromolecule networks is relatively high. Sub-components in exinite determine the distribution of long-chain alkanes extracted in the last stage. Odd-numbered carbon distribution appears when resin is most in exinite, while high carbon alkane distribution appears when exinite is dominant in cutinite. Small aromatic molecules are firstly packed in micropores, and exist in a free state after micropores are saturated.

关键词： coal fusain extraction fractional sample CS2 GC/MS

GC/MS Analysis of Organic Compounds in Hot Water-Extractable Fraction from Shenfu Coal

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Journal of China University of Mining and Technology 2007年第3期17卷 354-357页

作者： LI Bao-min YUAN Cheng ZONG Zhi-min CAO Jing-pei LIU Guang-feng wei xian-yong School of Chemical Engineering and Technology China University of Mining ＆ Technology Xuzhou Jiangsu 221008 China

Shenfu Coal was extracted with hot pure water and slurry was isolated. The concentrated benzene-soluble fraction (CBSF) was analyzed with GC/MS and four types of organic compounds (OCs) were detected: HACOCs,DTEs,DMDT and LCAs. The amount of benzyl benzoate which is the most abundant OC was calculated by an inter-nal standard method with an indicated amount of BP. The broken hydrogen bonds and ether bonds were responsible for the extraction of OCs from the coal .DTEs,DMDT and LCAs are essentially insoluble in water,whereas they are soluble,probably owing to intermolecular interaction of OCs with HACOCs.

关键词： thermal extraction GC/MS analysis water-soluble fraction benzene-soluble fraction

Planet wind: Planetary evolution dominated by electromagnetic forces

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Science China Earth Sciences 2024年第10期67卷 3331-3336页

作者： yong wei Key Laboratory of Earth and Planetary Physics Institute of Geology and GeophysicsChinese Academy of SciencesBeijing 100029China College of Earth and Planetary Sciences University of Chinese Academy of SciencesBeijing 100049China

1. Introduction Over the five centuries since Copernicus, the focus of planetary science has transitioned from the visible realm to the invisible. In the more than 60 years following the advent of the space age, our a... 详细信息

关键词： evolution dominated planetary

Study on the Reaction Mechanism of Naphthalene with Oxalyl Chloride

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Wuhan University Journal of Natural Sciences 2001年第4期6卷 854-858页

作者： Wu Lin Qin Yi-min Huang Bo Zong Zhi-ming wei xian-yong Chen Qing-ru Zou Guo-lin Wuhan University College of Life Sciences Wuhan China (GRID:grid.49470.3e) (ISNI:***) China University of Mining & Technology College of Chemical Engineering Xuzhou China (GRID:grid.411510.0) (ISNI:***)

The reaction of naphthalene with oxalyl chloride in the presence of anhydrous AlCl3 was investigated. The homolog of dinaphthyl methanone can be obtained mainly from this reaction. Naphthalene conversion does not have evident correlation with the amount of AlCl3. The results show that the reaction proceeds via carbon cation electrophilic substitution reaction-free radical substitution reaction pathway.

关键词： naphthalene oxalyl chloride carboncation free radical reaction mechanism

Group separation and analysis of a carbon disulfide-soluble fraction from Shenfu coal by column chromatography

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Journal of China University of Mining and Technology 2008年第1期18卷 27-32页

作者： DING Ming-jie ZONG Zhi-min ZONG Ying OUYANG Xiao-dong HUANG Yao-guo ZHOU Lei ZHENG Yu-xuan ZHOU Xiao wei Yan-bin wei xian-yong School of Chemical Engineering and Technology China University of Mining ＆ Technology Xuzhou Jiangsu 221008 China Department of Light Industry Luohe Vocational Technology College Luohe Henan 462002 China Key Laboratory of Coal Conversion and New Carbon Materials Wuhan University of Science and Technology Wuhan Hubei 430081 China

A carbon disulfide-soluble fraction (CDSSF) from Shenfu coal was separated into five fractions by silica-gel column chromatography using hexane and n-hexane/ethyl acetate binary eluent. The five fractions include four clear group fractions and a nonpolar fraction. All the fractions were analyzed by GC/MS. A total of 204 compounds were detected from the original CDSSF and its further separated fractions, with 173 compounds more than those detected by studying the original CDSSF directly. The results demonstrate a clear group separation by column chromatography in coal organic components and a more accessibility to coal components compared with the solvent extraction only.

关键词： group separation column chromatography coal

A novel method for producing benzene polycarboxylic acids by electrochemical oxidation of Zhaotong lignite in aqueous NaCl solution

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Carbon Resources Conversion 2024年第2期7卷 88-94页

作者： Ze-Zheng Li wei-Jia Jiang Yu-Gao Wang Zhi-Lei Wang Jun Shen xian-yong wei College of Chemical Engineering and Technology Taiyuan University of TechnologyTaiyuan 030024ShanxiChina School of Basic Medicine Shanxi University of Chinese MedicineJinzhong 030619China Institute of Environmental Science Shanxi UniversityTaiyuan 030031China Shanxi Huayang New Material Technology Group Co. Ltd.YangquanShanxi 045000China Key Laboratory of Coal Processing and Efficient Utilization Ministry of EducationChina University of Mining&TechnologyXuzhou 221116JiangsuChina

The development of a coal-based synthetic route to produce benzene polycarboxylic acids(BPCAs)is of great importance for the highly efficient utilization of *** this paper,aqueous NaCl^(-)electrolytic system was used to oxidize Zhaotong lignite to prepare *** electrochemical oxidation of lignite in aqueous NaCl solution could produce more BPCAs than that in aqueous NaOH *** aqueous NaCl electrolytic system could in-suit produce a stable OCl^(-),which was synthesized by the combination reaction between Cl_(2)and OH􀀀generated in the anode or cathode,*** in-suit produced OCl^(-)would degrade the organic structures of the lignite dispersing in the electrolyte to generate *** formation of BPCAs could be greatly affected by current density,electrolysis time and the addition amount of NaCl in the electrolytic system,which resulted from that the factors played an important role in the generation of OCl^(-).The coal related model compounds including anthracene and phenanthrene were used to investigate the electrochemical oxidation mechanism of the *** results indicated that the aromatic ring structures in the lignite were attacked by O_(2)•^(-)from the OCl^(-)to afford BPCAs.

关键词： Lignite Benzene polycarboxylic acids Electrochemical oxidation Aqueous NaCl electrolytic system Coal related model compounds

State of the art of lightweight aggregates used in lightweight refractories for working lining of high-temperature furnaces

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Journal of Iron and Steel Research International 2024年第6期31卷 1320-1343页

作者： wei Zhang Wen-yong Dai Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016LiaoningChina Research and Development Department AGC Plibrico(Dalian)Industries Inc.Dalian 116600LiaoningChina

Lightweight refractories for the working lining of high-temperature furnaces play an important role in the smelting of advanced steels and *** prepare lightweight refractories for the working lining of high-temperature furnaces,the synthesis of lightweight aggregates is the ***,the research on the synthesis of lightweight aggregates with high service temperature,low thermal conductivity,high strength,and good slag resistance has received widespread *** available literature on the synthesis of lightweight aggregates was summarized,including corundum,mullite,mullite-corundum,spinel,corundum-spinel,cordierite,cordierite-mullite,calcium hexaluminate,corundum-calcium hexaluminate,bauxite,magnesia,magnesia-based,and forsterite-based ***,the future development trend of lightweight aggregates was proposed.

关键词： Lightweight aggregate Lightweight refractory Working lining Apparent porosity Closed porosity Thermal conductivity Pore-forming approach