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Microscopic experiment on efficient construction of underground gas storages converted from water-invaded gas reservoirs

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Petroleum Exploration and Development 2024年第1期51卷 203-212页

作者： JIANG Tongwen QI Huan wang Zhengmao LI Yiqiang wang Jinfang LIU Zheyu cao Jinxin PetroChina Company Limited Beijing 100007China National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing 102249China College of Petroleum Engineering China University of Petroleum(Beijing)Beijing 102249China PetroChina Petroleum&New Energies Company Beijing 100007China PetroChina Research Institute of Petroleum Exploration&Development Beijing 100083China

Based on the microfluidic technology,a microscopic visualization model was used to simulate the gas injection process in the initial construction stage and the bottom water invasion/gas injection process in the cyclical injection-production stage of the underground gas storage(UGS)rebuilt from water-invaded gas *** analysis of the gas-liquid contact stabilization mechanism,flow and occurrence,the optimal control method for lifecycle efficient operation of UGS was *** results show that in the initial construction stage of UGS,the action of gravity should be fully utilized by regulating the gas injection rate,so as to ensure the macroscopically stable migration of the gas-liquid contact,and greatly improve the gas sweeping capacity,providing a large pore space for gas storage in the subsequent cyclical injection-production *** the cyclical injection-production stage of UGS,a constant gas storage and production rate leads to a low pore space *** increasing the gas storage and production rate,that is,transitioning from small volume to large volume,can continuously break the hydraulic equilibrium of the remaining fluid in the porous media,which then expands the pore space and flow *** is conducive to the expansion of UGS capacity and efficiency for purpose of peak shaving and supply guarantee.

关键词： water-invaded gas-reservoir underground gas storage cyclical injection-production gas-water contact gas storage and production rate UGS capacity expansion control method

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Adsorption limitation investigation on olefins for Cu–BTC

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Friction 2024年第4期12卷 606-617页

作者： Xiao YANG Yunbo wang Weihua cao Ruizheng JIANG Guoxin XIE Yuying cao Xiaowen QI School of Mechanical Engineering Yanshan UniversityQinhuangdao 066004China Key Laboratory of Self-Lubricating Spherical Plain Bearing Technology of Hebei Province Yanshan UniversityQinhuangdao 066004China State Key Laboratory of Tribology in Advanced Equipment Department of Mechanical EngineeringTsinghua UniversityBeijing 100084China Aviation Key Laboratory of Science and Technology on Generic Technology of Self-Lubricating Spherical Plain Bearing Yanshan UniversityQinhuangdao 066004China

To utilize Cu-benzene-1,3,5-tricarboxylate(Cu-BTC)adsorbed lubricant oils in the self-lubricating field,the adsorption properties of Cu-BTC on different 1-olefins must be *** this work,1-hexene,1-octene,1-nonene,1-decene,1-undecene,and 1-dodecene were studied by the Monte Carlo method and *** adsorption limit of Cu-BTC for n-olefins was determined as 1-undecene by the adsorption *** suggested a limit for even straight-chain molecules to the adsorption of *** maximum ratio of the olefin length of the largest pore diameter(L/D)of Cu-BTC was approximately ***,theoretical calculations(radial distribution function(RDF))and experiments(infrared(IR)spectra)confirmed the interaction of n-olefin adsorbates and the Cu-BTC framework occurred between the-CH=of olefins and the Cu and O atoms of the Cu-BTC *** work adds to the understanding and investigation of the adsorption of liquid lubricants using Cu-BTC as a metal-organic framework(MOF).

关键词： metal-organic framework(MOF) Cu-benzene-1,3,5-tricarboxylate(Cu-BTC) Monte Carlo method adsorption properties 1-olefins

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Dietary long-chain fatty acid metabolism boosts antitumorimmune response

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Cancer Communications 2024年第5期44卷 580-583页

作者： Jiaming wang Xuetao cao Department of Immunology Institute of Basic Medical SciencesPeking Union Medical CollegeChinese Academy of Medical SciencesBeijingP.R.China Institute of Immunology College of Life SciencesNankai UniversityTianjinP.R.China

Overcoming resistance to immune checkpoint blockade(ICB)therapy will pave the way for effective ICB cancer immunotherapy since a large proportion of cancer patients are not responsive to ICB immunotherapy[1].The molecular mechanisms of ICB resistance are diverse,including tumor-intrinsic resistant factors(such as genetic and epigenetic disorders),immunosuppressive/disabled factors(such as T cell exhaustion),and environmental restrictive factors(such as neuroendocrine stress and metabolic reprogramming).

关键词： metabolism cancer immune

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Effects of mesoclimate and microclimate variations mediated by high altitude and row orientation on sucrose metabolism and anthocyanin synthesis in grape berries

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Horticultural Plant Journal 2024年第3期10卷 713-731页

作者： Haining Yin Zhaoxiang wang Lin wang Jianhong cao Jiakui wang Zhumei Xi College of Enology Northwest A&F UniversityYanglingShaanxi 712100China Shangri-la Winery Co. LTDShangri-laYunnan 674400China

Climate change and extreme weather pose significant challenges to the traditional viticulture *** high-altitude grape-producing regions with diverse orientations have shown great potential in coping with this ***,high-quality wine grape production may be achieved by synchronizing the meso-and *** clarify the role of high altitude and row orientation in meso-and microclimate and the response of berries to it,we evaluated seven years(2012-2018)of climate data,two years of basic grape(Cabernet Sauvignon,Vitis vinifera L.)quality,and one-year microclimate from veraison to *** comparing two locations(Sidon 2047 m,Sinon 2208 m)in Yunnan Province,China,we found that the average temperature has been stable at approximately 15℃ for seven years,with no extreme weather or,noticeable global *** light intensity(LI)in the north-south(NS)was more balanced than the east-west(EW)direction,and the east-west to the south(EW-S)canopy side was almost higher than the other *** LI was associated with high photosynthetically active radiation(PAR),ultraviolet(UV),and infrared(IR)light and vice *** north-south to the east(NS-E)and east-west to the north(EWN)sides were characterized by lower LI and higher UV and IR light,and higher total anthocyanin *** anthocyanin synthesis-related genes,for example,VvF3'H and VvF3'5'H,were highly expressed in NS-E from veraison to *** UV and IR light induced their *** study provides new insights on the role of differently orientated rows in controlling grape quality due to varied light *** findings are globally significant,particularly in the context of climate change,and offer fresh insights into berry physiological responses and decision-making for the management of existing vineyards.

关键词： Vitis vinifera L. Orientated rows Berry composition Sugar Phenolic Light quality Solar radiation

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Carrying Capacity and Coupling Coordination of Water and Land Resources Systems in Arid and Semi-arid Areas: A Case Study of Yulin City, China

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Chinese Geographical Science 2024年第5期34卷 931-950页

作者： ZHANG Qianxi cao Zhi wang Yongsheng HUANG Yijia Institute of Geographic Sciences and Natural Resources Research Chinese Academy of SciencesBeijing 100101China College of Resources and Environment University of Chinese Academy of SciencesBeijing 100049China

Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development *** this work,taking Yulin City in China as a case study and employing the Criteria Importance Through Intercriteria Correlation(CRITIC)method,a modified model of coupling degree was developed to evaluate the car-rying capacity of water and land resources systems endowment and utilization,as well as their coupling coordination degree from 2013 to *** findings indicate that the water and land resources of Yulin are diminishing due to declines in agriculture,higher industrial water use,and wetland ***,reallocating domestic water for ecological sustainability and reducing sloping farmland can mitigate this trend of ***,as the coupling coordination between water and land resources system endowment in Yulin continuously improved,the coupling coordination between water and land resources system utilization first decreased and then in-creased with 2016 as the turning ***,the carrying capacity of water and land resources systems,the coupling coordination degree between water and land resources system endowment,and the coupling coordination degree between water and land resources system utilization in Yulin exhibited the same pattern of being higher in the six northern counties than in the six southern *** the water resources endowment is vital for the highly efficient use of water and land resources.

关键词： water and land resources systems carrying capacity coupling coordination human-earth system sustainable development Yulin City,China

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The Essential 2-rank for Classical Groups

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Acta Mathematica Sinica,English Series 2024年第9期40卷 2169-2186页

作者： Jian bei AN Yong XU Department of Mathematics University of AucklandAucklandNew Zealand School of Mathematics and Statistics He’nan University of Science and TechnologyLuoyang 471023P.R.China

Let G be a symplectic or orthogonal group defined over a finite field with odd characteristic and let D≤G be a Sylow *** this paper,we classify the essential 2-subgroups and determine the essential 2-rank of the Frobenius category FD(G).Together with the results of An–Dietrich and cao–An–Zeng,this completes the work of essential subgroups and essential ranks of classical groups.

关键词： Frobenius category conjugation families essential 2-rank symplectic groups orthogonal groups

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Impact pressure of waves generated by landslides on bank slopes

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Journal of Mountain Science 2024年第3期21卷 918-931页

作者： cao Ting wang Pingyi QIU Zhenfeng LIU Jie Key Laboratory of Hydraulic and Waterway Engineering of Ministry of Education Chongqing Jiaotong UniversityChongqing 400074China Engineering Research Center of Diagnosis Technology and Instruments of Hydro-Construction Chongqing Jiaotong UniversityChongqing 400074China

Impulse waves that are generated by landslides in narrow reservoir areas threaten the stability of buildings and bank *** discuss the action process and evolution law of the wave pressure on bank slopes,a three-dimensional physical model test that considers impulse waves generated by landslides was performed,and factors including landslide width,thickness,slope angles of the sliding surface,and bank slope angle were *** on wave forms on the bank slopes,wave pressure curve characteristics,and peak value,the action process of wave pressure could be divided into the following stages:maximum pulsating pressure stage,wave impact stage(when waves break),and stationary pulsation *** was found that wave breaking is dependent on the value of the surf similarity parameterξ.The distribution pattern of impact pressure decays linearly on both sides of the maximum impact pressure point,and the attenuation degree decreases when it attains 40%of the maximum ***,it is proposed that the prediction formula for the maximum effective impact pressure of the bank slope be related to the reciprocal of wave steepness,relative water depth,and slope *** prediction formula provides strong theoretical support for early safety warning and for predicting the bank slope under impulse waves generated by landslides.

关键词： Model test Impact pressure Action stage Breaking discrimination Distribution model

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COVID-19 vaccine updates for people under different conditions

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Science China Life Sciences 2024年第11期67卷 2323-2343页

作者： Yijiao Huang Weiyang wang Yan Liu Zai wang Bin cao National Center for Respiratory Medicine State Key Laboratory of Respiratory Health and Multimorbidity National Clinical Research Center for Respiratory Diseases Institute of Respiratory Medicine Chinese Academy of Medical Sciences Department of Pulmonary and Critical Care Medicine Center of Respiratory Medicine China-Japan Friendship Hospital School of Basic Medical Sciences Tsinghua Medicine Tsinghua University Tsinghua University-Peking University Joint Centre for Life Sciences Tsinghua University Peking Union Medical College Chinese Academy of Medical Sciences Department of Infectious Disease The Affiliated Yantai Yuhuangding Hospital of Qingdao University Institute of Clinical Medical Sciences China-Japan Friendship Hospital Changping Laboratory Department of Respiratory Medicine Capital Medical University New Cornerstone Science Laboratory China-Japan Friendship Hospital

SARS-Co V-2 has caused global waves of infection since December 2019 and continues to persist today. The emergence of SARS-Co V-2variants with strong immune evasion capabilities has compromised the effectiveness of existing vaccines against breakthrough ***, it is important to determine the best utilization strategies for different demographic groups given the variety of vaccine options available. In this review, we will discuss the protective efficacy of vaccines during different stages of the epidemic and emphasize the importance of timely updates to target prevalent variants, which can significantly improve immune protection. While it is recognized that vaccine effectiveness may be lower in certain populations such as the elderly, individuals with chronic comorbidities(e.g., diabetes with poor blood glucose control, those on maintenance dialysis), or those who are immunocompromised compared to the general population,administering multiple doses can result in a strong protective immune response that outweighs potential risks. However, caution should be exercised when considering vaccines that might trigger an intense immune response in populations prone to inflammatory flare or other complications. In conclusion, individuals with special conditions require enhanced and more effective immunization strategies to prevent infection or reinfection, as well as to avoid the potential development of long COVID.

关键词： SARS-CoV-2 vaccine variants of concern elderly immunocompromised

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Copper naphthalocyanine-based hole-transport material for highperformance and thermally stable perovskite solar cells

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Science China Chemistry 2024年第8期67卷 2701-2709页

作者： Yue Qiang Huaiman cao Yuzhen Pan Yi Chi Liangyu Zhao Yingguo Yang Hai-bei Li Yan Gao Licheng Sun Ze Yu State Key Laboratory of Fine Chemicals Frontier Science Center for Smart MaterialsDalian University of Technology(DUT).Dalian 116024China School of Chemistry Dalian University of Technology(DUT)Dalian 116024China School of Microelectronics Fudan UniversityShanghai 200433China Shanghai Synchrotron Radiation Facility(SSRF) Zhangjiang LabShanghai Advanced Research InstituteShanghai Institute of Applied PhysicsChinese Academy of SciencesShanghai 201800China School of Ocean Shandong UniversityWeihai 264209China Center of Artificial Photosynthesis for Solar Fuels and Department of Chemistry School of ScienceWestlake UniversityHangzhou 310024China Department of Chemistry School of Engineering Sciences in ChemistryBiotechnology and HealthKTH Royal Institute of Technology Stockholm 10044Sweden

Metal phthalocyanines(MPcs) have gained considerable research attention as hole-transport materials(HTMs) in perovskite solar cells(PSCs) because of their superb stability. However, the photovoltaic performance of MPc-based HTMs in PSCs is still lagging behind their small molecule and polymeric counterparts, largely due to their relatively low hole mobility. Here, we report for the first time the application of a copper naphthalocyanine derivative(namely t Bu-Cu Nc) as a hole-transport material(HTM)in perovskite solar cells(PSCs), and systematically study its optoelectronic and photovoltaic property compared with its Cu Pc analog(t Bu-Cu Pc). Combined experiments disclose that the extension of π-conjugation from Pc to Nc core leads to not only an enhanced hole-carrier mobility associated with a stronger intermolecular interaction, but also an elevated glass transition temperature(T_g) of 252 °C. The resultant PSCs employing t Bu-Cu Nc deliver an excellent power conversion efficiency of 24.03%, which is the record efficiency reported for metal complex-based HTMs in PSCs. More importantly, the encapsulated t Bu-Cu Nc-based devices also show dramatically improved thermal stability than the devices using the well-known SpiroOMe TAD, with a T_(80)lifetime for more than 1,000 h under damp-heat stress. This study unfolds a new avenue for developing efficient and stable HTMs in PSCs.

关键词： hole-transport materials perovskite solar cells copper naphthalocyanine extendedπ-conjugation thermal stability

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Impact of Quantum Coherence on Inelastic Thermoelectric Devices:From Diode to Transistor

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Chinese Physics Letters 2024年第7期41卷 117-125页

作者：曹蓓韩崇泽郝翔王晨陆金成 Jiangsu Key Laboratory of Micro and Nano Heat Fluid Flow Technology and Energy Application School of Physical Science and TechnologySuzhou University of Science and TechnologySuzhou 215009China Department of Physics Zhejiang Normal UniversityJinhua 321004China

We present a study on inelastic thermoelectric devices, wherein charge currents and electronic and phononic heat currents are intricately interconnected. The employment of double quantum dots in conjunction with a phonon reservoir positions them as promising candidates for quantum thermoelectric diodes and transistors. We illustrate that quantum coherence yields significant charge and Seebeck rectification effects. It is worth noting that, while the thermal transistor effect is observable in the linear response regime, especially when phononassisted inelastic processes dominate the transport, quantum coherence does not enhance thermal *** work may provide valuable insights for the optimization of inelastic thermoelectric devices.

关键词： quantum charge Quantum

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