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Coal-based activated carbon prepared by H2O activation process for supercapacitors using response surface optimization method

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Frontiers of Chemical Science and Engineering 2024年第6期18卷 31-40页

作者： Shanxin Xiong Fengyan Lv Chenxu wang Nana Yang Yukun Zhang Qingyong Duan Shuaishuai Bai Xiaoqin wang Zhen Li Jianwei Xu College of Chemistry and Chemical Engineering Xi’an University of Science and TechnologyXi’an 710054China Key Laboratory of Coal Resources Exploration and Comprehensive Utilization Ministry of Land and ResourcesXi’an 710021China Institute of Sustainability for Chemicals Energy and EnvironmentJurong Island 627833Singapore

The scalable production of high grade activated carbon from abundant coal for supercapacitors application is an efficient way to achieve high value-added utilization of coal ***,this technology is challenging due to lack of comprehensive understanding on the mechanism of activation process and effect of external *** this paper,the effect of activating temperature and time on the specific capacitance of coal-based activated carbon prepared by H2O steam activation was studied using the response surface *** optimal conditions,coal-based activated carbon exhibits the largest specific capacitance of 194.35 F·g^(−1),thanks to the appropriate pore/surface structure and defect *** functional theory calculations explain in detail the mechanism of contraction of aromatic rings and overflow of H2 and CO during the ***,oxygen-containing functional groups are introduced,contributing to the pseudocapacitance property of coal-based activated *** mechanism of reactions between aromatic carbon and H2O vapor provides understanding on the role of water during coal processing at the molecular level,offering great potential to regulate product distribution and predict rate of pore *** insight would contribute to the advancement of other coal processing technology such as gasification.

关键词： response surface optimization coal-based activated carbon supercapacitor activating mechanism

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Metal size effects over metal/zeolite bifunctional catalysts in the selective hydroalkylation of benzene

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Frontiers of Chemical Science and Engineering 2024年第4期18卷 107-114页

作者： junjie Li Chuang Liu Zhenlong Jia Yingchun Ye Dawei Lan Wei Meng Jianqiang wang Zhendong wang Yongfeng Hu Weimin Yang State Key Laboratory of Green Chemical Engineering and Industrial Catalysis Sinopec Shanghai Research Institute of Petrochemical Technology Co.Ltd.Shanghai 201208China School of Chemical Engineering East China University of Science and TechnologyShanghai 200237China

Bifunctional metal/zeolite materials are some of the most suitable catalysts for the direct hydroalkylation of benzene to *** overall catalytic performance of this reaction is strongly influenced by the hydrogenation,which is dependent on the metal ***,systematically investigating the metal size effects in the hydroalkylation of benzene is *** this work,we successfully synthesized Ru and Pd nanoparticles on Sinopec Composition Materials No.1 zeolite with various metal *** demonstrated the size-dependent catalytic activity of zeolite-supported Ru and Pd catalysts in the hydroalkylation of benzene,which can be attributed to the size-induced hydrogen spillover capability *** work presents new insights into the hydroalkylation reaction and may open up a new avenue for the smart design of advanced metal/zeolite bi-functional catalysts.

关键词： size effects bifunctional catalysts metal/zeolite hydroalkylation

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Prestoring lithium into SnO_(2)coated 3D carbon fiber cloth framework as dendrite-free lithium metal anode

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Particuology 2024年第1期84卷 89-97页

作者： Tao Wei Yanyan Zhou Cheng Sun Lesheng Liu Sijia wang Mengting wang Ye Liu Qing Huang Quanchao Zhuang Yongfu Tang School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang212003China College of Materials Science and Engineering Nanjing Forestry UniversityNanjing210037China Li-ion Batteries Lab School of Materials Science and EngineeringChina University of Mining and TechnologyXuzhouChina Hebei Key Laboratory of Applied Chemistry School of Environmental and Chemical EngineeringYanshan UniversityQinhuangdao066004China

For several decades,the promise of implementing of lithium(Li)metal anodes has been regarded as the"holy grail"for Li-based ***,we have proposed a facile design of a carbon fiber cloth(CFC)framework coated with SnO_(2)nanoparticles through a hydrothermal process,which served as a reliable host for prestoring molten Li to produce a CFC@SnO_(2)@Li composite ***,TEM,HRTEM,XPS and different electrochemical characterizations were carried *** to the synergetic effects of the 3D conductive CFC and the coated lithiophilic SnO_(2)nanoparticles,the designed CFC@SnO_(2)@Li electrodes can buffer the volume changes and reduce the local current density,thus suppress the Li dendrites during ***,the CFC@SnO_(2)electrodes showed a high and stable CE of 98.6%for 1000 cycles at a current density of 1 mA cm^(-2)(1 mAh cm^(-2)).What is more,at a high current density of 5 mA cm^(-2)and a high areal capacity of 5 mAh cm^(-2),the symmetric cell displayed relatively low overpotential and long cycling lifetime of 1600 *** results confirm its great potential as lithium metal anodes in practical battery applications.

关键词： Lithiophilic Lithium metal anodes SnO_(2) 3D anode Dendrite-free

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不同固结路径下钙质砂固结排水强度性状研究

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岩土力学 2024年第8期45卷 2290-2298页

作者：陈军浩张艳娥王刚王恒福建理工大学地下工程福建省高校重点实验室福建福州350118 福建理工大学土木工程学院福建福州350118 福建理工大学福建省土木工程新技术与信息化重点实验室福建福州350118

钙质砂是我国南海岛礁建设的主要吹填材料,岛礁建筑施工中钙质砂地基将受到不同固结路径外荷载作用,开展不同固结路径下钙质砂的固结排水强度特性研究是岛礁地基建设的迫切需求。对取自我国南海某吹填岛礁的钙质砂开展不同固结路径三轴... 详细信息

钙质砂是我国南海岛礁建设的主要吹填材料,岛礁建筑施工中钙质砂地基将受到不同固结路径外荷载作用,开展不同固结路径下钙质砂的固结排水强度特性研究是岛礁地基建设的迫切需求。对取自我国南海某吹填岛礁的钙质砂开展不同固结路径三轴固结排水剪切试验,探究钙质砂的强度参数和颗粒破碎程度随固结路径的演变规律。研究结果表明:钙质砂的应变软化和剪胀特性随平均有效应力的增大、有效主应力比的增大而逐渐减弱;与等向固结工况相比,随着有效主应力比减小至0.45时,钙质砂固结排水峰值强度折减系数介于0.60~0.95之间;在常规应力范围内,当有效主应力比增大,峰值内摩擦角呈减小趋势,介于38°~53°之间。在固结阶段,颗粒破碎程度随偏应力的增大而变大,但在剪切完成后颗粒破碎程度反而最小,剪切阶段的颗粒破碎占主导地位;验证了不同固结路径下峰值内摩擦角与相对破碎率的定量关系式,计算得到的峰值内摩擦角预测值为实测值的0.8~1.2倍。固结应力路径和固结压力不同引起的颗粒破碎程度差异,是导致剪切后钙质砂固结排水强度性质差异的主要原因。

关键词：钙质砂应力路径固结排水强度颗粒破碎内摩擦角

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USP45 acts as an oncogene to regulate the proliferation of esophageal cancer cells

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Genes & Diseases 2024年第5期11卷 44-47页

作者： Kai Li Qian wang Hua Bian Zhang Zhongjing College of Chinese Medicine Henan Key Laboratory of Zhang Zhongjing Formulae and Herbs for ImmunoregulationNanyang Institute of TechnologyNanyangHenan 473004China College of Orthopaedics and Traumatology Henan University of Chinese MedicineZhengzhouHenan 450046China

Deubiquitinases(DUBs)are a class of enzymes that are able to reverse the process of ubiquitination.1 Extensive research has revealed that there are more than 100 DUBs found in humans,which are classified into seven main families:ubiquitin-specific proteases(USPs),ubiquitin carboxyl-terminal hydrolases,the Machado-Joseph disease domain superfamily,the otubain/ovarian tumor-domain containing proteins,the ZUFSP(Zinc finger with UFM1-specific peptidase domain protein)family,the JAB1/MPN/MOV34 proteases,and the novel motif interacting with ubiquitin-containing DUB *** DUBs are cysteine proteases,except the JAB1/MPN/MOV34 proteases,which are Zn^(2+) metalloproteases.

关键词： esophageal cancer Zinc

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Mechanism of high-energy pulsed current-assisted rolling of 08AL carbon steel ultra-thin strip

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Journal of Iron and Steel Research International 2024年第2期31卷 416-427页

作者： Zhong-kai Ren Ya-nan Xu Jia-zhao Chen He Li Rui-lin Yuan Zhen-hua wang Tao wang Xiao Liu College of Mechanical and Vehicle Engineering Taiyuan University of TechnologyTaiyuan030024ShanxiChina Engineering Research Center of Advanced Metal Composites Forming Technology and Equipment(Ministry of Education) Taiyuan University of TechnologyTaiyuan030024ShanxiChina National Key Laboratory of Metal Forming Technology and Heavy Equipment China National Heavy Machinery Research Institute Co.Ltd.Xi’an710016ShaanxiChina

To improve the plastic deformation performance of a 08AL carbon steel ultra-thin strip,a pulsed electric field was integrated into the plastic processing of the ultra-thin strip,and the effects of high-energy current on its deformation ability were ***-assisted tensile tests were employed,and the results clarified that the pulsed current could reduce the activation energy of faults and promoted dislocation slip within grains and at grain boundaries,leading to a decrease in the deformation resistance of the metal and an increase in its plastic *** the current density of 2.0 A/mm2,the yield strength,tensile strength,and elongation of the rolled sample reached 425 MPa,467 MPa,and 12.5%,*** the rolling process,it was found that the pulsed current promoted the dynamic recrystallization of the ultra-thin strip,reduced its dislocation density and deformation resistance,and promoted the coordinated deformation of the metal.

关键词： 08AL ultra-thin strip High-energy pulsed current Mechanical property Dislocation density Dynamic recrystallization

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微观组织对U20Mn贝氏体钢疲劳裂纹扩展行为的影响

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材料热处理学报 2018年第2期39卷 119-124页

作者：陈林郭飞翔王慧军宿皓李琳郭善丽吴章忠涛雅内蒙古科技大学材料与冶金学院内蒙古包头014010 包钢技术中心内蒙古包头014010 包钢轨梁厂内蒙古包头014010

分别对轧态、空冷和盐浴等温3种条件下U20Mn新型贝氏体重轨钢紧凑型拉伸试样的Ⅱ区疲劳裂纹（疲劳扩展稳定区）的扩展速率进行了测定,并用激光扫描共聚焦显微镜（LEXT）对其疲劳裂纹的扩展轨迹进行观察分析,研究不同组织类型对贝氏体钢... 详细信息

分别对轧态、空冷和盐浴等温3种条件下U20Mn新型贝氏体重轨钢紧凑型拉伸试样的Ⅱ区疲劳裂纹（疲劳扩展稳定区）的扩展速率进行了测定,并用激光扫描共聚焦显微镜（LEXT）对其疲劳裂纹的扩展轨迹进行观察分析,研究不同组织类型对贝氏体钢疲劳裂纹扩展行为的影响。结果表明：疲劳裂纹在粒状贝氏体组织中的扩展偏折程度较为平缓,在条片状贝氏体组织中偏折严重,且随着条片的细化,其偏折程度也越大,所对应的Ⅱ区疲劳裂纹扩展速率也相应呈减缓趋势。

关键词：钢轨贝氏体组织疲劳裂纹扩展速率裂纹扩展路径

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Plastic mulch increases dryland wheat yield and water-use productivity,while straw mulch increases soil water storage

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Journal of Integrative Agriculture 2024年第9期23卷 3174-3185页

作者： Hubing Zhao Guanfei Liu Yingxia Dou huimin Yang Tao wang Zhaohui wang Sukhdev Malhi Adnan Anwar Khan College of Natural Resources and Environment Northwest A&F UniversityYangling 712100China Key Laboratory of Plant Nutrition and the Agri-environment in Northwest China Ministry of Agriculture and Rural AffairsYangling 712100China Department of Renewable Resources University of AlbertaEdmonton T6G 2H1Canada

Amplifying drought stress and high precipitation variability impair dryland wheat *** problems can potentially be minimized by using plastic mulch(PM)or straw mulch(SM).Therefore,wheat grain yield,soil water storage,soil temperature and water-use productivity of PM and SM treatments were compared with no mulch(CK)treatment on dryland wheat over a period of eight *** to the CK treatment,PM and SM treatments on average significantly increased grain yield by 12.6 and 10.5%,*** to the CK treatment,SM treatment significantly decreased soil daily temperature by 0.57,0.60 and 0.48℃ for the whole seasons,growing periods and summer fallow periods,*** contrast,compared to the CK treatment,PM treatment increased soil daily temperature by 0.44,0.51 and 0.27℃ for the whole seasons,growing periods and summer fallow periods,*** soil temperature under SM allowed greater soil water storage than under *** water storage pre-seeding was 17%greater under the SM than under the PM *** water storage post-harvest was similar for the PM and SM treatments,but evapotranspiration was 4.5%higher in the SM than in the PM ***,water-use productivity was 6.6%greater under PM than under the SM ***,PM treatment increased dryland wheat yield and water-use productivity,while straw mulch increased soil water storage.

关键词： plastic mulch soil water storage straw mulch water-use productivity winter wheat

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Polysulfide modified PtCu intermetallic nanocatalyst with enrichment realizes efficient electrooxidation ethanol to CO_(2)

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Nano Research 2024年第4期17卷 2320-2327页

作者： Shuanglong Zhou Zheng Lv Liang Zhao Dan Zhang Zuocao wang Yu Dai Bin Li Olga Starostenko Jianping Lai Lei wang Key Laboratory of Eco-chemical Engineering Ministry of EducationTaishan scholar advantage and characteristic discipline team of Eco-chemical process and technologyLaboratory of Inorganic Synthesis and Applied ChemistryCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042China College of Foreign Languages Qingdao City UniversityQingdao 266106China College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042China Institute of Macromolecular Chemistry of the National Academy of Sciences of Ukraine Kyiv 02160Ukraine Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection College of Environment and Safety EngineeringQingdao University of Science and TechnologyQingdao 266042China

The main problem faced by ethanol oxidation reaction(EOR)includes low activity,poor selectivity,and *** the study,we found that polysulfide modified on the surface of PtCu intermetallic(IM)/C can simultaneously enrich hydroxyl and ethanol,which could effectively improve the catalytic activity,CO_(2) selectivity,and durability of *** mass activity and the specific activity of the product in 1 M KOH electrolyte reached 17.83 A·mgPt^(-1) and 24.67 mA·cm^(-2).The CO_(2) selectivity of polysulfide modified product achieved 93.5%,which was 30 folds higher than Pt/*** addition,the catalyst showed high catalytic *** mechanism study demonstrates that the surface modified polysulfide could significantly boost the enrichment effect of ethanol and hydroxyl species,accelerating C–C bond cleavage and CO oxidation.

关键词： Pt CO_(2) selectivity enrichment effect ethanol oxidation reaction(EOR) electrocatalyst

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Effects of drought on non-structural carbohydrates and C,N,and P stoichiometric characteristics of Pinus yunnanensis seedlings

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Journal of Forestry Research 2024年第1期35卷 90-102页

作者： Zhijuan Zhao Lina wang Yuanxi Liu Jianli Sun Jiandong Xiao Qiong Dong Lianfang Li Wanjie Zhang Chao wang junwen Wu College of Forestry Southwest Forestry UniversityKunming 650224YunnanPeople’s Republic of China

To study non-structural carbohydrate character-istics and nutrient utilization strategies of Pinus yunnanen-sis under continuous drought conditions,2-year-old seed-lings were planted in pots with appropriate water,light and moderate and severe drought treatments[(80±5),(65±5),(50±5),and(35±5)%of field water-holding capacity].Non-structural carbohydrates,carbon(C),nitrogen(N),and phosphorus(P)concentrations were measured in each plant *** results show that:(1)With increasing drought,non-structural carbohydrates gradually increased in leaves,stems,and coarse roots,while gradually decreased in fine roots;(2)C concentrations of all were relatively stable under different stress *** utilization of each component increased under light and moderate drought conditions,while N and P utilization efficiency of each plant component decreased under severe *** was mainly restricted by N,first decreasing and then increasing with increased drought;(3)There was a correlation between the levels of non-structural carbohydrates and C,N,and P in each *** in N concentration affected the interconversion between soluble sugar and starch,which play a regulatory role in the fluctuation of the concentration of non-structural carbohydrates;and,(4)Plasticity analysis showed that *** seedlings responded to drought mainly by altering starch concentration,the ratio of soluble sugar to starch in leaves and stems,and further by alter-ing N and P utilization ***,these results suggest that the physiological activities of all organs of *** seedlings are restricted under drought and that trade-offs exist between different physiological indicators and *** findings are helpful in understanding non-structural carbohydrate and nutrient adaptation mechanisms under drought in *** seedlings.

关键词： Pinus yunnanensis seedlings Drought Non-structural carbohydrates C,N,P stoichiometric characteristics

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