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Steam reforming of acetic acid over Ni/biochar of low metal-loading:Involvement of biochar in tailoring reaction intermediates renders superior catalytic performance

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Chinese Journal of Chemical Engineering 2024年第4期68卷 241-252页

作者： Yunyu Guo Yiran Wang Shu Zhang Yi Wang Song Hu Jun Xiang walid nabgan Xun Hu School of Material Science and Engineering University of JinanJinan 250022China Joint International Research Laboratory of Biomass Energy and Materials College of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037China State Key Laboratory of Coal Combustion Huazhong University of Science and TechnologyWuhan 430074China Departament d'Enginyeria Química Universitat Rovira i VirgiliTarragona 43007Spain

Biochar is a reactive carrier as it may be partially gasified with steam in steam reforming,which could influence the formation of reaction intermediates and modify catalytic ***,the Ni/biochar as well as two comparative catalysts,Ni/Al_(2)O_(3) and Ni/SiO_(2),with low nickel loading(2%(mass))was conducted to probe involvement of the varied carriers in the steam *** results indicated that the Ni/biochar performed excellent catalytic activity than Ni/SiO_(2) and Ni/Al_(2)O_(3),as the biochar carrier facilitated quick conversion of the -OH from dissociation of steam to gasify the oxygen-rich carbonaceous intermediates like C=O and C-O-C,resulting in low coverage while high exposure of nickel species for maintaining the superior catalytic *** converse,strong adsorption of aliphatic intermediates over Ni/Al_(2)O_(3) and Ni/SiO_(2) induced serious coking with polymeric coke as the main type(21.5%and 32.1%,respectively),which was significantly higher than that over Ni/biochar(3.9%).The coke over Ni/biochar was mainly aromatic or catalytic type with nanotube morphology and high *** high resistivity of Ni/biochar towards coking was due to the balance between formation of coke and gasification of coke and partially biochar with steam,which created developed mesopores in spent Ni/biochar while the coke blocked pores in Ni/Al_(2)O_(3) and Ni/SiO_(2) catalysts.

关键词： Steam reforming Acetic acid Ni/biochar catalyst Property of coke Reaction intermediates

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Photocatalysis vs adsorption by metal oxide nanoparticles

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Journal of Materials Science & Technology 2022年第36期131卷 122-166页

作者： Usman Qumar Jahan Zeb Hassan Rukhsar Ahmad Bhatti Ali Raza Ghazanfar Nazir walid nabgan Muhammad Ikram Solar Cell Applications Research Lab Department of PhysicsGovernment College University Lahore54000 PunjabPakistan Department of Physics University of Lahore(Chenab Campus)Adjacent Chenab BridgeGujrat50700 PunjabPakistan Department of Physics University of Sialkot(USKT)1-Km Main Daska RoadSialkot51040 PunjabPakistan Department of Nanotechnology and Advanced Materials Engineering Sejong UniversitySeoul 05006Republic of Korea Departament d’Enginyeria Química Universitat Rovira i VirgiliAv Països Catalans 2643007 TarragonaSpain.

Background:Metal oxide(MO)nanomaterials and related nanocomposites have been extensively studied for their potential use in water *** of their controlled morphologies,texture qualities,variable surface chemistry,distinct crystalline nature,high stability,and tunable band edges,MO nanostructured materials are highly selective towards deleting organic contaminants and heavy metal ions via adsorption and semiconductor ***-enhanced photocatalysis has recently received increasing interest,mainly due to the ability of the metal to directly or indirectly degrade pollutants.A diverse selection of MOs,with titanium dioxide(Ti O2),zinc oxide(Zn O),iron oxides(IO),and tungsten(W),as well as graphene-MOs nanocomposites with variable structure,crystalline,and morphological properties,offers a powerful platform for the growth of effective ***:The current work discusses novel advancements and potential for the removal of adsorptive and photocatalytic degradation of organic compounds(phenolic,pesticide molecules,dyes,and so on)as well as heavy metal ions using semiconductor materials.A photocatalyst based on a MO-scheme heterostructure can manage the appropriate conduction band(CB)and valence band(VB)locations,securing considerable redox *** review should be of interest to the broad readership dealing with applied and fundamental aspects of water treatments and material *** strategies including surface modification,plasmonic enhancement,and metal cocatalysts have been introduced to enhance photocatalytic *** findings:The current article discussed the significantly utilized synthesis strategies and mechanism of heterojunction photocatalysts using a ***,adsorption sections guarantee that mercury,chromium,cadmium,arsenic,and lead-based ions are successfully removed from polluted water via the adsorption *** characteristics,such as concentration,coexisting ions,p H,and ki

关键词： Photocatalyst Adsorbate Metal Oxides Z-scheme Surface Modification Heterojunction Semiconductor heterostructures Nanoparticles

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