检索结果-南通市图书馆

维普期刊数据库博看期刊

在线全文

学校读者我要写书评

暂无评论

喜马拉雅吉隆花岗伟晶岩中锂矿物的研究

岩石学报 2024年第2期40卷 484-498页

作者：田恩农谢磊王汝成吴福元内生金属矿床成矿机制研究国家重点实验室南京大学地球科学与工程学院南京210023 河北地质大学河北省岩石矿物材料绿色开发重点实验室宝石与材料学院石家庄050031 河北省战略性关键矿产研究协同创新中心石家庄050031 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029 中国科学院大学地球与行星科学学院北京100049

喜马拉雅造山带中部的吉隆岩体出露有大量淡色花岗岩和花岗质伟晶岩,已有文献报道该岩体英雄沟和扎龙沟淡色花岗岩和伟晶岩中有铁锂云母、锂云母、锂辉石等锂矿物产出。本次研究对吉隆岩体北部扎龙沟的伟晶岩进行了岩相学和矿物学研究,... 详细信息

喜马拉雅造山带中部的吉隆岩体出露有大量淡色花岗岩和花岗质伟晶岩,已有文献报道该岩体英雄沟和扎龙沟淡色花岗岩和伟晶岩中有铁锂云母、锂云母、锂辉石等锂矿物产出。本次研究对吉隆岩体北部扎龙沟的伟晶岩进行了岩相学和矿物学研究,厘定了锂辉石伟晶岩和锂云母-锂电气石伟晶岩(含细晶岩)两种类型的富锂伟晶岩。研究结果显示,在锂辉石伟晶岩中主要的富锂矿物除了已知的锂辉石和锂云母,还发现了透锂长石,同时锂云母的边部出现的铯锂云母((Cs,K)Li_(2)Al[Si_(4)O_(10)]F_(2),Cs/(Cs+K)原子比>0.5)中Cs_(2)O含量达16.9%,该矿物首次在喜马拉雅发现,推测是由锂云母与后期富Cs流体作用后形成。在锂云母-锂电气石细晶岩中主要的富锂矿物包括锂云母和锂电气石,锂云母中的Li_(2)O含量为0.9%~6.7%;锂电气石中Li_(2)O含量最高可达2.4%,且FeO、MgO和CaO含量较低(分别<1.1%、<0.01%和<2.6%),接近锂电气石端元成分。结合吉隆扎龙沟含锂伟晶岩中大量产出铯沸石和细晶石,确认这些伟晶岩是典型的LCT(Li-Cs-Ta)型伟晶岩,矿物组成和成分显示它们具有极高的分异演化程度。

关键词：花岗质伟晶岩细晶岩富铯锂云母铯锂云母锂电气石

江西松树岗花岗岩型铌钽矿床的成矿机制及找矿方向

同方期刊数据库博看期刊评论

在线全文

学校读者我要写书评

暂无评论

岩石学报 2024年第9期40卷 2786-2802页

作者：诸泽颖王汝成王登红李建康任建国自然资源部成矿作用与资源评价重点实验室中国地质科学院矿产资源研究所北京100037 南京大学内生金属矿床成矿机制研究国家重点实验室南京大学地球科学与工程学院南京210023 南京大学关键地球物质循环教育部前沿科学中心南京210023 江西赣锋锂业集团股份有限公司新余338004

江西松树岗花岗岩型铌钽矿床位于江西省上饶市葛源镇,不仅是华南最大花岗岩型钽矿床,同时还共伴生有铌、铷、锂、钨、锡等多金属。松树岗花岗岩型铌钽矿床近地表产出石英脉型钨锡矿,深部隐伏为花岗岩型铌钽矿床。花岗岩体具有垂向分带性... 详细信息

江西松树岗花岗岩型铌钽矿床位于江西省上饶市葛源镇,不仅是华南最大花岗岩型钽矿床,同时还共伴生有铌、铷、锂、钨、锡等多金属。松树岗花岗岩型铌钽矿床近地表产出石英脉型钨锡矿,深部隐伏为花岗岩型铌钽矿床。花岗岩体具有垂向分带性,深部为花岗岩主体黄玉钠长石花岗岩,垂向向上依次为云英岩化花岗岩、钾长石花岗岩以及似伟晶岩壳。花岗岩具有特征的“雪球结构”,斑晶为石英或钾长石。松树岗铌钽矿床岩体产出铌钽氧化物(包括铌铁矿、钽铁矿、锡锰钽矿等)、锆石、锡石以及黑钨矿。铌铁矿原位U-Pb定年结果显示成矿年龄约为130Ma。铌钽氧化物、锆石、锡石等副矿物常显示明显的核边结构,其中铌钽氧化物核部为铌铁矿,边部为钽铁矿和锡锰钽矿,记录岩体经历了明显的岩浆-热液多阶段成矿过程。松树岗花岗岩云母以铁锂云母为主,Li_(2)O含量为2.89%~4.29%。主体钠长石花岗岩中铁锂云母可分为片状铁锂云母(Znw1)和细粒铁锂云母(Znw2),其中片状铁锂云母(Znw1)同样具有环带结构,且环带主要由Rb含量变化导致。片状铁锂云母核部Rb 2O为0.9%~1.16%,边部Rb 2O含量升高,最高可达4.08%。细粒铁锂云母(Znw2)分布于基质中,含有较高的Ta含量(110×10^(-6))。云英岩中出现束状或放射状产出的铁锂云母(Znw3),具有较高的Sn含量(464×10^(-6))。片状铁锂云母核边结构记录岩浆演化过程,云英化花岗岩中的铁锂云母为热液成因。松树岗花岗岩型铌钽矿床是一个高演化稀有金属花岗岩,造岩矿物铁锂云母和副矿物铌钽氧化物记录岩体经历了岩浆到热液阶段演化的过程。地表石英脉型钨锡矿以及岩体中特征的“雪球结构”是重要的高演化稀有金属花岗岩重要的找矿标志。松树岗岩体位于著名的灵山杂岩体周围,灵山岩体的边缘仍然具有出露有类似稀有金属矿床的可能,需加大对区域稀有金属矿床的找矿勘查及理论研究力度。

关键词：铌钽矿床松树岗岩体花岗岩型成矿机制

喜马拉雅东部库曲锂铍花岗质伟晶岩的稀有金属矿物学研究

同方期刊数据库博看期刊评论

在线全文

学校读者我要写书评

暂无评论

岩石学报 2024年第2期40卷 404-432页

作者：谢磊王汝成田恩农陶湘媛周威刘小驰吴福元内生金属矿床成矿机制研究国家重点实验室南京大学地球科学与工程学院南京210023 河北地质大学河北省岩石矿物材料绿色开发重点实验室宝石与材料学院石家庄050031 中国石化江苏油田分公司勘探开发研究院扬州225009 中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029 中国科学院大学地球与行星科学学院北京100049

在喜马拉雅造山带已发现普士拉、热曲、吉隆、洛扎等多个岩体中花岗岩-伟晶岩与锂铍等稀有金属成矿作用相关,并有大规模的锂辉石伟晶岩(含细晶岩)产出。喜马拉雅东部的库曲岩体也发现了锂辉石伟晶岩出露,主要侵入到主体白云母花岗岩中... 详细信息

在喜马拉雅造山带已发现普士拉、热曲、吉隆、洛扎等多个岩体中花岗岩-伟晶岩与锂铍等稀有金属成矿作用相关,并有大规模的锂辉石伟晶岩(含细晶岩)产出。喜马拉雅东部的库曲岩体也发现了锂辉石伟晶岩出露,主要侵入到主体白云母花岗岩中。本次研究对库曲岩体中不同类型的花岗质伟晶岩进行了详细的岩相学、矿物学和年代学的研究。根据不同矿物组合和产出位置,将库曲伟晶岩分为四类:广泛分布的伟晶岩I,主要包含长石-石英-白云母;岩体西部桑玉村出露伟晶岩II(包含钠长石-石英-白云母带和细粒钠长石带)和伟晶岩III(锂辉石-钠长石-石英带);岩体东部出露细晶岩脉。库曲伟晶岩都含不同体积百分比的石榴石和电气石,以及典型的稀有金属矿物如绿柱石、铌铁矿族矿物和少量锡石。独居石和铌铁矿族矿物的U(-Th)-Pb同位素年代学结果显示库曲伟晶岩主要形成于~25Ma,还存在稍晚一期的岩浆活动,细晶岩形成于~14Ma。同时代的伟晶岩I、II和III全岩成分呈现出明显的变化趋势,K_(2)O/Na_(2)O、Zr/Hf和Nb/Ta比值、REE总量和Eu/Eu^(*)呈降低趋势,而稀有金属(Li、Be、Nb、Ta、Rb和Cs)含量逐渐增加。矿物的成分变化趋势更明显,从伟晶岩I到III中白云母的K/Rb比值和MgO含量明显降低,电气石向更富集Li、石榴子石和铌铁矿族矿物向更富集Mn(在伟晶岩III中分别接近锰铝榴石和铌/钽锰矿端元组分)、绿柱石向更富集Li-Cs的方向变化。伟晶岩III中锡石含量相对增加,常与锂辉石共生。细晶岩脉的矿物学特征介于伟晶岩I和II之间。综合上述研究显示库曲伟晶岩是花岗质岩浆分异演化的最终产物,矿物是伟晶岩形成过程和分异程度的有效指示剂,库曲的稀有金属成矿作用显示出Be、Be-Nb-Ta(-Sn)、Li-Be-Nb-Ta-Sn(岩体最边缘)矿化的变化趋势。锂辉石是库曲伟晶岩中主要的原生锂矿物,次生的锂辉石和石英后成合晶可能是在富锂流体中形成的,而不是透锂长石降温过程中形成的,这与库曲伟晶岩侵入到白云母花岗岩的产状相符。

关键词：锂辉石伟晶岩绿柱石演化程度矿物指示剂端元矿物

Granites: Origin and associated mineralization

同方期刊数据库博看期刊评论

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2018年第12期61卷 1932-1933页

作者： rucheng wang Meifu ZHOU State Key Laboratory for Mineral Deposits Research School of Earth Sciences Nanjing University Department of Earth Sciences The University of Hong Kong

As a dominant components in continental crust,granite is certainly the key target to investigate the crustal evolution, and more economically,to explore the mineral resources. With the improvement of our analytical approaches at dif- ferent scales,significant advances have been made in the origin of granites and associated mineralization in China. This is mainly focused on the following three aspects:(1)the geochemical differentiation of granitic melts during their production by partial melting and emplacement by fractional crystallization,(2)the growth and reworking of crustal rocks at convergent plate boundaries,and (3)the concentration of metallogenic elements and eventually ore deposition in the crust.

关键词： Granites Origin associated mineralization

Granites:From felsic rocks to the recorder of continental evolution

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2015年第12期58卷 2353-2354页

作者： wang rucheng WU FuYuan State Key Laboratory for Mineral Deposits Research School of Earth Sciences and Engineering Nanjing University State Key Laboratory of Lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences

Granites are a common type of felsic intrusive rock that are composed of quartz, feldspar and micas as rock-forming minerals. They are the final products of the high- temperature, magmatic, predominantly endogenic, chemical differentiation of the earth （Clarke, 1996）. As the most abundant plutonic rocks in the continental crust, granites may form in various tectonic settings such as marginal arc, collisional orogen and intraplate rifting （Barbarin, 1999）.

关键词：花岗岩长英质岩石大陆演化酸性侵入岩碰撞造山带常见类型造岩矿物最终产品

在线全文

学校读者我要写书评

暂无评论

稀有金属矿物微区同位素定年与示踪

岩石学报 2024年第4期40卷 1023-1043页

作者：杨岳衡吴石头车旭东杨明黄超王浩杨进辉王汝成吴福元中国科学院地质与地球物理研究所岩石圈演化国家重点实验室北京100029 南京大学内生金属矿床成矿机制研究国家重点实验室南京大学地球科学与工程学院南京210023 浙江大学海南研究院三亚572025

作为战略性关键金属矿产资源,钨、锡、铌、钽、锂、铍、铷、铯、锆、铪、稀土等稀有金属,在国民经济与国家安全方面有着重要的研究意义。稀有金属矿石矿物微区同位素定年与示踪,是开展稀有金属矿床成矿作用研究的最直接手段,具有整体分... 详细信息

作为战略性关键金属矿产资源,钨、锡、铌、钽、锂、铍、铷、铯、锆、铪、稀土等稀有金属,在国民经济与国家安全方面有着重要的研究意义。稀有金属矿石矿物微区同位素定年与示踪,是开展稀有金属矿床成矿作用研究的最直接手段,具有整体分析无可比拟的优点。近年来,钨锡铌钽锆铪稀土等稀有金属矿物微区U-Pb定年与Sr-Nd-Hf同位素示踪发展迅速,而锂铍铷铯等稀有金属矿物微区Rb-Sr/Lu-Hf定年正蓬勃发展。本文综述了黑钨矿、白钨矿、锡石、铌钽矿(铌钽氧化物类矿物的简称)、独居石、磷钇矿、氟碳铈矿等稀有金属矿物微区U-Pb定年与Sr-Nd-Hf同位素示踪技术主要进展,展望了锂云母、铁锂云母、铯沸石、钾长石(天河石)等微区Rb-Sr定年与磷钇矿、磷灰石、褐帘石、独居石、黑钨矿、白钨矿等微区Sm-Nd和Lu-Hf定年的广阔前景,获得如下认识:(1)低铀矿物U-Pb定年,除了采用高灵敏度磁式等离子质谱外,元素成像技术能很好地揭示微量元素之间相关性,进而快速锁定高U/Pb区域,提高低铀矿物U-Pb定年成功率;(2)铌钽矿-锡石激光微区Hf同位素能够直接示踪花岗岩-伟晶岩稀有金属成岩成矿物质源区,但这方面工作仍需进一步加强;(3)碰撞/反应池等离子质谱的出现,使高Rb/Sr、Sm/Nd或高Lu/Hf比矿物的同位素定年成为现实,是未来稀有金属激光微区同位素年代学发展的新方向;(4)实验方法研发与标准物质研制相辅相成、相互促进,仍是当前迫切需要解决的关键技术难题。随着战略性关键金属日渐成为国内外成矿作用研究的热点,钨锡铌钽锂铍铷铯锆铪稀土等稀有金属矿物微区同位素定年与示踪方法研究,必将为我国新一轮稀有金属矿床学研究做出应有的学术贡献。

关键词：稀有金属微区分析同位素定年与示踪 U-Pb/Rb-Sr/Lu-Hf年代学

Anorthite dissolution promoted by bacterial adhesion:Direct evidence from dialytic experiment

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2011年第2期54卷 204-211页

作者： ZHOU YueFei wang rucheng LU XianCai State Key Laboratory for Mineral Deposits Research School of Earth Sciences and Engineering Nanjing University Nanjing 210093 China School of Resources and En virommentatl Engineering Hefei Univetwity of Teehnology Hefei 230009 China

Bacterial adhesion is crucial to the dissolution of minerals and rocks. By employing dialysis method, we designed comparative experiments to investigate the dissolution behavior of anorthite with the mediation of both adhered and non-adhered Paenibacillus polymyxa. The results show that during 10 experimental days, the dissolution of anorthite was promoted considerably by P. polymyxa and metabolites. Nanoscale precipitates were formed in contact experiment. Anorthite has a higher release of Ca and lower releases of Al and Si in dialysis experiment than in contact experiment. The difference implies that the release of Ca is controlled by mechanism of proton-exchange, whereas those of A1 and Si are controlled by ligand-complexation in which A1-O-Si bonds are destroyed first. Kinetically the release of Ca is controlled mainly by surface reaction and leached-layer diffusion. Both of them are restrained by adhered bacteria. The releases of AI and Si are controlled mainly by surface reaction, which is accelerated by adhered bacteria.

关键词： anorthite Paenibacillus polymyxa adhesion dissolution dialysis

Diversity of Mesozoic tin-bearing granites in the Nanling and adjacent regions,South China:Distinctive mineralogical patterns

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2017年第11期60卷 1909-1919页

作者： wang rucheng XIE Lei LU JianJun ZHU JinChu CHEN Jun State Key Laboratory for Mineral Deposits Research School of Earth Sciences and EngineeringNanjing UniversityNanjing 210023China

The Nanling and adjacent regions of South China host a series of tin deposits related to Mesozoic granites with diverse petrological characteristics. The rocks are amphibole-bearing biotite granites, or （topaz-） albite-lepidolite （zinnwaldite） granites, and geochemically correspond to mealuminous and peraluminous types, respectively. Mineralogical studies demonstrate highly distinctive and critical patterns for each type of granites. In mealuminous tin granites amphibole, biotite and perthite are the typical rock-forming mineral association; titanite and magnetite are typical accessory minerals, indicating highjO2 magmatic conditions; cassiterite, biotite and titanite are the principal Sn-bearing minerals; and pure cassiterite has low trace-element contents. However, in peraluminous tin granites zirmwaldite-lepidolite, K-feldspar and albite are typical rock-forming minerals; topaz is a common accessory phase, indicative of high peraluminity of this type of granites; cassiterite is present as a uniquely important tin mineral, typically rich in Nb and Ta. Mineralogical distinction between the two types of tin granites is largely controlled by redox state, volatile content and differentiation of magmatic melts. In oxidized metaluminous granitic melts, Sn4＋ is readily concentrated in Ti-bearing rock-forming and accessory minerals. Such Sn-bearing minerals are typical of oxidized tin granites, and are enriched in granites at the late fractionation stage. In relatively reduced peraluminous granitic melts, Sn2＋ is not readily incorporated into rock-forming and accessory minerals, except for cassiterite at fractionation stage of granite magma, which serves as an indicator of tin mineralization associated with this type of granites. The nature of magma and the geochemical behavior of tin in the two types of granites thus result in the formation of different types of tin deposits. Metaluminous granites host disseminated tin mineralization, and are locally related to deposits

关键词： Metaluminous tin granites Peraluminous granites Mineral assemblages Mineralogical indication of mineralization Nanling and adjacent regions

Study of the minerogenetic mechanism and origin of Qinghai nephrite from Golmud, Qinghai, Northwest China

在线全文

学校读者我要写书评

暂无评论

Science China Earth Sciences 2016年第8期59卷 1597-1609页

作者： YU HaiYan wang rucheng GUO JiChun LI JiaGui YANG XiaoWen State Key Laboratory for Mineral Deposits Research School of Earth Sciences and Engineering Nanjing University Nanjing 210023 China College of Materials Engineering Jinling Institute of Technology Nanjing 211169 China Center for Jewelry Research Nanjing University Nanjing 210093 China Jewelry Inspection Station Nanjing University Nanjing 210093 China Station of Precious Metal Gemstone Quality Control and Inspection Qinghai Province Xi'ning 810008 China

Electronic microprobe analysis showed that all QN samples are mainly composed of tremolite and minor accessory minerals, such as diopside, calcite, serpentinite, and magnetite. According to the cation coefficients, the crystallo-chemistrygenesis illustration demonstrates that all QN deposits are contact metasomatic. Depending on the mole percent of Fe^(2+(3+))/(Mg^(2+)+Fe^(2+(3+)) and the content of Cr, Co, and Ni in all QN samples measured by X-ray fluorescence spectroscopy(XRF) and inductively coupled plasma-mass spectrometry(ICP-MS), green and azure-green QNs are characterized as serpentinite-related contact metasomatic deposit(S-type), whereas white, green-white, brown, blue-violet, yellow, and viridis QNs are dolomite-related contact metasomatic deposit(D-type). The assemblages and chemical composition of accessory minerals of the eight-color QN samples show evident characteristics, which reveal four possible ore-forming processes. We also measured trace and rare earth elements(REEs) in these samples through ICP-MS to deduce the origin of and the changes in metallogenic conditions. The chondrite-normalized REE patterns of D-type QN exhibit moderately negative Eu anomalies with moderate light REE enrichment, flat heavy REE(HREE), and low(50)REE concentrations, similar to dolomitic marble. Green QN samples of S-type show enrichment in HREE and moderately negative Eu anomalies, which is consistent with characteristics of dunite. Whereas azure-green QN samples of S-type exhibit a right-dipping V-type curve with severe depletion in Eu(δEu=0.36–0.47), in accordance with the characteristics of gabbro from Yushigou ophiolite in North Qilian mountains. Furthermore, this finding is consistent with the content of trace elements and the petrographic analysis results. On the basis of several significant differences in the characteristic elements, which may have been affected by the metallogenic environment, we inferred the differences in oxygen fugacity and basicity of mine

关键词： Qinghai Nephrite Tremolite Type Process Origin Environment